scholarly journals ‘In-Situ’ Preparation of Carbonaceous Conductive Composite Materials Based on PEDOT and Biowaste for Flexible Pseudocapacitor Application

2020 ◽  
Vol 4 (3) ◽  
pp. 87
Author(s):  
Francisco J. González ◽  
Andreina Montesinos ◽  
Javier Araujo-Morera ◽  
Raquel Verdejo ◽  
Mario Hoyos
Keyword(s):  
Activated Carbon ◽  
Composite Materials ◽  
In Situ Polymerization ◽  
Activated Carbons ◽  
Spray Coating ◽  
Energy Storage Density ◽  
Conductive Composite ◽  
In Situ Preparation ◽  
Spent Grain

Composite materials of poly(3,4-ethylenedioxythiophene) (PEDOT)/activated carbon (AC) were prepared by ‘in-situ’ polymerization and subsequently deposited by spray-coating onto a flexible electrolyte prepared in our laboratories. Two activated carbons were tested: a commercial activated carbon and a lab-made activated carbon from brewer’s spent grain (BSG). The porous and spongy structure of the composite increased the specific surface area, which helps to enhance the energy storage density. This procedure to develop conductive composite materials using AC prepared from biowaste has the potential to be implemented for the preparation of polymer-based conductive inks for further applications as electrodes in pseudocapacitors.

scholarly journals In-Situ Approaches for the Preparation of Polythiophene-Derivative Cellulose Composites with High Flexibility and Conductivity

2019 ◽  
Vol 9 (16) ◽  
pp. 3371 ◽  
Author(s):  
Francisco González ◽  
Pilar Tiemblo ◽  
Mario Hoyos
Keyword(s):  
Composite Materials ◽  
In Situ Polymerization ◽  
Spray Coating ◽  
Surface Conductivity ◽  
Cellulose Composites ◽  
Cellulose Microfibers ◽  
Cellulose Membranes ◽  
High Flexibility ◽  
Polythiophene Derivative

Composite materials of conjugated polymers/cellulose were fabricated by incorporating different polythiophene-derivative polymers: Poly(3,4-ethylenedioxythiophene) (PEDOT) and an alkylated derivative of poly(3,4-propylenedioxythiophene) (PProDOT). These conjugated polythiophenes were deposited by casting or spray coating methodologies onto three different cellulose substrates: Conventional filters papers as cellulose acetate, cellulose grade 40 Whatman® and cellulose membranes prepared from cellulose microfibers. The preparation of composite materials was carried out by two methodologies: (i) by employing in-situ polymerization of 3,4-ethylenedioxithiophene (EDOT) or (ii) by depositing solutions of poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) or lab-synthetized PProDOT. Composite materials were studied in terms of electrical conductivity and surface morphology assessed by impedance spectroscopy, surface conductivity, SEM, and 3D optical profilometry. In-situ composite materials prepared by spray coating using iron trifluoromethane sulfonate as oxidizing agent can be handled and folded as the original cellulose membranes displaying a surface conductivity around 1 S∙cm−1. This versatile procedure to prepare conductive composite materials has the potential to be implemented in flexible electrodes for energy storage applications.

scholarly journals Photocatalytic Degradation of Methylene Blue under UV Light Irradiation on Prepared CarbonaceousTiO2

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Zatil Amali Che Ramli ◽  
Nilofar Asim ◽  
Wan N. R. W. Isahak ◽  
Zeynab Emdadi ◽  
Norasikin Ahmad-Ludin ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Activated Carbon ◽  
In Situ Polymerization ◽  
Uv Light ◽  
Carbon Composite ◽  
Light Irradiation ◽  
Uv Light Irradiation ◽  
Transmission Electron ◽  
Vis Spectroscopy

This study involves the investigation of altering the photocatalytic activity of TiO2using composite materials. Three different forms of modified TiO2, namely, TiO2/activated carbon (AC), TiO2/carbon (C), and TiO2/PANi, were compared. The TiO2/carbon composite was obtained by pyrolysis of TiO2/PANi prepared by in situ polymerization method, while the TiO2/activated carbon (TiO2/AC) was obtained after treating TiO2/carbon with 1.0 M KOH solution, followed by calcination at a temperature of 450°C. X-ray powder diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared (FTIR), thermogravimetric analysis (TG-DTA), Brunauer-Emmet-Teller (BET), and UV-Vis spectroscopy were used to characterize and evaluate the prepared samples. The specific surface area was determined to be in the following order: TiO2/AC > TiO2/C > TiO2/PANi > TiO2(179 > 134 > 54 > 9 m2 g−1). The evaluation of photocatalytic performance for the degradation of methylene blue under UV light irradiation was also of the same order, with 98 > 84.7 > 69% conversion rate, which is likely to be attributed to the porosity and synergistic effect in the prepared samples.

In situ Polymerization Technique for Obtaining Composite Materials Based on Polyethylene, Multi-walled Carbon Nanotubes and Cobalt Nanoparticles

2018 ◽  
Vol 91 (1) ◽  
pp. 127-135 ◽  
Author(s):  
M. A. Kazakova ◽  
N. V. Semikolenova ◽  
E. Yu. Korovin ◽  
S. I. Moseenkov ◽  
A. S. Andreev ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Composite Materials ◽  
In Situ Polymerization ◽  
Cobalt Nanoparticles ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

Preparation of Polyaniline @ Polypyrrole Conductive Composite via In Situ Polymerization

2013 ◽  
Vol 562-565 ◽  
pp. 1137-1142
Author(s):  
Hui Xia Feng ◽  
Bing Wang ◽  
Lin Tan ◽  
Na Li Chen
Keyword(s):  
Electron Microscopy ◽  
Electrical Conductivity ◽  
Scanning Electron Microscopy ◽  
Fourier Transform ◽  
In Situ Polymerization ◽  
Conductive Composite ◽  
The Core ◽  
Novel Method ◽  
Scanning Electron

We prepared the polyaniline@polypyrrole (PAn@PPy) conductive composite by a novel method. The struction like Pre-prepared PAn as the core and PPy as the shell for the composite has been prepared by in-situ polymerization. The PAn@PPy conductive composite presents an electrical conductivity of 12.5 S/cm, which is much higher than pure PAn. The synthesized polymer composites are characterized by Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM) and Thermogravimetric analysis (TG). The results indicated that PPy successfully grafted on PAn and the heat resistance of nanocomposite is remarkably increased.

Effect of Viscoelastic Behavior on Electroconductivity of Recycled Activated Carbon Composites

2011 ◽  
Vol 70 ◽  
pp. 231-236 ◽  
Author(s):  
Takenobu Sakai ◽  
Tomohiko Gushiken ◽  
Jun Koyanagi ◽  
Rolando Rios-Soberanis ◽  
Tomoki Masuko ◽  
...  
Keyword(s):  
Composite Material ◽  
Activated Carbon ◽  
Composite Materials ◽  
Activated Carbons ◽  
Viscoelastic Behavior ◽  
Intimate Relationship ◽  
Carbon Composites ◽  
Stress Relaxation Behavior ◽  
Carbon Particles ◽  
The Relationship

In the Waterworks Bureau, the activated carbon has been used for filtering water. After the life service of activated carbon, it is normally disposed. This work focuses on the processing of a composite material in order to recycle these wasted carbon particles. These activated carbons were used for the filler of composite materials, and a composite with carbon contents of 10% ~ 60% was manufactured and characterized. They exhibited electroconductive behavior because of the carbon particles used as fillers. The electroconductivity have an intimate relationship with the strain of the material. However, because of the composite viscoelasticity, the electroconductivity presented changes by their stress relaxation behavior with the same strain. In this study, it was revealed the relationship between the viscoelasticity and the electroconductivity of recycled activated carbon composites.

Composite materials based on graphene nanoplatelets and polypropylene derived via in situ polymerization

2013 ◽  
Vol 8 (1-2) ◽  
pp. 69-80 ◽  
Author(s):  
S. V. Pol’shchikov ◽  
P. M. Nedorezova ◽  
A. N. Klyamkina ◽  
V. G. Krashenninikov ◽  
A. M. Aladyshev ◽  
...  
Keyword(s):  
Composite Materials ◽  
In Situ Polymerization ◽  
Graphene Nanoplatelets

scholarly journals Preparation of Composite Materials Containing Polyethylene and Carbon Nanotubes by in situ Ethylene Polymerization over Titanium-Magnesium Catalyst Fixed on the Surface of Carbon Nanotubes

2020 ◽  
pp. 033-042
Author(s):  
A.A. Zdanovich ◽  
◽  
M.A. Matsko ◽  
A.V. Melezhik ◽  
A.G. Tkachev ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Composite Materials ◽  
Ethylene Polymerization ◽  
In Situ Polymerization ◽  
Organomagnesium Compound ◽  
Mwcnt Surface ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
Different Molecular Weight

The data on the preparation of composite materials containing polyethylene and multi-walled carbon nanotubes (MWCNTs) of the Taunit brand are presented. To obtain these composites by in situ polymerization, a catalytic system formed by the interaction of an organomagnesium compound and TiCl4 on the surface of nanotubes was used. The catalyst fixed on the MWCNT surface has a high activity in ethylene polymerization and allows to obtain a polymer with different molecular weight. The data on the formation of a polymer on the MWCNT surface and the morphology of composites formed on various Taunit samples are presented.

Chromium(VI) removal using in-situ nitrogenized activated carbon prepared from Brewers’ spent grain

Adsorption ◽  
2017 ◽  
Vol 24 (2) ◽  
pp. 147-156 ◽  
Author(s):  
S. R. H. Vanderheyden ◽  
K. Vanreppelen ◽  
J. Yperman ◽  
R. Carleer ◽  
S. Schreurs
Keyword(s):  
Activated Carbon ◽  
Chromium Vi ◽  
Spent Grain

scholarly journals In-Situ Preparation of Conducting Polymers/Copper (II)-Maghnite Clay Nanocomposites

2017 ◽  
Vol 14 (2) ◽  
pp. 204-211 ◽  
Author(s):  
Fatima Zeggai ◽  
Mohammed Belbachir ◽  
Aicha Hachmaoui
Keyword(s):  
Conducting Polymers ◽  
In Situ Polymerization ◽  
Ammonium Persulfate ◽  
Clay Nanocomposites ◽  
X Ray Diffraction ◽  
X Ray ◽  
In Situ Preparation ◽  
Ft Ir ◽  
The Fourier Transform

In this work we report a simple way for the conducting polymer nanocomposites synthesis using on algerian hydrophilic natural Montmorillonite (MMT) nanoclay named Maghnite (Mag) as dopant. The electrochemical properties study of the following conducting polymers: poly(4-aminobenzylamine) (P4ABA) and polyaniline (PANI) nanocomposites with copper maghnite (Mag-Cu) were successfully prepared by In-Situ polymerization, in presence of inorganic nanolayers of clay, and oxidizing agent ammonium persulfate. The synthesis of copolymers was developed at different feed mole fractions of monomer. The products were characterized by the Fourier transform Infrared (FT-IR), the ultraviolet-visible (UV–vis) spectroscopies and X-ray diffraction (XRD). The results showed that the in-situ polymerization produced real nanocomposites containing aniline and 4-aminobenzylamine units.

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