scholarly journals Post-Plasma Catalysis for Trichloroethylene Abatement with Ce-Doped Birnessite Downstream DC Corona Discharge Reactor

Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 946
Author(s):  
Grêce Abdallah ◽  
Jean-Marc Giraudon ◽  
Rim Bitar ◽  
Nathalie De Geyter ◽  
Rino Morent ◽  
...  

Trichloroethylene (TCE) removal was investigated in a post-plasma catalysis (PPC) configuration in nearly dry air (RH = 0.7%) and moist air (RH = 15%), using, for non-thermal plasma (NTP), a 10-pin-to-plate negative DC corona discharge and, for PPC, Ce0.01Mn as a catalyst, calcined at 400 °C (Ce0.01Mn-400) or treated with nitric acid (Ce0.01Mn-AT). One of the key points was to take advantage of the ozone emitted from NTP as a potential source of active oxygen species for further oxidation, at a very low temperature (100 °C), of untreated TCE and of potential gaseous hazardous by-products from the NTP. The plasma-assisted Ce0.01Mn-AT catalyst presented the best CO2 yield in dry air, with minimization of the formation of gaseous chlorinated by-products. This result was attributed to the high level of oxygen vacancies with a higher amount of Mn3+, improved specific surface area and strong surface acidity. These features also allow the promotion of ozone decomposition efficiency. Both catalysts exhibited good stability towards chlorine. Ce0.01Mn-AT tested in moist air (RH = 15%) showed good stability as a function of time, indicating good water tolerance also.

Author(s):  
Sebastian Herrmann ◽  
Hans-Joachim Kretzschmar ◽  
Vikrant C. Aute ◽  
Donald P. Gatley ◽  
Eckhard Vogel

Energies ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 4052
Author(s):  
Jie Wang ◽  
Hongfang Gu

When water vapor in moist air reaches supersaturation in a transonic flow system, non-equilibrium condensation forms a large number of droplets which may adversely affect the operation of some thermal-hydraulic equipment. For a better understanding of this non-equilibrium condensing phenomenon, a numerical model is applied to analyze moist air condensation in a transonic flow system by using the theory of nucleation and droplet growth. The Benson model is adopted to correct the liquid-plane surface tension equation for realistic results. The results show that the distributions of pressure, temperature and Mach number in moist air are significantly different from those in dry air. The dry air model exaggerates the Mach number by 19% and reduces both the pressure and the temperature by 34% at the nozzle exit as compared with the moist air model. At a Laval nozzle, for example, the nucleation rate, droplet number and condensation rate increase significantly with increasing relative humidity. The results also reveal the fact that the number of condensate droplets increases rapidly when moist air reaches 60% relative humidity. These findings provide a fundamental approach to account for the effect of condensate droplet formation on moist gas in a transonic flow system.


2010 ◽  
Vol 82 (6) ◽  
pp. 1329-1336 ◽  
Author(s):  
J. Christopher Whitehead

The combination of a nonthermal, atmospheric plasma with a catalyst is investigated as a means of destroying pollutants in waste gas streams. Using the examples of dichloromethane (DCM) and toluene in air streams, it is shown that the destruction of the pollutant can be increased whilst lowering the operating temperature, giving increasing energy efficiency. Unwanted by-products can also be reduced selectively by appropriate choice of catalyst and of the plasma–catalyst configuration. By studying the temperature dependence of plasma catalysis, some ideas can be obtained about the nature of the interaction between plasma and catalyst in the processing.


1999 ◽  
Vol 87 (5) ◽  
pp. 1724-1733 ◽  
Author(s):  
Arthur N. Freed ◽  
Yongqiang Wang ◽  
Sharron McCulloch ◽  
Teresa Myers ◽  
Ryoichi Suzuki

Bronchoalveolar lavage (BAL) of canine peripheral airways was performed at various times after hyperventilation, and BAL fluid (BALF) cell and mediator data were used to evaluate two hypotheses: 1) hyperventilation-induced mucosal injury stimulates mediator production, and 2) mucosal damage is correlated with the magnitude of hyperventilation-induced bronchoconstriction. We found that epithelial cells increased in BALF immediately after a 2- and a 5-min dry air challenge (DAC). Prostaglandins D2 and F2α and thromboxane B2 were unchanged immediately after a 2-min DAC but were significantly increased after a 5-min DAC. Leukotriene C4, D4, and E4 did not increase until 5 min after DAC. Hyperventilation with warm moist air did not alter BALF cells or mediators and caused less airway obstruction that occurred earlier than DAC. BALF epithelial cells were correlated with mediator release, and mediator release and epithelial cells were correlated with hyperventilation-induced bronchoconstriction. These observations are consistent with the hypothesis that hyperventilation-induced mucosal damage initiates peripheral airway constriction via the release of biochemical mediators.


2020 ◽  
Vol 6 (19) ◽  
pp. eaba1951 ◽  
Author(s):  
Seth D. Seidel ◽  
Da Yang

Moist air is lighter than dry air at the same temperature, pressure, and volume because the molecular weight of water is less than that of dry air. We call this the vapor buoyancy effect. Although this effect is well documented, its impact on Earth’s climate has been overlooked. Here, we show that the lightness of water vapor helps to stabilize tropical climate by increasing the outgoing longwave radiation (OLR). In the tropical atmosphere, buoyancy is horizontally uniform. Then, the vapor buoyancy in the moist regions must be balanced by warmer temperatures in the dry regions of the tropical atmosphere. These higher temperatures increase tropical OLR. This radiative effect increases with warming, leading to a negative climate feedback. At a near present-day surface temperature, vapor buoyancy is responsible for a radiative effect of 1 W/m2 and a negative climate feedback of about 0.15 W/m2 per kelvin.


2019 ◽  
Vol 12 (9) ◽  
pp. 5101-5118 ◽  
Author(s):  
Steven D. Miller ◽  
Louie D. Grasso ◽  
Qijing Bian ◽  
Sonia M. Kreidenweis ◽  
Jack F. Dostalek ◽  
...  

Abstract. Lofted mineral dust over data-sparse regions presents considerable challenges to satellite-based remote sensing methods and numerical weather prediction alike. The southwest Asia domain is replete with such examples, with its diverse array of dust sources, dust mineralogy, and meteorologically driven lofting mechanisms on multiple spatial and temporal scales. A microcosm of these challenges occurred over 3–4 August 2016 when two dust plumes, one lofted within an inland dry air mass and another embedded within a moist air mass, met over the southern Arabian Peninsula. Whereas conventional infrared-based techniques readily detected the dry air mass dust plume, they experienced marked difficulties in detecting the moist air mass dust plume, becoming apparent when visible reflectance revealed the plume crossing over an adjacent dark water background. In combining information from numerical modeling, multi-satellite and multi-sensor observations of lofted dust and moisture profiles, and idealized radiative transfer simulations, we develop a better understanding of the environmental controls of this event, characterizing the sensitivity of infrared-based dust detection to column water vapor, dust vertical extent, and dust optical properties. Differences in assumptions of dust complex refractive index translate to variations in the sign and magnitude of the split-window brightness temperature difference commonly used for detecting mineral dust. A multi-sensor technique for mitigating the radiative masking effects of water vapor via modulation of the split-window dust-detection threshold, predicated on idealized simulations tied to these driving factors, is proposed and demonstrated. The new technique, indexed to an independent description of the surface-to-500 hPa atmospheric column moisture, reveals parts of the missing dust plume embedded in the moist air mass, with the best performance realized over land surfaces.


Author(s):  
Jae-youn Park ◽  
Geon-ho Kim ◽  
Jong-dal Kim ◽  
Hee-seog Koh ◽  
Duck-chul Lee

AbstractThe effect of magnetic field on NOx removal characteristics of the Multipins-plate plasma reactor was experimentally investigated. Experiments were conducted for the simulated flue gas (NO: 0.17 %, N


Parasitology ◽  
1932 ◽  
Vol 24 (3) ◽  
pp. 419-428 ◽  
Author(s):  
Kenneth Mellanby

A method is described by which individual bed-bugs, weighing only 5 mg., can be accurately weighed, and their rate of loss of weight measured during starvation.Fasting bed-bugs were kept for various periods at five temperatures, ranging from 8° C. to 37° C., and at four humidities—0, 30, 60 and 90 per cent. relative humidity—at each temperature. Analysis after the experiments showed that the same amounts of food reserves were used up at each humidity for one temperature, and, as more water was evaporated from those kept in dry air than from those in moist, the proportion of dry matter rose most rapidly in dry air. Protein was the main food reserve used.Although the rate of loss of water was greatest in dry air, the rate of loss was relatively greater in moist air when the saturation deficiencies are compared. It appears that the insects conserve their water in dry air, but their surface area being so great in comparison with their volume, they cannot prevent all evaporation. This evaporation is at a rate nearly proportional to the saturation deficiency of the air.In moist air water appears to be evaporated freely. It is suggested that the spiracles are kept closed more in dry air and less in moist, which accounts for the fact that the rate of evaporation is proportionately greatest in moist air.A comparison is made between the results obtained with Cimex and Rhodnius.


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