scholarly journals Kraft Lignin Grafted with Polyvinylpyrrolidone as a Novel Microbial Carrier in Biogas Production

Energies ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 3246 ◽  
Author(s):  
Agnieszka A. Pilarska ◽  
Agnieszka Wolna-Maruwka ◽  
Krzysztof Pilarski
Keyword(s):  
Anaerobic Digestion ◽  
Sewage Sludge ◽  
Volatile Fatty Acids ◽  
Biogas Production ◽  
Kraft Lignin ◽  
Physicochemical Analysis ◽  
Process Efficiency ◽  
Total Alkalinity ◽  
Elementary Analysis ◽  
Biochemical Analyses

The objective of this study was to verify the effect of kraft lignin as a microbial carrier on biogas/methane yield. An anaerobic co-digestion test process was carried out, in which confectionery waste was used with sewage sludge. At the first stage of the study pure lignin and lignin combined with polyvinylpyrrolidone (PVP) were subjected to an extensive physicochemical analysis. Their morphology, dispersion and adsorption properties were determined. The two materials were also subjected to thermal, spectroscopic and elementary analysis. The anaerobic digestion of the two substrates was carried out with and without the addition of the carrier, under mesophilic conditions and in periodic operation. The monitoring and analysis of the two essential parameters, i.e., pH and volatile fatty acids/total alkalinity (VFA/TA) ratio, revealed that the process was stable in both tests. Microbial and biochemical analyses showed intensified proliferation of eubacteria and increased dehydrogenase activity in samples prepared with the lignin + PVP material. The cell count increased by 46% in the stuffed wafers (WAF) + sewage sludge (SS) variant with the carrier, whereas the enzyme activity increased by 43%. Cell immobilisation noticeably improved the process efficiency. The biogas production increased from 722 m3 Mg−1 VS to 850 m3 Mg−1 VS (VS – volatile solids), whereas the methane production increased from 428 m3 Mg−1 VS to 503 m3 Mg−1 VS (by about 18%). The research proved that lignin could be used as a very effective microbial carrier in anaerobic digestion (AD).

Effect of Ultrasonic Pretreatment for the Anaerobic Digestion of Sewage Sludge

2012 ◽  
Vol 531 ◽  
pp. 528-531 ◽  
Author(s):  
Na Wei
Keyword(s):  
Anaerobic Digestion ◽  
Sewage Sludge ◽  
Volatile Fatty Acids ◽  
Biogas Production ◽  
Oxygen Demand ◽  
High Concentration ◽  
Ultrasonic Pretreatment ◽  
Soluble Chemical Oxygen Demand ◽  
Pre Treatment ◽  
Settling Characteristics

Anaerobic digestion is an economic and environmentally friendly technology for treating the biomass material-sewage sludge, but has some limitations, such as the low efficient biogass production. In this paper ultrasound was proposed as pre-treatment for effective sludge anaerobic digestion. Sludge anaerobic digestion experiments with ultrasonic pretreatment was investigated. It can be seen that this treatment effectively leaded to the increase of soluble chemical oxygen demand(SCOD) and volatile fatty acids(VFA)concentration. High concentration of VFA leaded to a increase in biogas production. Besides, the SV of sludge was reduced and the settling characteristics of sludge was improved after ultrasonic pretreatment. It can be concluded that sludge anaerobic digestion with ultrasonic pretreatment is an effective method for biomass material transformation.

Investigation of Sewage Sludge Anaerobic Digestion Performance Using Peracetic Acid as a Pretreatment

2014 ◽  
Vol 989-994 ◽  
pp. 138-141 ◽  
Author(s):  
Na Wei
Keyword(s):  
Anaerobic Digestion ◽  
Sewage Sludge ◽  
Peracetic Acid ◽  
Volatile Fatty Acids ◽  
Biogas Production ◽  
Oxygen Demand ◽  
Paper Sludge ◽  
Acid Pretreatment ◽  
Speed Up ◽  
Soluble Chemical Oxygen Demand

Sewage sludge is difficult to degrade in anaerobic digestion systems and pretreatments have been shown to speed up the hydrolysis stage. In this paper sludge anaerobic digestion experiments with peracetic acid as a pretreatment were carried out and the effects of acid pretreatment using peracetic acid on subsequent digestion were investigated. It has been proved that this treatment effectively leads to a solubilisation of organic material and thus leads to a increase of soluble chemical oxygen demand (SCOD) and volatile fatty acids (VFA) concentration. Besides, the SV of sludge was reduced and the settling characteristics of sludge were improved. But high dosage of peracetic acid lead to a decrease in biogas production and the proper dosage was 20 g/kg DS. It can be concluded that sludge anaerobic digestion with peracetic acid pretreatment is an effective method for biomass material transformation.

scholarly journals Biogas potential of organic waste onboard cruise ships — a yet untapped energy source

2021 ◽  
Author(s):  
Kai Schumüller ◽  
Dirk Weichgrebe ◽  
Stephan Köster
Keyword(s):  
Energy Source ◽  
Anaerobic Digestion ◽  
Sewage Sludge ◽  
Food Waste ◽  
Energy Demand ◽  
Organic Waste ◽  
Biogas Production ◽  
Biogas Yield ◽  
Cruise Ships ◽  
Detailed Presentation

AbstractTo tap the organic waste generated onboard cruise ships is a very promising approach to reduce their adverse impact on the maritime environment. Biogas produced by means of onboard anaerobic digestion offers a complementary energy source for ships’ operation. This report comprises a detailed presentation of the results gained from comprehensive investigations on the gas yield from onboard substrates such as food waste, sewage sludge and screening solids. Each person onboard generates a total average of about 9 kg of organic waste per day. The performed analyses of substrates and anaerobic digestion tests revealed an accumulated methane yield of around 159 L per person per day. The anaerobic co-digestion of sewage sludge and food waste (50:50 VS) emerged as particularly effective and led to an increased biogas yield by 24%, compared to the mono-fermentation. In the best case, onboard biogas production can provide an energetic output of 82 W/P, on average covering 3.3 to 4.1% of the total energy demand of a cruise ship.

Alkali pre-treatment of Sorghum Moench for biogas production

2013 ◽  
Vol 67 (9) ◽  
Author(s):  
Karina Michalska ◽  
Stanisław Ledakowicz
Keyword(s):  
Anaerobic Digestion ◽  
Chemical Oxygen Demand ◽  
Volatile Fatty Acids ◽  
Biogas Production ◽  
Oxygen Demand ◽  
Total Phenolic ◽  
Methane Generation ◽  
Pre Treatment ◽  
Alkali Hydrolysis ◽  
Almost All

AbstractThis work studies the influence of the alkali pre-treatment of Sorghum Moench — a representative of energy crops used in biogas production. Solutions containing various concentrations of sodium hydroxide were used to achieve the highest degradation of lignocellulosic structures. The results obtained after chemical pre-treatment indicate that the use of NaOH leads to the removal of almost all lignin (over 99 % in the case of 5 mass % NaOH) from the biomass, which is a prerequisite for efficient anaerobic digestion. Several parameters, such as chemical oxygen demand, total organic carbon, total phenolic content, volatile fatty acids, and general nitrogen were determined in the hydrolysates thus obtained in order to define the most favourable conditions. The best results were obtained for the Sorghum treated with 5 mass % NaOH at 121°C for 30 min The hydrolysate thus achieved consisted of high total phenolic compounds concentration (ca. 4.7 g L−1) and chemical oxygen demand value (ca. 45 g L−1). Although single alkali hydrolysis causes total degradation of glucose, a combined chemical and enzymatic pre-treatment of Sorghum leads to the release of large amounts of this monosaccharide into the supernatant. This indicates that alkali pre-treatment does not lead to complete cellulose destruction. The high degradation of lignin structure in the first step of the pre-treatment rendered the remainder of the biomass available for enzymatic action. A comparison of the efficiency of biogas production from untreated Sorghum and Sorghum treated with the use of NaOH and enzymes shows that chemical hydrolysis improves the anaerobic digestion effectiveness and the combined pre-treatment could have great potential for methane generation.

scholarly journals MBR-Assisted VFAs Production from Excess Sewage Sludge and Food Waste Slurry for Sustainable Wastewater Treatment

2020 ◽  
Vol 10 (8) ◽  
pp. 2921 ◽  
Author(s):  
Mohsen Parchami ◽  
Steven Wainaina ◽  
Amir Mahboubi ◽  
David I’Ons ◽  
Mohammad J. Taherzadeh
Keyword(s):  
Wastewater Treatment ◽  
Sewage Sludge ◽  
Food Waste ◽  
Volatile Fatty Acids ◽  
Wastewater Treatment Plants ◽  
Biogas Production ◽  
Economic Assessment ◽  
Ph Control ◽  
Daily Basis ◽  
Solids Concentration

The significant amount of excess sewage sludge (ESS) generated on a daily basis by wastewater treatment plants (WWTPs) is mainly subjected to biogas production, as for other organic waste streams such as food waste slurry (FWS). However, these organic wastes can be further valorized by production of volatile fatty acids (VFAs) that have various applications such as the application as an external carbon source for the denitrification stage at a WWTP. In this study, an immersed membrane bioreactor set-up was proposed for the stable production and in situ recovery of clarified VFAs from ESS and FWS. The VFAs yields from ESS and FWS reached 0.38 and 0.34 gVFA/gVSadded, respectively, during a three-month operation period without pH control. The average flux during the stable VFAs production phase with the ESS was 5.53 L/m2/h while 16.18 L/m2/h was attained with FWS. Moreover, minimal flux deterioration was observed even during operation at maximum suspended solids concentration of 32 g/L, implying that the membrane bioreactors could potentially guarantee the required volumetric productivities. In addition, the techno-economic assessment of retrofitting the membrane-assisted VFAs production process in an actual WWTP estimated savings of up to 140 €/h for replacing 300 kg/h of methanol with VFAs.

scholarly journals Effect of liquid digestate recirculation on biogas production and enzyme activities for anaerobic digestion of corn straw

2020 ◽  
Author(s):  
Shuaixing Xue ◽  
Ling Qiu ◽  
Xiaohui Guo ◽  
Yiqing Yao
Keyword(s):  
Anaerobic Digestion ◽  
Enzyme Activities ◽  
Volatile Fatty Acids ◽  
Biogas Production ◽  
Coenzyme F420 ◽  
Total Volatile ◽  
Corn Straw ◽  
Liquid Digestate ◽  
Acid Accumulation ◽  
Peak Value

Abstract To accelerate the degradation of substrate, 50% liquid digestate recirculation (LDR) was used in the anaerobic digestion (AD) of corn straw. The effects of recirculation on the enzyme activities and biogas production were investigated by comparing with control reactor (ReactorCK). During the AD process, the fermentation system with 50% LDR was more stable. The average biogas and methane production in ReactorLDR were 7,891 mL·d−1 and 347 mL CH4·g−1 VSadded·d−1 respectively. The total volatile fatty acids (TVFAs) concentration in the two reactors both increased at first and then decreased with time. The LDR made the VFAs accumulation significant, especially propionic acid accumulation in 4 ∼ 16 days. The maximum peak value of cellulase, xylanase, dehydrogenase and coenzyme F420 activities in ReactorLDR were 0.51 mg·g−1·h−1, 0.29 mg·g−1·h−1, 4.88 mL·g−1·h−1 and 6.69 μmol·L−1, respectively, which were higher than that in ReactorCK. With or without recirculation, the concentration of TVFAs was positively correlated with cellulase, xylanase and dehydrogenase activities, while was negatively correlated with coenzyme F420 activity. Besides, a very significant correlation existed between hydrolase and dehydrogenase activities and daily biogas production in ReactorCK. And the peaks of cellulase, xylanase and dehydrogenase activities appeared ahead of the peak of daily biogas production with the LDR.

Study on the biogas potential of anaerobic digestion of coffee husks wastes in Ethiopia

2020 ◽  
pp. 0734242X2093961 ◽  
Author(s):  
Ning Du ◽  
Meng Li ◽  
Qian Zhang ◽  
Mihret Dananto Ulsido ◽  
Ruyi Xu ◽  
...  
Keyword(s):  
Trace Elements ◽  
Organic Matter ◽  
Anaerobic Digestion ◽  
Volatile Fatty Acids ◽  
Biogas Production ◽  
Dual Purpose ◽  
Effective Utilization ◽  
Leading Role ◽  
Initial Ph ◽  
Waste Reclamation

The poorly controlled discharge of coffee husks in Ethiopia causes severe environmental pollution and is a waste of resources. The volatile solid and carbon content in coffee husks waste indicates that it is rich in organic matter and has huge potential to produce biogas. This study investigated the feasibility of coffee husks to produce biomass through anaerobic digestion, based on temperature, initial pH, inoculum/substrate (I/S) ratio and carbon/nitrogen (C/N) ratio. The study demonstrated that the maximum production of biogas and methane reached 3359.6 ml and 2127.30 ml, respectively, under the conditions of mesophilic temperature (35±1°C), an initial pH of 7, an I/S ratio of 0.75 and a C/N ratio of 30. Based on this result, the effects of trace elements (Fe2+, Ni2+, Co2+) on biogas production and methane content were also explored. Compared with the group with no addition of trace elements, the experiment adding trace elements had significant enhancement effects on the production of biogas and methane, in which Fe2+ played a leading role ( p<0.05). Fe2+ promoted the hydrolysis and acidification of coffee husks, resulting in the production of a series of intermediates such as volatile fatty acids and the other kinds of dissolved organic matter. Furthermore, the cooperation of Ni2+, Co2+ and Fe2+ enhanced the activity of the enzyme system in methanogens, promoting methane production. The results in this paper show that coffee husks have clear biogas potential through anaerobic digestion, and its effective utilization could fulfill the dual purpose of solid waste reclamation and local environmental protection in Ethiopia.

Effect of a Cellulose-Degrading Strain on Anaerobic Fermentation of Corn Straw

2011 ◽  
Vol 356-360 ◽  
pp. 2510-2514 ◽  
Author(s):  
Ming Fen Niu ◽  
Sai Yue Wang ◽  
Wen Di Xu ◽  
An Dong Ge ◽  
Hao Wang
Keyword(s):  
Fatty Acids ◽  
Anaerobic Digestion ◽  
Methane Production ◽  
Volatile Fatty Acids ◽  
Anaerobic Fermentation ◽  
Biogas Production ◽  
Corn Straw ◽  
High Efficient ◽  
Important Significance ◽  
Strong Capacity

In order to improve the rate of degradation of cellulose in corn straw, the study has an important significance that compost corn straw with inoculating high-efficient microbe agents. The experiment inoculated a cellulose-degrading strain F2 which was screened from compost into compost pretreatment, the VS of corn straw reduced from 93.14% to 71.69% after 15 days, the content of cellulose reduced from 34.12g·kg-1 to 25.66g·kg-1, the rate of degradation was 24.79% which was 10.60% higher than those without the strain. An anaerobic fermentation experiment was carried out with the two groups of composted corn straw and mixed pig feces with a certain ratio, and investigations of biogas production, pH, content of volatile fatty acids(VFA) and rate of methane production were conducted. The results were that the corn straw composted with the cellulose-degrading strain peaked 4 days earlier, the maximal daily biogas production was 1470mL, the cumulative biogas production reached 23641mL which was 16.87% higher and operated stably earlier. The study showed that the cellulose-degrading strain had a strong capacity to degrade cellulose in corn straw, and then improved the performance of anaerobic digestion.

Sludge electrooxidation as pre-treatment for anaerobic digestion

2016 ◽  
Vol 75 (4) ◽  
pp. 775-781 ◽  
Author(s):  
J. A. Barrios ◽  
U. Duran ◽  
A. Cano ◽  
M. Cisneros-Ortiz ◽  
S. Hernández
Keyword(s):  
Anaerobic Digestion ◽  
Volatile Fatty Acids ◽  
Biogas Production ◽  
Oxygen Demand ◽  
Wastewater Sludge ◽  
Boron Doped Diamond ◽  
Boron Doped ◽  
Treatment Conditions ◽  
Volatile Solids ◽  
Pre Treatment

Anaerobic digestion of wastewater sludge is the preferred method for sludge treatment as it produces energy in the form of biogas as well as a stabilised product that may be land applied. Different pre-treatments have been proposed to solubilise organic matter and increase biogas production. Sludge electrooxidation with boron-doped diamond electrodes was used as pre-treatment for waste activated sludge (WAS) and its effect on physicochemical properties and biomethane potential (BMP) was evaluated. WAS with 2 and 3% total solids (TS) achieved 2.1 and 2.8% solubilisation, respectively, with higher solids requiring more energy. After pre-treatment, biodegradable chemical oxygen demand values were close to the maximum theoretical BMP, which makes sludge suitable for energy production. Anaerobic digestion reduced volatile solids (VS) by more than 30% in pre-treated sludge with a food to microorganism ratio of 0.15 g VSfed g−1 VSbiomass. Volatile fatty acids were lower than those for sludge without pre-treatment. Best pre-treatment conditions were 3% TS and 28.6 mA cm−2.

Potentials and limits of anaerobic digestion of sewage sludge: Energy self-sufficient municipal wastewater treatment plant?

2012 ◽  
Vol 66 (6) ◽  
pp. 1277-1281 ◽  
Author(s):  
P. Jenicek ◽  
J. Bartacek ◽  
J. Kutil ◽  
J. Zabranska ◽  
M. Dohanyos
Keyword(s):  
Wastewater Treatment ◽  
Energy Consumption ◽  
Anaerobic Digestion ◽  
Sewage Sludge ◽  
Wastewater Treatment Plant ◽  
Municipal Wastewater ◽  
Biogas Production ◽  
Treatment Plant ◽  
Self Sufficiency ◽  
Digestion Efficiency

Anaerobic digestion is the only energy-positive technology widely used in wastewater treatment. Full-scale data prove that the anaerobic digestion of sewage sludge can produce biogas that covers a substantial amount of the energy consumption of a wastewater treatment plant (WWTP). In this paper, we discuss possibilities for improving the digestion efficiency and biogas production from sewage sludge. Typical specific energy consumptions of municipal WWTPs per population equivalent are compared with the potential specific production of biogas to find the required/optimal digestion efficiency. Examples of technological measures to achieve such efficiency are presented. Our findings show that even a municipal WWTP with secondary biological treatment located in a moderate climate can come close to energy self-sufficiency. However, they also show that such self-sufficiency is dependent on: (i) the strict optimization of the total energy consumption of the plant, and (ii) an increase in the specific biogas production from sewage sludge to values around 600 L per kg of supplied volatile solids.

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