scholarly journals Neutralization of Acidic Wastewater from a Steel Plant by Using CaO-Containing Waste Materials from Pulp and Paper Industries

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2653
Author(s):  
Tova Jarnerud ◽  
Andrey V. Karasev ◽  
Pär G. Jönsson

In this study, CaO-containing wastes from pulp and paper industries such as fly ash (FA) and calcined lime mud (LM) were utilized to neutralize and purify acidic wastewaters from the pickling processes in steel mills. The investigations were conducted by laboratory scale trials using four different batches of wastewaters and additions of two types of CaO-containing waste materials. Primary lime (PL), which is usually used for the neutralization, was also tested in the same experimental set up in the sake of comparison. The results show that these secondary lime sources can effectively increase the pH of the acidic wastewaters as good as the commonly used primary lime. Therefore, these secondary lime sources could be potential candidates for application in neutralization processes of industrial acidic wastewater treatment. Moreover, concentrations of metals (such as Cr, Fe, Ni, Mo and Zn) can decrease dramatically after neutralization by using secondary lime. The LM has a purification effect from the given metals, similar to the PL. Application of fly ash and calcined lime mud as neutralizing agents can reduce the amount of waste from pulp and paper mills sent to landfill and decrease the need for nature lime materials in the steel industry.

2020 ◽  
Vol 261 ◽  
pp. 121182 ◽  
Author(s):  
Xianfeng Hu ◽  
Tova Jarnerud ◽  
Andrey Karasev ◽  
Pär G. Jönsson ◽  
Chuan Wang

2019 ◽  
Vol 11 (16) ◽  
pp. 4394 ◽  
Author(s):  
Chinchu Cherian ◽  
Sumi Siddiqua

The continual growth of pulp and paper industry has led to the generation of tremendous volumes of fly ash as byproducts of biomass combustion processes. Commonly, a major part of it is landfilled; however, updated environmental regulations have tended to restrict the landfilling of fly ash due to rising disposal costs and the scarcity of suitable land. The pulp and paper industries are therefore urgently seeking energy-efficient mechanisms and management for the beneficial use of fly ash in an ecological and economical manner. This paper offers a comprehensive review of existing knowledge on the major physicochemical and toxicological properties of pulp and paper mill fly ash to assess its suitability for various bound and unbound applications. The current state of various methods used for the valorization of pulp and paper mill fly ash into more sustainable geomaterials is briefly discussed. This paper also presents promising and innovative applications for pulp and paper mill fly ash, with particular reference to agriculture and forestry, the construction and geotechnical industries, and the immobilization of contaminants. It was identified from a literature review that modified pulp and paper mill fly ash can be environmentally and economically advantageous over commercial coal-based fly ash in various sustainable applications.


1996 ◽  
Vol 1 (4) ◽  
pp. 379-401 ◽  
Author(s):  
David A. Sonnenfeld

This paper analyzes how a key conflict in Australia's pulp and paper industry became generalized to other sites through environmental action, government regulation, and industry initiative. From 1987–91, Australians debated construction of a new, world-class, export-oriented pulp mill in Tasmania. Rural residents, fishermen, and environmentalists, allied with the Australian Labor Party, succeeded in scuttling the project. Subsequently, the national government launched a major research program, state governments tightened regulations, and industry reduced elemental chlorine use. Any new mills constructed in Australia today would be among the cleanest in the world. This paper is part of a larger, comparative study of technological innovation in the pulp and paper industries of Australia, Indonesia, Malaysia, and Thailand. The author interviewed industry officials, government regulators, research scientists, and environmentalists; visited pulp and paper mills; attended technical conferences; and conducted archival work in these countries during a 12-month period.


Cerâmica ◽  
2018 ◽  
Vol 64 (371) ◽  
pp. 443-453 ◽  
Author(s):  
L. Simão ◽  
D. Hotza ◽  
F. Raupp-Pereira ◽  
J. A. Labrincha ◽  
O. R. K. Montedo

Abstract The production of pulp and paper is increasing worldwide, and wastes are therefore being generated in appreciable amounts. Various materials are generated in pulp and paper mills, such as ash, dregs, grits, lime mud and pulp mill sludge. Over the years, these wastes have typically been sent to landfills or incinerated. However, with increased environmental awareness new alternatives have been investigated, especially the valorization of these materials. In this review, the characteristics of the manufacturing process, generated wastes, main destinations and recycling alternatives are addressed. The state of the art indicates that dregs are useful in agriculture as soil amendments, while lime mud can be used in agriculture and in environmental technology, mainly in wastewater treatment. Grits are commonly employed in construction, and pulp mill sludge shows applications in agriculture, construction and energy processes. In conclusion, this review shows several successful cases of recycling wastes from pulp and paper mills.


2017 ◽  
Vol 9 (2) ◽  
pp. 247-284 ◽  
Author(s):  
Art Fraas ◽  
Alex Egorenkov

Under the 1990 Clean Air Act Amendments, the U.S. Environmental Protection Agency (EPA) was required to establish standards limiting air toxics emissions from industrial plants. This paper examines the effects of five of the largest-cost rules issued by EPA in the initial round of air toxics rulemaking over the 1995 to 2000 period. Our estimates suggest that plants in the printing and publishing and pulp and paper industries realized important reductions in their air toxics emissions in the period between publication of the final rule and the effective date for compliance with the rule – although the reduction in air toxics emissions by pulp and paper mills fell short of EPA’s ex ante projections. However, our estimates also suggest that plants in three other industries – petroleum refining, pharmaceuticals, and wood furniture – achieved little or no additional reduction in air toxics emissions over the compliance period in response to EPA’s rules. Finally, the paper explores steps that EPA should take in setting up future retrospective analyses.


2020 ◽  
Vol 13 (3) ◽  
pp. 174-180
Author(s):  
Uma Shankar Singh ◽  
Suresh Panwar ◽  
R.K. Jain ◽  
Y.C. Tripathi

The pulp and paper industries discharge of large amount of effluent as wastewater in the surrounding streams thereby causing serious health and environmental problems. These large quantities of effluents need to be characterized for evolving proper treatment strategy prior to their disposal. Physicochemical characteristics of effluents from an agro-based paper mills located in Uttarakhand state of India were analyzed in terms of pH, colour, TS, TDS, TSS, turbidity, BOD, COD, and AOX. The effluent samples collected from different processing units of the paper mill varied considerably across the discharge streams. The mean values pH, colour, TS, TDS, TSS, turbidity, BOD, COD, and AOX were found in the range of 2.559.8±0.05, 4102802 PCU, 1980.652785.79 ppm, 1650.672470.35 ppm, 315.44 401.35 ppm, 73.22349.37 NTU, 170.32670.42, 705.522000.55 ppm, and 14.9840.82 respectively. Result shows that all the studied physicochemical parameters of effluents at different processing units of the mill are higher than the permissible standards that need proper treatment for their safe disposal.


TAPPI Journal ◽  
2018 ◽  
Vol 17 (03) ◽  
pp. 167-178 ◽  
Author(s):  
Xin Tong ◽  
Jiao Li ◽  
Jun Ma ◽  
Xiaoquan Chen ◽  
Wenhao Shen

Studies were undertaken to evaluate gaseous pollutants in workplace air within pulp and paper mills and to consider the effectiveness of photo-catalytic treatment of this air. Ambient air at 30 sampling sites in five pulp and paper mills of southern China were sampled and analyzed. The results revealed that formaldehyde and various benzene-based molecules were the main gaseous pollutants at these five mills. A photo-catalytic reactor system with titanium dioxide (TiO2) was developed and evaluated for degradation of formaldehyde, benzene and their mixtures. The experimental results demonstrated that both formaldehyde and benzene in their pure forms could be completely photo-catalytic degraded, though the degradation of benzene was much more difficult than that for formaldehyde. Study of the photo-catalytic degradation kinetics revealed that the degradation rate of formaldehyde increased with initial concentration fitting a first-order kinetics reaction. In contrast, the degradation rate of benzene had no relationship with initial concentration and degradation did not conform to first-order kinetics. The photo-catalytic degradation of formaldehyde-benzene mixtures indicated that formaldehyde behaved differently than when treated in its pure form. The degradation time was two times longer and the kinetics did not reflect a first-order reaction. The degradation of benzene was similar in both pure form and when mixed with formaldehyde.


2014 ◽  
Vol 10 (1) ◽  
pp. 1-15
Author(s):  
Z. Láng

The possible effect of shaker harvest on root damage of 10-year-old cherry trees was studied on a simple tree structure model. The model was composed of elastic trunk and rigid main roots, the ends of which were connected to the surrounding soil via springs and dumping elements. Equations were set up to be able to calculate the relation between shaking height on the trunk and strain in the roots. To get the data for root break and their elongation at different shaking heights on the trunk, laboratory and field experiments were carried out on cherry trees and on their roots. Having evaluated the measured and calculated data it could be concluded that root damage is to be expected even at 3.6% strain and the risk of it increases with increased trunk amplitudes, i.e.with the decrease of shaking heightat smaller stem diameters (i.e. in younger plantation), andif the unbalanced mass of the shaker machine is too large for the given tree size.


2012 ◽  
Vol 11 (1) ◽  
pp. 81-85 ◽  
Author(s):  
Dan Gavrilescu ◽  
Adrian Catalin Puitel ◽  
Gheorghe Dutuc ◽  
Grigore Craciun

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