scholarly journals A Simple Cement Hydration Model Considering the Influences of Water-to-Cement Ratio and Mineral Composition

2021 ◽  
Vol 127 (3) ◽  
pp. 1059-1067
Author(s):  
Baoyu Ma ◽  
Guansuo Dui ◽  
Zhenglin Jia ◽  
Bo Yang ◽  
Chunyan Yang ◽  
...  
Keyword(s):  
Mineral Composition ◽  
Cement Hydration ◽  
Cement Ratio ◽  
Water To Cement Ratio ◽  
Hydration Model

Dispersion and Absorption of SBR Latex in the System of Mono-Dispersed Cement Particles in Water

2013 ◽  
Vol 687 ◽  
pp. 347-353 ◽  
Author(s):  
Xiao Xin Shi ◽  
Ru Wang ◽  
Pei Ming Wang
Keyword(s):  
Cement Hydration ◽  
Single Layer ◽  
Optical Microscope ◽  
Solution Phase ◽  
Environmental Scanning ◽  
Cement Particle ◽  
Microstructure Formation ◽  
Cement Ratio ◽  
Water To Cement Ratio ◽  
Cement Based Materials

This paper investigates the dispersion of cement particles in water at different mix proportions using optical microscope, and the dispersion and absorption of SBR latex in the system of mono-dispersed cement particles in water using environmental scanning electron microscope (ESEM). The results show that the mono-dispersed cement can be well obtained at the water to cement ratio (mw/mc) of 10:1. The ESEM images present that SBR latex is dispersed on the surface of the cement particles as well as the solution phase. SBR latex does not prefer to be absorbed on the cement particles in spite of their opposite electric charge but chooses to be dispersed in the system proportionally. In addition, SBR particles are single-layer absorbed on the surface of cement particles in all the SBR latex to cement ratios (mp/mc). Several SBR particles absorbed on the surface of cement particle get close enough to form groups at the mp/mc of 15% and 20%. The results of this paper provide some bases for analyzing the influence of polymer on cement hydration and the microstructure formation of polymer-modified cement-based materials in a new view.

scholarly journals Experimental Study on Effective Chloride Diffusion Coefficient of Cement Mortar by Different Electrical Accelerated Measurements

Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 240
Author(s):  
Jianlan Chen ◽  
Jiandong Wang ◽  
Rui He ◽  
Huaizhu Shu ◽  
Chuanqing Fu
Keyword(s):  
Diffusion Coefficient ◽  
Cement Mortar ◽  
Early Stage ◽  
Chloride Concentration ◽  
Chloride Diffusion ◽  
Chloride Diffusion Coefficient ◽  
Cement Ratio ◽  
Water To Cement Ratio ◽  
Good Consistency ◽  
Determination Methods

This study investigated the effective chloride diffusion coefficient of cement mortar with different water-to-cement ratio (w/c) under electrical accelerated migration measurement. The cumulative chloride concentration in anode cell solution and the cumulative chloride concentration drop in the cathode cell solution was measured by RCT measurement and the results were further used to calculate the chloride diffusion coefficient by Nordtest Build 355 method and Truc method. The influence of w/c on cement mortar’s chloride coefficient was investigated and the chloride diffusion coefficient under different determination methods were compared with other researchers’ work, a good consistency between this work’s results and literatures’ results was obtained. The results indicated that the increased w/c of cement mortar samples will have a higher chloride diffusion coefficient. The cumulative chloride concentration drop in the cathode cell solution will have deviation in early stage measurement (before 60 h) which will result in overestimation of the effective chloride diffusion coefficient.

Assessment of Hydration Degree of Cement in the Fly Ash-Cement Pastes Based on the Calcium Hydroxide Content

2014 ◽  
Vol 875-877 ◽  
pp. 177-182 ◽  
Author(s):  
Xiang Li ◽  
Hua Quan Yang ◽  
Ming Xia Li
Keyword(s):  
Fly Ash ◽  
Calcium Hydroxide ◽  
Cement Hydration ◽  
Ash Content ◽  
Content Increase ◽  
Hydration Degree ◽  
Equilibrium Calculation ◽  
Cement Pastes ◽  
Cement Ratio ◽  
Water Cement Ratio

The hydration degree of fly ash and the calcium hydroxide (CH) content were measured. Combined with the equilibrium calculation of cement hydration, a new method for assessment of the hydration degree of cement in the fly ash-cement (FC) pastes based on the CH content was developed. The results reveal that as the fly ash content increase, the hydration degree of fly ash and the CH content decrease gradually; at the same time, the hydration degree of cement increase. The hydration degree of cement in the FC pastes containing a high content of fly ash (more than 35%) at 360 days is as high as 80%, even some of which hydrates nearly completely. The effect of water-cement ratio to the hydration degree of cement in the FC pastes is far less distinct than that of the content of fly ash.

scholarly journals Cementitious Composites Reinforced with Polypropylene, Nylon and Polyacrylonitile Fibres

2012 ◽  
Vol 730-732 ◽  
pp. 271-276
Author(s):  
H.R. Pakravan ◽  
M. Jamshidi ◽  
M. Latifi ◽  
F. Pacheco-Torgal
Keyword(s):  
Absorption Capacity ◽  
Cement Matrix ◽  
Cementitious Composites ◽  
Scanning Electron Micrographs ◽  
Energy Absorption Capacity ◽  
Cement Ratio ◽  
Pull Out ◽  
Water To Cement Ratio ◽  
Before And After ◽  
Scanning Electron

This paper compares the adhesion strength between three polymeric fibres (polypropylene (PP), nylon66 (N66) and polyacrylonitrile (PAN)) embedded in a cement paste. The specimens were prepared at a water to cement ratio (w/c) of 0.5 and tested after 7, 14 and 28 curing days. It was found that although the adhesion between the polymeric fibres to the cement matrix is an important factor, the energy absorption capacity or energy dissipation ability of the fibres, plays a more important role in the improvement of the cementitious composites fracture toughness. Scanning electron micrographs were used to characterize the fibres surface before and after the Pull-out tests.

Durability of concrete containing chloride-based accelerating admixtures

1990 ◽  
Vol 17 (1) ◽  
pp. 102-112
Author(s):  
T. Rezansoff ◽  
D. Stott
Keyword(s):  
Calcium Chloride ◽  
Dynamic Modulus ◽  
Linseed Oil ◽  
Standard Test ◽  
Test Method ◽  
Concrete Durability ◽  
Freezing And Thawing ◽  
Cement Ratio ◽  
Freeze Thaw ◽  
Water To Cement Ratio

The influence of CaCl2 or a chloride-based accelerating admixture on the freeze–thaw resistance of concrete was evaluated. Three air entrained mix designs were investigated using ASTM C666-84, Standard Test Method for Resistance of Concrete to Rapid Freezing and Thawing. All mix designs were similar, using cement contents of 340–357 kg/m3 of concrete, except for the addition of either 2% calcium chloride or 2% High Early Pozzolith, while no accelerating admixture was added to the control mix. The entire test program was repeated four times with water-to-cement ratio of 0.46 and three times with the ratio of 0.43. For the Pozzolith-accelerated concrete, half the samples were coated with boiled linseed oil in all seven series. For the control (unaccelerated) concrete, half the samples were coated with boiled linseed oil in one series for each water-to-cement ratio. Performance was monitored using the dynamic modulus of elasticity as obtained from transverse resonant frequency measurements. Weight loss of the specimens was also measured. Only the control samples (no accelerators) showed sufficient durability to satisfy the standard of maintaining at least 60% of the original dynamic modulus after 300 cycles of alternate freezing and thawing. Sealing with linseed oil showed inconsistent improvement in the durability in the various test series when defined in terms of the dynamic modulus; however, weight losses were the lowest of all categories and surface scaling was minimal. Key words: concrete, durability, freeze–thaw testing, calcium chloride, admixtures, sealants, air void system.

scholarly journals Effect of Flyash Addition on Mechanical and Gamma Radiation Shielding Properties of Concrete

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Kanwaldeep Singh ◽  
Sukhpal Singh ◽  
Gurmel Singh
Keyword(s):  
Gamma Radiation ◽  
Attenuation Coefficient ◽  
Cement Content ◽  
Mass Attenuation Coefficient ◽  
Radiation Shielding ◽  
Mechanical Parameters ◽  
Cement Ratio ◽  
Concrete Mixtures ◽  
Water To Cement Ratio ◽  
Shielding Properties

Six concrete mixtures were prepared with 0%, 20%, 30%, 40%, 50%, and 60% of flyash replacing the cement content and having constant water to cement ratio. The testing specimens were casted and their mechanical parameters were tested experimentally in accordance with the Indian standards. Results of mechanical parameters show their improvement with age of the specimens and results of radiation parameters show no significant effect of flyash substitution on mass attenuation coefficient.

Chloride Ingress Control and Promotion of Internal Curing in Concrete Using Superabsorbent Polymer

2021 ◽  
Vol 888 ◽  
pp. 67-75
Author(s):  
Ariel Verzosa Melendres ◽  
Napoleon Solo Dela Cruz ◽  
Araceli Magsino Monsada ◽  
Rolan Pepito Vera Cruz
Keyword(s):  
Compressive Strength ◽  
Cementitious Materials ◽  
Internal Curing ◽  
Mix Design ◽  
Chloride Ingress ◽  
Superabsorbent Polymer ◽  
Cement Slurry ◽  
Chloride Permeability ◽  
Cement Ratio ◽  
Water To Cement Ratio

Chloride ingress into concrete from the surrounding environment can result in the corrosion of the embedded steel reinforcement and cause damage to the concrete. Superabsorbent polymer (SAP) with fine particle size was incorporated into the structure of concrete for controlling the chloride ingress and improving its compressive strength via promotion of internal curing. The SAP used in this study was evaluated for its absorbency property when exposed to cementitious environment such as aqueous solution of Ca (OH)2 and cement slurry. The results were compared to that in sodium chloride solution, the environment where absorbency of most of the SAP found in the market are well studied. Results showed that although SAP absorbency decreased with increasing concentration of Ca (OH)2 and cement, the results suggest that water containing cementitious materials are able to be absorbed by SAP. Chloride ingress into 28-day cured concrete specimens were determined using Rapid Chloride Penetration Test (RCPT) method employing 60V DC driving force. Concrete samples with size of 50 mm height x 100 mm diameter were prepared using a M25 mix design with 0.4 and 0.45 water to cement ratios and different percentages of SAP such as 0.05%, 0.1% and 0.15% with respect to cement mass. Results showed that concrete with 0.15% SAP gave the best result with 14% less chloride permeability than concrete with no SAP for a 0.4 water to cement ratio. Concrete samples for compressive strength tests with size of 200 mm height x 100 mm diameter were prepared using the same mix design and percentages of SAP and cured for 28 days. Results showed that the best results for compressive strength was found at 0.1% SAP at a 0.4 water to cement ratio which can be attributed to internal curing provided by SAP.

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