scholarly journals Effect of chemical composition on corrosion resistance of zircaloy fuel cladding tube for BWR.

Author(s):  
Masahisa INAGAKI ◽  
Kimihiko AKAHORI ◽  
Jirou KUNIYA ◽  
Isao MASAOKA ◽  
Masateru SUWA ◽  
...  
Author(s):  
G. A. Kunitsin ◽  
А. А. Pridein ◽  
O. V. Samokhina ◽  
D. V. Nizhel’skii ◽  
E. M. Gitman

At present decreasing of costs and increasing of efficiency are the most priority directions in any industry. Developing in this way, JSC “Ural steel” together with FGUP “CNIIchermet after I.P. Barding” had mastered production of sheet metal product with increased resistivity against atmosphere corrosion made of steel 14ХГНДЦ for construction of bridges. Because of specific chemical composition of the steel, in the process of metal structures running in the open air, a solid strong oxide film is formed on the metal of the structures which prevents further corrosion without painting. For bridge builders elimination of costly operation of painting of span structures will enable to decrease considerably the costs of bridges construction and running. Having many advantages, steel 14ХГНДЦ has some restrictions in applications for steel structures without painting, as follows: - in sea zone according to domestic norms no close than 500 m from coastline; - in case of disorderly conditions of protective film formation and/or application of salt solutions for surface cleaning (as a rule the restrictions refer to traffic area of bridge span). In view of that for JSC “Ural Steel”, as the leading producer of bridge steel in Russia, an actual task erose: to elaborate and create a weatherproof steel, which could not only operate the whole period of a bridge running without additional protection at bridges con­struction through sea areas or close to coastline, but also withstand severe climate conditions of our country, including areas of High North with temperature lower -50°С. To solve the task together with OJSC “Institute Giprostroymost” and JSC BNIIZhT, a research work was accomplished to elaborate a system of alloying new steel 06ГН3МД with nickel content ~3.0 %, as well as production modes ensuring required corrosion resistance for operation in sea zone. Results of laboratory studies of the new weatherproof steel 06ГН3МД for application in bridge  structures for coastal conditions and sea areas presented. Results of mechanical, technological, corrosion as well as fatigue tests of rolling products of the elaborated steel presented. It was established by laboratory studies that the new steel is weatherproofed and ensures lower corrosion losses, higher impact toughness at negative temperatures and plasticity comparing with steels used at present. It was shown that the strength class, technology and modes of factory welding of steel 06ГН3МД meet the  requirements to steel span structures of bridges. Base on the results of the studies, the chemical composition of the steel 06ГН3МД was specified, as well as modes of heat treatment, ensuring the required characteristics with significant acceding. It was established that samples of the new steel 06ГН3МД showed considerably higher corrosion resistance - in average by 20% comparing with steel 14ХГНДЦ. At that corrosion resistance tests of welded joints of the new steel showed even higher resistance of the seam comparing with the basic metal, which speaks about quality selection of welding modes and welding materials.


2017 ◽  
Vol 8 (5) ◽  
pp. 544-564
Author(s):  
Argyro Drakakaki ◽  
Charis Apostolopoulos ◽  
Alexandros Katsaounis ◽  
Hasa Bjorn

Purpose Corrosive agent constitutes a major problem for constructions located in coastal areas, since it keeps affecting their durability. This phenomenon, in synergy with moisture and high temperatures, leads to premature deterioration of the structures. Under these conditions, the need for management of the problem of resistance of steel against corrosion is an issue of paramount importance and a challenge to the structural integrity and reliability. The paper aims to discuss these issues. Design/methodology/approach The need for management of the problem of resistance of steel against corrosion is an issue of paramount importance and a challenge to the structural integrity and reliability. In the present study, an effort was made to increase the corrosion resistance of the high strength and ductility dual-phase steel B500c category, with the use of different shot blasting processes, without any interference in the chemical composition or in the production mode. In particular, shot blasting treatment was used for both cleaning and creating compressive stresses on the surface of steel bars, according to the pertinent protocols. The modified samples were studied via both conventional characterization methods and electrochemical techniques. Findings Through the whole surface treatment process of B500c steel, a positive impact came about not only the corrosion resistance, but also the mechanical performance. Originality/value Shot blasting process aims to increase the corrosion resistance of high ductility dual-phase steel (B500c), without any interference in the chemical composition or in the production mode.


2019 ◽  
Vol 63 (2) ◽  
pp. 328-332 ◽  
Author(s):  
Ákos Horváth ◽  
Attila R. Imre ◽  
György Jákli

The Supercritical Water Cooled Reactor (SCWR) is one of the Generation IV reactor types, which has improved safety and economics, compared to the present fleet of pressurized water reactors. For nuclear applications, most of the traditional materials used for power plants are not applicable, therefore new types of materials have to be developed. For this purpose corrosion tests were designed and performed in a supercritical pressure autoclave in order to get data for the design of an in-pile high temperature and high-pressure corrosion loop. Here, we are presenting some results, related to corrosion resistance of some potential structural and fuel cladding materials.


2020 ◽  
Vol 66 (3) ◽  
pp. 139-148
Author(s):  
Maja Vončina ◽  
Peter Cvahte ◽  
Ana Kračun ◽  
Tilen Balaško ◽  
Jožef Medved

AbstractThe alloys from Al–Mg–Si system provide an excellent combination of mechanical properties, heat treatment at extrusion temperature, good weldability, good corrosion resistance and formability. Owing to the high casting speed of rods or slabs, the solidification is rather non-equilibrium, resulting in defects in the material, such as crystalline segregations, the formation of low-melting eutectics, the unfavourable shape of intermetallic phases and the non-homogeneously distributed alloying elements in the cross-section of the rods or slabs and in the entire microstructure. The inhomogeneity of the chemical composition and the solid solution negatively affects the strength, the formability in the warm and the corrosion resistance, and can lead to the formation of undesired phases due to segregation in the material. In this experimental investigation, the cross-sections of the rods from two different alloys of the 6xxx group were investigated. From the cross-sections of the rods, samples for differential scanning calorimetry (DSC) at three different positions (edge, D/4 and middle) were taken to determine the influence of inhomogeneity on the course of DSC curve. Metallographic sample preparation was used for microstructure analysis, whereas the actual chemical composition was analysed using a scanning electron microscope (SEM) and an energy dispersion spectrometer (EDS).


Metals ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1658
Author(s):  
Xiaochen Zhang ◽  
Zhijuan Yin ◽  
Bateer Buhe ◽  
Jiajie Wang ◽  
Lin Mao ◽  
...  

The effect of temperature on the corrosion resistance of layered double hydroxide (LDH) conversion coatings on AZ91D magnesium alloy, based on a closed-cycle system, was investigated. Scanning electron microscopy (SEM), photoelectron spectroscopy (XPS), and X-ray diffractometry (GAXRD) were used to study the surface morphology, chemical composition, and phase composition of the conversion coating. The corrosion resistance of the LDH conversion coating was determined through electropotentiometric polarisation curve and hydrogen evolution and immersion tests. The results showed that the conversion coating has the highest density and a more uniform, complete, and effective corrosion resistance at 50 °C. The chemical composition of the LDH conversion coating mainly comprises C, O, Mg, and Al, and the main phase is Mg6Al2(OH)16CO3·4H2O.


2020 ◽  
Vol 405 ◽  
pp. 245-250
Author(s):  
Martin Juliš ◽  
Lenka Klakurková ◽  
Pavel Gejdoš

For the corrosion resistance analysis of the heat exchanger plates (made of AISI 316L steel) the samples with visible damage was delivered. The major part of the surface damages was located at the place of "close proximity" (or surface contact) of individual plates. Some of delivered samples showed an unequal layers of sediments, which indicating a different flow velocities of operating fluid through the plates. At locations of the upper part of the plates with no sedimentation (high velocity flow), the most surface damage was detected in "near contact" areas as well as outside. On the other hand, the area of the lower part of the plates, where the sediment deposition was massive (lowest velocity flow), was observed the smallest surface damage. The results of the chemical composition analyses showed a lower amount of molybdenum and a higher amount of phosphorus in case of all samples. The contents of the key elements necessary for the corrosion resistance (chromium and nickel) were only just above the lower limit of the prescribed chemical composition interval. For detailed study of surface damage, selected defects were observed and documented using scanning electron microscopy. Localized damage showed intercrystalline failure of material with typical surface morphology degraded as a result of cavitation damage under hydrodynamic stress.


2019 ◽  
Vol 97 (5) ◽  
pp. 230-236
Author(s):  
G. P. da Silva ◽  
R. N. de Lima ◽  
F. J. N. Santos ◽  
F. P. S. de Menezes ◽  
L. P. L. Morais ◽  
...  

2015 ◽  
Vol 227 ◽  
pp. 523-526 ◽  
Author(s):  
Anita Kajzer ◽  
Wojciech Kajzer ◽  
Jacek Semenowicz ◽  
Adam Mroczka

The aim of the paper was to compare physicochemical features of hip joint cups coated with hydroxyapatite in the initial state and after period of 36 months of implantation. The cups we produced from stainless steel Cr-Ni-Mo with increased content of azote dedicated to implants which chemical composition is compatible with recommended ISO 5832-9 standards. On the basis of obtained results it can be stated that hydroxyapatite resorption did not affect equally the entire surface of the cup. It was also stated that tested biomaterial of the cup was well wetted (hydrophilic). For all the tested samples prepared from cups in the initial state and cups after the implantation the presence of transpassivation potential Etr was stated, which proves not only good corrosion resistance but also biocompatibility of analyzed cups.


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