Spraying Coatings by Supersonic Metallization

Author(s):  
I. Karp ◽  
A. Rudoy

Abstract A technology and a specialized equipment complex based on supersonic arc spraying gun, where a supersonic stream of combustion products of hydrocarbon-gas (HC-gas) with air is used as an atomizing gas, have been developed. Durable and safe work of coated parts functioning under conditions of intensive loading is determined (except general requirement to coatings: wear resistance, hardness) to a large extent by the fatigue strength, porosity and stability of the properties of coatings. New possibilities for satisfying all the requirement to coatings on parts type are opened up by a high speed spraying of wire. This is provided at the expanse of raising the kinetic energy of particles under spray, increase of their concentration in metal stream, lowering of the spread of parameters in the vicinity of a substrate. This, in its turn, determines the increase of adhesive and cohesive strength of coating, the decrease of oxidation, the improvement of stability and reproducibility of its properties. The results of the investigations of the influence of the variable parameters of the process on the listed above properties of coatings are presented. This technology and equipment complex is appreciated for repair of wearied motor component and deposition of corrosion protective coatings.

2019 ◽  
Vol 69 (4) ◽  
pp. 133-146 ◽  
Author(s):  
Student Mykhailo ◽  
Gvozdetsky Volodymyr ◽  
Student Oleksandra ◽  
Prentkovskis Olegas ◽  
Maruschak Pavlo ◽  
...  

AbstractThe melting conditions of the electrode wires and the structure of coatings, obtained by the electric arc spraying method depending on the pressure of the spraying air flow, are analysed in the current paper. The effect of air pressure on the spraying angle of the flow of melted metal droplets is demonstrated. It is established that due to the decrease in this spraying angle, the temperature of the droplets increases. In addition, high-speed airflow is more easily captured by smaller molten metal droplets and during the contact with the substrate surface their deformations were more strongly. Due to such phenomenon, the porosity of the coatings was reduced and the number of lamellae, welded to each other, increased. With the increasing pressure of the air flow, the thicknesses of the lamellae were decreased, however, the amount of the oxide phase in the coatings has increased. As a result, the hardness, wear resistance and cohesive strength of the coatings, obtained at a higher pressure of the air flow, have increased, and the level of residual stresses of the first kind in them decreased.


2021 ◽  
Vol 1 ◽  
Author(s):  
K. B. Povarova ◽  
◽  
A. E. Morozov ◽  
A. V. Antonova ◽  
M. A. Bulakhtina ◽  
...  

Refractory (Tm = 2100 °C), heat-resistant ruthenium monoaluminide RuAl, lighter (ρ = 7.97 g/cm3) than Ni superalloys, is considered as a promising candidate material for operation at high temperatures and relatively low loads in high-speed gas oxidizing flows at temperatures higher not only the twork, but also the melting point of both nickel superalloys and nickel and titanium aluminides. RuAl is also an ideal candidate for potential use in protective coatings. In the second part of the article, the possibilities of obtaining alloys based on RuAl directly from the initial powders of ruthenium and aluminum are considered by combining the temperature-time modes of reaction sintering (RS), the sequence and intensity of pressure application during RS, without the use of specialized equipment for obtaining initial powders of a given composition and without restrictions on the particle size distribution of the original powders.


Author(s):  
M. Assad ◽  
V. V. Grushevski ◽  
O. G. Penyazkov ◽  
I. N. Tarasenko

The concentration of 16 polycyclic aromatic hydrocarbons (PAHs) in the gasoline combustion products emitted into the atmosphere by internal combustion engines (ICE) has been measured using the gas chromatography method. The concentrations of PAHs in the exhaust gases sampled behind a catalytic converter has been determined when the ICE operates in five modes: idle mode, high speed mode, load mode, ICE cold start mode (engine warm-up) and transient mode. Using 92 RON, 95 RON and 98 RON gasoline the effect of the octane number of gasoline on the PAHs content in the exhaust gases has been revealed. The concentration of the most carcinogenic component (benzo(α)pyrene) in the exhaust gases behind a catalytic converter significantly exceeds a reference value of benzo(α)pyrene in the atmospheric air established by the WHO and the EU for ICE in the load mode.


Author(s):  
E. Yu. Gerashchenkova ◽  
T. I. Bobkova ◽  
E. A. Samodelkin ◽  
B. V. Farmakovsky

The paper presents results of the development of technology for producing cladded and surfacealloyed powder materials. High-speed mechanosynthesis of matrix powders of FeCrAl and solid nanosized particles of tungsten carbide occurs in a disintegrator in the presence of an active gas phase (nitrogen).


Author(s):  
E. Yu. Geraschenkova ◽  
A. F. Vasiliev ◽  
E. A. Samodelkin ◽  
B. V. Farmakovsky

This article presents the results of the development of technology for producing clad powder and coatings based on it. The possibility of obtaining a clad powder using high-speed mechanosynthesis in disintegrator plants is shown on the example of the Hadfield steel – aluminum powder composition.


2015 ◽  
Vol 1111 ◽  
pp. 211-216
Author(s):  
Bogdan Florin Toma ◽  
Iulian Ionita ◽  
Diana Antonia Gheorghiu ◽  
Lucian Eva ◽  
Costică Bejinariu ◽  
...  

Influence of the process parameters and geometry of the spraying nozzle on the properties of titanium deposits obtained in wire arc spraying. Wire arc spraying is a process in which through minor modifications of the spray parameters, they can have a major impact on the coatings properties. In this paper there is presented a study on the influence of process parameters and fluid dynamics of the atomization gas on the properties of titanium deposits (14T - 99.9% Ti). For this there were used three different frontal spraying nozzles, having different geometries, and were varied the spraying gas pressure and the electrical current on three levels. There were evaluated the particles velocity, coating density, chemical composition and characteristic interface between deposition and substrate. Obviously, the high speed of the atomization gas determinate the improving of all properties, but in the same time increased the oxide content in the layer. However, the oxidation can be drastically reduced if the melting and atomization of the wire droplets is produced at the point of formation of the electric arc, and the spraying jet is designed to constrain the electric arc. The assessment of deposits adherence allowed the observation of process parameters that contribute to its improvement.


1991 ◽  
Vol 239 ◽  
Author(s):  
Fred M. Kimock ◽  
Alex J. Hsieh ◽  
Peter G. Dehmer ◽  
Pearl W. Yip

ABSTRACTWe report on a recently commercialized Diamond-Like Carbon (DLC) coating that has been deposited on polycarbonate at near room temperature, via a unique ion beam system. Aspects of high speed impact behavior, chemical resistance, abrasion resistance, and thermal stability of the coating are examined. Results of scanning electron microscopy studies indicate that adhesion of the DLC coating is very good; no delamination of the coating was found on ballistically tested specimens. The well-bonded DLC coating did not cause the impact performance of polycarbonate to become brittle. Chemical exposure test results show that the DLC coating is capable of protecting polycarbonate from chemical attack by aggressive organic liquids. These ion beam deposited DLC coatings have considerable potential as protective coatings for optical systems.


Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 173
Author(s):  
Alessandro Pistone ◽  
Cristina Scolaro ◽  
Annamaria Visco

The accumulation of marine organisms on ship hulls, such as microorganisms, barnacles, and seaweeds, represents a global problem for maritime industries, with both economic and environmental costs. The use of biocide-containing paints poses a serious threat to marine ecosystems, affecting both target and non-target organisms driving science and technology towards non-biocidal solutions based on physico-chemical and materials properties of coatings. The review reports recent development of hydrophobic protective coatings in terms of mechanical properties, correlated with the wet ability features. The attention is focused mainly on coatings based on siloxane and epoxy resin due to the wide application fields of such systems in the marine industry. Polyurethane and other systems have been considered as well. These coatings for anti-fouling applications needs to be both long-term mechanically stable, perfectly adherent with the metallic/composite substrate, and capable to detach/destroy the fouling organism. Prospects should focus on developing even “greener” antifouling coatings solutions. These coatings should also be readily addressable to industrial scale-up for large-scale product distribution, possibly at a reasonable cost.


Author(s):  
V. V. Komar ◽  
T. A. Poсhodina ◽  
N. V. Kulinich ◽  
N. P. Krutko ◽  
L. V. .Ovseenko

The process of modifying aqueous powder suspension materials (APS) based on solid epoxy film-forming agents with highly dispersed powders of magnesium oxide was studied: production by ChemPur (n-MgO – primary size of particles is 36 nm), and magnesium oxide synthesized by a template method from the concentrated bischofite solution (MgOlab – primary size of particles is 102.8 nm). It was shown that presence of active functional surface OHgroups in both samples of magnesium oxide leads to the formation of secondary structures: aggregates and agglomerates. The nature of the influence of the size of aggregates of MgO particles and the conditions of dispersion on the properties of protective coatings is established. The nature of the influence of particle size and dispersion conditions on the properties of protective coatings is established. Optimal properties of coatings based on APS, sedimentation and aggregative stability of suspensions are implemented only under the condition of effective mechanical dispersion in a bead mill, when the most intensive destruction of large aggregates of n-MgO up to 50–60 nm occurs. The distribution of nanoparticle agglomerates in APS at the micro level (700–800 nm) using the MgO-lab does not lead to a significant change in the properties of APS and coatings based on them.It is shown that the introduction of n-MgO into APS allows reduces the curing temperature of the coatings from 110 to 90–100 °С. It is caused by the increase in the density of cross-linking of the spatial structure of polymer. The strength of modified coatings upon impact and tension increases by 2 times in comparison with the base composition, which does not contain nanomodifier, during curing of coatings at100 °C. In comparison with the known water-borne epoxy paints and varnishes, APS compositions are one-pack, they are more technological in use, have a long lifetime (up to 12 months in comparison with the viability of known two-pack epoxies, 1-8 hours). Materials can be used in industry for the protection of metal products, both as primers and as independent coatings.


Author(s):  
R.S. Asatryan ◽  
N.R. Khachatryan ◽  
H.S. Karayan

Passive Infrared (IR) Spectral-radiometry of gases in the atmosphere is extremely important today, when pollution of the environment by natural ejections and those produced by human activity is growing very high. Particularly, spectral analysis of hot gas ejections i.e. combustion products from industrial plants is an essential part of ecological monitoring of the atmosphere. In this paper we present the results of IR spectral analysis of hot gas ejections from industrial plants in the spectral range from 2.5 to 5.5µm, at a distance of 3000m. The obtained with a hydrocarbon gas group, SO2, N2 O, CO and CO2 gases, as well as H2 O vapor. Relative content of ejected gases (to CO-CO2 group) per unit time was evaluated by means of an integral intensity ratio for each gas. Distant IR Spectral analysis of hot gas ejections (both industrial firms, and various vehicles) have huge value, in particular at ecological monitoring of an environment.


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