UPPER CATCHMENT OF BRIBIN UNDERGROUND RIVER HYDROGEOCHEMISTRY (GUNUNG SEWU KARST, GUNUNG KIDUL, JAVA, INDONESIA)
This research was conducted within Bribin underground river, the primary river in the Gunung Sewu karst area, Gunung Kidul, Java, Indonesia. The main purpose of this study is to describe hydrogeochemical processes that occur at the upstream of Bribin River. In addition, this study also differentiates hydrogeochemical dominant processes, which come about in rainy season and dry season. Study area boundary is the upper rainfall catchment of Bribin River that is focused on three locations: Pentung River (surface), Luweng Jomblangan, and Gilap Cave. Discharge measurements for one yearperiod are conducted to define discharge hydrograph. Furthermore, baseflow separation analysis is conducted to determine the percentage of base flow (PAD) throughout the year. Water sampling for hydrogeochemical analysis is taken everymonth to represent dry season and rainy season condition. To describe the hydrogeochemical processes, scatter plot analysis with small sample size is conducted. The result shows that within dry season, dominant hydrogeochemical process is water rock interaction that indicates by: achieving maximum level of Ca2+-HCO3- ; strong relationship between discharge increment and PAD reduction; strong relationship between increasing of Ca2+-HCO3- and increasing of PAD. In addition,strong relationship between the increase in Ca2+-HCO3- and reduction of carbondioxide in water as well as minimum level of carbondioxide gas in water at the peak of dry season, is also present. In rainy season, hydrogeochemical process shifted from water-rock interaction to dilution by precipitation as a result of rain water supply through conduit system channel,which is characterized by: declining in Ca2+-HCO3- when discharge increase; increasing Ca2+-HCO3- when discharge decrease; low correlation of spesific conductivity vs Ca2+-HCO3 -; low correlation of PAD vs Ca2+-HCO3 - when discharge increase, strong correlation between declining in PAD by increasing of CO2 in the water, and rising of CO2 when discharge increase.