scholarly journals Applications of Chemically Modified Clay Minerals and Clays to Water Purification and Slow Release Formulations of Herbicides

Minerals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 9
Author(s):  
Tomas Undabeytia ◽  
Uri Shuali ◽  
Shlomo Nir ◽  
Baruch Rubin
Keyword(s):  
Clay Minerals ◽  
Field Experiments ◽  
Slow Release ◽  
Freeze Fracture ◽  
Nano Particles ◽  
Organic Cations ◽  
Small Scale ◽  
High Exposure ◽  
Model Calculations ◽  
Slow Release Formulations

This review deals with modification of montmorillonite and other clay-minerals and clays by interacting them with organic cations, for producing slow release formulations of herbicides, and efficient removal of pollutants from water by filtration. Elaboration is on incorporating initially the organic cations in micelles and liposomes, then producing complexes denoted micelle- or liposome-clay nano-particles. The material characteristics (XRD, Freeze-fracture electron microscopy, adsorption) of the micelle– or liposome–clay complexes are different from those of a complex of the same composition (organo-clay), which is formed by interaction of monomers of the surfactant with the clay-mineral, or clay. The resulting complexes have a large surface area per weight; they include large hydrophobic parts and (in many cases) have excess of a positive charge. The organo-clays formed by preadsorbing organic cations with long alkyl chains were also addressed for adsorption and slow release of herbicides. Another examined approach includes “adsorptive” clays modified by small quaternary cations, in which the adsorbed organic cation may open the clay layers, and consequently yield a high exposure of the siloxane surface for adsorption of organic compounds. Small scale and field experiments demonstrated that slow release formulations of herbicides prepared by the new complexes enabled reduced contamination of ground water due to leaching, and exhibited enhanced herbicidal activity. Pollutants removed efficiently from water by the new complexes include (i) hydrophobic and anionic organic molecules, such as herbicides, dissolved organic matter; pharmaceuticals, such as antibiotics and non-steroidal drugs; (ii) inorganic anions, e.g., perchlorate and (iii) microorganisms, such as bacteria, including cyanobacteria (and their toxins). Model calculations of adsorption and kinetics of filtration, and estimation of capacities accompany the survey of results and their discussion.

Validation of a fast gas chromatographic method for the study of semiochemical slow release formulations

2010 ◽  
Vol 53 (4) ◽  
pp. 962-972 ◽  
Author(s):  
Stéphanie Heuskin ◽  
Eric Rozet ◽  
Stéphanie Lorge ◽  
Julien Farmakidis ◽  
Philippe Hubert ◽  
...  
Keyword(s):  
Chromatographic Method ◽  
Slow Release ◽  
Slow Release Formulations ◽  
Gas Chromatographic Method

Novel highly-swellable and pH-responsive slow release formulations of clotrimazole with chitosan-g-PEG/starch microparticles

2019 ◽  
Vol 135 ◽  
pp. 32-43 ◽  
Author(s):  
Ozioma Udochukwu Akakuru ◽  
Hitler Louis ◽  
Romanus Uwaoma ◽  
Elias Emeka Elemike ◽  
Obinna Chigoziem Akakuru
Keyword(s):  
Slow Release ◽  
Ph Responsive ◽  
Slow Release Formulations

scholarly journals On the relationship between acetone and carbon monoxide in air masses of different origin

2003 ◽  
Vol 3 (1) ◽  
pp. 1017-1049
Author(s):  
M. de Reus ◽  
H. Fischer ◽  
F. Arnold ◽  
J. de Gouw ◽  
R. Holzinger ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Carbon Monoxide ◽  
Field Experiments ◽  
Marine Boundary Layer ◽  
Biogenic Emissions ◽  
Model Calculations ◽  
Single Observation ◽  
Tropical Regions ◽  
Air Masses ◽  
Clean Air

Abstract. Carbon monoxide and acetone measurements are presented for five aircraft measurement campaigns at mid-latitudes, polar and tropical regions in the northern hemisphere. Throughout all campaigns, free tropospheric air masses, which were influenced by anthropogenic emissions, showed a similar linear relation between CO and acetone, with a slope of 21–25 pptv acetone/ppbv CO. Measurements in the anthropogenically influenced marine boundary layer revealed a slope of 13–16 pptv acetone/ppbv CO. The different slopes observed in the marine boundary layer and the free troposphere indicate that acetone is emitted by the ocean in relatively clean air masses and taken up by the ocean in polluted air masses. In the lowermost stratosphere, a good correlation between CO and acetone was observed as well, however, with a much smaller slope (~5 pptv acetone/ppbv CO) compared to the troposphere. This is caused by the longer photochemical lifetime of CO compared to acetone in the lower stratosphere, due to the increasing photolytic loss of acetone and the decreasing OH concentration with altitude. No significant correlation between CO and acetone was observed over the tropical rain forest due to the large direct and indirect biogenic emissions of acetone. The common slopes of the linear acetone-CO relation in various layers of the atmosphere, during five field experiments, makes them useful for model calculations. Often a single observation of the CO-acetone correlation, determined from stratospheric measurements, has been used in box model applications. This study shows that different slopes have to be considered for marine boundary layer, free tropospheric and stratospheric air masses, and that the CO-acetone relation cannot be used for air masses which are strongly influenced by biogenic emissions.

A new matrix for toxic baits for control of the leaf-cutting ant Acromyrmex octospinosus (Reich) (Hymenoptera: Formicidae)

1981 ◽  
Vol 71 (4) ◽  
pp. 607-616 ◽  
Author(s):  
A. R. Jutsum ◽  
J. M. Cherrett
Keyword(s):  
Slow Release ◽  
Weight Ratio ◽  
Small Scale ◽  
Pest Species ◽  
Light Weight ◽  
Acromyrmex Octospinosus ◽  
Aerial Application ◽  
Citrus Pulp ◽  
Leaf Cutting ◽  
Excellent Control

AbstractA new easily-produced cheap compound for use as a bait matrix is described. The light-weight matrix of polyurethane is prepared from dense precursors into which suitable attractants and toxicants can be incorporated for the pest species in question. It has a high bait effectiveness/weight ratio, and so is very suitable for aerial application as large economically viable payloads can be achieved. When tested both in the laboratory and in the field on a small scale against the leaf-cutting ant Acromyrmex octospinosus (Reich), the bait was highly acceptable to the ants. Some formulations, especially those coated with mirex gave excellent control of ants in the field in Trinidad, killing all occupants of nests within four days of baiting. The bait exhibited good weathering properties, was resistant to fungus attack, and allowed the slow release of pheromones. It was much cheaper than the citrus pulp baits normally used in Trinidad.

Progress towards small-scale field trials of coastal enhanced weathering of olivine

2021 ◽  
Author(s):  
Stephen Romaniello ◽  
Shanee Stopnitzky ◽  
Tom Green ◽  
Francesc Montserrat ◽  
Eric Matzner ◽  
...  
Keyword(s):  
Real World ◽  
Field Experiments ◽  
Ecological Impact ◽  
Field Trials ◽  
Research Strategy ◽  
Unintended Consequences ◽  
Ecological Impacts ◽  
Small Scale ◽  
Climate Mitigation ◽  
Stage Of Development

<p>Slow progress towards achieving global greenhouse gas emissions targets significantly increases the likelihood that future climate efforts may require not only emissions cuts but also direct climate mitigation via negative emissions technologies (IPCC AR5). Currently, such technologies exist at only a nascent stage of development, with significant uncertainties regarding their feasibility, cost, and potential unintended consequences and/or co-benefits.</p><p>Coastal enhanced weathering of olivine (CEWO) has been suggested as one potential pathway for achieving net negative CO<sub>2</sub> emissions at scale. CEWO involves the mining of olivine-rich ultramafic rocks (such as dunite) for incorporation during beach augmentation and restoration work. While grinding this rock into increasingly fine particle sizes is essential for increasing its surface area and reactivity, this step is also costly and energetically expensive. CEWO attempts to minimize this cost and energy penalty by relying on wave and tidal action to provide ongoing physical weathering of olivine grains once distributed on beaches. Laboratory experiments and carbon emissions assessments of CEWO suggest that these approaches may be technically feasible and carbon negative, but significant uncertainties remain regarding the real-world kinetics of coastal olivine dissolution. Furthermore, concerns about the fate and ecological impact of nickel (Ni) and chromium (Cr)—potentially toxic trace metals found in olivine—require careful evaluation.</p><p>In 2019, Project Vesta was established as a nonprofit, philanthropically funded effort to evaluate the technical feasibility and ecological impacts of CEWO through a dedicated research program ultimately culminating in small-scale, real-world field trials of CEWO. This presentation will provide an overview and discussion of our overall research strategy, share insights from interim modeling and mesocosm experiments designed to ensure the practicality and safety of future field experiments, and explain our approach for ensuring transparent, responsible, and ethical research oversight and governance.</p>

scholarly journals The relationship between small-scale and large-scale ionospheric electron density irregularities generated by powerful HF electromagnetic waves at high latitudes

2006 ◽  
Vol 24 (11) ◽  
pp. 2901-2909 ◽  
Author(s):  
E. D. Tereshchenko ◽  
B. Z. Khudukon ◽  
M. T. Rietveld ◽  
B. Isham ◽  
T. Hagfors ◽  
...  
Keyword(s):  
Geomagnetic Field ◽  
Electromagnetic Waves ◽  
Large Scale ◽  
Small Scale ◽  
Direction Parallel ◽  
Model Calculations ◽  
Amplitude Fluctuations ◽  
Field Lines ◽  
Experimental Values ◽  
Magnetic Zenith

Abstract. Satellite radio beacons were used in June 2001 to probe the ionosphere modified by a radio beam produced by the EISCAT high-power, high-frequency (HF) transmitter located near Tromsø (Norway). Amplitude scintillations and variations of the phase of 150- and 400-MHz signals from Russian navigational satellites passing over the modified region were observed at three receiver sites. In several papers it has been stressed that in the polar ionosphere the thermal self-focusing on striations during ionospheric modification is the main mechanism resulting in the formation of large-scale (hundreds of meters to kilometers) nonlinear structures aligned along the geomagnetic field (magnetic zenith effect). It has also been claimed that the maximum effects caused by small-scale (tens of meters) irregularities detected in satellite signals are also observed in the direction parallel to the magnetic field. Contrary to those studies, the present paper shows that the maximum in amplitude scintillations does not correspond strictly to the magnetic zenith direction because high latitude drifts typically cause a considerable anisotropy of small-scale irregularities in a plane perpendicular to the geomagnetic field resulting in a deviation of the amplitude-scintillation peak relative to the minimum angle between the line-of-sight to the satellite and direction of the geomagnetic field lines. The variance of the logarithmic relative amplitude fluctuations is considered here, which is a useful quantity in such studies. The experimental values of the variance are compared with model calculations and good agreement has been found. It is also shown from the experimental data that in most of the satellite passes a variance maximum occurs at a minimum in the phase fluctuations indicating that the artificial excitation of large-scale irregularities is minimum when the excitation of small-scale irregularities is maximum.

Pharmacokinetic comparison of two carbamazepine slow-release formulations

2009 ◽  
Vol 82 (2) ◽  
pp. 135-137 ◽  
Author(s):  
P. K. Jensen ◽  
A. Møller ◽  
L. Gram ◽  
N. O. Jensen ◽  
M. Dam
Keyword(s):  
Slow Release ◽  
Slow Release Formulations

Non-Linear Space-Time Evolution of Wave Groups With a High Crest

2003 ◽  
Author(s):  
Felice Arena ◽  
Francesco Fedele
Keyword(s):  
Time Evolution ◽  
Field Experiments ◽  
Surface Displacement ◽  
Fixed Time ◽  
Space Time ◽  
Second Order ◽  
Small Scale ◽  
Free Surface Displacement ◽  
Non Linear ◽  
Space Time Evolution

The theory of quasi-determinism, for the mechanics of linear three-dimensional waves, was obtained by Boccotti in the eighties. The first formulation of the theory deals with the largest crest amplitude; the second formulation deals with the largest wave height. The theory was verified in the nineties with some small-scale field experiments. In this paper the first formulation of Boccotti’s theory, valid for the space-time domain, is extended to the second order. The analytical expressions of the non-linear free surface displacement and velocity potential are obtained. Therefore the space-time evolution of a wave group, to the second-order in a Stokes expansion, when a very large crest occurs at a fixed time and location, is investigated. Finally the second-order probability of exceedance of the crest amplitude is obtained, as a function of two deterministic parameters.

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