scholarly journals Hyperfine Interactions in the NV-13C Quantum Registers in Diamond Grown from the Azaadamantane Seed

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1303
Author(s):  
Alexander P. Nizovtsev ◽  
Aliaksandr L. Pushkarchuk ◽  
Sergei Ya. Kilin ◽  
Nikolai I. Kargin ◽  
Alexander S. Gusev ◽  
...  
Keyword(s):  
Organic Molecules ◽  
Quantum Information Processing ◽  
Hyperfine Interactions ◽  
Spin Systems ◽  
Diamond Growth ◽  
Color Centers ◽  
Nuclear Spins ◽  
Electronic Spin ◽  
Nv Center ◽  
Optically Detected

Nanostructured diamonds hosting optically active paramagnetic color centers (NV, SiV, GeV, etc.) and hyperfine-coupled with them quantum memory 13C nuclear spins situated in diamond lattice are currently of great interest to implement emerging quantum technologies (quantum information processing, quantum sensing and metrology). Current methods of creation such as electronic-nuclear spin systems are inherently probabilistic with respect to mutual location of color center electronic spin and 13C nuclear spins. A new bottom-up approach to fabricate such systems is to synthesize first chemically appropriate diamond-like organic molecules containing desired isotopic constituents in definite positions and then use them as a seed for diamond growth to produce macroscopic diamonds, subsequently creating vacancy-related color centers in them. In particular, diamonds incorporating coupled NV-13С spin systems (quantum registers) with specific mutual arrangements of NV and 13C can be obtained from anisotopic azaadamantane molecule. Here we predict the characteristics of hyperfine interactions (hfi) for the NV-13C systems in diamonds grown from various isotopically substituted azaadamantane molecules differing in 13C position in the seed, as well as the orientation of the NV center in the post-obtained diamond. We used the spatial and hfi data simulated earlier for the H-terminated cluster C510[NV]-H252. The data obtained can be used to identify (and correlate with the seed used) the specific NV-13C spin system by measuring, e.g., the hfi-induced splitting of the mS = ±1 sublevels of the NV center in optically detected magnetic resonance (ODMR) spectra being characteristic for various NV-13C systems.

Neutral Silicon-Vacancy Color Center in Diamond: Cluster Simulation of Spatial and Hyperfine Characteristics

2019 ◽  
Vol 18 (03n04) ◽  
pp. 1940010 ◽  
Author(s):  
A. L. Pushkarchuk ◽  
S. A. Kuten ◽  
V. A. Pushkarchuk ◽  
A. P. Nizovtsev ◽  
S. Ya. Kilin
Keyword(s):  
Color Center ◽  
Hyperfine Interactions ◽  
Pulse Sequences ◽  
Nitrogen Vacancy ◽  
Color Centers ◽  
Nuclear Spins ◽  
Silicon Vacancy ◽  
Nv Center ◽  
Long Time

One of the most promising platforms to implement quantum technologies are coupled electron-nuclear spins in solids in which electrons can play a role of “fast” qubits, while nuclear spins can store quantum information for a very long time due to their exceptionally high isolation from the environment. The well-known representative of such systems is the “nitrogen-vacancy” (NV) center in diamond coupled by a hyperfine interaction to its intrinsic [Formula: see text]N/[Formula: see text]N nuclear spin or to [Formula: see text]C nuclear spins presenting in the diamond lattice. More recently, other paramagnetic color centers in diamond have been identified exhibiting even better characteristics in comparison to the NV center. Essential prerequisite for a high-fidelity spin manipulation in these systems with tailored control pulse sequences is a complete knowledge of hyperfine interactions. Development of this understanding for one of the new color centers in diamond, viz., neutral “silicon-vacancy” (SiV0) color center, is a primary goal of this paper, in which we are presenting preliminary results of computer simulation of spatial and hyperfine characteristics of SiV0 center in H-terminated clusters C[Formula: see text][SiV0]H[Formula: see text] and C[Formula: see text][SiV0]H[Formula: see text].

scholarly journals Deep learning enhanced individual nuclear-spin detection

2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Kyunghoon Jung ◽  
M. H. Abobeih ◽  
Jiwon Yun ◽  
Gyeonghun Kim ◽  
Hyunseok Oh ◽  
...  
Keyword(s):  
Deep Learning ◽  
Nuclear Spin ◽  
Quantum Information Processing ◽  
Nuclear Interaction ◽  
Spin Systems ◽  
Nitrogen Vacancy ◽  
Atomic Scale ◽  
Automatic Identification ◽  
Nuclear Spins ◽  
Wide Range

AbstractThe detection of nuclear spins using individual electron spins has enabled diverse opportunities in quantum sensing and quantum information processing. Proof-of-principle experiments have demonstrated atomic-scale imaging of nuclear-spin samples and controlled multi-qubit registers. However, to image more complex samples and to realize larger-scale quantum processors, computerized methods that efficiently and automatically characterize spin systems are required. Here, we realize a deep learning model for automatic identification of nuclear spins using the electron spin of single nitrogen-vacancy (NV) centers in diamond as a sensor. Based on neural network algorithms, we develop noise recovery procedures and training sequences for highly non-linear spectra. We apply these methods to experimentally demonstrate the fast identification of 31 nuclear spins around a single NV center and accurately determine the hyperfine parameters. Our methods can be extended to larger spin systems and are applicable to a wide range of electron-nuclear interaction strengths. These results pave the way towards efficient imaging of complex spin samples and automatic characterization of large spin-qubit registers.

scholarly journals Photon-mediated interactions between quantum emitters in a diamond nanocavity

Science ◽  
2018 ◽  
Vol 362 (6415) ◽  
pp. 662-665 ◽  
Author(s):  
R. E. Evans ◽  
M. K. Bhaskar ◽  
D. D. Sukachev ◽  
C. T. Nguyen ◽  
A. Sipahigil ◽  
...  
Keyword(s):  
Degrees Of Freedom ◽  
Quantum Information Processing ◽  
Color Centers ◽  
Quantum Networks ◽  
Network Nodes ◽  
Electronic Spin ◽  
Coherent Interaction ◽  
The Common ◽  
Spectrally Resolved ◽  
Common Cavity

Photon-mediated interactions between quantum systems are essential for realizing quantum networks and scalable quantum information processing. We demonstrate such interactions between pairs of silicon-vacancy (SiV) color centers coupled to a diamond nanophotonic cavity. When the optical transitions of the two color centers are tuned into resonance, the coupling to the common cavity mode results in a coherent interaction between them, leading to spectrally resolved superradiant and subradiant states. We use the electronic spin degrees of freedom of the SiV centers to control these optically mediated interactions. Such controlled interactions will be crucial in developing cavity-mediated quantum gates between spin qubits and for realizing scalable quantum network nodes.

scholarly journals Optical spin-state polarization in a binuclear europium complex towards molecule-based coherent light-spin interfaces

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Kuppusamy Senthil Kumar ◽  
Diana Serrano ◽  
Aline M. Nonat ◽  
Benoît Heinrich ◽  
Lydia Karmazin ◽  
...  
Keyword(s):  
Ground State ◽  
Quantum Information Processing ◽  
Optical Transition ◽  
Molecular Engineering ◽  
Coherent Light ◽  
Nuclear Spins ◽  
Rare Earth Ion ◽  
Molecular Systems ◽  
Homogeneous Linewidth ◽  
State Spin

AbstractThe success of the emerging field of solid-state optical quantum information processing (QIP) critically depends on the access to resonant optical materials. Rare-earth ion (REI)-based molecular systems, whose quantum properties could be tuned taking advantage of molecular engineering strategies, are one of the systems actively pursued for the implementation of QIP schemes. Herein, we demonstrate the efficient polarization of ground-state nuclear spins—a fundamental requirement for all-optical spin initialization and addressing—in a binuclear Eu(III) complex, featuring inhomogeneously broadened 5D0 → 7F0 optical transition. At 1.4 K, long-lived spectral holes have been burnt in the transition: homogeneous linewidth (Γh) = 22 ± 1 MHz, which translates as optical coherence lifetime (T2opt) = 14.5 ± 0.7 ns, and ground-state spin population lifetime (T1spin) = 1.6 ± 0.4 s have been obtained. The results presented in this study could be a progressive step towards the realization of molecule-based coherent light-spin QIP interfaces.

scholarly journals Hyperfine Interactions in Organic Fragments

2021 ◽  
Author(s):  
◽  
John Patrick Macarthur Bailey
Keyword(s):  
High Speed ◽  
Organic Molecules ◽  
Electronic Computer ◽  
Applied Mathematics ◽  
Hyperfine Interactions ◽  
Industrial Research ◽  
Molecular Orbital Calculations ◽  
Master Of Science ◽  
Alternative Approaches ◽  
Division Department

<p>This thesis, the first thesis in theoretical chemistry submitted for the degree of Master of Science at Victoria University of Wellington, has been designed to illustrate two alternative approaches to theoretical studies. The first five chapters illustrate the modern use of operator methods; the last two are concerned mainly with molecular orbital calculations for large organic molecules, using a giant high speed electronic computer. I am deeply indebted to Mr Keith Morris, of the Applied Mathematics Division, Department of Scientific and Industrial Research, for his generous and highly competent help in writing computing programs, and operating computers, at all odd hours of the day and night, for the calculations in this thesis. I would also like to thank Dr R.M. Golding, for useful discussions, and the Director, Applied Mathematics Division, Department of Scientific and Industrial Research, for making computing facilities available.</p>

Investigation of silicon-vacancy centers formation during the CVD diamond growth of thin and delta doped layers

2021 ◽  
Author(s):  
Mikhail Lobaev ◽  
Alexey Gorbachev ◽  
Dmitry Radishev ◽  
Anatoly Vikharev ◽  
Sergey Bogdanov ◽  
...  
Keyword(s):  
Cvd Diamond ◽  
Diamond Growth ◽  
Color Centers ◽  
Silicon Vacancy ◽  
Silicon Doped ◽  
The Relationship

The results of a study of the deposition of silicon-doped epitaxial diamond layers in a microwave CVD reactor to create silicon-vacancy color centers are presented. The relationship between the optical...

Implementation of CVD Diamond Growth Methods for Selective and Efficient Formation of Color-Centers in Diamond

2015 ◽  
Vol 1728 ◽  
Author(s):  
Stefano Gay ◽  
Giacomo Reina ◽  
Ilaria Cianchetta ◽  
Emanuela Tamburri ◽  
Mariglen Angjellari ◽  
...  
Keyword(s):  
Diamond Films ◽  
Cvd Diamond ◽  
Structural Features ◽  
Diamond Growth ◽  
Color Centers ◽  
Diamond Synthesis ◽  
Substrate Preparation ◽  
Photoluminescence Emission ◽  
Diamond Phase ◽  
Growth Methods

ABSTRACTWe report here on the chemical methodologies that are being settled in our labs for the insertion in diamond of foreign atoms and consequent creation of fluorescent defects. The inclusion of Si, Cr, Ge, able to produce color centers, is directly obtained during the process of diamond synthesis by means of a CVD technique. The deposition of the diamond films takes place on substrates of different nature, treated following procedures specifically settled to control the insertion of the different species. The photoluminescence emission from a series of diamond samples grown on different substrates (Si, Ge and Ti) has been investigated and is discussed with reference to the morphological/structural features of the diamond phase and to the experimental procedures adopted for substrate preparation.

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