scholarly journals Preparation and Characterization of Nanoporous Activated Carbon Derived from Prawn Shell and Its Application for Removal of Heavy Metal Ions

Materials ◽  
2019 ◽  
Vol 12 (2) ◽  
pp. 241 ◽  
Author(s):  
Jian Guo ◽  
Yaqin Song ◽  
Xiaoyang Ji ◽  
Lili Ji ◽  
Lu Cai ◽  
...  

The aim of this study was to optimize the adsorption performance of activated carbon (AC), derived from the shell of Penaeus vannamei prawns, on heavy metal ions. Inexpensive, non-toxic, and renewable prawn shells were subjected to carbonization and, subsequently, KOH-activation to produce nanoporous K-Ac. Carbonized prawn shells (CPS) and nanoporous KOH-activated carbon (K-Ac) from prawn shells were prepared and characterized by FTIR, XRD, BET, SEM, and TEM. The results showed that as-produced K-Ac samples were a porous material with microporous and mesoporous structures and had a high specific surface area of 3160 m2/g, average pore size of about 10 nm, and large pore volume of 2.38 m3/g. Furthermore, batches of K-Ac samples were employed for testing the adsorption behavior of Cd2+ in solution. The effects of pH value, initial concentration, and adsorption time on Cd2+ were systematically investigated. Kinetics and isotherm model analysis of the adsorption of Cd2+ on K-Ac showed that experimental data were not only consistent with the Langmuir adsorption isotherm, but also well-described by the quasi-first-order model. Finally, the adsorption behaviors of as-prepared K-Ac were also tested in a ternary mixture of heavy metal ions Cu2+, Cr6+, and Cd2+, and the total adsorption amount of 560 mg/g was obtained.

2019 ◽  
Vol 80 (8) ◽  
pp. 1407-1412 ◽  
Author(s):  
Rue Chiramba ◽  
Gratitude Charis ◽  
Nonhlanhla Fungura ◽  
Gwiranai Danha ◽  
Tirivaviri Mamvura

Abstract Contamination of water bodies by heavy metal ions is a challenge many developing nations like Zimbabwe face, with negative environmental and socio-economic repercussions. Treating affected bodies usually requires a costly consignment of chemicals and activated carbon. This research investigates the possible use of an abundant waste resource – poultry feathers – to make activated carbon for heavy metal ion removal. Poultry consumption in this nation generates more than five million tonnes of feathers a year, with very few uses of this by-product. This research was carried out to evaluate the effectiveness of activated carbon synthesized from poultry feathers with sodium hydroxide as the activating agent. It was tested for removing heavy metal ions from waste water at Lake Chivero and the experimental work done showed that it had a removal efficiency as high as 97%, with a high affinity for lead ions as compared with chromium ions. Upon characterization, the activated carbon showed an iodine number of 520 mg and it worked best at a pH value of 8. The efficiency removal also increased with increasing adsorbent concentration as well as contact time up to a period where these factors ceased to be the limiting factors of the reaction.


2013 ◽  
Vol 773 ◽  
pp. 283-288
Author(s):  
Xing Zou ◽  
Xiang Quan Chen ◽  
Hai Chao Xie ◽  
Xiao Dan Qiu

The manganese sulfate solution leached from low-grade pyrolusite with pyrite and H2SO4 contains heavy metal ions of high concentration, influencing the quality of the final products of manganese compounds and causing manganese ions not to be electrolyzed. The present study was focused on the separation of Co, Ni and Zn ions from the leached solution with BaS. By controlling the pH value at 5.0-6.5, temperature at 50-60°C, reaction time at 15 min and mixing velocity at 78 rpm, the heavy metal ions could be separated effectively. Under the above optimized conditions, the ion concentration of Co, Ni, and Zn in the solution was reduced to 0.06 mg.L-1, 0.27mg.L-1 and 0.01mg.L-1, and the separation efficiency was 99.72%, 99.18% and 99.9% respectively. The obtained pure solution meets the demands of manganese electrowinning.


2021 ◽  
Vol 221 ◽  
pp. 239-251
Author(s):  
Syed Muhammad Salman ◽  
Fouzia Kamal ◽  
Muhammad Zahoor ◽  
Muhammad Wahab ◽  
Durr e Shahwar ◽  
...  

2020 ◽  
Vol 17 (1) ◽  
pp. 74-90 ◽  
Author(s):  
Nader Ghaffari Khaligh ◽  
Mohd Rafie Johan

: A variety of processes were reported for efficient removing of heavy metal from wastewater, including but not limited to ion exchange, reverse osmosis, membrane filtration, flotation, coagulation, chemical precipitation, solvent extraction, electrochemical treatments, evaporation, oxidation, adsorption, and biosorption. Among the aforementioned techniques, adsorption/ion exchange has been known as a most important method for removing heavy metal ions and organic pollutants due to great removal performance, simple and easy process, cost-effectiveness and the considerable choice of adsorbent materials. : Nanotechnology and its applications have been developed in most branches of science and technology. Extensive studies have been conducted to remove heavy metal ions from wastewater by preparation and applications of various nanomaterials. Nanomaterials offer advantages in comparison to other materials including an extremely high specific surface area, low-temperature modification, short intraparticle diffusion distance, numerous associated sorption sites, tunable surface chemistry, and pore size. In order to evaluate an adsorbent, two key parameters are: the adsorption capacity and the desorption property. The adsorption parameters including the absorbent loading, pH and temperature, concentration of heavy metal ion, ionic strength, and competition among metal ions are often studied and optimized. : Several reviews have been published on the application of Graphene (G), Graphene Oxide (GO) in water treatment. In this minireview, we attempted to summarize the recent research advances in water treatment and remediation process by graphene-based materials and provide intensive knowledge of the removal of pollutants in batch and flow systems. Finally, future applicability perspectives are offered to encourage more interesting developments in this promising field. This minireview does not include patent literature.


2020 ◽  
Vol 6 (2) ◽  
pp. 331-340 ◽  
Author(s):  
Cuijiao Zhao ◽  
Xinlei Wang ◽  
Shengbo Zhang ◽  
Na Sun ◽  
Hongjian Zhou ◽  
...  

Porous graphitic carbon nanosheets functionalized by ultrafine Fe3O4 NPs and amino-functionalized activated carbon were developed to construct a hybrids capacitive deionization for efficient removal of multiple heavy metal ions in water.


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