scholarly journals High-Temperature Oxidation Behaviors of TA15 Titanium Alloy after Mechanical Grinding and Laser Cleaning

Coatings ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1090
Author(s):  
Zhi-Chao Li ◽  
Jie Xu ◽  
Dong-He Zhang ◽  
Zhen-Hai Xu ◽  
Shi-Rui Yang ◽  
...  
Keyword(s):  
Titanium Alloy ◽  
High Temperature ◽  
Oxide Film ◽  
High Temperature Oxidation ◽  
Laser Cleaning ◽  
Mechanical Grinding ◽  
Widespread Application ◽  
Temperature Oxidation ◽  
X Ray ◽  
Ta15 Titanium Alloy

This paper presents the results of a study on the high-temperature oxidation characteristics after mechanical and laser removal of TA15 titanium alloy oxide film. The morphology, components, and roughness of the surface were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and laser confocal microscope (OM). The oxide film can be effectively removed with mechanical grinding and laser cleaning, and the oxide film after mechanical grinding is thicker and looser than that of after laser cleaning. The oxide film is principally composed of TiO2, Ti2O3 and TiO. Besides, there is a small amount of aluminum oxide on the surface. The surface after mechanical grinding was rougher than that of after laser cleaning. Thus, this work indicates that laser can not only clean the oxide film completely, but also strengthen the surface, which is a promising way to favor the widespread application of laser cleaning technology.

ENHANCING HIGH-TEMPERATURE OXIDATION RESISTANCE OF TITANIUM ALLOY WITH KF110-B4C-Ag THROUGH LASER TECHNOLOGY

2021 ◽  
Author(s):  
ZHAO ZHANG ◽  
JIANING LI ◽  
ZHIYUN YE ◽  
CAINIAN JING ◽  
MENG WANG ◽  
...  
Keyword(s):  
Titanium Alloy ◽  
High Temperature ◽  
Oxidation Resistance ◽  
High Temperature Oxidation ◽  
Mass Gain ◽  
Temperature Oxidation ◽  
Laser Technology ◽  
X Ray ◽  
Ta15 Titanium Alloy ◽  
Oxidation Resistant

In this paper, the high-temperature oxidation resistant coating on the TA15 titanium alloy by laser cladding (LC) of the KF110-B4C-Ag mixed powders was analyzed in detail. The scanning electron microscope (SEM) and energy dispersive X-ray spectrometer (EDS) images indicated that a good metallurgy bond between the fabricated coating/TA15 was formed; also the fine/compact microstructure was produced after a cladding process. The oxidation mass gain of TA15 was higher than that of the coating after LC process, which were 3.72 and 0.91[Formula: see text]mg[Formula: see text]cm[Formula: see text], respectively, at 60[Formula: see text]h, greatly enhancing the high temperature oxidation resistance.

scholarly journals High-Temperature Oxidation Properties and Microstructural Evolution of Nanostructure Fe-Cr-Al ODS Alloys

Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 526
Author(s):  
Zhengyuan Li ◽  
Lijia Chen ◽  
Haoyu Zhang ◽  
Siyu Liu
Keyword(s):  
High Temperature ◽  
Oxide Layer ◽  
Microstructural Evolution ◽  
High Temperature Oxidation ◽  
Oxide Dispersion Strengthened ◽  
Al Alloy ◽  
Temperature Oxidation ◽  
X Ray ◽  
Plasma Sintering ◽  
Ods Alloys

The oxidation behavior and microstructural evolution of the nanostructure of Fe-Cr-Al oxide dispersion strengthened (ODS) alloys prepared by spark plasma sintering were investigated by high-temperature oxidation experiments in air at 1200 °C for 100 h. The formation of Al2O3 scale was observed by X-ray diffraction (XRD) and scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDS) line scans. The oxidation rate of Fe-Cr-Al ODS alloys is lower than that of conventional Fe-Cr-Al alloys, and the oxide layer formed on the Fe-Cr-Al alloy appeared loose and cracked, whereas the oxide layer formed on the Fe-Cr-Al ODS alloys was adherent and flat. This is due to the high density of dispersed nano-oxides hindering the diffusion of Al element and the formation of vacancies caused by them. In addition, the nano-oxides could also adhere to the oxide layer. Besides, the microstructure of the Fe-Cr-Al ODS alloy had excellent stability during high-temperature oxidation.

scholarly journals Additively Manufactured NiTi and NiTiHf Alloys: Estimating Service Life in High-Temperature Oxidation

Materials ◽  
2020 ◽  
Vol 13 (9) ◽  
pp. 2104 ◽  
Author(s):  
Hediyeh Dabbaghi ◽  
Keyvan Safaei ◽  
Mohammadreza Nematollahi ◽  
Parisa Bayati ◽  
Mohammad Elahinia
Keyword(s):  
High Temperature ◽  
Oxidation Rate ◽  
High Temperature Oxidation ◽  
Oxidation Behavior ◽  
Early Stage ◽  
Niti Alloy ◽  
Temperature Oxidation ◽  
X Ray ◽  
Rate Law ◽  
Parabolic Rate

In this study, the effect of the addition of Hf on the oxidation behavior of NiTi alloy, which was processed using additive manufacturing and casting, is studied. Thermogravimetric analyses (TGA) were performed at the temperature of 500, 800, and 900 °C to assess the isothermal and dynamic oxidation behavior of the Ni50.4Ti29.6Hf20 at.% alloys for 75 h in dry air. After oxidation, X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy were used to analyze the oxide scale formed on the surface of the samples during the high-temperature oxidation. Two stages of oxidation were observed for the NiTiHf samples, an increasing oxidation rate during the early stage of oxidation followed by a lower oxidation rate after approximately 10 h. The isothermal oxidation curves were well matched with a logarithmic rate law in the initial stage and then by parabolic rate law for the next stage. The formation of multi-layered oxide was observed for NiTiHf, which consists of Ti oxide, Hf oxide, and NiTiO3. For the binary alloys, results show that by increasing the temperature, the oxidation rate increased significantly and fitted with parabolic rate law. Activation energy of 175.25 kJ/mol for additively manufactured (AM) NiTi and 60.634 kJ/mol for AM NiTiHf was obtained.

scholarly journals The high temperature oxidation of metals

1926 ◽  
Vol 111 (757) ◽  
pp. 203-209 ◽  
Keyword(s):  
High Temperature ◽  
Oxide Film ◽  
High Temperature Oxidation ◽  
Protective Action ◽  
Protective Film ◽  
Parent Metal ◽  
Compact Structure ◽  
Temperature Oxidation ◽  
Protective Properties ◽  
Porous Oxide

The oxidation of metals at high temperatures has been investigated with some thoroughness by Pilling and Bedworth. They found that the metals could be divided into two great classes according to the nature of the oxide produced. If the volume of the oxide is greater than that of the metal from which it was produced an oxide film of compact structure and protective properties will be produced. If the volume of the oxide is less than that of its parent metal a porous oxide is produced which has no protective action whatever. The oxidation of the metals of the first class is controlled by the diffusion of oxygen through the protective film of oxide and the application of the diffusion laws to this process lead us to expect that the oxidation law will be W 2 = K t W 2 = amount of oxygen absorbed t = time K is a constant.

An Advanced Technique for High Temperature X-Ray Elastic Constant and Stress Investigations

1992 ◽  
Vol 36 ◽  
pp. 411-422
Author(s):  
Chun Liu ◽  
Jean-Lou Lebrun ◽  
François Sibieude
Keyword(s):  
High Temperature ◽  
Elastic Constant ◽  
High Temperature Oxidation ◽  
Differential Method ◽  
Stress Evolution ◽  
Advanced Technique ◽  
Temperature Oxidation ◽  
X Ray ◽  
Refractory Alloys

AbstractA high temperature in situ X-Tay diffraction (HTXRD) instrument was devised for residual stress (RS) and X-ray elastic constant (XECs) investigations. The aim was to gain a better understanding of the stresses developed during high temperature oxidation, which is essential for the lifetime improvement of refractory alloys. The investigators use sin2ψ method to survey the stress evolution during oxidation in both the scale and the substrate, and differential method to determine the XECs that relate the measured/measurable deformation to the stress state of the materials studied. The stresses on the Ni/NiO system are measured in situ. The XECs are determined on XC75 steel samples. This paper presents the theories of stresses and XECs determined by HTXRD and briefly discusses the experimental results.

Performance of Fe-33Ni-18Cr Alloy at High Temperature Oxidation

2020 ◽  
Vol 1010 ◽  
pp. 65-70
Author(s):  
Zahraa Zulnuraini ◽  
Noraziana Parimin
Keyword(s):  
Weight Gain ◽  
High Temperature ◽  
Oxide Scale ◽  
High Temperature Oxidation ◽  
Thick Layer ◽  
X Ray Diffraction ◽  
Temperature Oxidation ◽  
X Ray ◽  
Oxide Particles ◽  
Lower Temperature

This paper investigates the performance of Fe-33Ni-18Cr alloy at high temperature oxidation. The samples were isothermally oxidized at three different oxidation temperatures, namely, 600 °C, 800 °C and 1000 °C for 150 hours. This alloy was ground by using several grits of SiC paper as well as weighed by using analytical balance and measured by using Vernier caliper before oxidation test. The characterization was carried out using scanning electron microscope (SEM) equipped with energy dispersive x-ray (EDX) and x-ray diffraction (XRD). The results show that, the higher oxidation temperatures, the weight gain of the samples were increase. Sample of 1000 °C indicate more weight gain compared to samples oxidized at 600 °C and 800 °C. The kinetic of oxidation of all samples followed the parabolic rate law. The surface morphology of oxide scale at lower temperature is thin and form a continuous layer, while at high temperature, the oxide scale develops thick layer with angular oxide particles.

High-Temperature Oxidation Behaviors of 30Cr25Ni20Si Heat-Resistant Steel in Air

2020 ◽  
Vol 861 ◽  
pp. 83-88
Author(s):  
You Yang ◽  
Xiao Dong Wang
Keyword(s):  
High Temperature ◽  
Oxide Film ◽  
High Temperature Oxidation ◽  
Film Growth ◽  
Surface Oxidation ◽  
Mass Gain ◽  
Resistant Steel ◽  
Temperature Oxidation ◽  
Heat Resistant Steel ◽  
Heat Resistant

High temperature oxidation dynamic behaviors and mechanisms for 30Cr25Ni20Si heat-resistant steel were investigated at 800, 900 and 1000°C. The oxide layers were characterized by scanning electron microscopy (SEM-EDS), X-ray diffractometer (XRD). The results showed that the oxidation rate of test alloys is increased with increasing the oxidation time. The oxidation dynamic curves at 800 and 900°C follow from liner to parabolic oxidation law. The transition point is 10 h. At 1000°C, the steel exhibits a catastrophic oxidation, and the oxidation mass gain value at 50 h is 0.77 mg/cm2. This suggests that the steel at 900°C has formed a dense protective surface oxidation film, effectively preventing the diffusion of the oxygen atoms and other corrosive gas into the alloy. Therefore, at the first stage of oxidation, chemical adsorption and reaction determine the oxide film composition and formation process. At the oxide film growth stage, oxidation is controlled by migration of ions or electrons across the oxide film. When the spinel scale forms, it acts as a compact barrier for O element and improving the oxidation resistance.

scholarly journals Properties of High Temperature Oxidation of Heat-resistant Steel with Aluminium and Copper

2019 ◽  
Vol 25 (4) ◽  
pp. 394-400
Author(s):  
Hong LI ◽  
Chengzhi ZHAO ◽  
Tao YAN ◽  
Chao DING ◽  
Hexin ZHANG ◽  
...  
Keyword(s):  
High Temperature ◽  
High Temperature Oxidation ◽  
Oxide Films ◽  
Main Element ◽  
Resistant Steel ◽  
Temperature Oxidation ◽  
Heat Resistant Steel ◽  
X Ray ◽  
Heat Resistant ◽  
Test Steel

The research is focused on a novel aluminum and copper-containing heat-resistant steel. The steel was designed by the material performance simulation software JmatPro, performed high-temperature oxidation tests at 650 °C and 700 °C atmospheric conditions, and analyzed the high-temperature oxidation processes and its mechanisms.The phase transtions and surface morphology of the oxide films were studied using X-ray diffraction (XRD), electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS). The results showed that the equilibrium phase of the test steel is composed of γ phase and δ phase at 1050 °C and tranforms to tempered martensite and δ-Fe mixed structure after heat treatment. The preferential oxidation of Fe and Cr and the internal oxidation of Al occurred during the high temperature oxidation of the test steel. The oxide films were formed with various shape and weak bonding properties after high-temperature oxidation at 650℃. To the contrary, the oxide films more regular and evenly distributed, and has a certain protective effect after high-temperature oxidation at 700 ℃. The oxide films were divided into two layers, Fe2O3 is main element in the outer layer, the inner layer is mainly consisting the oxide of Cr. However, the addition of Cu element can promote the diffusion of Al and Si elements, which is beneficial to the formation of Al2O3 and SiO2 protective oxide films and excellent in high temperature oxidation resistance.

Microstructural Evolution during High-Temperature Oxidation of Ti2AlN Ceramics

2010 ◽  
Vol 65 ◽  
pp. 106-111
Author(s):  
Bai Cui ◽  
Rafael Sa ◽  
Daniel Doni Jayaseelan ◽  
Fawad Inam ◽  
Michael J. Reece ◽  
...  
Keyword(s):  
High Temperature ◽  
Microstructural Evolution ◽  
High Temperature Oxidation ◽  
Oxidation Mechanism ◽  
X Ray Diffraction ◽  
Temperature Oxidation ◽  
X Ray ◽  
Oxidation In Air ◽  
Α Al2o3 ◽  
Increasing Temperature

Microstructural evolution of Ti2AlN ceramics during high-temperature oxidation in air has been revealed by X-ray diffraction (XRD), field emission gun scanning electron microscopy (FEGSEM), and energy-dispersive spectroscopy (EDS). After oxidation below 1200 °C, layered microstructures formed on Ti2AlN surfaces containing anatase, rutile, and α-Al2O3. Above 1200 °C, more complex layered microstructures formed containing Al2TiO5, rutile, α-Al2O3, and continuous void layers. With increasing temperature, anatase gradually transformed to rutile, and TiO2 reacted with α-Al2O3 to form Al2TiO5. Based on these microstructural observations, an oxidation mechanism for Ti2AlN ceramics is proposed.

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