scholarly journals The Role of Manganese as a Controller for Gold Mineralization

2019 ◽  
Author(s):  
Ricardo A. Valls ◽  
Jorge Cruz Martín

The San José de Las Malezas quartz-gold deposit is located on the North side of the Cuban Ophiolitic Complex, within the Structural-Facial Zone "Zaza", Province of Villa Clara, Cuba. In the area of the deposit there is a well developed listwanite zone that begins with (i) massive and relatively little altered serpentinites that pass into (ii) iron-altered serpentinites which are in gradational contact with (iii) completely carbonatized rocks and (iv) a core of silicified rocks and quartz veins. Copper and gold mineralization are associated with these quartz bodies, but binary correlation analysis of geochemical data suggests that the ores are genetically independent of one another. In concordance with the proposed genetic model supported by thermodynamic calculations and field observations, copper is thought to be introduced by a hydrothermal process, whereas gold was leached from the serpentinites. The evolution of manganese minerals from anaerobic to aerobic species provoked a reducing environment which difficulted the precipitation of gold and other ores inside and near the serpentinites. Accordingly, a significant negative correlation between gold and manganese in similar areas of hydrothermally altered serpentinites, may be good indicators of possible gold concentrations. The mechanical transportation of very small and thin scales of native gold from the serpentinites by the fluids is also suggested as a possible mechanism to explain the presence of this kind of scales inside the iron-altered zone.

2021 ◽  
Author(s):  
Gao-Hua Fan ◽  
Jian-Wei Li ◽  
Xiao-Dong Deng ◽  
Wen-Sheng Gao ◽  
Si-Yuan Li

Abstract Dongping is the largest Au-Te vein deposit (~120 t Au) in the North China craton, but its age, origin, and setting remain unsolved. Here, we integrate paragenesis, geochemistry, and in situ U-Pb geochronology of garnet to constrain the timing and possible origin of the Dongping Au-Te deposit. Gold mineralization at Dongping is hosted in the Shuiquangou alkaline complex (ca. 401–390 Ma) and dominated by quartz-sulfide veins with minor ores in adjacent alteration envelopes. Andradite to grossular garnets are recognized in pre-, syn-, and post-ore quartz veins as well as mineralized alteration envelopes and are closely associated with a variety of ore and gangue minerals, mainly including K-feldspar, quartz, specularite, magnetite, pyrite, tellurides, epidote, and calcite. The paragenetic, textural, fluid inclusion, and compositional data suggest that garnets precipitated directly from a low-salinity fluid at 302° to 383°C and 90 to 330 bar. Garnets from various veins and alteration envelopes have similar U contents ranging from 0.80 to 13.89 mg/kg and yield reproducible U-Pb dates of 142 ± 5 to 139 ± 6 Ma (1σ) by laser ablation-inductively coupled plasmamass spectrometry. The dating results suggest that gold mineralization at Dongping occurred in the Early Cretaceous and thus preclude a genetic link between Au-Te mineralization and the ore-hosting alkaline intrusion as commonly suggested. When combined with independent geologic, geochemical, and geochronological studies, the new garnet U-Pb dates allow us to classify the Dongping Au-Te deposit as an oxidized intrusion-related gold deposit, with the causative magma likely derived from melting of an ancient enriched lithospheric mantle source due to destruction of the subcontinental lithospheric keel beneath the North China craton—a catastrophic event induced by the westward subduction of the Paleo-Pacific plate. This study highlights garnet U-Pb dating as a potential robust geochronometer for gold vein deposits elsewhere.


2016 ◽  
Vol 1 (2) ◽  
pp. 63 ◽  
Author(s):  
Arifudin Idrus ◽  
Suaib Mansur ◽  
Ahmad Ahmad ◽  
Rahmayuddin Rahmayuddin ◽  
Abdul Abdul

This study is aimed to identify the occurences, characterisatics and genetic type of gold mineralization, and to elucidate the preliminary gold potential in the study area. Research method includes field observation of prospect geology, hydrothermal alteration and ore mineralization. Laboratory analysis consists of petrography, ore microscopy and ore chemistry. Geologically, quartz ± gold veins were found in Rampi block prospect, which are mainly hosted by metamorphic and metasediment rocks. The quartz veins has structurally segmented with massive, brecciated and laminated textures. Orientation and distribution of veins is controlled by NW–SE and NE–SW trending structures. Sulfides are present with minor abundance (<1 %). Pyrite is obviously observed and partially oxidized. Arsenopyrite and stibnite are minor, while basemetal (Pb, Zn) sulfides are very rare. Gold mineralization occurred in quartz veins and closely related to silica-clay and silicic alteration. Gold grade varies from 0.1 to 11 ppm Au (29 samples). Quartz veins contained high gold grade (>9 ppm) commonly show laminated and brecciated texture and has been undergone a supergene enrichment. According to several characteristics above, gold deposit in Rampi block prospect tends to meet the criteria of orogenic/mesothermal gold type (cf. Groves et al., 2003). The deposit shares similarities with Awak Mas prospect, which is already confirmed to be a mesothermal type in Luwu district (cf. Querubin and Walters, 2011). Therefore, discoveries of economic mesothermal gold deposits are still open in the metamorphic terrains, and thus, it requires a systematic exploration based on the genetic model of the deposit.


2014 ◽  
Vol 962-965 ◽  
pp. 277-281
Author(s):  
Cheng Long Shi ◽  
Yang Song ◽  
Jian Zhong Hu

The Huajian gold deposit is located in the metallogenic belt of the northern part of the North China block. This deposit's ore bodies are mainly hosted in metamorphosed Neoarchean and Mesoproterozoic sedimentary rocks, of which Mesozoic volcano-intrusive complexes are closely associated with the Gold mineralization. The FIs of the Huajian deposit are primarily aqueous FIs with minor gas FIs. The pure gas or liquid FIs are very few. The ore-forming fluids were characterised by moderate–low temperature, low salinity and high oxygen fugacity and belonged to an H2O–NaCl ± CO2system. The FIs in quartz veins primarily developed in temperature intervals of 202–380°C, 191–407°C and 170–307°C., corresponding to salinities of 3.85wt.% to 11.23 wt.%, 3.69wt.% to 10.99 wt.% and 2.06wt.% to 17 wt.% NaCl eq.., respectively. The trapping pressures of the FIs from high temperature fluids in the quartz veins are 10-90 MPa, corresponding to depths of 1.0–10 km, assuming a density of the overlying rocks of 0.54 g/cm3–0.98 g/cm3. Multiple stages of phase separation or immiscibility of ore-forming fluid was critical for the formation of the Huajian deposit.


Author(s):  
Xiang Ge ◽  
Chuanbo Shen ◽  
Renjie Zhou ◽  
Peng He ◽  
Jianxin Zhao ◽  
...  

Fluid migration in sedimentary basins enable mass and energy transport and play critical roles in geochemical and geodynamical evolution of sedimentary basins. Moreover, reconstructing sedimentary basin fluid evolution from the geological record aids in constraining the evolution of associated petroleum and mineralization systems. As a relict of fluid flow activity, calcite is often a record of fluid flow and therefore can be used to characterize the fluids responsible for its precipitation. Here we study the Nanpanjiang Basin in South China where petroleum reservoirs and Carlin-type gold deposits spatially coincide. Through in situ U-Pb dating and geochemical analysis (87Sr/86Sr, δ18OVienna standard mean ocean water, δ13CVienna Peedee belemnite, rare earth elements) of calcite, this work constrains the key times related to petroleum migration/accumulation and Carlin-type gold mineralization, defines the basin fluid evolution, and proposes a genetic model for petroleum accumulation and gold mineralization within the Nanpanjiang Basin. The U-Pb age (ca. 241.4 Ma) for the gray/black calcite related to bitumen indicates the petroleum migration/accumulation occurred during the Triassic. The U-Pb date (ca. 106−121 Ma) of the white calcite associated with the gold-bearing pyrite, realgar, and fluorite record the lower timing limit of the Carlin-type gold systems. The geochemical data suggest both calcite types are cogenetic but suffered complex evolution with the gray/black calcite precipitating under low temperatures related to the continuous basin burial and the white calcite affected by post formation alteration related to both hydrothermal and meteoric fluids. Combined with the regional tectonic history, the Early Triassic petroleum migration/accumulation and the Early Cretaceous secondary Carlin-type gold mineralization events are considered to be related to the collision between the Indo-China and South China blocks, and the subduction between the Paleo-Pacific and Eurasian plates, respectively.


2019 ◽  
Vol 114 (5) ◽  
pp. 897-915 ◽  
Author(s):  
Degao Zhai ◽  
Anthony E. Williams-Jones ◽  
Jiajun Liu ◽  
David Selby ◽  
Chao Li ◽  
...  

Abstract The Haigou lode gold deposit (>40 tons [t] at 3.4 g/t), which is located near the eastern boundary of the Central Asian orogenic belt and the North China craton, is one of the largest gold deposits in northeastern China. Native gold is intergrown with molybdenite and pyrite in auriferous quartz veins hosted by a monzogranite-monzonite stock and locally by Proterozoic gneiss, thereby offering an excellent opportunity to directly date the mineralizing event. Uranium-Pb age determinations for zircon yielded ages for the monzogranite and monzonite of 327.1 ± 1.1 and 329.5 ± 1.0 Ma, respectively. Numerous mafic to felsic dikes, which are crosscut by ore veins (pre-ore), parallel to these veins (possibly synore), or crosscut by them (post-ore), were carefully examined and dated. Their zircon 206Pb/238U ages are 318.3 ± 1.0, 310.9 ± 1.1, and 134.9 ± 0.4 Ma, respectively, thereby placing the timing of gold mineralization within the relatively large interval of 318.3 ± 1.0 to 134.9 ± 0.4 Ma. The age of mineralization was determined directly using the Re-Os method applied to molybdenite. A total of 19 molybdenite samples separated from auriferous quartz veins yielded widely differing Re-Os model ages of 467 to 155 Ma, and replicate analyses of individual samples also yielded widely differing ages. Significantly, the wide range is attributable entirely to the results obtained for some coarse-grained molybdenite samples and is interpreted to be due to Re and Os isotope decoupling, the considerable spatial Re heterogeneity, the analytical procedure (e.g., use of small sample aliquots), and the post-ore deformation. Nine of the samples, which are all fine grained, yielded a robust weighted mean model age of 310 ± 3 Ma and an isochron age of 309 ± 8 Ma. Thus, the molybdenite Re-Os ages are identical, within uncertainty, to those of the dikes that are parallel to the ore veins, indicating that these dikes were emplaced contemporaneously with the ore and that they and the Haigou gold mineralization are of late Paleozoic age (ca. 310 Ma). Finally, a sericite sample obtained from an auriferous vein returned a 40Ar/39Ar plateau age of 165.3 ± 1.2 Ma, which is much younger than the age of the mineralization constrained by Re-Os age determinations of molybdenite. This indicates that the 40Ar/39Ar isotope system was reset by post-ore thermal events. Our new geochronological data provide evidence for late Paleozoic gold mineralization in Haigou, which makes it the oldest known lode gold deposit in the easternmost Central Asian orogenic belt, a finding that has important implications for precious metal mineral exploration in the eastern part of the Solonker-Xar Moron-Changchun-Yanji suture zone between the Central Asian orogenic belt and the North China craton. This study also indicates that accurate and reproducible molybdenite Re-Os ages representing the true timing of ore deposition need an integrated combination of careful petrography, proper sampling procedures, sufficiently large analyzed aliquots, multiple analyses of individual samples, and multiple dating methods.


Minerals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 250
Author(s):  
Chuanpeng Liu ◽  
Wenjie Shi ◽  
Junhao Wei ◽  
Huan Li ◽  
Aiping Feng ◽  
...  

The Longquanzhan deposit is one of the largest gold deposits in the Yi-Shu fault zone (central section of the Tan-Lu fault zone) in Shandong Province, China. It is an altered-rock type gold deposit in which ore bodies mainly occur at the contact zone between the overlying Cretaceous rocks and the underlying Neoarchean gneissic monzogranite. Shi et al. reported that this deposit formed at 96 ± 2 Ma using pyrite Rb–Sr dating method and represents a new gold mineralization event in the Shandong Province in 2014. In this paper, we present new He–Ar–S isotopic compositions to further decipher the sources of fluids responsible for the Longquanzhan gold mineralization. The results show that the δ34S values of pyrites vary between 0.9‰ and 4.4‰ with an average of 2.3‰. Inclusion-trapped fluids in ore sulfides have 3He/4He and 40Ar/36Ar ratios of 0.14–0.78 Ra and 482–1811, respectively. These isotopic data indicate that the ore fluids are derived from a magmatic source, which is dominated by crustal components with minor mantle contribution. Air-saturated water may be also involved in the hydrothermal system during the magmatic fluids ascending or at the shallow deposit site. We suggest that the crust-mantle mixing signature of the Longquanzhan gold deposit is genetically related to the Late Cretaceous lithospheric thinning along the Tan-Lu fault zone, which triggers constantly uplifting of the asthenosphere surface and persistent ascending of the isotherm plane to form the gold mineralization-related crustal level magma sources. This genetic model can be applied, to some extent, to explain the ore genesis of other deposits near or within the Tan-Lu fault belt.


1996 ◽  
Vol 60 (399) ◽  
pp. 317-324 ◽  
Author(s):  
R. A. Ixer ◽  
B. Young ◽  
C. J. Stanley

AbstractBismuthinite-bearing quartz veins from the Alston Block of the North Pennine Orefield are all close to, or above, the Rookhope and Tynehead cupolas of the buried Weardale Granite. They are uniform in composition and paragenesis and are earlier than the main fluorite-baryte-galena-sphalerite mineralization of the orefield. Rhythmical crystallization of quartz, chalcopyrite and minor pyrite is followed by fluorite-quartz-chalcopyrite-minor sphalerite-altered pyrrhotite mineralization. Early tin-bearing (up to 0.29 wt.% Sn) chalcopyrite encloses trace amounts of bismuthinite (Bi2S3), synchysite (CaREE(CO3)F2), argentopentlandite (Ag(FeNi)8S8) (close to being stoichiometric), pyrrhotite, cubanite and cosalite (Pb2Bi2S5), while early pyrite carries monoclinic pyrrhotite (close to Fe7S8) and tungsten-bearing cassiterite (up to 1.03 wt.% WO3). Bismuthinite is macroscopically visible and is associated with native bismuth and small, fine-grained, spherical aggregates that qualitative analysis suggests may be cosalite crystals. Synchysite and more rarely monazite, xenotime and adularia are intergrown with bismuthinite. These mineralogical data form part of the basis for an increasing awareness of the contribution of the Weardale Granite to the early phases of mineralization in the Alston Block.


2016 ◽  
Vol 72 ◽  
pp. 510-531 ◽  
Author(s):  
Milton J. Morales ◽  
Rosaline C. Figueiredo e Silva ◽  
Lydia M. Lobato ◽  
Sylvio D. Gomes ◽  
Caio C.C.O. Gomes ◽  
...  

2021 ◽  
Author(s):  
Cemil Arkula ◽  
Nalan Lom ◽  
John Wakabayashi ◽  
Grant Rea-Downing ◽  
Mark Dekkers ◽  
...  

&lt;p&gt;The western edge of the North America plate contains geological records that formed during the long-lived convergence between plates of the Panthalassa Ocean and North America. The geology of different segments along western North America indicates different polarities (eastward and westward) for subducted slabs and thereby various tectonic histories and settings. The western United States (together with Mexico) plays a key role in this debate, many geologic interpretations assume continuous eastward subduction in contrast to observations within proximal geologic segments and tomographic images of the lower mantle below North America and the eastern Pacific Ocean which suggest a more complex subduction history. In this study, we aim to evaluate the plate tectonic setting in which the Jurassic ophiolites of California formed. Geochemical data from these ophiolites suggest that they formed above a nascent intra-oceanic or continental margin subduction zone. We first developed a kinematic reconstruction of the western US geology back to the Jurassic based on published structural geological data. Importantly, we update the reconstruction of the various branches of the San Andreas fault system to determine the relative position of the ophiolite fragments and adopt a previous restoration of Basin and Range extension which we expand northward towards Washington state. We then reconstruct North American margin deformation associated with Cretaceous to Paleogene shortening and strike-slip faulting. We find no clear candidates in the geological record that may have accommodated major subduction between the Jurassic ophiolite belt and the North American margin and consequently concur with the school of thought that considers that the ophiolite belt, as well as the underlying subduction-accretionary Franciscan Complex, likely formed in the North American fore-arc. We collected paleomagnetic data to reconstruct the spreading direction of the Jurassic Californian ophiolites, by providing new paleomagnetic data from sheeted dykes of the Josephine and Mt. Diablo Ophiolites. These suggest a NE-SW paleo-ridge orientation, oblique to the North American margin which may be explained by partitioning of a dextral component of subduction obliquity relative to North America. We used this spreading direction in combination with published ages of the ophiolites and our restoration of the relative position of these ophiolites prior to post-Jurassic deformation to construct a ridge-transform system at which the Jurassic ophiolites accreted. The results will be used to evaluate which parts of the subduction systems that existed in the eastern Panthalassa Ocean may reside in the western US, and which parts may be better sought in the northern Canadian Segment or/and in the southern Caribbean region.&lt;/p&gt;


1980 ◽  
Vol 70 (6) ◽  
pp. 2221-2228
Author(s):  
C. E. Mortensen ◽  
E. Y. Iwatsubo

abstract A tilt anomaly preceded a pair of earthquakes (ML = 4.2, origin time 0014 UTC, and ML = 3.9, origin time 0018 UTC, both on 29 August 1978) on the Calaveras Fault near San Jose, California. These earthquakes occurred at hypocentral depths of 8.5 and 9.0 km, respectively, and were located 6.7 and 5.2 km northwest of the Mt. Hamilton tiltmeter site. The anomaly is similar in shape and time scale to signals observed on other tiltmeters at the times of recorded surface creep events. The anomaly began approximately 40 hr before the earthquake pair and consisted of gradual down-to-the-east tilting followed by rapid tilting down-to-the-north-northeast at a rate of 12 μrad/hr. This was followed by 1 hr of rapid down-to-the-east tilting amounting to 1.5 μrad. The maximum peak tilt of 10.6 μrad down-to-the-northeast was followed by gradual decelerating tilting down-to-the-southwest constituting partial recovery. An anomaly of nearly identical form, but smaller in amplitude and duration, preceded an ML = 2.2 aftershock on 5 September 1978. Other nearby earthquakes as large as ML = 4.7 have occurred without accompanying creep-like signals. A similar, but a much smaller (0.74 μrad) creep-event-like signal preceded an ML = 3.5 earthquake with epicenter 3 km east of the Black Mountain tiltmeter site. In general, however, short-term tilt anomalies such as these are not observed to precede local earthquakes within the central California tiltmeter network. The tilt signal preceding the 29 August earthquake pair may be interpreted in terms of a model of a propagating creep event, at depth, associated with seismic failure at a “stuck” patch on the fault. However, the data are not adequate to constrain the model sufficiently to constitute a test of the hypothesis.


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