Геннадий Тимофеевич Земский
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Владимир Александрович Зуйков
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Александр Валерьевич Ильичев
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Наталья Валентиновна Кондратюк
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Александр Владимирович Зуйков
Возможность взрыва паровоздушной смеси при аварийном проливе жидкости из технологического аппарата во многом зависит от интенсивности испарения жидкости. Для определения интенсивности испарения существуют уравнения, в которые входят величины, характеризующие свойства жидкости, условия ее нахождения в аппарате перед аварией и условия, в которые попадает выливающаяся жидкость. Критически рассмотрены известные уравнения для определения интенсивности испарения, начиная от уравнения Ленгмюра - Кнудсена и заканчивая уравнениями, вошедшими в нормативные документы по обеспечению пожарной безопасности. Рассмотрены варианты аварийного пролива пожароопасных жидкостей в зависимости от сочетания следующих температур: температуры кипения жидкости, температуры вспышки жидкости, температуры жидкости до пролива и температуры окружающей среды.
The possibility of an explosion of a steam-air mixture in the event of an emergency spillage of liquid from the process apparatus largely depends on the liquid evaporation intensity. The evaporation intensity is influenced by the following factors: the properties of the liquid (such as critical parameters, liquid temperature, saturated vapor pressure, flash point) as well as the temperature and pressure of the surrounding atmosphere. To determine the intensity of evaporation there are equations that include values that characterize the properties of the liquid, the conditions of its presence in the device before the accident, and the conditions for the spilling liquid after the accident. There is critically considered the wide range of known equations for determining the evaporation intensity beginning with the Langmuir-Knudsen equation and ending with the equations included in the normative documents on fire safety. The Langmuir-Knudsen equation is valid when liquid evaporation occurs in vacuum. When liquid vaporizes in real conditions it is necessary to take into account the non-isothermic nature of the process and the diffusion of vapors into the atmosphere, as well as the possible entrainment of vapors by convective air flows. After the appropriate corrections as a result of special tests there was obtained the equation for determining the evaporation rate. Variants of emergency spillage of fire-hazardous liquids are considered depending on a combination of the following temperatures: the boiling temperature of the liquid, the flash temperature of the liquid, the temperature of the liquid before the spill and the ambient temperature. Equations for calculating the evaporation intensity are defined for every variant. There is carried out correlation of the variants with liquid evaporation during emergency spill with the classification of liquids according to the state diagram in relation to the range of ambient temperatures according to Marshall.