Rheology of pulp suspensions of bleached sugarcane bagasse: Effect of consistency and temperature

TAPPI Journal ◽  
2015 ◽  
Vol 14 (9) ◽  
pp. 601-606 ◽  
Author(s):  
JORGE H. SÁNCHEZ ◽  
GERMÁN C. QUINTANA ◽  
MERY E. FAJARDO

Rheological properties, such as yield stress and apparent viscosity, of pulp suspensions of bleached sugarcane bagasse were studied in a stress-shear rate controlled rheometer using concentric cylinders geometry. Results were statistically analyzed and presented as a function of the suspension consistency (0.5% ≤ Cm ≤ 4.0%) and temperature (20°C, 40°C, and 60°C). The yield stress was influenced by the consistency and temperature. The apparent viscosity was influenced only by the consistency. A power law model was fitted to the experimental results of yield stress. In flow tests, all the suspensions showed shear-thinning behavior, which was in agreement with the Carreau-Yasuda model.

2018 ◽  
Vol 61 (3) ◽  
pp. 1113-1120
Author(s):  
Ibrahim Denka Kariyama ◽  
Xiaodong Zhai ◽  
Binxin Wu

Abstract. This literature review was conducted on the physical and rheological properties of animal manure slurries and their applications. The review revealed the importance of these properties in the design of anaerobic treatment plants, pipe systems to transport slurries to treatment and storage units, and other applications and management of raw and treated slurries. The selection of pumping and mixing equipment and their power requirements, the flow behavior, mass, and heat transfer, the quality of mixing, pressure head loss, and other applications of manure slurries are affected by the physical and rheological properties. The review shows that manure slurries generally exhibit non-Newtonian pseudoplastic fluid behavior with a decreasing apparent viscosity as the shear rate increases and that the power law equation can successfully be used to describe the relationship between shear stress and shear rate, especially for low total solids concentrations. Keywords: Animal manure slurries, Apparent viscosity, Non-Newtonian pseudoplastic fluids, Power law equation, Rheological properties.


2021 ◽  
Vol 71 (3) ◽  
pp. 290-297
Author(s):  
Yucheng Peng ◽  
Changlei Xia ◽  
Brian Via

Abstract Interest in cellulose nanocrystal (CNC) recently has been growing significantly. Many applications have been developed for CNC and appropriate procedures to handle the CNC suspensions are critical for these applications. In this study, we explored a method evaluating CNC suspensions based on rheological property characterization. We used a rotational viscometer to characterize CNC suspensions at concentrations of 3, 4, 5, and 6 wt.%. We collected primary readings from the rotational viscometer, including spindle rotation speed and torque, to generate apparent viscosity and shear rate for CNC suspensions. We applied three different methods summarized from the literature to calculate apparent viscosity and real shear rate. We critically analyzed differences among calculation results from the three methods. Shearing thinning behaviors obeyed the power law flow model for all CNC suspensions in the shear rate tested. At different concentrations, consistency and flow behavior indices in the model differed in the measured shear rate range. With the same shear rate, higher concentration CNC suspension had a higher apparent viscosity. The apparent viscosity of the CNC suspension was associated with its weight concentration in a power law relationship. This study indicated that a rotational viscometer can be used as a quality control tool for characterizing the rheological properties of the CNC suspensions. We made recommendations for using appropriate calculation methods to obtain shear rate and apparent viscosity of CNC suspensions from the primary readings of a rotational viscometer under different situations.


1976 ◽  
Vol 16 (01) ◽  
pp. 31-36 ◽  
Author(s):  
R.E. Robertson ◽  
H.A. Stiff

Abstract The Newtonian, Bingham, and power law models previously have been used to approximate the previously have been used to approximate the rheology of drilling fluids and cements. The proposed yield-pseudoplastic model provides more consistently accurate descriptions of the rheology of such fluids. Simple explicit relationships between the wall shear rate and the volumetric flow rate in both pipe and annular flow have been derived from this model for use in engineering calculations. Introduction Two mathematical models have been widely used with drilling fluids and cement slurries for relating shear stress to shear rate. The most popular is that of Bingham,.T = Ty + ny, .............................(1) which describes this relationship as linear after an initial yield. Very few, if any, drilling fluids or cement slurries conform to this model, and no explicit relationship can be derived between the shear rate and the volumetric flow rate in a pipe or an annulus. In recent years, the Ostwald-de Waele or "power law" model,.T = K yn,...................................(2) has gained popularity. Eq. 2 describes a fluid with no yield stress and a constant ratio between the logarithms of the shear stress and the shear rate over a workable range. Simple explicit relationships between the shear rate and the volumetric flow rate in a pipe and an annulus can be derived from the equation, but the model often does not fit actual shear stress and shear rate data. Actual shear stress/shear rate data for many fluids place them in the category of yield-pseudoplastics, fluids that exhibit a yield stress as well as a nonlinear relationship between shear stress and shear rate once flow is initiated. A three-parameter model for such fluids, proposed by Herschel and Bulkley, combines the characteristics of the Bingham and power law models:.T = Ty + K yn ..............................(3) Eq. 3 describes the behavior of yield-pseudoplastics reasonably well, but again, no explicit relationship can be derived between the shear rate and the volumetric flow rate in a pipe or an annulus. Thus, the need exists for a model that will adequately describe yield-pseudoplastics, such as drilling fluids and cement slurries, and that has the analytical utility of the power law model for engineering calculations. PROPOSED MODEL PROPOSED MODEL The proposed model takes the form.T = A (y + C)B,.............................(4) It adequately describes the relationship between shear rate and shear stress for most drilling fluids and cement slurries. A simple explicit equation replacing shear rate to the volumetric flow rate in a pipe or annulus can be derived from Eq. 4. As an pipe or annulus can be derived from Eq. 4. As an added feature, the values of the constants characterize the fluid. Thus, it can be seen that when B = 1.0 and C = 0, Eq. 4 becomes.T = A y, ...................................(5) which describes the flow properties of a Newtonian fluid. When B = 1.0 and C 0, the fluid is a Bingham plastic, as described in Eq. 1. When B 1.0 and plastic, as described in Eq. 1. When B 1.0 and C = 0, the fluid follows the power law model, as shown in Eq. 2. The parameters A and B can be considered similarly to the parameters of the power law model. However, the third parameter, C, has a somewhat different connotation than the yield stress of the Bingham model. SPEJ P. 31


2009 ◽  
Vol 52 (6) ◽  
pp. 1541-1553 ◽  
Author(s):  
Dayane Rosalyn Izidoro ◽  
Agnes de Paula Scheer ◽  
Maria-Rita Sierakowsk

In this work, the rheological behaviour of emulsions (mayonnaises) stabilized by green banana pulp using the response surface methodology was studied. In addition, the emulsions stability was investigated. Five formulations were developed, according to design for constrained surfaces and mixtures, with the proportion, respectively: water/soy oil/green banana pulp: F1 (0.10/0.20/0.70), F2 (0.20/0.20/0.60), F3 (0.10/0.25/0.65), F4 (0.20/0.25/0.55) and F5 (0.15/0.225/0.625) .Emulsions rheological properties were performed with a rotational Haake Rheostress 600 rheometer and a cone and plate geometry sensor (60-mm diameter, 2º cone angle), using a gap distance of 1mm. The emulsions showed pseudoplastic behaviour and were adequately described by the Power Law model. The rheological responses were influenced by the difference in green banana pulp proportions and also by the temperatures (10 and 25ºC). The formulations with high pulp content (F1 and F3) presented higher shear stress and apparent viscosity. Response surface methodology, described by the quadratic model,showed that the consistency coefficient (K) increased with the interaction between green banana pulp and soy oil concentration and the water fraction contributed to the flow behaviour index increase for all emulsions samples. Analysis of variance showed that the second-order model had not significant lack-of-fit and a significant F-value, indicating that quadratic model fitted well into the experimental data. The emulsions that presented better stability were the formulations F4 (0.20/0.25/0.55) and F5 (0.15/0.225/0.625).


Author(s):  
Arild Saasen ◽  
Jan David Ytrehus

Abstract The most common viscosity models used in the drilling industry are the Bingham, the Power-Law and the Herschel-Bulkley models. The scope of the present paper is to outline how to select the individual models, and how the models need to be re-formulated to be able to have parameters with a physical meaning. In principle, the Bingham model itself have physical parameters being the yield point and the plastic viscosity. However, the Bingham model very often only very poorly describe the viscosity in complex fluids. This yield stress can be described within a reasonable accuracy by application of the low-shear yield point. A similar problem exists with the Power-Law model resulting from the model’s absence of a yield stress. The compromise model is the Herschel-Bulkley model which contains a yield stress and a power-law term. This model describes the drilling fluid viscosity with reasonable accuracy and includes both the Bingham and Power-Law models as limit formulations. It is not possible to select fluids based on the Herschel-Bulkley traditional parameters alone. The reason is that the Herschel-Bulkley power-law term’s viscosity parameter has a unit dependent on its power-law exponent. In the present approach the fluid is described using a yield stress, a surplus stress at a characteristic shear rate of the fluid flow and finally a power-law exponent making the fluid applicable in the practical shear rate ranges. The surplus stress is no-longer dependent on other parameters. Hence, we have re-arranged the viscosity model to have independent measurable quantities.


2019 ◽  
Vol 29 (1) ◽  
pp. 80-93 ◽  
Author(s):  
Liuhua Yang ◽  
Hongjiang Wang ◽  
Aixiang Wu ◽  
Hong Li ◽  
Arlin Bruno Tchamba ◽  
...  

Abstract Cemented paste backfill (CPB) is considered to be a concentrated suspension in which tailings are bonded together by the hydraulic binder and water, and it has a high solid volume concentration (≥50 vol.%). Although the shear thinning and thickening of CPB has been extensively reported in literature, the shear history effects have been ignored in previous studies. In this paper, by using rheometer and Focused Beam Reflectance Measurement, the relationship between the rheological properties and microstructure of the paste under different shear histories was studied. The results have shown that at a low shear rate, CPB revealed shear thinning, low yield stress and low index parameters; while exhibited shear thickening, high yield stress and high consistency index when at high shear rates of shear history. This agreed with the general trends shown in the FBRM analysis. It was proposed that the action of shear is beneficial to particle dispersion, whereas a high shear rate history tends to promote the aggregation of particles. It was revealed that both shear thinning and thickening of paste are related to the situation of particles (flocculation, dispersion and aggregation), and shear history effects play an important role in rheological properties of CPB.


2019 ◽  
Vol 11 (1) ◽  
pp. 89-100
Author(s):  
K. Begum ◽  
M. A. Islam

The rheological properties of melt jute fiber reinforced polypropylene (PP) composites were conducted at constant shear stress. The measured shear stress and shear rate data are fitted to a power law model for measuring stress-independent melt viscosity of the composites. The viscosity increased with the increase of fiber loading and decreased with the rise of temperature. The flow behavior index, n was found to decrease with the increase of fiber loading and increase with the rise of temperature. The shear stress and shear rate data collected from different specialized research journals have also been fitted to the power law model to measure the stress-independent melt viscosity and flow index as in all the previous literatures viscosity is treated as stress dependent parameter. It was found that the dependence of the viscosity and the flow index observed from previous literature data with fiber loading and temperature was quite consistent with the present study.


2016 ◽  
Vol 12 (3) ◽  
pp. 4322-4339
Author(s):  
Salah Hamza

Knowledge of rheological properties of polymer and their variation with temperature and concentration have been globally important for processing and fabrication of polymers in order to make useful products. Basheer et al. [1] investigated, experimentally, the changes in rheological properties of metallocene linear low density polyethylene (mLLDPE) solutions by using a rotational rheometer model AR-G2 with parallel plate geometry. Their work covered the temperature range from  to  and  concentration from  to . In this paper, we reconsider Basheer work to describe the rheological behavior of mLLDPE solutions and its dependence on concentration and temperature.Until now, several models have been built to describe the complex behavior of polymer fluids with varying degrees of success. In this article, Oldroyd 4-constant, Giesekus and Power law models were tested for investigating the viscosity of mLLDPE solution as a function of shear rate. Results showed that Giesekus and power law models provide the best prediction of viscosity for a wide range of shear rates at constant temperature and concentration. Therefore, Giesekus and power law models were suitable for all mLLDPE solutions while Oldroyd 4-constant model doesn't.A new proposed correlation for the viscosity of mLLDPE solutions as a function of shear rate, temperature and concentration has been suggested. The effect of temperature and concentration can be adequately described by an Arrhenius-type and exponential function respectively. The proposed correlation form was found to fit the experimental data adequately.


Author(s):  
Zurriye Yilmaz ◽  
Mehmet Dogan ◽  
Mahir Alkan ◽  
Serap Dogan

In the food industry, rheological properties, such as viscosity, shear rate, and shear stress, are the most important parameters required in the design of a technological process. Therefore, in this study, we determined the flow behavior and the time-dependent flow properties of Turkish Delight (TD) in the temperature range of 25-75°C using a capillar rheometer. The structure and thermal properties of TD were investigated by XRD and a simultaneous DTA/TG analysis. The shear rate values ranged from 5 to 300s-1. We found that: (i) TD behaved as non- Newtonian pseudoplastic foodstuff; (ii) while the measurement temperature increased, viscosity decreased; and (iii) TD was a rheopectic material. The effect of temperature on viscosity was described by means of the Arrhenius equation. The activation energies for the flow of pseudoplastic TD varied from 50.1-74.2 kJ/mol, depending on shear rate. Three models were used to predict the flow behavior of TD, namely, the Power law, Bingham and Casson models. The Power law model adequately described well the flow behavior of TD at different temperatures.


2013 ◽  
Vol 747 ◽  
pp. 627-630
Author(s):  
Watcharapong Chookaew ◽  
Yanichsa Sukniyom ◽  
Somjate Patcharaphun ◽  
Narongrit Sombatsompop

The influences of shear rate and vulcanizing system on the rheological properties and melt fracture of natural rubber compounds were investigated by using a rate-controlled capillary rheometer. The rheological properties of rubber compounds were characterized with respect to the apparent viscosity and extrudate swell. The measured results indicated that the apparent viscosity tended to decrease with increasing shear rate. This was due to the pseudoplastic behavior of molten rubber compound. It was evident that rubber compound using EV system showed the lowest apparent viscosity as compared to those obtained by CV and NS systems, respectively. This was due to the occurrences of premature crosslink at the skin layer and the wall slip of rubber compound during the flow in capillary die. Furthermore, the onset of smooth surface was also observed which depending on the types of crosslink at the skin layer.


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