scholarly journals Thermodynamics and transport properties of the supercritical fluid of metals

2020 ◽  
Vol 49 (1-2) ◽  
pp. 143-154
Author(s):  
ALEXANDER L. KHOMKIN ◽  
ALEKSEY S. SHUMIKHIN
Keyword(s):  
Experimental Data ◽  
Electrical Conductivity ◽  
Equation Of State ◽  
Transport Properties ◽  
Supercritical Fluid ◽  
Bound States ◽  
Unified Approach ◽  
Metal Vapors ◽  
Proposed Model ◽  
Electrons And Ions

The proposed model allows to calculate the composition, thermodynamic and transport properties of the supercritical metal vapors within unified approach. The model includes atoms, immersed in jellium, and thermally ionized electrons and ions. The jellium is the part of the bound states electron density. The density of electron jellium increases with the compression of atomic gas and does not depend on temperature directly. At compression, the electrical conductivity passes through the minimum from the conductivity of thermal electrons to the conductivity of electrons of jellium accordingly. Calculations of the equation of state and the electrical conductivity of supercritical metal vapors agree well with physical and numerical experimental data.

scholarly journals Transport properties of warm dense matter behind intense shock waves

2014 ◽  
Vol 33 (1) ◽  
pp. 41-50 ◽  
Author(s):  
V. B. Mintsev ◽  
V. E. Fortov
Keyword(s):  
Experimental Data ◽  
Electrical Conductivity ◽  
Transport Properties ◽  
Shock Compression ◽  
Shear Viscosity ◽  
Dense Matter ◽  
Warm Dense Matter ◽  
Strongly Coupled ◽  
Intense Shock ◽  
Strongly Coupled Plasma

AbstractThis report presents the overview of the results of investigation of transport properties of warm dense matter in the conditions with strong coupling generated as a result of the shock or multiple shock compression of substance up to the megabar pressure range. We consider the results of measurements of the electrical conductivity in two different regions. The first one is the high temperature region, where the temperatures are of the order or much higher than the ionization potential I of the compressed substance. The region of “pressure ionization” where T ≪ I is the most interesting from the point of view of the specific plasma phase transitions. A few amounts of experimental data on shock compressed matter viscosity are discussed. For the estimations of shear viscosity of strongly coupled plasma experimental data on measurements of electrical conductivity of hydrogen, deuterium and rare gases under intense shock compression were used. It is shown that the ratio of shear viscosity coefficient to volume density of entropy of strongly coupled plasma is of the order of a lower bound, predicted by Kovtun et al. (2005) in frames of string theory methods.

Dual Release Model to Evaluate Dissolution Profiles from Swellable Drug Polyelectrolyte Matrices

2020 ◽  
Vol 17 (6) ◽  
pp. 511-522 ◽  
Author(s):  
Alicia Graciela Cid ◽  
María Verónica Ramírez-Rigo ◽  
María Celeste Palena ◽  
Elio Emilio Gonzo ◽  
Alvaro Federico Jimenez-Kairuz ◽  
...  
Keyword(s):  
Experimental Data ◽  
Drug Release ◽  
Inflection Point ◽  
Release Profile ◽  
Experimental Point ◽  
Extended Model ◽  
Release Process ◽  
Proposed Model ◽  
Dual Release ◽  
Release Model

Background: Mathematical modeling in modified drug release is an important tool that allows predicting the release rate of drugs in their surrounding environment and elucidates the transport mechanisms involved in the process. Objective: The aim of this work was to develop a mathematical model that allows evaluating the release profile of drugs from polymeric carriers in which the swelling phenomenon is present. Methods: Swellable matrices based on ionic complexes of alginic acid or carboxymethylcellulose with ciprofloxacin were prepared and the effect of adding the polymer sodium salt on the swelling process and the drug release was evaluated. Experimental data from the ciprofloxacin release profiles were mathematically adjusted, considering the mechanisms involved in each stage of the release process. Results: A proposed model, named “Dual Release” model, was able to properly fit the experimental data of matrices presenting the swelling phenomenon, characterized by an inflection point in their release profile. This entails applying the extended model of Korsmeyer-Peppas to estimate the percentage of drug released from the first experimental point up to the inflection point and then a model called Lumped until the final time, allowing to adequately represent the complete range of the drug release profile. Different parameters of pharmaceutical relevance were calculated using the proposed model to compare the profiles of the studied matrices. Conclusion: The “Dual Release” model proposed in this article can be used to predict the behavior of complex systems in which different mechanisms are involved in the release process.

Viscosity, electrical conductivity and density of the system ammonium nitrate-dimethyl sulphoxide

1984 ◽  
Vol 49 (5) ◽  
pp. 1109-1115
Author(s):  
Jindřich Novák ◽  
Zdeněk Kodejš ◽  
Ivo Sláma
Keyword(s):  
Electrical Conductivity ◽  
Aqueous Solutions ◽  
Ammonium Nitrate ◽  
Transport Properties ◽  
Calcium Nitrate ◽  
Dimethyl Sulphoxide ◽  
Present System ◽  
Empirical Equations ◽  
Concentrated Solutions ◽  
Nitrate Solutions

The density, viscosity, and electrical conductivity of highly concentrated solutions of ammonium nitrate in dimethyl sulphoxide have been determined over the temperature range 10-60 °C and the concentration range 7-50 mol% of the salt. The variations in the quantities as a function of temperature and concentration have been correlated by empirical equations. A comparison is made between the transport properties for the present system, aqueous solutions of ammonium nitrate, and calcium nitrate solutions in dimethyl sulphoxide.

scholarly journals Topological isoconductance signatures in Majorana nanowires

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
L. S. Ricco ◽  
J. E. Sanches ◽  
Y. Marques ◽  
M. de Souza ◽  
M. S. Figueira ◽  
...  
Keyword(s):  
Quantum Dot ◽  
Transport Properties ◽  
Spin Polarization ◽  
Bound States ◽  
Spin Asymmetry ◽  
Experimental Protocol ◽  
Zero Bias ◽  
Topological Superconductor ◽  
Hybrid Device ◽  
Majorana Bound States

AbstractWe consider transport properties of a hybrid device composed by a quantum dot placed between normal and superconducting reservoirs, and coupled to a Majorana nanowire: a topological superconducting segment hosting Majorana bound states (MBSs) at the opposite ends. It is demonstrated that if highly nonlocal and nonoverlapping MBSs are formed in the system, the zero-bias Andreev conductance through the dot exhibits characteristic isoconductance profiles with the shape depending on the spin asymmetry of the coupling between the dot and the topological superconductor. Otherwise, for overlapping MBSs with less degree of nonlocality, the conductance is insensitive to the spin polarization and the isoconductance signatures disappear. This allows to propose an alternative experimental protocol for probing the nonlocality of the MBSs in Majorana nanowires.

scholarly journals Revisiting Kelvin equation and Peng–Robinson equation of state for accurate modeling of hydrocarbon phase behavior in nano capillaries

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ilyas Al-Kindi ◽  
Tayfun Babadagli
Keyword(s):  
Experimental Data ◽  
Surface Tension ◽  
Equation Of State ◽  
Phase Behavior ◽  
Pore Radius ◽  
Microfluidic Chips ◽  
Tight Sandstone ◽  
Kelvin Equation ◽  
Rock Samples ◽  
Robinson Equation

AbstractThe thermodynamics of fluids in confined (capillary) media is different from the bulk conditions due to the effects of the surface tension, wettability, and pore radius as described by the classical Kelvin equation. This study provides experimental data showing the deviation of propane vapour pressures in capillary media from the bulk conditions. Comparisons were also made with the vapour pressures calculated by the Peng–Robinson equation-of-state (PR-EOS). While the propane vapour pressures measured using synthetic capillary medium models (Hele–Shaw cells and microfluidic chips) were comparable with those measured at bulk conditions, the measured vapour pressures in the rock samples (sandstone, limestone, tight sandstone, and shale) were 15% (on average) less than those modelled by PR-EOS.

scholarly journals Pressure-Induced Structural Phase Transition and Metallization in Ga2Se3 up to 40.2 GPa under Non-Hydrostatic and Hydrostatic Environments

Crystals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 746
Author(s):  
Meiling Hong ◽  
Lidong Dai ◽  
Haiying Hu ◽  
Xinyu Zhang
Keyword(s):  
Phase Transition ◽  
Electrical Conductivity ◽  
High Pressure ◽  
Phase Transformation ◽  
Transport Properties ◽  
Electrical Transport ◽  
Structural Phase ◽  
Structure Evolution ◽  
Systematic Research ◽  
Electrical Transport Properties

A series of investigations on the structural, vibrational, and electrical transport characterizations for Ga2Se3 were conducted up to 40.2 GPa under different hydrostatic environments by virtue of Raman scattering, electrical conductivity, high-resolution transmission electron microscopy, and atomic force microscopy. Upon compression, Ga2Se3 underwent a phase transformation from the zinc-blende to NaCl-type structure at 10.6 GPa under non-hydrostatic conditions, which was manifested by the disappearance of an A mode and the noticeable discontinuities in the pressure-dependent Raman full width at half maximum (FWHMs) and electrical conductivity. Further increasing the pressure to 18.8 GPa, the semiconductor-to-metal phase transition occurred in Ga2Se3, which was evidenced by the high-pressure variable-temperature electrical conductivity measurements. However, the higher structural transition pressure point of 13.2 GPa was detected for Ga2Se3 under hydrostatic conditions, which was possibly related to the protective influence of the pressure medium. Upon decompression, the phase transformation and metallization were found to be reversible but existed in the large pressure hysteresis effect under different hydrostatic environments. Systematic research on the high-pressure structural and electrical transport properties for Ga2Se3 would be helpful to further explore the crystal structure evolution and electrical transport properties for other A2B3-type compounds.

scholarly journals Transport Properties of Natural and Artificial Smart Fabrics Impregnated by Graphite Nanomaterial Stacks

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 1018
Author(s):  
Carola Esposito Corcione ◽  
Francesca Ferrari ◽  
Raffaella Striani ◽  
Antonio Greco
Keyword(s):  
Electrical Conductivity ◽  
Transport Properties ◽  
Low Cost ◽  
Empirical Relationship ◽  
Theoretical Models ◽  
Expandable Graphite ◽  
Easy Method ◽  
Textile Materials ◽  
Fabric Materials ◽  
The Impact

In this work, we studied the transport properties (thermal and electrical conductivity) of smart fabric materials treated with graphite nanomaterial stacks–acetone suspensions. An innovative and easy method to produce graphite nanomaterial stacks–acetone-based formulations, starting from a low-cost expandable graphite, is proposed. An original, economical, fast, and easy method to increase the thermal and electrical conductivity of textile materials was also employed for the first time. The proposed method allows the impregnation of smart fabric materials, avoiding pre-coating of the fibers, thus reducing costs and processing time, while obtaining a great increase in the transport properties. Two kinds of textiles, cotton and Lycra®, were selected as they represent the most used natural and artificial fabrics, respectively. The impact of the dimensions of the produced graphite nanomaterial stacks–acetone-based suspensions on both the uniformity of the treatment and the transport properties of the selected textile materials was accurately evaluated using several experimental techniques. An empirical relationship between the two transport properties was also successfully identified. Finally, several theoretical models were applied to predict the transport properties of the developed smart fabric materials, evidencing a good agreement with the experimental data.

Dual percolations of electrical conductivity and electromagnetic interference shielding in progressively agglomerated CNT/polymer nanocomposites

2021 ◽  
pp. 108128652110214
Author(s):  
Xiaodong Xia ◽  
George J. Weng
Keyword(s):  
Experimental Data ◽  
Electrical Conductivity ◽  
Carbon Nanotube ◽  
Percolation Threshold ◽  
Polymer Nanocomposites ◽  
Electromagnetic Interference ◽  
Effective Medium Theory ◽  
Scale Model ◽  
Shielding Effectiveness ◽  
Emi Shielding

Recent experiments have revealed two distinct percolation phenomena in carbon nanotube (CNT)/polymer nanocomposites: one is associated with the electrical conductivity and the other is with the electromagnetic interference (EMI) shielding. At present, however, no theories seem to exist that can simultaneously predict their percolation thresholds and the associated conductivity and EMI curves. In this work, we present an effective-medium theory with electrical and magnetic interface effects to calculate the overall conductivity of a generally agglomerated nanocomposite and invoke a solution to Maxwell’s equations to calculate the EMI shielding effectiveness. In this process, two complex quantities, the complex electrical conductivity and complex magnetic permeability, are adopted as the homogenization parameters, and a two-scale model with CNT-rich and CNT-poor regions is utilized to depict the progressive formation of CNT agglomeration. We demonstrated that there is indeed a clear existence of two separate percolative behaviors and showed that, consistent with the experimental data of poly-L-lactic acid (PLLA)/multi-walled carbon nanotube (MWCNT) nanocomposites, the electrical percolation threshold is lower than the EMI shielding percolation threshold. The predicted conductivity and EMI shielding curves are also in close agreement with experimental data. We further disclosed that the percolative behavior of EMI shielding in the overall CNT/polymer nanocomposite can be illustrated by the establishment of connective filler networks in the CNT-poor region. It is believed that the present research can provide directions for the design of CNT/polymer nanocomposites in the EMI shielding components.

scholarly journals Measurement of the sound velocity of shock compressed water

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Hua Shu ◽  
Jiangtao Li ◽  
Yucheng Tu ◽  
Junjian Ye ◽  
Junyue Wang ◽  
...  
Keyword(s):  
Experimental Data ◽  
Molecular Dynamics ◽  
Equation Of State ◽  
Liquid Water ◽  
Diamond Anvil Cell ◽  
Quantum Molecular Dynamics ◽  
Laser Shock ◽  
Diamond Anvil ◽  
Ionization Processes ◽  
Sound Velocities

AbstractThe sound velocities of water in the Hugoniot states are investigated by laser shock compression of precompressed water in a diamond anvil cell. The obtained sound velocities in the off-Hugoniot region of liquid water at precompressed conditions are used to test the predictions of quantum molecular dynamics (QMD) simulations and the SESAME equation-of-state (EOS) library. It is found that the prediction of QMD simulations agrees with the experimental data while the prediction of SESAME EOS library underestimates the sound velocities probably due to its improper accounting for the ionization processes.

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