scholarly journals Karakterisasi Bionanofiller Dari Limbah Padi Sebagai Alternatif Penguatan Pada Polimer Komposit

2018 ◽  
Vol 3 (2) ◽  
Author(s):  
Eryani . ◽  
Sri Aprilia ◽  
Farid Mulana

<p>Agricultural waste such as rice straw, rice husk and rice husk ash have not been utilized properly. This waste of agricultural produce can actually be used as an alternative to bionanofiller because it contains an excellent source of silica. The silica content contained in the rice waste when combined with the polymer matrix can produce composites having high thermal and mechanical properties. Characterization of bionanofiller from this rice waste is done by SEM, XRF, FTIR, XRD and particle density. The result of SEM analysis from this rice waste is feasible to be used as filler because it has size 1 μm. Likewise with the results of XRF analysis that rice waste contains a high enough silica component that is 80.6255% - 89.83%. FTIR test results also show that bionanoparticles from rice waste have the same content of silica. In the XRD analysis the best selective gain of rice waste is found in rice husk ash which is characteristic of amorp silica at a range of 2ϴ = 22<br />. The largest density analysis of paddy waste was found in rice husk 0.0419 gr / cm , followed by rice straw by of 0.0417 gr / cm 3 and rice hulk ash 0.0407 g / cm 3</p>

2022 ◽  
Author(s):  
Sunita Kumari ◽  
Dhirendra Singhal ◽  
Rinku Walia ◽  
Ajay Rathee

Abstract The present project proposes to utilize rice husk and maize cob husk ash in the cement to mitigate the adverse impact of cement on environment and to enhance the disposal of waste in a sustainable manner. Ternary concrete / MR concrete was prepared by using rise husk and maize cob ash with cement. For the present project, five concrete mixes MR-0 (Control mix), MR-1 (Rice husk ash 10% and MR-2.5%), MR-2 (Rice husk ash 10% and MR-5%), MR-3 (Rice husk ash 10% and MR-2.5%), MR-4 (Rice husk ash 10% and MR-2.5%) were prepared. M35 concrete mix was designed as per IS 10262:2009 for low slump values 0-25mm. The purpose is to find the optimum replacement level of cement in M35 grade ternary concrete for I – Shaped paver blocks.In order to study the effects of these additions, micro-structural and structural properties test of concretes have been conducted. The crystalline properties of control mix and modified concrete are analyzed by Fourier Transform Infrared Spectroscope (FTIR), Scanning Electron Microscopy (SEM), and X-Ray Diffraction (XRD). The results indicated that 10% Rice husk ash and 5% maize cob ash replaced with cement produce a desirable quality of ternary concrete mix having good compressive strength. The results of SEM analysis indicated that the morphology of both concrete were different, showing porous structure at 7 days age and become unsymmetrical with the addition of ashes. After 28 day age, the control mix contained more quantity of ettringite and became denser than ternary concrete. XRD analysis revealed the presence of portlandite in large quantity in controlled mix concrete while MR concrete had the partially hydrated particle of alite.


Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3440
Author(s):  
Mohd Na’im Abdullah ◽  
Mazli Mustapha ◽  
Nabihah Sallih ◽  
Azlan Ahmad ◽  
Faizal Mustapha ◽  
...  

The utilisation of rice husk ash (RHA) as an aluminosilicate source in fire-resistant coating could reduce environmental pollution and can turn agricultural waste into industrial wealth. The overall objective of this research is to develop a rice-husk-ash-based geopolymer binder (GB) fire-retardant additive (FR) for alkyd paint. Response surface methodology (RSM) was used to design the experiments work, on the ratio of RHA-based GB to alkyd paint. The microstructure behaviour and material characterisation of the coating samples were studied through SEM analysis. The optimal RHA-based GB FR additive was formulated at 50% wt. FR and 82.628% wt. paint. This formulation showed the result of 270 s to reach 200 °C and 276 °C temperature at equilibrium for thermal properties. Furthermore, it was observed that the increased contents of RHA showed an increment in terms of the total and open porosities and rough surfaces, in which the number of pores on the coating surface plays an important role in the formation of the intumescent char layer. By developing the optimum RHA-based GB to paint formulation, the coating may potentially improve building fire safety through passive fire protection.


2019 ◽  
Vol 22 (6) ◽  
pp. 220-226 ◽  
Author(s):  
Emil Zacky Effendi ◽  
Yudhi Christian Hariady ◽  
Muhammad Daffa Salaahuddin ◽  
Chairul Irawan ◽  
Iryanti Fatyasari Nata

Rice husk (RH) is an agricultural waste that contains cellulose. Rice husk fiber (RHF) can be used as a source of fiber in the manufacture of magnetic nanoparticle biocomposite. The purpose of this study is to synthesize and characterize magnetic nanoparticle biocomposite used as an adsorbent and evaluate its performance on the adsorption of  Mn2+ ions and Total Suspended Solid (TSS) in peat water. Rice husk fiber was delignified to eliminate lignin levels. Furthermore, the biocomposite was made through the solvothermal method with and without the addition of hexanediamine. The products produced are two types of adsorbents, namely magnetic nanoparticle biocomposite with an amino group (RHB-MH) and rice husk fiber biocomposite without an amino group (RHB-M). These biocomposites were used to adsorb Mn2+ ions in peat water. Evaluations were carried out at pH 5, 6, 7, and 8 with an optimum adsorption time of 60 minutes. The solutions at the time of adsorption were evaluated to determine the optimum conditions of the adsorption process carried out. The observation of magnetic nanoparticle biocomposite based on the analysis of Scanning Electron Microscopy (SEM) shows magnetic nanoparticles formed on the surface of rice husk fiber with a diameter of 30-50 nm. X-Ray Diffraction (XRD) analysis showed that the delignification of rice husk increased Crystallinity Index (CrI) by 64.98% and reduced silica content by 78%. Fourier Transform Infra-Red (FT-IR) spectrometer show absorption peak at 570 cm-1 for Fe-O bonds and Fe3O4 peak around 1627 cm−1, indicating the presence of N-H bending. The optimum condition for Mn2+ adsorption was achieved at pH 5 and 60-minutes duration with an adsorption capacity of 54.7 mg/g and 190.78 mg/g for RHB-M and RHB-MH. The TSS reduction achieved the effectiveness of 60.2% and 90.3% for BSP-M and BSP-MH, respectively.


Rekayasa ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 112-117
Author(s):  
Dwi Nurtanto ◽  
Muhammad Fahad Kustantiyo ◽  
Nanin Meyfa Utami ◽  
Hernu Suyoso

Study ini membandingkan kuat hancur, berat volume antara beton ringan dengan beton dengan mengganti sebagian semen (PC) dengan limbah pertanian.  Limbah pertanian yang dimaksud adalah sekam padi dan ampas tebu. Penggunaan limbah pertanian tersebut sebaga material pengganti semen dikarenakan mempunyai sifat pozzolan yang cukup tinggi.  Pemakaian limbah pertanian ini dengan membakar ampas tebu dan sekam padi dengan suhu tertentu sehingga menjadi abu. Limbah tebu diambil dari Pabrik Gula Prajekan Bondowoso, dibakar dengan suhu 8000C  selama 8 jam. Limbah Padi diambil dari limbah Pabrik Padi di Kalisat Jember, dibakar dengan suhu 8500C selama 45 menit. Kandungan silika dari hasil pembakaran tersebut masing-masing sebesar 59,5% dan 79,5% . Prosentase pengganti sebagian PC sebesar 5%, 10%, 15% dan 20%, dengan perbandingan campuran abu ampas tebu (AAT) dan abu sekam padi (ASP) adalah 1:1. Pengujian dilakukan pada umur 28 hari dengan bentuk benda uji silender berukuran 10x20 cm. Hasil kuat hancur tertinggi pada benda uji dengan subsitusi PC sebesar 5% dan berat volume yang terendah pada benda uji dengan pengantian semen sebesar 20%. Effect of Cement Substitution with Agricultural Waste on Lightweight Structural ConcreteThis study compares the shattering strength, volume weight between lightweight concrete and concrete by replacing part of the Portland cement (PC) with agricultural waste. The agricultural waste in question is rice husk and sugarcane bagasse. The use of agricultural waste is as a substitute for cement because it has quite high pozzolanic properties. Use of this agricultural waste by burning sugarcane bagasse and rice husk with a certain temperature so that it becomes ash. Sugarcane waste is taken from Bondowoso Prajekan Sugar Mill, burned at 8000C for 8 hours. Rice waste is taken from the rice factory waste in Kalisat Jember, burned at 8500C for 45 minutes. The silica content of the combustion products was 59.5% and 79.5%, respectively. The percentage of partial PC replacement is 5%, 10%, 15%, and 20%, with a ratio of bagasse ash (BA) to rice husk ash (RHA) is 1: 1. The test was carried out at 28 days in the form of a 10 x 20 cm slender test object. The highest yield of crushing strength in specimens with PC substitution of 5% and the lowest volume weight in specimens with cement replacement of 20%.


2018 ◽  
Vol 156 ◽  
pp. 05020 ◽  
Author(s):  
Bastian Arifin ◽  
Sri Aprilia ◽  
Pocut Nurul Alam ◽  
Farid Mulana ◽  
Amri Amin ◽  
...  

The current development of the packaging industry is increasing as well as the dependence of non-renewable oil-based materials encouraging researchers to look for alternative polymeric strengthening materials from biomass. Especially used from agricultural waste because it is cheap and widely available in nature and it can be renewed. In this study, agriculture waste used were rice husk and rice husks ash that prepared as organic nanofillers for the development of polymer nanocomposites. XRF analysis showed that rice husk ash has the highest silica (SiO2) content of 89. 835%, while rice husk has SiO2 contents of 82.540%. From XRD analysis on 2 theta there is a crystalline silica region at 22° and this analysis shows the sample is amorphous. FTIR analysis showed Si-H at peak 2339 cm−1 in rice husk and 2129 cm−1 for rice husk ash.


2021 ◽  
Vol 2 (1) ◽  
pp. 011-020
Author(s):  
Godwin Adie Akeke

This paper presents the effects of variability in the chemical and elemental composition of Rice Husk Ash (RHA) sourced from four (4) different locations on Tensile Properties of Concrete. RHA is an agricultural waste gotten from rice mills after removal of rice paddy for food and burnt in open air or under controlled processes. RHA is found to be pozzolanic and can be used to partially replace cement to enhance the strength and quality of concrete. The different sources where RHA was gotten are; Ogoja, Abakaliki, Adani and Adikpo in Nigeria. It is discovered that the pozolanic properties of RHA varies based on their source location. Samples from Ogoja where found to have the highest pozzolanic properties followed by Abakaliki, Adani, and Adikpo, their silica content was found to be 84.55, 76.3, 70.12, 70.11, respectively. RHA was used to replace cement in concrete at 5, 10,15,20,25 and 30%. The compressive strength was determined and the values are as follows; And the compressive strength values at 28 days was found to be in the range of 37-42N/mm2 at 5%RHA, 35-39.5N/mm2 at 10%RHA, 30-34.5N/mm2 at 15%RHA, 27-29N/mm2 at 20%RHA, 22-25.6N/mm2 at 25% RHA and 21-24N/mm2 at 30% RHA compared to the controlled sample with a strength value of 42.64N/mm2. Cylindrical columns concrete of size 100mm diameter by 200mm long were moulded and stored in water for 28 days before testing for tensile splitting strength. The values determined from the split tensile test are as follows; 2.1-3.1N/mm2 at 5%RHA, 2.1-2.5N/mm2 at 10% RHA, 1.8-2.10 N/mm2 at 15% RHA, 1.2-1.7 N/mm2 at 20%RHA, 1.1-1.3 N/mm2 at 25% RHA and 0.62-0.9 N/mm2 at 30% RHA while the results of the controlled sample is 3.1 N/mm2.From the results above it can be deduced that source location influences the chemical properties of RHA strength characteristics of the Concrete with RHA as partial replacement.


Materials ◽  
2021 ◽  
Vol 14 (18) ◽  
pp. 5193
Author(s):  
Hamisah Ismail ◽  
Hasmaliza Mohamad

Recently, there has been an increase in interest in agricultural waste in scientific, technological, environmental, economic, and social contexts. The processing of rice husk ash/rice straw ash into biocompatible products—also known as biomaterials—used in biomedical implants is a technique that can enhance the value of agricultural waste. This method has effectively converted unprocessed agricultural waste into high-value products. Rice husk and straw are considered to be unwanted agricultural waste and are largely discarded because they pollute the environment. Because of the related components present in bone and teeth, this waste can produce wollastonite. Wollastonite is an excellent material for bone healing and implants, as well as tissue regeneration. The use of rice husk ash or rice straw ash in wollastonite production reduces the impact of agricultural waste on pollution and prompts the ensuing conversion of waste into a highly beneficial invention. The use of this agricultural waste in the fabrication of wollastonite using rice husk ash or rice straw ash was investigated in this paper. Wollastonite made from rice husk ash and rice straw ash has a fair chance of lowering the cost of bone and tooth repair and replacement, while having no environmental effects.


Tibuana ◽  
2020 ◽  
Vol 3 (01) ◽  
pp. 47-52
Author(s):  
Yanatra budi Pramana ◽  
M. Amin Pahlevi ◽  
Zhulianto Ashari ◽  
M. Fariz Effendi ◽  
Fibra Gilang Ramadhan

Utilization of rice husks in Indonesia in general is still very limited. Utilization of silica contained in rice husk ash, which has been used, among others, in the manufacture of sodium silicate. Silica compounds themselves can be used in and manufacturing basic materials for electronic and ceramic equipment, glass, rubber, cosmetic products, and pharmaceuticals. The addition of Mg can increase the silica content (SiO2) in rice husk ash. The best results show an effective Mg ratio of Mg addition to increase silica content is 1: 1. produces the highest amount of silica which is 58.12% of the rice husk ash with a size of 140 mesh


2019 ◽  
Vol 20 (1) ◽  
pp. 16 ◽  
Author(s):  
Duha Hussien Attol ◽  
Hayder Hamied Mihsen

Rice husk ash (RHA) was used to prepare sodium silicate, which in turn was functionalized with 3-(chloropropyl)triethoxysilane employing the sol-gel technique to form RHACCl. Chloro group in RHACCl was replaced with iodo group forming RHACI. Ethylenediamine was immobilized on RHACI in order to prepare it for the reaction with salicylaldehyde to form a silica derivative-salen. FT-IR analysis indicated the presence of secondary amine and –NH and C=N absorption bands. XRD analysis revealed the occurrence of the broad diffused peak with maximum intensity at 22–23° (2θ). BET measurements showed also that the surface area of the prepared compound is 274.55 m2/g. Elemental analysis proved the existence of nitrogen in the structure of the prepared compound. The silica derivative-salen showed high potential for extraction and removal of heavy contaminating metal ions Ni(II), Cu(II), and Co(II) from aqueous solutions. The kinetic study demonstrates that the adsorption of the metal ions follows the pseudo-second order.


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