scholarly journals Characterizing the Diffusion and Rheological Properties of Aged Asphalt Binder Rejuvenated with Bio-Oil Based on Molecular Dynamic Simulations and Laboratory Experimentations

Molecules ◽  
2021 ◽  
Vol 26 (23) ◽  
pp. 7080
Author(s):  
Xiaorui Zhang ◽  
Chao Han ◽  
Xinxing Zhou ◽  
Frédéric Otto ◽  
Fan Zhang
Keyword(s):  
Soybean Oil ◽  
Rheological Properties ◽  
Chemical Structure ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Dynamic Simulations ◽  
Bio Oil ◽  
Aged Asphalt ◽  
Complex Shear ◽  
Potential Use

Soybean-derived bio-oil is one of the vegetable-based oils that is gaining the most interest for potential use in the rejuvenation of aged asphalt binders. This laboratory study was conducted to characterize and quantify the diffusion and rheological properties of bio-oil-rejuvenated aged asphalt binder (BRAA) using soybean oil. In the study, the chemical structure of the soybean oil was comparatively characterized using an element analyzer (EA), gel permeation chromatography (GPC), and a Fourier infrared (FTIR) spectrometer, respectively. Based on the chemical structure of the bio-oil, BRAA molecular models were built for computing the diffusion parameters using molecular dynamic simulations. Likewise, a dynamic shear rheometer (DSR) test device was used for measuring and quantifying the rheological properties of the aged asphalt binder rejuvenated with 0%, 1%, 2%, 3%, 4%, and 5% soybean oil, respectively. The laboratory test results indicate that bio-oil could potentially improve the diffusion coefficients and phase angle of the aged asphalt binder. Similarly, the corresponding decrease in the complex shear modulus has a positive effect on the low-temperature properties of BRAA. For a bio-oil dosage 4.0%, the diffusion coefficients of the BRAA components are 1.52 × 10−8, 1.33 × 10−8, 3.47 × 10−8, 4.82 × 10−8 and 3.92 × 10−8, respectively. Similarly, the corresponding reduction in the complex shear modulus from 1.27 × 107 Pa to 4.0 × 105 Pa suggests an improvement in the low-temperature properties of BRAA. Overall, the study contributes to the literature on the potential use of soybean-derived bio-oil as a rejuvenator of aged asphalt binders.

Rheological Properties of High Grade Asphalt and its Mixture

2014 ◽  
Vol 599 ◽  
pp. 244-247 ◽  
Author(s):  
Qun Shan Ye ◽  
Chang Jian Ye ◽  
Zhi Lin Sun
Keyword(s):  
Rheological Properties ◽  
Dynamic Modulus ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Asphalt Mixture ◽  
Asphalt Binders ◽  
Test Results ◽  
Complex Shear Modulus ◽  
Complex Shear ◽  
Dynamic Modulus Test

Viscosity test, dynamic shear test, dynamic modulus test and creep test were conducted to investigate the rheological properties of high modulus asphalt and its mixture. Test results indicated that the viscosity of hard grade asphalt could be increased when compared with the ordinary asphalt, especially at high temperatures. The complex shear modulus and dynamic modulus of hard-grade asphalt binder and its mixture were increased, which implied that the stiffness of them was enhanced. Furthermore, the elastically portions for viscoelastic property of asphalt binders were increased, which resulted in the reduction of phase angle for hard grade asphalt binders and mixtures. The rutting parameter for hard-grade asphalt mixture was increased remarkably, which revealed that the resistance to permanent deformation could be significantly improved for hard grade asphalt mixture.

scholarly journals Changes in Nanoscaled Mechanical and Rheological Properties of Asphalt Binders Caused by Aging

2015 ◽  
Vol 2015 ◽  
pp. 1-6 ◽  
Author(s):  
Ben Liu ◽  
Junan Shen ◽  
Xuyan Song
Keyword(s):  
Thin Film ◽  
Atomic Force Microscope ◽  
Rheological Properties ◽  
Asphalt Binder ◽  
Adhesive Force ◽  
Asphalt Binders ◽  
Dynamic Shear ◽  
Short Term ◽  
Atomic Force ◽  
Aged Asphalt

Aging of an asphalt binder causes the changes in the microstructure and, consequently, in the nanomechanical and rheological properties of the aged asphalt binder. Short-term aging on asphalt binders was simulated using rotating thin film oven (RTFO). These changes in the microstructure and nanomechanical and rheological properties were measured using atomic force microscope (AFM) and dynamic shear rheometer (DSR). The results indicated that (1) the adhesive force of the asphalt binder from AFM tests was increased after RTFO aging; (2)G*of the asphalt binder from DSR tests increased after RTFO aging; (3) the results from AFM were consistent with those from DSR, explaining the mechanism of the changes of rheological properties.

Dynamic Properties of Asphalt Binders Containing Fiber Modifiers

2010 ◽  
Vol 97-101 ◽  
pp. 724-727 ◽  
Author(s):  
Qun Shan Ye ◽  
Shao Peng Wu
Keyword(s):  
Shear Test ◽  
Dynamic Properties ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Test Results ◽  
Modified Asphalt ◽  
Rate Versus ◽  
Complex Shear ◽  
Creep Modulus ◽  
Phase Angles

Dynamic shear test and creep shear test were employed to investigate the dynamic properties of various fiber modified asphalt binders with the fiber content of 1.0%. The test results indicate that complex shear modulus of asphalt binders containing fibers are increased while the phase angles are decreased greatly, which implies that the asphalt binder is reinforced by the addition of fibers and the elastic property of asphalt binder is improved significantly, especially at high frequency levels. The total strain during loading period and the residual strain after the creep shear test of asphalt binders are reduced greatly by the addition of fibers. Furthermore, the creep modulus of fiber modified asphalt binders is increased and the development rate versus loading time of creep modulus is decreased.

scholarly journals Effects of WMA Additive on the Rheological Properties of Asphalt Binder and High Temperature Performance Grade

2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Jiupeng Zhang ◽  
Guoqiang Liu ◽  
Li Xu ◽  
Jianzhong Pei
Keyword(s):  
Critical Temperature ◽  
Rheological Properties ◽  
Asphalt Binder ◽  
Aging Effect ◽  
Asphalt Binders ◽  
Short Term ◽  
Performance Grade ◽  
Temperature Performance ◽  
Effects Of Temperature ◽  
Increasing Temperature

Sasobit additives with different dosages were added into 70# and 90# virgin asphalt binders to prepare WMA binders. The rheological properties, includingG∗andδ, were measured by using DSR at the temperature ranging from 46°C to 70°C, and the effects of temperature, additive dosage and aging onG∗/sin⁡δ, critical temperature, and H-T PG were investigated. The results indicate that WMA additive improvesG∗but reducesδ, and the improvement on 70# virgin binder is more significant.G∗/sin⁡δexponentially decreases with the increasing temperature but linearly increases with the increasing additive dosage. Aging effect weakens the interaction between binder and additive but significantly increases the binder’s viscosity; that is whyG∗/sin⁡δis higher after short-term aging. In addition, the critical temperature increases with the increasing additive dosage, and the additive dosage should be more than 3% and 5% to improve H-T PG by one grade for 70# and 90# virgin binder, respectively.

Rheological characterization of asphalt binders treated with bio sealants for pavement preservation

2018 ◽  
Vol 45 (5) ◽  
pp. 407-412
Author(s):  
Debaroti Ghosh ◽  
Mugurel Turos ◽  
Ed Johnson ◽  
Mihai Marasteanu
Keyword(s):  
Rheological Properties ◽  
Asphalt Binder ◽  
Field Investigation ◽  
Asphalt Binders ◽  
Rheological Characterization ◽  
Softening Effect ◽  
Laboratory Findings ◽  
Pavement Preservation ◽  
Performance Grade ◽  
Water Based

Pavement preservation is playing an increasingly significant role in maintaining our aged pavement infrastructure under severe budget constraints. One important component is the use of surface treatments based on application of sealants. Recently, a number of new products, called bio sealants, have been used to treat aging pavement surfaces. The objective of this study is to investigate rheological properties of the binders treated with these materials to understand the mechanism by which they may improve pavement performance. One plain asphalt binder and four types of sealants, two oil-based sealants, one water-based sealant, and one traditional emulsion were used in the experimental work. The results obtained using a dynamic shear rheometer and a bending beam rheometer were used to determine the changes in rheological properties and the change in performance grade. It was observed that the oil-based sealants have a significant softening effect of the control binder compared to the water-based sealants. The transverse cracking histories from field investigation were used to verify the laboratory findings.

The Applicability of Estimated Equations of Recycling Agents on the Viscosity Variety of Aged Asphalt Binders

2013 ◽  
Vol 723 ◽  
pp. 670-677 ◽  
Author(s):  
Ping Sien Lin ◽  
Chi Wen Chang ◽  
Tung Lin Wu
Keyword(s):  
Asphalt Binder ◽  
Asphalt Binders ◽  
Apparent Effect ◽  
Reclaimed Asphalt ◽  
Aged Asphalt

This study was to perform the viscosity test of adding different ratios (from 10% to 40%) of three recycling agents (RAs), namely RA25, RA75 and RA250, to the reclaimed asphalt binder (RAB) containing a viscosity of 42800 poises. The purpose of the study was to determine the effects of various RAs on the viscosity of aged asphalt binders. The viscosity values were also estimated based on the recycling model of aged asphalt binder developed by authors and the equations developed by Arrhenius (1887), Grunberg and Nissan (1949) and Epps et al. (1980). The results show that there are significant variations in the viscosity of recycling asphalt binder when being added different ratios of RA. The estimated viscosity values computed by the recycling model of aged asphalt binder are closer to the tested results when compared with the equations developed by Arrhenius (1887), Grunberg and Nissan (1949) and Epps et al. (1980). Furthermore, the Recycling Index (RI) developed by the recycling model of aged asphalt binder can clearly and precisely reveal the recycling performance of different kinds of RAs. The Gmix from the equation developed by Grunberg and Nissan (1949) has an apparent effect on estimating the viscosity when adding RA to the RAB.

Correlating Long-Term Chip Seals Performance and Rheological Properties of Aged Asphalt Binders

2016 ◽  
Vol 28 (5) ◽  
pp. 04015190 ◽  
Author(s):  
Readul Mohammad Islam ◽  
William “Bill” King ◽  
Nazimuddin M. Wasiuddin
Keyword(s):  
Rheological Properties ◽  
Asphalt Binders ◽  
Aged Asphalt ◽  
Chip Seals

scholarly journals Effect of Recycled Shell Waste as a Modifier on the High- and Low-Temperature Rheological Properties of Asphalt

2021 ◽  
Vol 13 (18) ◽  
pp. 10271
Author(s):  
Yuchen Guo ◽  
Xuancang Wang ◽  
Guanyu Ji ◽  
Yi Zhang ◽  
Hao Su ◽  
...  
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Low Temperatures ◽  
High Speed ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Modified Asphalt ◽  
Temperature Performance

The deteriorating ecological environment and the concept of sustainable development have highlighted the importance of waste reuse. This article investigates the performance changes resulting from the incorporation of shellac into asphalt binders. Seashell powder-modified asphalt was prepared with 5%, 10%, and 15% admixture using the high-speed shear method. The microstructure of the seashell powder was observed by scanning electron microscope test (SEM); the physical-phase analysis of the seashell powder was carried out using an X-ray diffraction (XRD) test; the surface characteristics and pore structure of shellac were analyzed by the specific surface area Brunauer-Emmett-Teller (BET) test; and Fourier infrared spectroscopy (FTIR) qualitatively analyzed the composition and changes of functional groups of seashell powder-modified asphalt. The conventional performance index of seashell powder asphalt was analyzed by penetration, softening point, and ductility (5 °C) tests; the effect of seashell powder on asphalt binder was studied using a dynamic shear rheometer (DSR) and bending beam rheometer (BBR) at high and low temperatures, respectively. The results indicate the following: seashell powder is a coarse, porous, and angular CaCO3 bio-material; seashell powder and the asphalt binder represent a stable physical mixture of modified properties; seashell powder improves the consistency, hardness, and high-temperature performance of the asphalt binder but weakens the low-temperature performance of it; seashell powder enhances the elasticity, recovery performance, and permanent deformation resistance of asphalt binders and improves high-temperature rheological properties; finally, seashell powder has a minimal effect on the crack resistance of asphalt binders at very low temperatures. In summary, the use of waste seashells for recycling as bio-modifiers for asphalt binders is a practical approach.

scholarly journals Evaluating the Rheological Properties of High-Modulus Asphalt Binders Modified with Rubber Polymer Composite Modifier

Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7727
Author(s):  
Xiaorui Zhang ◽  
Chao Han ◽  
Jun Yang ◽  
Xinquan Xu ◽  
Fan Zhang
Keyword(s):  
Low Temperature ◽  
Rheological Properties ◽  
Polymer Composite ◽  
Complex Modulus ◽  
Asphalt Binder ◽  
Climatic Conditions ◽  
Morphological Properties ◽  
Asphalt Binders ◽  
High Modulus ◽  
Petroleum Asphalt

With the increasing traffic loading and changing climatic conditions, there is a need to use novel superior performing pavement materials such as high-modulus asphalt binders and asphalt mixtures to mitigate field distress such as rutting, cracking, etc. This laboratory study was thus conducted to explore and substantiate the usage of Rubber Polymer Composite Modifier (RPCM) for high-modulus asphalt binder modification. The base asphalt binder used in the study comprised A-70# Petroleum asphalt binder with RPCM dosages of 0.25%, 0.30%, 0.35%, 0.40% and 0.45%, separately. The laboratory tests conducted for characterizing the asphalt binder rheological and morphological properties included the dynamic mechanical analysis (DM), temperature-frequency sweep in the dynamic shear rheometer (DSR) device, bending beam rheometer (BBR), and florescence microscopic (FM) imaging. The corresponding test results exhibited satisfactory compatibility and potential for using RPCM as a high-modulus asphalt binder modifier to enhance the base asphalt binder’s rheological properties, both with respect to high- and low-temperature performance improvements. For the A-70# Petroleum asphalt binder that was evaluated, the optimum RPCM dosage was found to be 0.30–0.35%. In comparison to styrene–butadiene–styrene (SBS), asphalt binder modification with RPCM exhibited superior high-temperature rutting resistance properties (as measured in terms of the complex modulus and phase angle) and vice versa for the low-temperature cracking properties. Overall, the study beneficially contributes to the literature through provision of a reference datum toward the exploratory usage of RPCM for high-modulus asphalt binder modification and performance enhancements.

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