scholarly journals SPIN-CROSSOVER IRON(II) COORDINATION COM­POUNDS: FABRICATION OF FUNCTIONAL MATERIALS AND THEIR INTEGRATION INTO MICRO- AND NANOCONSTRUCTIONS

2021 ◽  
Vol 87 (11) ◽  
pp. 3-20
Author(s):  
Volodymyr Hiiuk ◽  
Iurii Suleimanov ◽  
Igor Fritsky

Development of micro- and nanosized spin-crossover (SCO) materials has become an important research direction within the past decade. Such an interest is associated with high perceptive of practical application of these materials in nanoelectronic devices. Therefore, researches working in the field of SCO put considerable efforts to obtain SCO complexes in various functional forms, such as nanoparticles, thin films, etc. Fabrication of these materials is realized through different chemical and/or lithographical approaches, which allow to adjust size, shape and even organization of nanoobjects. In this review theoretical background of SCO phenomenon is described, additionally different classes of coordination compounds exhibiting spin crossover are covered. It is demonstrated that electric field, temperature and light irradiation can be effectively used for switching and control of spin state in nanosized SCO systems. Cooperative SCO with transition close to room temperature, wide hysteresis loop and distinct thermochromic effect is most often observed for Fe(II) coordination complexes. Therefore, Fe(II) SCO compounds form one of the most perspective classes of compounds for obtaining functional materials. It is shown that integration of Fe(II) compounds into micro- and nanohybrid devi­ces allows to combine unique functional pro­perties in one material due to synergy between SCO and physical properties (luminescent, electrical, etc.) of the other component. As a result, SCO compounds are interesting not only from the fundamental point of view, but also from practical, thanks to the possibility of integration of SCO Fe(II) complexes as active materials in devices of different configurations. It is expected that obtaining of new Fe(II) coordination polymers with unique SCO cha­racteristics will favor the development of new functional materials and devices on their basis in the nearest future.

2014 ◽  
Vol 644-650 ◽  
pp. 1223-1226
Author(s):  
Jin Yao

Piezoelectric smart structure is chosen as the piezoelectric material sensing and driving elements, and control system combine to form a structure with identification, analysis, judgment, action, and other functions. The active vibration control for structures is an important research direction.


Author(s):  
T. E. Mitchell ◽  
M. R. Pascucci ◽  
R. A. Youngman

1. Introduction. Studies of radiation damage in ceramics are of interest not only from a fundamental point of view but also because it is important to understand the behavior of ceramics in various practical radiation enyironments- fission and fusion reactors, nuclear waste storage media, ion-implantation devices, outer space, etc. A great deal of work has been done on the spectroscopy of point defects and small defect clusters in ceramics, but relatively little has been performed on defect agglomeration using transmission electron microscopy (TEM) in the same kind of detail that has been so successful in metals. This article will assess our present understanding of radiation damage in ceramics with illustrations using results obtained from the authors' work.


2015 ◽  
Vol 52 (2) ◽  
pp. 221-232
Author(s):  
Pál Dömösi ◽  
Géza Horváth

In this paper we introduce a novel block cipher based on the composition of abstract finite automata and Latin cubes. For information encryption and decryption the apparatus uses the same secret keys, which consist of key-automata based on composition of abstract finite automata such that the transition matrices of the component automata form Latin cubes. The aim of the paper is to show the essence of our algorithms not only for specialists working in compositions of abstract automata but also for all researchers interested in cryptosystems. Therefore, automata theoretical background of our results is not emphasized. The introduced cryptosystem is important also from a theoretical point of view, because it is the first fully functioning block cipher based on automata network.


2019 ◽  
pp. 37-47
Author(s):  
Yao Yueqin ◽  
Oleksiy Kozlov ◽  
Oleksandr Gerasin ◽  
Galyna Kondratenko

Analysis and formalization of the monitoring and automatic control tasks of the MR for the movement and execution of various types of technological operations on inclined and vertical ferromagnetic surfaces are obtained. Generalized structure of mobile robotic complex is shown with main subsystems consideration. Critical analysis of the current state of the problem of development of universal structures of mobile robots (MRs) for the various types of technological operations execution and elaborations of computerized systems for monitoring and control of MR movement is done. In particular, wheeled, walked and crawler type MRs with pneumatic, vacuum-propeller, magnetic and magnetically operated clamping devices to grip with vertical and ceiling surfaces are reviewed. The constructive features of the crawler MR with magnetic clamping devices capable of moving along sloping ferromagnetic surfaces are considered. The basic technical parameters of the MR are shown for the further synthesis of computerized monitoring and automatic control systems. Formalization of the tasks of monitoring and control of the MR positioning at the processing of large area ferromagnetic surfaces is considered from the point of view of control theory.


Author(s):  
B. A. Katsnelson ◽  
M. P. Sutunkova ◽  
N. A. Tsepilov ◽  
V. G. Panov ◽  
A. N. Varaksin ◽  
...  

Sodium fluoride solution was injected i.p. to three groups of rats at a dose equivalent to 0.1 LD50 three times a week up to 18 injections. Two out of these groups and two out of three groups were sham-injected with normal saline and were exposed to the whole body impact of a 25 mT static magnetic field (SMF) for 2 or 4 hr a day, 5 times a week. Following the exposure, various functional and biochemical indices were evaluated along with histological examination and morphometric measurements of the femur in the differently exposed and control rats. The mathematical analysis of the combined effects of the SMF and fluoride based on the a response surface model demonstrated that, in full correspondence with what we had previously found for the combined toxicity of different chemicals, the combined adverse action of a chemical plus a physical agent was characterized by a tipological diversity depending not only on particular effects these types were assessed for but on the dose and effect levels as well. From this point of view, the indices for which at least one statistically significant effect was observed could be classified as identifying (I) mainly single-factor action; (II) additive unidirectional action; (III) synergism (superadditive unidirectional action); (IV) antagonism, including both subadditive unidirectional action and all variants of contradirectional action.


Author(s):  
Wei Jia ◽  
Wei Xia ◽  
Yang Zhao ◽  
Hai Min ◽  
Yan-Xiang Chen

AbstractPalmprint recognition and palm vein recognition are two emerging biometrics technologies. In the past two decades, many traditional methods have been proposed for palmprint recognition and palm vein recognition and have achieved impressive results. In recent years, in the field of artificial intelligence, deep learning has gradually become the mainstream recognition technology because of its excellent recognition performance. Some researchers have tried to use convolutional neural networks (CNNs) for palmprint recognition and palm vein recognition. However, the architectures of these CNNs have mostly been developed manually by human experts, which is a time-consuming and error-prone process. In order to overcome some shortcomings of manually designed CNN, neural architecture search (NAS) technology has become an important research direction of deep learning. The significance of NAS is to solve the deep learning model’s parameter adjustment problem, which is a cross-study combining optimization and machine learning. NAS technology represents the future development direction of deep learning. However, up to now, NAS technology has not been well studied for palmprint recognition and palm vein recognition. In this paper, in order to investigate the problem of NAS-based 2D and 3D palmprint recognition and palm vein recognition in-depth, we conduct a performance evaluation of twenty representative NAS methods on five 2D palmprint databases, two palm vein databases, and one 3D palmprint database. Experimental results show that some NAS methods can achieve promising recognition results. Remarkably, among different evaluated NAS methods, ProxylessNAS achieves the best recognition performance.


2020 ◽  
pp. 1-14
Author(s):  
Longjie Li ◽  
Lu Wang ◽  
Hongsheng Luo ◽  
Xiaoyun Chen

Link prediction is an important research direction in complex network analysis and has drawn increasing attention from researchers in various fields. So far, a plethora of structural similarity-based methods have been proposed to solve the link prediction problem. To achieve stable performance on different networks, this paper proposes a hybrid similarity model to conduct link prediction. In the proposed model, the Grey Relation Analysis (GRA) approach is employed to integrate four carefully selected similarity indexes, which are designed according to different structural features. In addition, to adaptively estimate the weight for each index based on the observed network structures, a new weight calculation method is presented by considering the distribution of similarity scores. Due to taking separate similarity indexes into account, the proposed method is applicable to multiple different types of network. Experimental results show that the proposed method outperforms other prediction methods in terms of accuracy and stableness on 10 benchmark networks.


Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 650
Author(s):  
Jose Maria Alonso ◽  
Jon Andrade del Olmo ◽  
Raul Perez Gonzalez ◽  
Virginia Saez-Martinez

The transfer of some innovative technologies from the laboratory to industrial scale is many times not taken into account in the design and development of some functional materials such as hydrogels to be applied in the biomedical field. There is a lack of knowledge in the scientific field where many aspects of scaling to an industrial process are ignored, and products cannot reach the market. Injectable hydrogels are a good example that we have used in our research to show the different steps needed to follow to get a product in the market based on them. From synthesis and process validation to characterization techniques used and assays performed to ensure the safety and efficacy of the product, following regulation, several well-defined protocols must be adopted. Therefore, this paper summarized all these aspects due to the lack of knowledge that exists about the industrialization of injectable products with the great importance that it entails, and it is intended to serve as a guide on this area to non-initiated scientists. More concretely, in this work, the characteristics and requirements for the development of injectable hydrogels from the laboratory to industrial scale is presented in terms of (i) synthesis techniques employed to obtain injectable hydrogels with tunable desired properties, (ii) the most common characterization techniques to characterize hydrogels, and (iii) the necessary safety and efficacy assays and protocols to industrialize and commercialize injectable hydrogels from the regulatory point of view. Finally, this review also mentioned and explained a real example of the development of a natural hyaluronic acid hydrogel that reached the market as an injectable product.


2001 ◽  
Vol 10 (3) ◽  
pp. 312-330 ◽  
Author(s):  
Bernard Harper ◽  
Richard Latto

Stereo scene capture and generation is an important facet of presence research in that stereoscopic images have been linked to naturalness as a component of reported presence. Three-dimensional images can be captured and presented in many ways, but it is rare that the most simple and “natural” method is used: full orthostereoscopic image capture and projection. This technique mimics as closely as possible the geometry of the human visual system and uses convergent axis stereography with the cameras separated by the human interocular distance. It simulates human viewing angles, magnification, and convergences so that the point of zero disparity in the captured scene is reproduced without disparity in the display. In a series of experiments, we have used this technique to investigate body image distortion in photographic images. Three psychophysical experiments compared size, weight, or shape estimations (perceived waist-hip ratio) in 2-D and 3-D images for the human form and real or virtual abstract shapes. In all cases, there was a relative slimming effect of binocular disparity. A well-known photographic distortion is the perspective flattening effect of telephoto lenses. A fourth psychophysical experiment using photographic portraits taken at different distances found a fattening effect with telephoto lenses and a slimming effect with wide-angle lenses. We conclude that, where possible, photographic inputs to the visual system should allow it to generate the cyclopean point of view by which we normally see the world. This is best achieved by viewing images made with full orthostereoscopic capture and display geometry. The technique can result in more-accurate estimations of object shape or size and control of ocular suppression. These are assets that have particular utility in the generation of realistic virtual environments.


2011 ◽  
Vol 335-336 ◽  
pp. 419-422 ◽  
Author(s):  
Yuan Lian ◽  
Jian Yi Wu ◽  
Da Peng Zhou ◽  
Hong Mei Wang ◽  
Dian Wu Huang ◽  
...  

Alginate fibre has attracted great attention in the area of biological medical materials due to its unique biological properties. But its low tenacity greatly hinders its application area. Therefore, the preparation technology of alginate fibre has been as an important research direction in this area in recent years. The purpose of this article is to prepare the calcium alginate fibre with good properties by wet spinning. The structure and properties of this fibre are analyzed by scanning electron microscope,infrared spectrometer,thermal gravimetric analyzer and DSC.


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