scholarly journals Synthesis of Graphene Oxide Enhanced Agar Composites: A Biocompatible Photo-catalyst for Degradation of Organic Dyes

2020 ◽  
Vol 17 (3) ◽  
pp. 29-40
Author(s):  
Shreyas Dindorkar ◽  
Jaymin Mistry ◽  
Jayesh Hire ◽  
Khushi Jain ◽  
Nandini Khona ◽  
...  

Herein we report the synthesis of graphene oxide-based agar composites using a solution casting method. Graphene oxide was synthesized by modified Hummer’s method and was characterized using X-ray diffraction (XRD) and Raman spectroscopy. The graphene oxide-based agar composites were characterized using X-ray diffraction (XRD) and UV-visible spectroscopy. Optical band gap obtained from the Tauc plot showed that the composites could be used in the photodegradation of dyes. The synthesized composite material was checked for its practical applicability in the degradation of methylene blue dye under solar irradiation; with an increase in the concentration of graphene oxide, catalyst, and H2O2, the rate constant increases. The rate constant was found to be inversely proportional to the concentration of methylene blue dye. Dosage of graphene oxide was found to be the most prominent factor in increasing the rate of photodegradation. It is clear from the data for the reaction system that the degradation reaction follows pseudo-first-order kinetics. Keywords: Composites; Ultra-sonication; Photodegradation; Methylene Blue; XRD; Graphene Oxide; Kinetics; Biocompatibility

Author(s):  
Sridharan Balu ◽  
Kasimayan Uma ◽  
Guan-Ting Pan ◽  
Thomas C.-K. Yang ◽  
Sayee Kannan Ramaraj

Semiconductor materials have been shown to have better photocatalytic behavior and can be utilized for the photodegradation of organic pollutants. In this work, three-dimensional flower-like SnS2 were synthesized by a facile hydrothermal method. Core-shell structured SiO2@α-Fe2O3 nanocomposites were then deposited on the top of the SnS2 flowers. The as-synthesized nanocomposites were characterized by X-ray diffraction (XRD), Raman spectroscopy, field emission scanning electron microscopy (FE-SEM), Brunauer-Emmett-Teller (BET) and photoluminescence spectroscopy (PL). The photocatalytic behavior of the SnS2-SiO2@α-Fe2O3 nanocomposites was observed by observing the degradation of methylene blue (MB). The results show an effective enhancement of photocatalytic activity for the degradation of MB especially for the 15 wt. % SiO2@α-Fe2O3 nanocomposites on SnS2 flowers.


2014 ◽  
Vol 970 ◽  
pp. 29-32 ◽  
Author(s):  
Pongsaton Amornpitoksuk ◽  
Sumetha Suwanboon

The co-effect of PO43- and I- on the formation of a heterosturucture photocatalyst in the Ag3PO4-AgI system was studied by the co-precipitation method between AgNO3 and the precipitating agent. The precipitating agent was prepared by varying the mole ratios between Na2HPO4 and KI. At 10 mol.% KI, the product showed the mixed phase between Ag3PO4 and un-identified phase. For 30 - 90 mol.% KI, the un-identified phase and AgI were detected in the x-ray diffraction patterns. The un-identified phase strongly adsorbed the methylene blue dye. The product prepared from 30 mol.% KI had the highest content of un-identified phase and also showed the highest degree of decolorization in the dark. The photocatalytic properties of products in this system were confirmed by the decolorization of methylene blue under visible illumination.


2010 ◽  
Vol 10 (1) ◽  
pp. 20-25 ◽  
Author(s):  
Aarti Ameta ◽  
Indu Bhati ◽  
Rakshit Ameta ◽  
Suresh C. Ameta

The photocatalytic degradation of methylene blue dye under visible light has been investigated using chromium modified titanium dioxide supported on zeolite (Cr-TiO2/zeolite). The photocatalyst was prepared by sol-gel method and characterized by X-ray diffraction and SEM. The rate of photodegradation of dye was monitored spectrophotometrically. The effect of pH, dye concentration, amount of photocatalyst and intensity of light on the rate of photocatalytic reaction was observed. The results showed that the use of Cr-doped TiO2 increased the rate of photocatalytic degradation of methylene blue as compared to untreated TiO2. The photocatalytic mechanism of Cr-TiO2 catalyst has been tentatively discussed.   Keywords: Methylene blue, zeolite, chromium, photocatalytic degradation


2011 ◽  
Vol 335-336 ◽  
pp. 1508-1511
Author(s):  
Shu Kai Zheng

Transparent TiO2 thin films were deposited onto microscope glass slides by means of d.c. magnetron sputtering method. In order to enhance the photocatalytic activity of TiO2 thin films, Mo ions with different nominal doses were implanted into the TiO2 thin films. The samples were characterized by different technologies including X-ray diffraction (XRD), X-ray photoelectron spectroscope (XPS) and UV-VIS-NIR spectrophotometer. The photodegradation results of methylene blue dye solution indicated that optimal dose of 2×1012ions/cm2 Mo ion-implantation resulted in a higher photocatalytic activity in the implanted TiO2 thin films.


2003 ◽  
Vol 21 (5) ◽  
pp. 451-462 ◽  
Author(s):  
Sameer Al-Asheh ◽  
Fawzi Banat ◽  
Leena Abu-Aitah

An improvement in the adsorption capacity of naturally available bentonite towards water pollutants such as Methylene Blue dye (MBD) is certainly needed. For this purpose, sodium bentonite was activated by two methods: (1) treatment with sodium dodecyl sulphate (SDS) as an ionic surfactant and (2) thermal treatment in an oven operated at 850°C. Batch adsorption tests were carried out on removing MBD from aqueous solution using the above-mentioned bentonites. It was found that the effectiveness of bentonites towards MBD removal was in the following order: thermal-bentonite > SDS-bentonite > natural bentonite. X-Ray diffraction analysis showed that an increase in the microscopic bentonite platelets on treatment with SDS was the reason behind the higher uptake of MBD. An increase in sorbent concentration or initial pH value of the solutions resulted in a greater removal of MBD from the solution. An increase in temperature led to an increase in MBD uptake by the bentonites studied in this work. The Freundlich isotherm model was employed and found to represent the experimental data well.


2019 ◽  
Vol 487 ◽  
pp. 539-549 ◽  
Author(s):  
Mohamed Mokhtar Mohamed ◽  
Mohamed A. Ghanem ◽  
Mohamed Khairy ◽  
Eman Naguib ◽  
Nouf H. Alotaibi

2020 ◽  
Vol 309 ◽  
pp. 113171 ◽  
Author(s):  
Mehmet Harbi Calimli ◽  
Mehmet Salih Nas ◽  
Hakan Burhan ◽  
Sibel Demiroglu Mustafov ◽  
Özkan Demirbas ◽  
...  

2017 ◽  
Vol 751 ◽  
pp. 825-830 ◽  
Author(s):  
Phuri Kalnaowakul ◽  
Tonghathai Phairatana ◽  
Aphichart Rodchanarowan

In this study, the photocatalytic properties and morphology of TiO2, ZnO, Ag-graphene-zinc oxide (Ag-G-ZnO) and Ag-graphene-titanium dioxide (Ag-G-TiO2) nanocomposite were compared. The Ag-G-ZnO and Ag-G-TiO2 nanocomposite were successfully prepared by thermal decomposition of colloidal solution. These prepared composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), UV-Vis spectroscopy and photocatalytic activities. The results from XRD patterns show that Ag-G-TiO2 composites and the Ag-G-ZnO nanocomposites were in the form of fcc and hcp crystal structure, respectively. The SEM images show that at calcination of 500 °C for 3 h, the composite thin film of Ag-G-ZnO and Ag-G-TiO2 were homogenous. In the case of the photocatalytic experiments using methylene blue dye (MB) under UV irradiation, the order of the photocatalytic activities from high to low performances are Ag-G-ZnO, Ag-G-TiO2, ZnO and TiO2, respectively.


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