scholarly journals Validation Of The Cadmium Analysis Method (Cd) by Atomic Absorption Spectrophotometry in Traditional Scrub

2021 ◽  
Vol 12 (2) ◽  
pp. 311
Author(s):  
Eddy Suhardiana ◽  
Srie Rezeki Nur Endah
Keyword(s):  
Heavy Metal ◽  
Atomic Absorption ◽  
Heavy Metal Contamination ◽  
Atomic Absorption Spectrophotometry ◽  
Analysis Method ◽  
Cosmetic Products ◽  
Linear Calibration ◽  
Digestion Method ◽  
Absorption Spectrophotometry ◽  
The City

Scrub is a type of cosmetics that has been widely used for skin care. However, many women do not realize that among the cosmetic products, including the scrubs they usually use, they may contain dangerous ingredients such as heavy metals. The use of scrubs, especially traditional scrubs that contain ingredients from nature, allows heavy metal contamination. This study aims to validate the analysis method of cadmium heavy metal content in traditional scrubs in the city of Tasikmalaya. Sample preparation used the wet digestion method using HNO3: H2O2 (3: 1). Cadmium was analyzed by Atomic Absorption Spectrophotometry at a specific wavelength of 283.3 nm, respectively. After obtaining the optimum digestion process and tools, the cadmium method was validated with Atomic Absorption Spectrophotometry (AAS) which included linearity tests, detection limits, quantification limits, precision and accuracy. The results of the validation of the analysis method obtained a linear calibration curve in the concentration range of 1-8 ppm with a linear regression equation y = 0.1237x + 0.0247, the value of the correlation coefficient = 0.9982. The detection and quantitation limits were 0.63 ppm and 2.11 ppm. Intra-day and inter-day precision is SBR <2%. The retrieval or accuracy obtained is 101.64 - 105.49%. 

Relationship Between Body-Lead Concentration of Mysis relicta and Sediment-Lead Concentration in Kootenay Lake, B.C.

1983 ◽  
Vol 40 (1) ◽  
pp. 78-81 ◽  
Author(s):  
R. D. Evans ◽  
D. C. Lasenby
Keyword(s):  
Heavy Metal ◽  
Atomic Absorption ◽  
Strong Correlation ◽  
Metal Contamination ◽  
Heavy Metal Contamination ◽  
Lead Concentration ◽  
Atomic Absorption Spectrophotometry ◽  
Mysis Relicta ◽  
Absorption Spectrophotometry ◽  
Kootenay Lake

The potentially important mechanism of biological mobilization of lead from lake sediments was investigated. Lead concentrations of the crustacean Mysis relicta from Kootenay Lake, determined using atomic absorption spectrophotometry, were compared to published lead sediment concentrations from the same sites. There is a strong correlation between sediment-lead concentration and Mysis-lead concentration. This correlation may indicate that Mysis can accumulate lead from the sediment and return it to the open water.Key words: Mysis relicta, lead, heavy metal contamination, contaminated sediments.

scholarly journals Determination of Heavy Metal Contaminations of Lead and Cadmium in Selected Lipstick Products Sold in Padang City Using Atomic Absorption Spectrophotometry

2019 ◽  
Vol 2 (1) ◽  
pp. 13-18
Author(s):  
Ridho Asra ◽  
Rusdi ◽  
Robi Budi Yandra ◽  
Nessa
Keyword(s):  
Heavy Metal ◽  
Atomic Absorption ◽  
Metal Contamination ◽  
Heavy Metal Contamination ◽  
Atomic Absorption Spectrophotometry ◽  
National Agency ◽  
Absorption Spectrophotometry ◽  
Lead And Cadmium ◽  
Study Results ◽  
The Republic

The study was aimed at assessing the levels of some toxic metals of lead and cadmium in selected lipstick products sold in Padang city. Four brands of lipsticks were taken which were BL, NK, PS and WD. The lipsticks were grinded and analyzed for heavy metals (lead and cadmium) using atomic absorption spectrophotometry. Each sample was destructed by nitric acid and perchloric acid (3:1). Destructed samples were added with sodium hydroxide to liberate ammonia and filtered into a 25 mL volumetric flask. The concentrations of heavy metal were measured by using atomic absorption spectrophotometry. The results showed that lead heavy metal contamination was not detected. Whereas, the heavy metal contamination of cadmium in lipstick brands BL, NK, PS and WD were 0.2287, 0.2000, 0.1796 and 0.1220 mg/kg, respectively. The study results showed that all metal contaminations of lead and cadmium were not over the limit which were regulated by National Agency of Drug and Food Control of the Republic of Indonesia.

Analysis of Lead Heavy Metal (Pb) Contamination on Matte Lipstick Preparations for Sale in Banda Aceh City Aceh Market

2020 ◽  
Vol 2 (1) ◽  
Author(s):  
Rizki Andalia ◽  
Mulia Aria Suzanni ◽  
Rini Rini
Keyword(s):  
Heavy Metal ◽  
Atomic Absorption ◽  
Atomic Absorption Spectrophotometry ◽  
The Body ◽  
Permissible Limit ◽  
The Sun ◽  
Absorption Spectrophotometry ◽  
Pb Contamination ◽  
Body Organ ◽  
Banda Aceh

Lipstick or lip dye is a cosmetic dose that serves to coloring, decorative the lips, as a moisturizing material and protect the lips from exposure the sun to provide optimum results. Lipstick should not contain chemicals such as lead (Pb) because the Pb is a heavy metal that is very dangerous when continuously used on the skin, because it will be absorbed into the blood and attack the body organ causing the onset of disease. According to BPOM that the lead rate on the lipstick does not exceed the permissible limit of 20 mg/kg or 20 ppm.This research aims to know the levels contained in the samples are 4 brands of matte lipstick that are sold in the Aceh market in Banda Aceh City with the method of atomic absorption spectrophotometry (AAS). The results showed that on the 4 brands of lipstick matte contain heavy metal lead (Pb) with a rate still qualified allowed by BPOM  is samples A, B, C, and D, respectively at 0.24 ppm; 0.10 ppm; 2.87 ppm and 1.32 ppm, so that the 4 brands of lipstick matte are still used.

scholarly journals Kandungan Logam Berat Besi (Fe) Pada Air, Sedimen, Dan Kerang Hijau (Perna viridis) Di Perairan Tanjung Emas Semarang

2015 ◽  
Vol 18 (1) ◽  
Author(s):  
Endang Supriyantini ◽  
Hadi Endrawati
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Flow Velocity ◽  
Atomic Absorption ◽  
Key Words ◽  
Atomic Absorption Spectrophotometry ◽  
Pollution Level ◽  
Perna Viridis ◽  
Absorption Spectrophotometry ◽  
Living Organisms

Logam berat Fe merupakan logam berat essensial yang keberadaannya dalam jumlah tertentu sangat dibutuhkan oleh organisme hidup, namun dalam jumlah yang berlebih dapat menimbulkan efek racun.Penelitian ini bertujuan untuk menganalisis kandungan dan tingkat pencemaran logam berat Fe pada air, sedimen, dan kerang hijau (Perna viridis) di perairan Tanjung Emas Semarang. Penelitian ini dilaksanakan pada tanggal 7 November dan 7 Desember 2013 dengan metode penelitian deskriptif. Logam berat Fe dalam sampel air, sedimen dan kerang hijau dianalisis di Laboratorium Balai Besar Teknologi Pencegahan Pencemaran Industri (BTPPI) Semarang dengan menggunakan metode AAS (AtomicAbsorption Spectrophotometry). Hasil penelitian menunjukkan bahwa perairan Tanjung Emas masih dalam taraf terkontaminasi logam Fe. Sedangkan pada sedimen dan pada kerang hijau (Perna viridis) sudah terindikasi tercemar logam Fe.Meskipun demikian variasi faktor lingkungan seperti suhu, salinitas, pH, kecepatan arus dan jenis sedimen juga memberikan kontribusi yang cukup penting terhadap kandungan logam Fe.Kata Kunci: logam Fe, Air, Sedimen, Perna viridis, metode AAS Heavy metalsiron(Fe) is anessentialheavy metalswhose presencein a certain amountis neededby living organisms, but inexcessiveamountscan causetoxic effects.The aims of the research is to analyze the heavy metals coccentration and the pollution level of Fe in water, sediment, and green mussels (Perna viridis) at Tanjung Emas Semarang. This research was conducted from 7 November and 7 December 2013 using the Atomic Absorption Spectrophotometry (AAS) and research methodswithdescriptive. The results showed that the waters of the Tanjung Emas is still in the stage of heavy metals contaminated iron (Fe). Sediment and green mussels (Perna viridis)already indicated heavy metal contaminatediron. However, variations inenvironmental factorssuch astemperature, salinity, pH, flow velocity an dsediment types also providean important contributionto heavy metal contentof iron(Fe).Key Words: Fe, water, sediment, Perna viridis, metode AAS

scholarly journals GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROPHOTOMETRY SEBAGAI METODE ANALISIS LOGAM BERAT

OSEANA ◽  
2017 ◽  
Vol 42 (3) ◽  
pp. 9-20
Author(s):  
Fitri Budiyanto
Keyword(s):  
Heavy Metal ◽  
Atomic Absorption ◽  
Light Emission ◽  
Graphite Furnace ◽  
Atomic Absorption Spectrophotometry ◽  
Trace Level ◽  
Absorption Spectrophotometry ◽  
Graphite Furnace Atomic Absorption ◽  
Ultra Trace ◽  
Hazardous Pollutants

GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROPHOTOMETRY AS A METHOD FOR ANALYZING HEAVY METAL. Heavy metal, mostly present in a (ultra) trace-level, becomes one of the hazardous pollutants due to its toxicity, bioaccumulative, biomagnification characters. Conducting a micro analysis of these trace-level pollutants, a sensitive instrument and method are strongly recommended. Graphite Furnace Atomic Absorption Spectrophotometer (GFAAS) offers a solution for the challenge. It uses the principle of light emission absorption by nascent atom cloud from the metals. The analysis has been developed in three stages of the tube heating programs, i.e. drying, ashing and then atomizing element at 3000° C. Since the injected sample is almost completely atomized, the sensitivity of GFAAS is extremely high and this value is covering up the disadvantages of the other analyses. Therefore, the GFAAS analysis is suitable fo ultra-trace analysis of ultra-trace pollutants like heavy metals in environment.

scholarly journals Heavy Metal Concentration in Eight Fish Species from Epe Lagoon (Nigeria)

2019 ◽  
Vol 21 (1) ◽  
pp. 69-82
Author(s):  
Iyabode Olusola Taiwo ◽  
Olaniyi Alaba Olopade ◽  
Nathanael Akinsafe Bamidele
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Atomic Absorption ◽  
Metal Concentration ◽  
Fish Species ◽  
Heavy Metal Concentration ◽  
Atomic Absorption Spectrophotometry ◽  
Human Consumption ◽  
Heavy Metal Concentrations ◽  
Absorption Spectrophotometry

Abstract This research was undertaken to find out the levels of five heavy metals (Cu, Fe, Mn, Pb, and Zn) in the muscles of eight fish species from Epe Lagoon. The levels of heavy metals were determined by atomic absorption spectrophotometry after digestion of the samples using Kjldahl heating digester. The heavy metal concentrations among the fish species were statistically dissimilar (P < 0.5). The heavy metals of Pb, Fe, and Mn were above the FAO/WHO agreeable limits for human consumption.

scholarly journals THE EFFECT OF TEMPERATURE AND TIME ON THE MIGRATION OF LEAD METAL (PB) IONS IN CANNED ORANGE JUICE DRINK USING ATOMIC ABSORPTION SPECTROPHOTOMETRY ANALYSIS

2021 ◽  
Vol 18 (38) ◽  
pp. 164-175
Author(s):  
Kiagus Ahmad RONI ◽  
Elfidiah ELFIDIAH ◽  
Ryan PASONGKO ◽  
Dian KHARISMA ◽  
Sri MARTINI
Keyword(s):  
Heavy Metal ◽  
Atomic Absorption ◽  
Orange Juice ◽  
Storage Time ◽  
Open Space ◽  
Fruit Juice ◽  
Atomic Absorption Spectrophotometry ◽  
Absorption Spectrophotometry ◽  
Refrigerator Temperature ◽  
Canned Fruit

Background: Indonesia is a country that has a tropical climate throughout the year along with relatively less difference of temperature during both dry and rainy seasons. The mobile community influences people’s interest in packaged drinks, including canned fruit juice. However, the first obstacle is the condition of the place and the temperature-related heavy metal lead (Pb) migration in canned orange juice drinks. Methods: This study focused on the relationship between Pb metal content, storage treatment, storage temperature, and storage time. This study used a canned orange juice drink from the distributor warehouse of Palembang city, standard Pb(NO3)2 (Merck) powder, 0.5 mol/l concentrated HNO3 solutions (Merck), concentrated HCl solution (Merck), demineralized water, Buffer pH 4.7, and 10. The sample was conducted from 5 °C to 40 °C with the testing period within 1-30 days. The sample at certain day intervals would then be tested to change pH and Pb ion concentration using the Atomic Absorption Spectrophotometry (AAS) test. Results and Discussion: In this study, the sample of orange juice was given different treatments, and each treatment has a differentiated analysis code consisting of S-SBJ-1-1 (Distributor warehouse) for one day of storage time, and the codes for 10 of storage time are SSBJ-10-1 (Freezer, temperature 5 °C), S-SJB-10-2 (Refrigerator, temperature 20 °C), S-SJB-10-3 (Homeroom, temperature 28 °C), S-SJB-10-4 (Oven, temperature 40 °C), S-SJB-10-5 (Open space, temperature 22°C - 38 °C). Furthermore, codes for 30 days of sample storage are S-SBJ-30-1 (Freezer, temperature 5 °C), S-SJB-30-2 (Refrigerator, temperature 20 °C), S-SJB-30-3 (Room house, temperature 28 °C, S-SJB-30-4 (Oven, temperature 40°C), and S-SJB-30-5 (Open space, temperature 22 °C-38 °C). Conclusions: Temperature and time have a significant influence on the migration of the heavy metal lead (Pb) from the can to orange juice drinks, and, for the minimum pH value, there is a less significant change. Overall, canned fruit juice should be stored at a temperature below 28 °C, and the drink is protected from direct sunlight and high humidity.

scholarly journals Use of Microwave Digestion and Atomic Absorption Spectrophotometry To Determine Chromic Oxide as a Digestibility Marker in Feed, Feces, and Ileal Content

1999 ◽  
Vol 82 (3) ◽  
pp. 575-578 ◽  
Author(s):  
Leticia García-Rico ◽  
Rita E Ramos Ruiz ◽  
Lourdes Gutiérrez Coronado
Keyword(s):  
Atomic Absorption ◽  
Microwave Digestion ◽  
Atomic Absorption Spectrophotometry ◽  
Chromium Concentration ◽  
Heating Cycle ◽  
Digestion Method ◽  
Absorption Spectrophotometry ◽  
Flame Atomic Absorption ◽  
Dry Ashing ◽  
Wet Ashing

Abstract Most conventional digestion procedures, such as dry ashing and wet ashing, are tedious and labor intensive. Microwave digestion is agood alternative, because microwave dissolution is faster, safer, and simpler, and provides more controlled reproducible conditions than conventional methods. The purpose of this study was to develop a microwave digestion method for mineralizing meat and bone meal diets, feces, and ileal contents. Each sample was heated on a hot plate for 10 min, dry ashed at 65°C for 4 h, and transferred into microwave vessels. Then, 10 mL 70% HNO3 was added. Samples were digested for 7,10, and 20 min at 95,90, and 85% power, respectively. After the heating cycle, 6 mL 30% H2O2 was added, and samples were returned to the microwave for a second heating cycle of 1 and 7 min at 95 and 90% power, respectively. Finally, chromium concentration was determined by flame atomic absorption spectrophotometry. The digestion method was validated by using a standard reference material, SRM domestic sludge 2781, with a certified chromium value of 195 ± 9 μg/g. The value obtained in this study was 178 ± 11 μg/g, for a difference of 17 μg/g. Spike recovery experiments resulted in 103.16 and 100.35% recoveries of chromium from diet and feces samples, respectively. Coefficients of variation were 10.8 and 7.8%, respectively.

scholarly journals VALIDATION OF LEAD (Pb) ANALYSIS METHOD IN FISH MEAL MATRIX BY ELECTROTHERMAL ATOMIC ABSORPTION SPECTROPHOTOMETRY

2021 ◽  
Vol 5 (5) ◽  
pp. 8-16
Author(s):  
Suwari ◽  
Sherlly M.F. Ledoh ◽  
Philiphi de Rozari
Keyword(s):  
Atomic Absorption ◽  
Fish Meal ◽  
Atomic Absorption Spectrophotometry ◽  
Test Method ◽  
Performance Parameters ◽  
Analysis Method ◽  
Validation Process ◽  
Absorption Spectrophotometry ◽  
Accuracy And Precision ◽  
Lamp Current

ABSTRACT Validation of analytical methods is the process of proving that the methods used are scientifically good and suitable for certain purposes. The aim of this study was to validate the analytical method of lead in fish meal matrix by electrothermal atomic absorption spectroscopy (ETAAS) using a phosphate modifier. The research begins with optimization of the analytical conditions that include pyrolysis (ashing) and atomizing temperature, and continues with the validation process by evaluating the analytical performance parameters using a certified reference material (CRM). Method validation was carried out by determining the level of accuracy and precision as well as lead content in a CRM Cod Muscle-422 from BCR. Each experiment was conducted at a wavelength of 283.3 nm, a lamp current of 9.0 amperes, a slit width of 1.3 nm and an argon carrier gas. The optimal pyrolysis and atomizing temperature of lead obtained by adding phosphate modifier was 650 oC and 2000 oC, respectively. The results obtained in this study indicate that the ETAAS lead analysis method using a phosphate modifier is feasible as a test method with an RSD of 3.79%, precision of 0.0043, relative error of 4.0%, accuracy of 104% and recovery of 98% ± 3%. The results of the validation method obtained that the 95% confidence interval for Pb content was 0.088 ± 0.023 µg/g, still within the range of Pb levels in the certificate, namely 0.085 ± 0.015 µg/g of Pb. Keywords: Validation, CRM, Cod Muscle, ETAAS, Lead

scholarly journals Kandungan Logam Berat Timbal (Pb) Pada Air, Sedimen, Dan Rumput Laut Sargassum sp. Di Perairan Teluk Awur, Jepara

2018 ◽  
Vol 21 (2) ◽  
pp. 155 ◽  
Author(s):  
Rotua Malau ◽  
Ria Azizah ◽  
AB Susanto ◽  
Gunawan Widi Santosa ◽  
Irwani Irwani
Keyword(s):  
Heavy Metal ◽  
Atomic Absorption ◽  
Human Activities ◽  
Sampling Method ◽  
Quality Standard ◽  
Atomic Absorption Spectrophotometry ◽  
Lead Content ◽  
Purposive Sampling ◽  
Absorption Spectrophotometry ◽  
The Status

Concentration of the Heavy Metal Lead (Pb) in the Seawater, Sediment, and the Seaweed Sargassum sp. in Teluk Awur, Jepara The increasing human activities led to an increase in waste disposal which eventually accumulates and decrease the water quality of rivers and seas. One of the pollutant resulted by human activities is heavy metal. The presence of heavy metals in the waters could directly harm the bioorganisms and indirectly affect human health by food chains. The purpose of this research is to investigate the lead content (Pb) in the water, sediment, and seaweed Sargassum sp., as well as to determine the status of pollution in Teluk Awur waters, Jepara. The research was conducted in November 2017 and January 2018 using descriptive method. Sampling sites were decided by Purposive Sampling Method. Analysis of lead content was conducted using AAS (Atomic Absorption Spectrophotometry). The results showed that the lead content of seawater in Teluk Awur, Jepara, was within 0.003 mg/L and not on the level of concern, according to KepMen LH No. 51/2004. The range of lead content in the sediment was 47- 68,35 mg/kg and considered as polluted, according to NRCC GBW07313. The range of lead content in the seaweed Sargassum sp. was 0.22-0.79 mg/kg and has exceeded the quality standard  specified by PerBPOM No. 23/2017. Meningkatnya  kegiatan  manusia  menyebabkan  peningkatan  pembuangan  limbah  yang pada akhirnya bermuara ke sungai maupun laut, yang mengakibatkan perairan laut menjadi tercemar. Salah satu pencemar akibat aktivitas   manusia   adalah   logam   berat   timbal yang dapat membahayakan kehidupan organisme perairan secara langsung, maupun tidak langsung terhadap kesehatan manusia. Tujuan penelitian ini adalah untuk mengetahui kandungan logam berat Pb pada air, sedimen, dan rumput laut Sargassum sp. serta untuk mengetahui status pencemaran di Perairan Teluk Awur, Jepara. Penelitian dilakukan pada bulan November 2017 dan Januari 2018. Metode penelitian yang digunakan  adalah  metode  deskriptif.  Penentuan  lokasi  penelitian  dilakukan dengan Purposive Sampling Method. Analisis logam berat Pb dilakukan dengan menggunakan AAS (Atomic Absorption Spectrophotometry). Hasil penelitian menunjukan kandungan logam berat Pb di Perairan Teluk Awur, Jepara, pada air laut yaitu 0,003 mg/L dan masih belum tercemar menurut KepMen LH No.51/2004. Kandungan logam berat Pb pada sedimen yaitu berkisar 47 - 68,35 mg/kg dan telah tercemar menurut NRCC GBW07313. Kandungan logam berat Pb pada rumput laut Sargassum sp. yaitu berkisar 0,22 - 0,79 mg/kg dan telah melebihi baku mutu yang ditentukan oleh PerBPOM No. 23 Tahun 2017 

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