scholarly journals Tequila Still Distillation Fractioned Residual Streams for Use in Biorefinery

Energies ◽  
2020 ◽  
Vol 13 (23) ◽  
pp. 6222
Author(s):  
Edgardo Martinez-Orozco ◽  
Pablo Gortares-Moroyoqui ◽  
Norberto Santiago-Olivares ◽  
Juan Napoles-Armenta ◽  
Ruth Gabriela Ulloa-Mercado ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Gas Chromatography ◽  
Energy Analysis ◽  
Oxygen Demand ◽  
Solid Content ◽  
Co2 Production ◽  
Second Stage ◽  
Stage Process ◽  
Very High ◽  
Tequila Vinasses

Tequila vinasses is a mixture made from up to six still distillation two-stage process residual effluents. First stage fractions: residual must (60%), heads (0.9%) and tails (20.0%); second stage fractions: non-evaporated (8.0%), heads (0.1%) and tails (1.0%); the result is a more complex effluent for its treatment or biorefining. The objectives of this study were to: (a) characterize the five still distillation volatile streams in the Tequila 100% Agave processing; compounds: methanol, ethanol, acetaldehyde, ethyl acetate, sec-butanol, n-propanol, iso-butanol, n-butanol, iso-amyl, n-amyl, and ethyl lactate were detected by gas chromatography; calculated chemical oxygen demand from chemical composition had very high values (53,760–1,239,220 mg/L); measurement of pH (3.24–4.80), color (38.6 UC Pt-Co max), turbidity (46.1 max), electrical conductivity (3.30–172.20 μS/cm), and solid content (0 mg/L) was also made; (b) report an energy analysis (2.02 × 109 KWh) and CO2 production (429 × 106 kg) in the Tequila industry during 2019; (c) up to date residues (365.2 × 106 kg agave bagasse, 1146.1 × 106 kg agave leaves and 3300.0 × 106 L agave vinasse) in 2019; (d) economic analysis, current tequila vinasses treatment price is 16.00 USD/m3 but could reach a considerable fraction value if is bio-refined, a break down component analysis reach for five volatile streams $51.23–$140.00 USD/m3.

APLIKASI PROSES DIGESTASI ANAEROBIK LUMPUR BIOLOGI INSTALASI PENGOLAHAN AIR LIMBAH INDUSTRI KERTAS

2014 ◽  
Vol 4 (02) ◽  
Author(s):  
Rina S. Soetopo ◽  
Sri Purwati ◽  
Henggar Hardiani ◽  
Mukharomah Nur Aini ◽  
Krisna Adhitya Wardhana
Keyword(s):  
Oxygen Demand ◽  
Total Solid ◽  
Pilot Scale ◽  
Organic Content ◽  
Solid Content ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Organic Loading ◽  
Total Solid Content ◽  
Average Value

A continuous pilot scale study has been conducted to investigate the effectiveness of anaerobic digestion of biological sludge. The sludge has a total solid content of 0.53% - 1.1%, pH of 7.20 to 7.32. Its organic content is about 97 %, The research were conducted in two stages, which are acidification (performed in 3 m3 the Continously Stirred Tank Reactor/CSTR at pH of 5.5 to 6.0) and methanation (performed in 5 m3 the Up Flow Anaerobic Sludge Blanket/UASB reactor at pH 6.5 to 7.0). The retention time (RT) was gradually shortened from 6 days to 1 day for acidification and from 8 days to 2 days for methanation. The results showed that operating the CSTR at the RT of 1 day and the organic loading of 8.23 g Volatile Solid (VS)/m3.day could produce Volatile Fatty Acid (VFA) at an average value of 17.3 g/kg VS.day. Operating the UASB reactor at the RT of 2 days and the organic loading (Chemical Oxygen Demand/COD) of 2.4 kg COD/m3.day could produce biogas at an average value of 66.3 L/day, with an average methane content of 69.9%, methane rate of 0.17 L CH4/g COD reduction or 19.06 L CH4/kg VS. Furthermore, methanation could reduce COD at an average value of 51.2 %, resulting in the effluent average value of COD filtrate and COD total of 210.1 mg/L and 375.2 mg /L, respectively.Keywords: acidification, methanation, CSTR, UASB, biogas ABSTRAKPercobaan digestasi anaerobik lumpur IPAL biologi industri kertas secara kontinyu skala pilot telah dilakukan di industri kertas dengan tujuan mengkaji efektivitas proses digestasi anaerobik dalam mengolah lumpur tersebut. Lumpur yang digunakan memiliki total solids sekitar 0,53% – 1,1%, pH netral (7,20 – 7,32) dengan komponen utama senyawa organik sekitar 97%. Percobaan dilakukan dalam dua tahap yaitu asidifikasi dalam reaktor CSTR berkapasitas 3 m3 pada pH 5,5 – 6,0 dan metanasi dalam reaktor UASB berkapasitas 5 m3 pada pH 6,5 – 7,0. Percobaan dilakukan dengan waktu retensi yang dipersingkat secara bertahap dari 6 hari ke 1 hari untuk proses asidifikasi dan dari 8 hari ke 2 hari untuk proses metanasi. Hasil percobaan menunjukkan bahwa pengoperasian reaktor CSTR dengan waktu retensi 1 hari dan beban organik 8,3 g VS/m3.hari dapat menghasilkan VFA rata-rata 17,3 g/kg VS.hari dengan kisaran 8,36 – 30,59 g/kg VS.hari, sedangkan pengoperasian reaktor UASB pada waktu retensi 2 hari dan beban organik 2,4 kg COD/m3.hari dapat menghasilkan biogas rata-rata 66,3 L/hari dengan kadar metana rata-rata 69,9% atau 0,17 L CH4/g COD reduksi atau 19,06 L CH4/kg VS. Selain itu proses metanasi dapat menurunkan COD terlarut rata-rata 51,2%, dengan konsentrasi efluen COD terlarut  rata-rata 210,1 mg/L dan COD total rata-rata 375,2 mg/L.Kata kunci: asidifikasi, metanasi, CSTR, UASB, biogas

Anaerobic/aerobic biodegradation of pentachlorophenol using GAC fluidized bed reactors: optimization of the empty bed contact time

1997 ◽  
Vol 36 (6-7) ◽  
pp. 107-115 ◽  
Author(s):  
Gregory J. Wilson ◽  
Amid P. Khodadoust ◽  
Makram T. Suidan ◽  
Richard C. Brenner
Keyword(s):  
Fluidized Bed ◽  
Oxygen Demand ◽  
Aerobic Biodegradation ◽  
Fluidized Bed Reactors ◽  
Reactor Performance ◽  
Reactor Operation ◽  
Significant Cost ◽  
Second Stage ◽  
Primary Substrate ◽  
Chlorinated Phenolic Compounds

An integrated reactor system has been developed to remediate pentachlorophenol (PCP) containing wastes using sequential anaerobic and aerobic biodegradation. Anaerobically, PCP was degraded to predominately equimolar concentrations (>99%) of monochlorophenol (MCP) in two GAC fluidized bed reactors at Empty Bed Contact Times (EBCTs) ranging from 18.6 to 1.15 hours. However, at lower EBCTs, MCP concentrations decreased to less than 10% of the influent PCP concentration suggesting mineralization. The optimal EBCT was determined to be 2.3 hours based on PCP conversion to MCPs and stable reactor operation. Decreasing the EBCT fourfold did not inhibit degradation of PCP and its intermediates, thus allowing removal of PCP at much lower detention time and resulting in a significant cost advantage. Analytical grade PCP was fed via syringe pumps into two fluidized bed reactors at influent concentrations of 100 mg/l and 200 mg/l, respectively. Acting as the primary substrate, ethanol was also fed into the reactors at concentrations of 697 and 1388 mg/l. Effluent PCP and chlorinated phenolic compounds were analyzed weekly to evaluate reactor performance. Biodegradation pathways were also identified. 3-chlorophenol (CP) was the predominant MCP and varied simultaneously with 3,5-dichlorophenol (DCP) concentrations. Likewise, 4-CP concentrations varied simultaneously with 3,4-DCP concentrations. A second stage aerobic GAC fluidized bed reactor was added after the anaerobic reactor to completely mineralize the remaining MCP and phenols. Data show no presence of phenol and MCP in the effluent or on the GAC. Overall, the chemical oxygen demand (COD) fed to the system was reduced from 75 g/d in the influent to less than 1.5 g/d in the effluent.

Advanced Treatment of Coking Wastewater by Oxidation Process Using Pyrite and Hydrogen Peroxide

2013 ◽  
Vol 726-731 ◽  
pp. 2521-2525
Author(s):  
Zhi Yong Zhang ◽  
De Li Wu
Keyword(s):  
Hydrogen Peroxide ◽  
Oxidation Process ◽  
Low Cost ◽  
Oxygen Demand ◽  
Utilization Efficiency ◽  
Advanced Treatment ◽  
Coking Wastewater ◽  
Second Stage ◽  
Potential Alternative ◽  
High Utilization

Coking wastewater is a kind of recalcitrant wastewater including complicate compositions. Advanced treatment of coking wastewater by Fenton-Like reaction using pyrite as catalyst was investigated in this paper. The results show that the chemical oxygen demand (COD) of coking wastewater decreased significantly by method of coagulation combined with two-stage oxidation reaction. COD of wastewater can decrease from 250mg/l to 45mg/l after treatment, when 2g/L pyrite was used in each stage oxidation and the dosage of hydrogen peroxide (H2O2) is 0.2ml/l for first stage treatment, 0.1ml/l for second stage treatment respectively. The pyrite is effective to promote Fenton-Like reaction with low cost due to high utilization efficiency of H2O2, moreover, catalyst could be easily recovered and reused. The Fenton-Like reaction might be used as a potential alternative to advanced treatment of recalcitrant wastewater.

scholarly journals A new methodology for polyvalent intravenous immunoglobulin solution production with a two-stage process of viral inactivation

2010 ◽  
Vol 46 (4) ◽  
pp. 777-783
Author(s):  
Antônio Edson de Souza Lucena ◽  
Divaldo de Almeida Sampaio ◽  
Ednaldo Rosas da Silva ◽  
Virgínia Florêncio de Paiva ◽  
Ana Cláudia Santiago ◽  
...  
Keyword(s):  
Intravenous Immunoglobulin ◽  
Immunoglobulin G ◽  
Cation Exchanger ◽  
Product Analysis ◽  
Viral Inactivation ◽  
Two Stage ◽  
Second Stage ◽  
Neutralizing Capacity ◽  
Stage Process ◽  
Sodium Caprylate

Highly purified intravenous immunoglobulin G concentrate (IV IgG) was produced with the use of polyethylene glycol associated to a single-stage precipitation by ethanol, instead of the classic Cohn-Oncley process, which employs cold alcohol as the precipitating agent, in a three-stage process. Precipitation of crude fraction containing more than 95% of immunoglobulin G was performed by liquid chromatography with a cation exchanger, CM-Sepharose, as a stationary phase. During the process, the product was subjected to two-stage viral inactivation. The first stage was performed by the action of sodium caprylate, 30 mM at pH 5.1+/- 0.1, and the second stage was performed by the action of a solvent-detergent mixture. The finished product was formulated at 5% with 10% sucralose as the stabilizing agent. The process yields 3.3g of IgG/liter of plasma. The finished product analysis showed an anti-complementary activity lower than 1CH50. Polymer and aggregate percent levels were lower than 3% in the five batches studied. The analysis of neutralizing capacity showed the presence of antibacterial and antiviral antibodies in at least three times higher concentrations than the levels found in source plasma. The finished product fulfilled all purity requirements stated in the 4th edition of the European pharmacopeia.

scholarly journals Investigation of the relationship between landform classes and electrical conductivity (EC) of water and soil using a fuzzy model in a GIS environment

Solid Earth ◽  
2016 ◽  
Vol 7 (3) ◽  
pp. 873-880
Author(s):  
Marzieh Mokarram ◽  
Dinesh Sathyamoorthy
Keyword(s):  
Electrical Conductivity ◽  
Fuzzy Model ◽  
Chemical Properties ◽  
Geographical Information ◽  
Fars Province ◽  
Fuzzy Method ◽  
The North ◽  
The Relationship ◽  
Very High ◽  
Soil And Water

Abstract. Soil genesis is highly dependent on landforms as they control the erosional processes and the soil physical and chemical properties. The relationship between landform classification and electrical conductivity (EC) of soil and water in the northern part of Meharloo watershed, Fars province, Iran, was investigated using a combination of a geographical information system (GIS) and a fuzzy model. The results of the fuzzy method for water EC showed 36.6 % of the land to be moderately land suitable for agriculture; high, 31.69 %; and very high, 31.65 %. In comparison, the results of the fuzzy method for soil EC showed 24.31 % of the land to be as not suitable for agriculture (low class); moderate, 11.78 %; high, 25.74 %; and very high, 38.16 %. In total, the land suitable for agriculture with low EC is located in the north and northeast of the study area. The relationship between landform and EC shows that EC of water is high for the valley classes, while the EC of soil is high in the upland drainage class. In addition, the lowest EC levels for soil and water are in the plains class.

Treatment of dairy wastewaters by electrocoagulation using iron electrodesTraitement des eaux résiduaires d'une laiterie par électrocoagulation avec des électrodes de fer

2014 ◽  
Vol 50 (2) ◽  
pp. 198-209 ◽  
Author(s):  
Malika Aoudjehane ◽  
Mohamed Elghazali Benatallah
Keyword(s):  
Electrical Conductivity ◽  
Removal Efficiency ◽  
Current Density ◽  
Oxygen Demand ◽  
Operating Conditions ◽  
Electrolysis Time ◽  
Electrode Consumption ◽  
Treatment Conditions ◽  
Consumption Energy ◽  
Optimal Efficiency

A procedure of electrocoagulation (EC) using iron electrodes has been used for the treatment of the wastewaters produced by the Beni-Tamou dairy in Algeria. The effect of the operating conditions, such as the current intensity, the electrolysis time, the pH of the solution and the electrical conductivity, on the removal efficiency of chemical oxygen demand (COD) and the total suspended solids (TSS) has been studied. An inter-electrode distance of 1 cm has been maintained constant during the tests. It has been found that an increase in electrolysis time and current density improved the treatment significantly, albeit with a greater consumption of energy as well as an increased electrode consumption. The results of the electrocoagulation treatment under various operating conditions show that the optimal efficiency has been obtained under the following conditions: 60 minutes of electrolysis, a current density of 200 A/m2, a pH 8, an electrical conductivity of 4.72 mS/cm and a consumption energy of 13.57 kWh/m3. Under these conditions, the removal efficiency for the COD and TSS parameters is 93.26 and 99.3%, respectively. The optimal treatment conditions of dairy wastewaters have resulted in final COD and TSS concentrations of 41.5 and 27 mg/L, respectively, values that are conform to industrial liquid effluents discharge norms.

scholarly journals Quality of surface water related to land use: a case study in a catchment with small farms and intensive vegetable crop production in southern Brazil

2014 ◽  
Vol 38 (2) ◽  
pp. 656-668 ◽  
Author(s):  
Karina Hacke Ribeiro ◽  
Nerilde Favaretto ◽  
Jeferson Dieckow ◽  
Luiz Cláudio de Paula Souza ◽  
Jean Paolo Gomes Minella ◽  
...  
Keyword(s):  
Water Quality ◽  
Electrical Conductivity ◽  
Land Use ◽  
Surface Water ◽  
Total Nitrogen ◽  
Total Phosphorus ◽  
Oxygen Demand ◽  
Lower Percentage ◽  
Native Forest ◽  
Particulate Nitrogen

Water degradation is strongly related to agricultural activity. The aim of this study was to evaluate the influence of land use and some environmental components on surface water quality in the Campestre catchment, located in Colombo, state of Parana, Brazil. Physical and chemical attributes were analyzed (total nitrogen, ammonium, nitrate, total phosphorus, electrical conductivity, pH, temperature, turbidity, total solids, biological oxygen demand, chemical oxygen demand and dissolved oxygen). Monthly samples of the river water were taken over one year at eight monitoring sites, distributed over three sub-basins. Overall, water quality was worse in the sub-basin with a higher percentage of agriculture, and was also affected by a lower percentage of native forest and permanent preservation area, and a larger drainage area. Water quality was also negatively affected by the presence of agriculture in the riparian zone. In the summer season, probably due to higher rainfall and intensive soil use, a higher concentration of total nitrogen and particulate nitrogen was observed, as well as higher electrical conductivity, pH and turbidity. All attributes, except for total phosphorus, were in compliance with Brazilian Conama Resolution Nº 357/2005 for freshwater class 1. However, it should be noted that these results referred to the base flow and did not represent a discharge condition since most of the water samples were not collected at or near the rainfall event.

scholarly journals Two-Stage Discrete Mechanical Modelin Three-Dimensional Space for Garment Simulation

2019 ◽  
Vol 19 (1) ◽  
pp. 26-35 ◽  
Author(s):  
Xuan Luo ◽  
Gaoming Jiang ◽  
Honglian Cong
Keyword(s):  
Mechanical Model ◽  
Dimensional Space ◽  
Three Dimensional ◽  
Mathematical Expression ◽  
Two Stage ◽  
Second Stage ◽  
Simulation Speed ◽  
Optimal Value ◽  
Variable Distance ◽  
Stage Process

Abstract This paper focuses on the better performance between the garment simulation result and the simulation speed. For simplicity and clarity, a notation “PART” is defined to indicate the areas between the garment and the human body satisfying some constraints. The discrete mechanical model can be achieved by the two-stage process. In the first stage, the garment can be divided into several PARTs constrained by the distance. In the second stage, the mechanical model of each PART is formulated with a mathematical expression. Thus, the mechanical model of the garment can be obtained. Through changing the constrained distance, the simulation result and the simulation speed can be observed. From the variable distance, a desired value can be chosen for an optimal value. The results of simulations and experiments demonstrate that the better performance can be achieved at a higher speed by saving runtime with the acceptable simulation results and the efficiency of the proposed scheme can be verified as well.

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