scholarly journals Porphyroclasts: Source and Sink of Major and Trace Elements During Deformation-Induced Metasomatism (Finero, Ivrea-Verbano Zone, Italy)

Geosciences ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 196
Author(s):  
Stefania Corvò ◽  
Antonio Langone ◽  
José Alberto Padrón-Navarta ◽  
Andrea Tommasi ◽  
Alberto Zanetti
Keyword(s):  
Trace Elements ◽  
Shear Zone ◽  
Major And Trace Elements ◽  
Trace Element Composition ◽  
Lower Jurassic ◽  
Coarse Grained ◽  
Geochemical Data ◽  
Fine Grained ◽  
Mantle Peridotites ◽  
Scale Shear

Petrographic and geochemical data for mylonites from a metric-scale shear zone in mantle peridotites from the Finero massif (Southern Alps) record large mineralogical and geochemical modifications compared to surrounding coarse-grained ultramafic rocks, which were pervasively deformed in presence of hydrous melts. The mylonites are composed by olivine and orthopyroxene and, less frequently, clinopyroxene, phlogopite, and pargasite porphyroclasts enclosed in a fine-grained matrix of phlogopite and olivine, with subordinate amounts of orthopyroxene, clinopyroxene, pargasite, and chromite. P-T estimates indicate that deformation occurred under granulite- to upper-amphibolite facies conditions. Field relationships and U-Pb dating indicate that the shear zone was active during Lower Jurassic and/or later, in an extensional setting at the western margin of the Adria plate, which led to the opening of the Alpine Tethys. The major and trace element composition of the porphyroclasts in the mylonites significantly differ from those in the hosting coarse-grained ultramafics. Porphyroclasts were chemically active during deformation acting as source (diffusion-out) or sink (diffusion-in) for some trace elements. The chemical modifications were promoted by the interaction with aqueous fluids and the composition varied from mantle- (enriched in Ni, Co, Li, Na, REE, Y, and Sr) to crustal-derived (enriched in Zn, K, Al, Ti, and Fe).

Mineralogy, geochemistry, and Sr–Nd isotopes of the Cretaceous leucogranite from Karamadazı (Kayseri), central Turkey: implications for their sources and geological setting

2008 ◽  
Vol 45 (8) ◽  
pp. 949-968 ◽  
Author(s):  
Kerim Kocak
Keyword(s):  
Mafic Magma ◽  
Mineral Chemistry ◽  
Major And Trace Elements ◽  
Quartz Diorite ◽  
Coarse Grained ◽  
Major Constituent ◽  
Geochemical Data ◽  
Nd Isotopes ◽  
Northern Margin ◽  
Central Turkey

The leucogranite is the major constituent of the bimodal Late Cretaceous Karamadazı granitoid, developed in relation with evolution of the Inner Tauride Ocean along the northern margin of the Taurides in central Turkey. New analyses of minerals major and trace elements (including rare-earth elements (REE)), and of Sr and Nd isotopes are performed to determine the origin and geochemical characteristics of the leucogranites. Medium-coarse-grained leucogranite contains normally zoned plagioclase (An12–20), mildly alkaline biotite, and xenocrystic magneziohornblende, actinolite, and ferrohornblende. It is characterized by concave-up REE patterns with respect to middle–heavy REE. Field relations, mineral chemistry, geochemical data, and isotopic data suggest that the leucogranite could have originated from an amphibole-bearing igneous source in lower to middle crust by low-rate partial melting (<40%) under low pressure and low H2O activity conditions, possibly coupled by mixing–mingling with mafic magma and high-level feldspar and minor biotite fractionation. In contrast, the quartz diorite and mafic microgranular enclave (MME) are probably developed from an enriched mantle, with possible mingling–mixing. MME, quartz diorite, and leucogranite may represent a magmatic suite, which formed in an extensional tectonic regime by bimodal magmatic activity probably because of lithospheric delamination or slab break off or after the Alpine thicken within the Gondwanan Tauride–Anatolide platform. Initial Sr data exhibit an age of 65 ± 13 Ma for the leucogranite, but it does not indicate a true intrusion age of the magma due to isotopic modification of the magma.

scholarly journals The distribution of the trace element contents in lignite and ash from Drama lignite deposit, using multivariate statistical analysis

2001 ◽  
Vol 34 (3) ◽  
pp. 1255
Author(s):  
S. PANILAS ◽  
G. HATZIYANNIS
Keyword(s):  
Trace Elements ◽  
Rare Earth ◽  
Statistical Analysis ◽  
Rare Earth Elements ◽  
Multivariate Statistical Analysis ◽  
Major And Trace Elements ◽  
Major Elements ◽  
Geochemical Data ◽  
Multivariate Statistical ◽  
Inorganic Matter

Multivariate statistical analysis was used on existing geochemical data of the Drama lignite deposit, eastern Macedonia, Greece. Factor analysis with varimax rotation technique was applied to study the distribution of major, trace and rare earth elements in the lignite and 850°C lignitic ash, to find a small set of factors that could explain most of the geochemical variability. The study showed that major elements AI, Na, Κ, contained in the lignite samples, presented high correlation with most of the trace and rare earth elements. In 850°C lignitic ashes major and trace elements present different redistribution. Only Al remained correlated with the trace elements Co, Cr, Rb, Ta, Th, Ti, Sc and rare earths related with inorganic matter in the lignite beds. Trace elements Fe, Mo, U, V, W, and Lu were associated with organic matter of lignite and had also been affected by the depositional environment.

scholarly journals Localization effect on AMS fabric revealed by microstructural evidence across small-scale shear zone in marble

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
V. K. Kusbach ◽  
M. Machek ◽  
Z. Roxerová ◽  
M. Racek ◽  
P. F. Silva
Keyword(s):  
Shear Zone ◽  
Magnetic Fabric ◽  
Small Scale ◽  
Angular Deviation ◽  
Localized Deformation ◽  
Fine Grained ◽  
Localization Of Deformation ◽  
Strain Relationship ◽  
Rock Microstructure ◽  
Scale Shear

AbstractAnisotropy of magnetic susceptibility (AMS) is regularly applied as a tool to infer structural analysis of deformation and flow in rocks, particularly, with low anisotropy. AMS integrates the magnetic signature of crystallographic and shape preferred orientation of all mineral grains present in the rock microstructure. Those preferred orientations result from multiple processes affecting the rock during its evolution, therefore the desirable AMS-strain relationship is not straightforward. Here we show that due to localization of deformation, AMS is indirectly dependent on the magnitude and character of deformation. In order to decipher the AMS-strain relationship, AMS studies should be accompanied by microstructural analyses combined with numerical modelling of magnetic fabric. A small-scale shear zone produced by single deformation event was studied. The resultant AMS fabric is “inverse” due to the presence of Fe-dolomite and controlled by calcite and dolomite crystallographic preferred orientations. The localized deformation resulted in the angular deviation between macroscopic and magnetic fabric in the shear zone, systematically increasing with increasing strain. This is a result of the presence of microstructural subfabrics of coarse porphyroclasts and fine-grained recrystallized matrix produced by localization.The localization of deformation is a multiscale and widespread process that should be considered whenever interpreting AMS in deformed rocks and regions.

Uncommon preservation of dinosaur footprints in a tidal breccia: Eubrontes giganteus from the Early Jurassic Mongisty tracksite of Aveyron, southern France

2021 ◽  
pp. 1-18
Author(s):  
Jean-David Moreau ◽  
Jacques Sciau ◽  
Georges Gand ◽  
Emmanuel Fara
Keyword(s):  
Scale Up ◽  
Lower Jurassic ◽  
Depositional Environments ◽  
Early Jurassic ◽  
Coarse Grained ◽  
Southern France ◽  
Fine Grained ◽  
The North ◽  
Dinosaur Tracks ◽  
First Time

Abstract A recent excavation yielded 118 large tridactyl footprints in the Lower Jurassic Dolomitic Formation of the Causses Basin, at Mongisty in southern France. Most of the tracks are ascribed to Eubrontes giganteus Hitchcock, 1845. They are preserved on a surface of 53 m2 and form parallel rows with a preferential orientation towards the north. Such an abundance and density of E. giganteus is observed for the first time in the Early Jurassic from the Causses Basin. Sedimentological and ichnotaphonomical analyses show that the footprints were made at different time intervals, thus excluding the passage of a large group. In contrast to all other tracksites from the Dolomitic Formation, where tracks are preserved in fine-grained sediments corresponding to low-energy depositional palaeoenvironments, the tracks from Mongisty are preserved in coarse-grained sediment which is a matrix- to clast-supported breccia. Clasts consist of angular to sub-rounded, millimetric to centimetric-scale (up to 2 cm), poorly sorted, randomly oriented, homogeneous dolostone intraclasts floating in a dolomudstone matrix. Sedimentological analysis shows that the depositional environments of Mongisty varied from subtidal to intertidal/supratidal settings in a large and protected flat marsh. The lithology of the track-bearing surfaces indicates that the mudflat of the Causses Basin was sporadically affected by large mud flows that reworked and redeposited mudstone intraclasts coming from the erosion of upstream, dry and partially lithified mud beds. Throughout the world, this type of preservation of dinosaur tracks in tidal matrix- to clast-supported breccias remains rare.

scholarly journals Passive degassing at Nyiragongo (D.R. Congo) and Etna (Italy) volcanoes

2015 ◽  
Vol 57 ◽  
Author(s):  
Sergio Calabrese ◽  
Sarah Scaglione ◽  
Silvia Milazzo ◽  
Walter D'Alessandro ◽  
Nicole Bobrowski ◽  
...  
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Major And Trace Elements ◽  
Trace Element Composition ◽  
Bulk Deposition ◽  
Volcanic Plume ◽  
Strong Impact ◽  
Volcanic Emissions ◽  
Endemic Plant ◽  
The Impact

<p>Volcanoes are well known as an impressive large natural source of trace elements into the troposphere. Etna (Italy) and Nyiragongo (D.R. Congo) are two stratovolcanoes located in different geological settings, both characterized by persistent passive degassing from their summit craters. Here, we present some results on trace element composition in volcanic plume emissions, atmospheric bulk deposition (rainwater) and their uptake by the surrounding vegetation, with the aim to compare and identify differences and similarities between these two volcanoes. Volcanic emissions were sampled by using active filter-pack for acid gases (sulfur and halogens) and specific teflon filters for particulates (major and trace elements). The impact of the volcanogenic deposition in the surrounding of the crater rims was investigated by using different sampling techniques: bulk rain collectors gauges were used to collect atmospheric bulk deposition, and biomonitoring technique was carried out to collect gases and particulates by using endemic plant species. The estimates of the trace element fluxes confirm that Etna and Nyiragongo are large sources of metals into the atmosphere, especially considering their persistent state of passive degassing. The large amount of emitted trace elements has a strong impact on the close surrounding of both volcanoes. This is clearly reflected by in the chemical composition of rainwater collected at the summit areas both for Etna and Nyiragongo. Moreover, the biomonitoring results highlight that bioaccumulation of trace elements is extremely high in the proximity of the crater rim and decreases with the distance from the active craters.</p>

scholarly journals Petrology and geochemistry of granitoids and their mafic micogranular enclaves (MME) in marginal part of the Małopolska Block (S Poland)

Mineralogia ◽  
2012 ◽  
Vol 43 (1-2) ◽  
pp. 3-127 ◽  
Author(s):  
Anna Wolska
Keyword(s):  
Trace Elements ◽  
Continental Crust ◽  
Coarse Grained ◽  
Granitic Rocks ◽  
Mixing Process ◽  
Na2o Content ◽  
Fine Grained ◽  
Małopolska Block ◽  
First Time ◽  
Different Sources

AbstractGranitic plutons (the Dolina Będkowska valley and Pilica area) were found in a few boreholes in the Małopolska Block (MB). These granitic rocks may represent apical parts (apophyses) of a great magmatic bodies (batholiths) located in deeper level of the Ediacaran/Paleozoic basement. They are described as ‘stitching intrusions’, generated during/after collision in Carboniferous/Permian period (~300 Ma) between the Upper Silesian Block (USB) and the Małopolska Block (MB).These rocks are fresh, unaltered granodiorites that are pale grey in colour. They have holocrystalline, medium- to coarse-grained structure and massive texture. For the first time, several mafic microgranular enclaves (MME), varying in size and colour, were found in the granodioritic host (HG). The occurrence of MME in the host granodioritic rocks is evidence of a mingling process between mafic and felsic magmas.The MME are pale/dark grey in colour, fine-grained rocks with ‘porphyritic’ textures. They consist of large megacrysts/xenocrysts of plagioclase, quartz, alkali feldspars and the fine-grained groundmass of pseudo-doleritic textures (lath-shaped plagioclases, blade-shaped amphiboles/biotites). According to their modal/mineral composition, they represent Q-diorites and tonalites.The MME, similar to the host granodiorites (HG), are I-type rocks, exhibit high Na2O content >3.2 wt%; normative diopside or normative corundum occurs (mainly <1%). They are metaluminous to slightly peraluminous (ASI <1.1) and have calc-alkaline, medium-K to high-K character. They generally belong to magnesian series (#Mg=0.20-0.40) and have low agpaitic index (<0.87). They are low evolved magmatic rocks. The rocks studied are enriched in LREEs (La, Ce, Sm) compared to HREEs. The Eu* negative anomaly and high Sr contents point to varying degrees of plagioclase fractionation connected to the mixing process rather than simple fractional crystallization. Both rocks studied (HG and MME) are characterized by a high content of LILEs (K, Ba, Rb) in normalized patterns and a low HFS/LIL elements ratio (Ta, Nb)/(K, Rb, La). The projection points of the rocks studied plot in different fields of various petrochemical diagrams: mainly in the arc granites that are rare in the pre-collisional granites as well as the syn-subductional to post-collisional granites fields.For the first time, inner textures in rock-forming minerals related to mixing processes are described both in the granodioritic host (HG) and in the MME. Mantled boxy cellular plagioclase megacrysts with ‘old cores’ of labradorite composition, and amphibole aggregates with titanite and opaque minerals, represent peritectic rather than primary residual minerals. The plagioclase, quartz and alkali feldspar megacrysts/xenocrysts were mechanically transferred from the granodioritic host (HG) to MME. The presence of lath-shaped plagioclases, blade-shaped amphiboles/biotites and acicular-shaped apatites in the groundmass of the MME is evidence of undercooling of hot mafic blobs in a relatively cold granodioritic magma chamber. The MME were hybridized by leucocratic melt squeezed from the granodioritic magma in a later stage of the mixing process (quartz and alkali crystals in the interstices in the MME groundmass). In the granodiorites (HG), the spike and spongy cellular zones as well as biotite/amphibole zones in plagioclase megacrysts are connected to the mixing process.Both of the rocks studied are characterized by different amounts of major elements (SiO2, Na2O and K2O), trace elements (Ni, Cr, V, Ti and P), #Mg and modified alkali-lime index (MALI) that is related to their origins from different sources. On the other hand, they have similar chondrite-normalized patterns (for trace elements and REE), LILEs contents (Sr, Ba, Rb), aluminum saturation index (ASI) and isotopic signatures (high 86Sr/87Sr (0.079-0.713) and low 143Nd/144Nd (0.512) values but lower than in continental crust), which are evidence of the strong hybridisation of mafic enclaves by the granodioritic host magma. The parental rocks of both rocks studied have a similar mafic signature but were generated in different sources: the host granodiorites (HG) magma in lower continental crust rocks, and the MME magma in enriched upper mantle. The MME crystallized from strongly hybridized magma of intermediate compositions (Q-diorite, tonalite) rather than from primary mafic magma. The host granodiorites (HG) originated from completely homogenized crustal granodioritic magma which inherited its geochemical signature from ancient arc-rocks in a subduction-related setting

Imposed strain localization in the mantle section of an oceanic transform zone revealed by microstructural and stress variations

2020 ◽  
Author(s):  
Vasileios Chatzaras ◽  
Basil Tikoff ◽  
Seth C. Kruckenberg ◽  
Sarah J. Titus ◽  
Christian Teyssier ◽  
...  
Keyword(s):  
Shear Zone ◽  
Upper Mantle ◽  
Temporal Variations ◽  
Coarse Grained ◽  
Transform Fault ◽  
Differential Stress ◽  
Transform Faults ◽  
Fine Grained ◽  
Micro Deformation ◽  
Mantle Section

&lt;p&gt;Mantle earthquakes that occur deeper than the 600 &amp;#176;C isotherm in oceanic transform faults indicate seismic rupturing at conditions where viscous deformation (bulk ductile behavior) is dominant.&amp;#160; However, direct geological evidence of earthquake-related deformation at ambient upper mantle conditions is rare, impeding our understanding of earthquake dynamics in plate-boundary fault systems.&amp;#160; The Bogota Peninsula Shear Zone (BPSZ), New Caledonia, is an ancient oceanic transform fault exhumed from upper mantle depths.&amp;#160; Ductile structures in the BPSZ formed at temperatures &gt; 800 &amp;#176;C and microstructures indicate that differential stress varies spatially and temporally.&amp;#160; Spatial variation is observed as an increase in differential stress with strain toward localized zones of high strain; stress increases from 6&amp;#8211;14 MPa in coarse grained tectonites to 11&amp;#8211;22 MPa within 1&amp;#8211;2 km wide mylonite zones.&amp;#160; Temporal stress variation is observed by the formation of micro-deformation zones that seem to have brittle precursors, are filled with fine-grained recrystallized olivine grains and crosscut the background fabrics in the harzburgites that host them.&amp;#160; The micro-deformation zones are not restricted to the mylonite zones, but rather are located throughout the BPSZ, having affected the protomylonites and the coarse grained tectonites. &amp;#160;The micro-deformation zones record stresses of 22&amp;#8211;81 MPa that are 2&amp;#8211;6 times higher than the background, steady-state stresses in the surrounding mantle rocks.&amp;#160; We interpret the observed spatial and temporal variations in microstructures and stresses in the upper mantle to demonstrate the influence of seismic events in the upper part of the oceanic transform fault system.&amp;#160; We attribute the increase in stress with strain to be the result of imposed localization induced by downward propagation of the seismic rupture into the underlying mantle.&amp;#160; The micro-deformation zones could result from brittle fractures caused by earthquake-related deformation in the mantle section of the transform fault, which are in turn overprinted by ductile deformation.&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;Synthesizing the spatial and temporal variations in stresses and microstructures in the Bogota Peninsula Shear Zone we propose a conceptual model where brittle fracturing and shearing take place during coseismic rupture at increased stress, ductile flow at decaying stress is concentrated in the micro-deformation zones during postseismic relaxation, and uniformly distributed creep at low stress occurs in the host-rocks of the micro-deformation zones during interseismic deformation.&amp;#160; The critical result from the studied paleotransform zone is that the fine-grained micro-deformation zones and the mylonites do not represent weak zones. &amp;#160;Instead, they form by dislocation creep at transient high-stress deformation during the seismic cycle. &amp;#160;The spatial distribution of the micro-deformation zones also suggests that repeated stress cycles in oceanic transform faults may not localize strain in pre-existing shear zones but disperse strain across the structure.&lt;/p&gt;

Mid-Cretaceous ductile deformation on the Eastern Palmer Land Shear Zone, Antarctica, and implications for timing of Mesozoic terrane collision

2002 ◽  
Vol 139 (4) ◽  
pp. 465-471 ◽  
Author(s):  
ALAN P. M. VAUGHAN ◽  
SIMON P. KELLEY ◽  
BRYAN C. STOREY
Keyword(s):  
Shear Zone ◽  
Antarctic Peninsula ◽  
Early Cretaceous ◽  
Lower Jurassic ◽  
Ductile Deformation ◽  
Fine Grained ◽  
Form Part ◽  
Tectonic Boundary ◽  
The Antarctic ◽  
Reverse Deformation

Ar–Ar dating of high-strain ductile mylonites of the Eastern Palmer Land Shear Zone in the southern Antarctic Peninsula indicates that reverse movement on the shear zone occurred in late Early Cretaceous times (Albian), and not latest Jurassic times as previously supposed. The Eastern Palmer Land Shear Zone forms a major tectonic boundary, separating suspect arc terranes from rocks of Gondwana continental affinity. The dated mylonites are developed in Lower Jurassic plutonic rocks at Mount Sullivan, eastern Palmer Land, and form part of a zone of ductile reverse deformation up to 25 km wide. Biotite from a fine-grained mafic mylonite yields an Ar–Ar cooling age of 102.8±3.3 Ma. Movement of this age on the Eastern Palmer Land Shear Zone is coeval with circum-Pacific deformation, possibly related to a mantle superplume event, and provides support for allochthonous-terrane models for the Antarctic Peninsula with accretion in post-Early Cretaceous times.

scholarly journals Crystallization and Segregation of Syenite in Shallow Mafic Sills: Insights from the San Rafael Subvolcanic Field, Utah

2020 ◽  
Author(s):  
Aurelie Germa ◽  
Danielle Koebli ◽  
Paul Wetmore ◽  
Zachary Atlas ◽  
Austin Arias ◽  
...  
Keyword(s):  
Volcanic Rocks ◽  
Mafic Magma ◽  
Coarse Grained ◽  
Geochemical Data ◽  
Fine Grained ◽  
Mantle Sources ◽  
Plumbing Systems ◽  
Order Of Magnitude ◽  
Magma Compositions ◽  
San Rafael

Abstract Exposed plumbing systems provide important insight into crystallization and differentiation in shallow sills beneath volcanic fields. We use whole rock major element, trace element and radiogenic isotopic compositions, along with mineral geochemical data on 125 samples to examine the conditions of melt differentiation in shallow sills from the exposed 4-Ma-old San Rafael subvolcanic field (SRVF), Utah. The field consists of ∼2000 dikes, 12 sills and 63 well preserved volcanic conduits. Intrusive rocks consist of mainly fine-grained trachybasalts and coarse-grained syenites, which are alkaline, comagmatic and enriched in Ba, Sr and LREE. Within sills, syenite is found as veins, lenses, and sheets totally enveloped by the basalt. The SRVF intrusions have geochemical signatures of both enriched sub-continental lithospheric and asthenospheric mantle sources. We estimate partial melting occurred between 1·2 and 1·9 GPa (50–70 km), with mantle potential temperatures in the range 1260–1326 ± 25°C, consistent with those estimated for volcanic rocks erupted on the Colorado Plateau. Geobarometry results based on clinopyroxene chemistry indicate that (1) basalt crystallized during ascent from at least 40 km deep with limited lithospheric storage, and (2) syenites crystallized only in the sills, ∼1 km below the surface. San Rafael mafic magma was emplaced in sills and started to crystallize inward from the sill margins. Densities of basalt and syenite at solidus temperatures are 2·6 and 2·4 g/cc, respectively, with similar viscosities of ∼150 Pa s. Petrographic observations and physical properties suggest that syenite can be physically separated from basalt by crystal compaction and segregation of the tephrophonolitic residual liquid out of the basaltic crystal mush after reaching 30–45% of crystallization. Each individual sill is 10–50 m thick and would have solidified fairly rapidly (1–30 years), the same order of magnitude as the duration of common monogenetic eruptions. Our estimates imply that differentiation in individual shallow sills may occur during the course of an eruption whose style may vary from effusive to explosive by tapping different magma compositions. Our study shows that basaltic magmas have the potential to differentiate to volatile-rich magma in shallow intrusive systems, which may increase explosivity.

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