scholarly journals An Integrated Study of Water Weakening and Fluid Rock Interaction Processes in Porous Rocks: Linking Mechanical Behavior to Surface Properties

2021 ◽  
Vol 11 (23) ◽  
pp. 11437
Author(s):  
Davide Geremia ◽  
Christian David ◽  
Rachid Ismail ◽  
Alae El Haitami

We investigated the impact of water weakening on the mechanical behavior of Obourg Chalk and Ciply Chalk (Mons Basin, Belgium). Different mechanical tests were conducted to estimate the unconfined compressive strength (UCS), tensile strength, Young’s modulus, mechanical strength under triaxial loading, critical pressure, fracture toughness, cohesion, and internal friction coefficient on samples either dry or saturated with water or brine. This extensive dataset allowed us to calculate wet-to-dry ratios (WDR), i.e., the ratio between any property for a dry sample to that for the water-saturated sample. For both chalks, we found that water has a strong weakening effect with WDR ranging from 0.4 to 0.75. Ciply Chalk exhibits more water weakening than Obourg Chalk. The highest water weakening effect was obtained for UCS, critical pressure, and Young’s modulus. Weakening effects are still present in brine-saturated samples but their magnitude depends on the fluid composition. The mechanical data were correlated to variations in surface energy derived from three different methods: fracture mechanics, contact angle goniometry, and atomic force microscopy. Water weakening in the tested chalks can be explained by a clear reduction in surface energy and by the existence of repulsive forces which lower the cohesion.

2021 ◽  
Vol 138 (27) ◽  
pp. 50648 ◽  
Author(s):  
Roberto Yáñez‐Macías ◽  
Jorge E. Rivera‐Salinas ◽  
Silvia Solís‐Rosales ◽  
Daniel Orduña‐Altamirano ◽  
David Ruíz‐Mendoza ◽  
...  

2017 ◽  
Vol 19 (35) ◽  
pp. 23887-23897 ◽  
Author(s):  
Arzu Çolak ◽  
Jingjing Wei ◽  
Imad Arfaoui ◽  
Marie-Paule Pileni

The Young's modulus of three-dimensional self-assembled Ag nanocrystals, as so-called supracrystals, is correlated with the type of coating agent as well as the nanocrystal morphology.


2020 ◽  
Author(s):  
Jackie E. Kendrick ◽  
Lauren N. Schaefer ◽  
Jenny Schauroth ◽  
Andrew F. Bell ◽  
Oliver D. Lamb ◽  
...  

Abstract. Volcanoes represent one of the most critical geological settings for hazard modelling due to their propensity to both unpredictably erupt and collapse, even in times of quiescence. Volcanoes are heterogeneous at multiple scales, from porosity which is variably distributed and frequently anisotropic to strata that are laterally discontinuous and commonly pierced by fractures and faults. Due to variable and, at times, intense stress and strain conditions during and post-emplacement, volcanic rocks span an exceptionally wide range of physical and mechanical properties. Understanding the constituent materials' attributes is key to improving the interpretation of hazards posed by the diverse array of volcanic complexes. Here, we examine the spectrum of physical and mechanical properties presented by a single dome-forming eruption at a dacitic volcano, Mount Unzen (Japan) by testing a number of isotropic and anisotropic lavas in tension and compression and using monitored acoustic emission (AE) analysis. The lava dome was erupted as a series of 13 lobes between 1991–1995, and its ongoing instability means much of the volcano and its surroundings remain within an exclusion zone today. During a field campaign in 2015, we selected 4 representative blocks as the focus of this study. The core samples from each block span range in porosity from 9.14 to 42.81 %, and permeability ranges from 1.54 × 10−14 to 2.67 × 10−10 m2 (from 1065 measurements). For a given porosity, sample permeability varies by > 2 orders of magnitude is lower for macroscopically anisotropic samples than isotropic samples of similar porosity. An additional 379 permeability measurements on planar block surfaces ranged from 1.90 × 10−15 to 2.58 × 10−12 m2, with a single block having higher standard deviation and coefficient of variation than a single core. Permeability under confined conditions showed that the lowest permeability samples, whose porosity largely comprises microfractures, are most sensitive to effective pressure. The permeability measurements highlight the importance of both scale and confinement conditions in the description of permeability. The uniaxial compressive strength (UCS) ranges from 13.48 to 47.80 MPa, and tensile strength (UTS) using the Brazilian disc method ranges from 1.30 to 3.70 MPa, with crack-dominated lavas being weaker than vesicle-dominated materials of equivalent porosity. UCS is lower in saturated conditions, whilst the impact of saturation on UTS is variable. UCS is between 6.8 and 17.3 times higher than UTS, with anisotropic samples forming each end member. The Young's modulus of dry samples ranges from 4.49 to 21.59 GPa and is systematically reduced in water-saturated tests. The interrelation of porosity, UCS, UTS and Young's modulus was modelled with good replication of the data. Acceleration of monitored acoustic emission (AE) rates during deformation was assessed by fitting Poisson point process models in a Bayesian framework. An exponential acceleration model closely replicated the tensile strength tests, whilst compressive tests tended to have relatively high early rates of AEs, suggesting failure forecast may be more accurate in tensile regimes, though with shorter warning times. The Gutenberg-Richter b-value has a negative correlation with connected porosity for both UCS and UTS tests which we attribute to different stress intensities caused by differing pore networks. b-value is higher for UTS than UCS, and typically decreases (positive Δb) during tests, with the exception of cataclastic samples in compression. Δb correlates positively with connected porosity in compression, and negatively in tension. Δb using a fixed sampling length may be a more useful metric for monitoring changes in activity at volcanoes than b-value with an arbitrary starting point. Using coda wave interferometry (CWI) we identify velocity reductions during mechanical testing in compression and tension, the magnitude of which is greater in more porous samples in UTS but independent of porosity in UCS, and which scales to both b-value and Δb. Yet, saturation obscures velocity changes caused by evolving material properties, which could mask damage accrual or source migration in water-rich environments such as volcanoes. The results of this study highlight that heterogeneity and anisotropy within a single system not only add uncertainty but also have a defining role in the channelling of fluid flow and localisation of strain that dictate a volcano's hazards and the geophysical indicators we use to interpret them.


2020 ◽  
Vol 93 (4) ◽  
pp. 704-728
Author(s):  
Anil K. Bhowmick ◽  
Subhabrata Saha ◽  
Anshul Baral ◽  
Kumar Vineet ◽  
Arup S. Deuri ◽  
...  

ABSTRACT Aspects of penetration resistance of rubber compounds have been studied by developing a quasi-static test. The effects of indenter material and design, nature and dosage of fillers, and crosslinking density were investigated. Indenter material was found to have a negligible contribution to the penetration characteristics of the rubber compounds, whereas the conical indenter's shape and size of the tip were important. A change in the slope of the generalized penetration characteristic curve of the developed quasi-static test was considered to be the fracture initiation point. Although fracture initiation was early at higher carbon black loading, the overall penetration resistance was improved due to hysteresis, which was in accord with the impact energy method. This was a unique observation. The carbon black–filled sample was compared with the silica-filled vulcanizate. Surface morphology of the specimens penetrated at different energy levels was examined using scanning electron microscopy. A theoretical interpretation of the forces acting at the tip of the indenter and the energy requirement while penetrating a rubber compound against a conical indenter has been proposed. The initiation energy for penetration has inverse square root dependence on the Young's modulus of the compounds. The energy required for crack propagation in contrast, was directly proportional to the Young's modulus and also correlated with the hysteresis loss and frictional coefficient for the carbon black–filled vulcanizates.


2020 ◽  
Vol 2020 ◽  
pp. 1-11
Author(s):  
Wen-Jen Liu ◽  
Yung-Huang Chang ◽  
Sin-Liang Ou ◽  
Yuan-Tsung Chen ◽  
You-Cheng Liang ◽  
...  

In this study, a Co40Fe40W20 alloy was sputtered onto Si (100) with thicknesses (tf) ranging from 18 to 90 nm, and the corresponding structure, magnetic properties, adhesive characteristics, and nanomechanical properties were investigated. X-ray diffraction (XRD) patterns of the Co40Fe40W20 films demonstrated a significant crystalline body-centered cubic (BCC) CoFe (110) structure when the thickness was 42 nm, and an amorphous status was shown when the thickness was 18 nm, 30 nm, 60 nm, and 90 nm. The saturation magnetization (Ms) showed a saturated trend as tf was increased. Moreover, the coercivity (Hc) showed a minimum 1.65 Oe with 30 nm. Hc was smaller than 4.5 Oe owing to the small grain size distribution and amorphous structure, indicating that the Co40Fe40W20 film had soft magnetism. The low-frequency alternating current magnetic susceptibility (χac) decreased as the frequency was increased. The χac revealed a thickness effect when greater thicknesses had a large χac. The maximum χac and optimal resonance frequency (fres) of Co40Fe40W20 were investigated. The maximum χac indicated the spin sensitivity and was maximized at the optimal resonance frequency. The 90 mm thickness had the highest χac 0.18 value at an fres of 50 Hz. The contact angles of the Co40Fe40W20 films are less than 90°, which indicated that the film had a good wetting effect and hydrophilicity. The surface energy was correlated with the adhesion and displayed a concave-down trend. CoFeW films can be used as a seed or buffer layer; therefore, the surface energy and adhesion are very important. The highest surface energy was 30.12 mJ/mm2 at 42 nm and demonstrated high adhesion. High surface energy has corresponding strong adhesive performance. The increased surface roughness can induce domain wall pinning effect and high surface energy, causing a high coercivity and strong adhesion. The increase of hardness and Young’s modulus could be reasonably inferred from the thinner CoFeW films. The hardness and Young’s modulus of CoFeW films are also displayed to saturated tendency when increasing thickness.


2009 ◽  
Vol 131 (6) ◽  
Author(s):  
Huiyang Luo ◽  
Chenkai Dai ◽  
Rong Z. Gan ◽  
Hongbing Lu

The mechanical behavior of human tympanic membrane (TM) has been investigated extensively under quasistatic loading conditions in the past. The results, however, are sparse for the mechanical properties (e.g., Young's modulus) of the TM at high strain rates, which are critical input for modeling the mechanical response under blast wave. The property data at high strain rates can also potentially be converted into complex modulus in frequency domain to model acoustic transmission in the human ear. In this study, we developed a new miniature split Hopkinson tension bar to investigate the mechanical behavior of human TM at high strain rates so that a force of up to half of a newton can be measured accurately under dynamic loading conditions. Young’s modulus of a normal human TM is reported as 45.2–58.9 MPa in the radial direction, and 34.1–56.8 MPa in the circumferential direction at strain rates 300–2000 s−1. The results indicate that Young’s modulus has a strong dependence on strain rate at these high strain rates.


2018 ◽  
Vol 29 (20) ◽  
pp. 205706 ◽  
Author(s):  
Mohammad Reza Zamani Kouhpanji ◽  
Mahmoud Behzadirad ◽  
Daniel Feezell ◽  
Tito Busani

2015 ◽  
Vol 73 (3) ◽  
pp. 727-738 ◽  
Author(s):  
Marie Collard ◽  
Samuel P. S. Rastrick ◽  
Piero Calosi ◽  
Yoann Demolder ◽  
Jean Dille ◽  
...  

Abstract Increased atmospheric CO2 concentration is leading to changes in the carbonate chemistry and the temperature of the ocean. The impact of these processes on marine organisms will depend on their ability to cope with those changes, particularly the maintenance of calcium carbonate structures. Both a laboratory experiment (long-term exposure to decreased pH and increased temperature) and collections of individuals from natural environments characterized by low pH levels (individuals from intertidal pools and around a CO2 seep) were here coupled to comprehensively study the impact of near-future conditions of pH and temperature on the mechanical properties of the skeleton of the euechinoid sea urchin Paracentrotus lividus. To assess skeletal mechanical properties, we characterized the fracture force, Young's modulus, second moment of area, material nanohardness, and specific Young's modulus of sea urchin test plates. None of these parameters were significantly affected by low pH and/or increased temperature in the laboratory experiment and by low pH only in the individuals chronically exposed to lowered pH from the CO2 seeps. In tidal pools, the fracture force was higher and the Young's modulus lower in ambital plates of individuals from the rock pool characterized by the largest pH variations but also a dominance of calcifying algae, which might explain some of the variation. Thus, decreases of pH to levels expected for 2100 did not directly alter the mechanical properties of the test of P. lividus. Since the maintenance of test integrity is a question of survival for sea urchins and since weakened tests would increase the sea urchins' risk of predation, our findings indicate that the decreasing seawater pH and increasing seawater temperature expected for the end of the century should not represent an immediate threat to sea urchins vulnerability.


2002 ◽  
Author(s):  
Toshiyuki Sawa ◽  
Yoshihito Suzuki ◽  
Shoichi Kido

The stress variations in butt adhesive joints of dissimilar hollow cylinders under impact tensile loadings are analyzed in elastic and elasto-plastic deformation using a finite element method. The FEM code employed is DYNA3D. The effect of Young’s modulus of the adhesive, adhesive thickness and the inside diameter of the hollow cylinders and Young’s modulus ratio between dissimilar adherends on the stress variations at the interfaces are examined. In addition, a process in rupture at the interface of the joint is analyzed. The stress distributions in the joints under static loadings are also analyzed by an FEM. The characteristics of the stress variations in the joints under impact loadings are compared with those in the joints under the static loadings. Also, the joint strenths under impact loadings are estimated. As the results, it is found that the maximum value of the maximum principal stress σl occurs at the outside of the interface. It is also found that the maximum principal stress σl at the interface decreases as the inside diameter of the hollow cylinders increases. The characteristics of the joints subjected to the impact loadings are found to be opposite to those subjected to the static loadings. In addition, the experiments were carried out to measure the strain response of the butt adhesive joints under impact tensile loads using strain gauges. Furthermore, the joint strengths under impact loadings were measured. Fairly good agreements are observed between the numerical and the measured results.


2002 ◽  
Vol 16 (06n07) ◽  
pp. 933-945 ◽  
Author(s):  
B. K. TAY ◽  
Y. H. CHENG ◽  
S. P. LAU ◽  
X. SHI

Nanocomposite amorphous carbon (a-C:Me) films including a-C:Ni , a-C:Co , a-C:Ti , a-C:W , a-C:Fe , a-C:Al , and a-C:Si films were deposited using metal-carbon composite target by filtered cathodic vacuum arc (FCVA) technique. Atomic force microscopy (AFM), Raman, and X-ray photoelectron spectroscopy (XPS) were used to characterize the morphology and structure of the films. Nanoindenter and surface profilometer were used to determine the hardness, Young's modulus, and internal stress. Contact angle and field emission experiments were used to study the surface energy and field emission properties of the films respectively. The influence of the type of elements and its composition in the target on the structural, mechanical, surface energy, and field emission properties were studied. The incorporation of elements into the films results in the decrease of sp 3 C fraction, internal stress in the deposited films, but the hardness and Young's modulus remains at high level. The effect of non-carbide forming elements in the films on the mechanical properties is more pronounced than that of carbide forming elements. The surface energy of the films increases with incorporating Ni atoms, but decreases after incorporating Fe and Al atoms into the films. After heat treatment, the incorporation of metal into ta-C films can greatly improve the field emission performance.


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