scholarly journals Aluminum-Magnesium Hydroxycarbonate/Azo Dye Hybrids as Novel Multifunctional Colorants for Elastomer Composites

Polymers ◽  
2018 ◽  
Vol 11 (1) ◽  
pp. 43 ◽  
Author(s):  
Bolesław Szadkowski ◽  
Anna Marzec ◽  
Przemysław Rybiński ◽  
Waldemar Maniukiewicz ◽  
Marian Zaborski
Keyword(s):  
Heat Release ◽  
Mechanical Analysis ◽  
Experimental Investigations ◽  
Rubber Composites ◽  
New Approach ◽  
Peroxide Curing ◽  
Elastomer Composites ◽  
Flame Retardant Properties ◽  
Microscale Combustion Calorimetry

This study presents the preparation and characterization of new organic-inorganic pigments based on aluminum-magnesium hydroxycarbonate (LH) and azo dyes. Solvent resistance studies, XRD, SEM, and TGA confirmed the successful formation of hybrid pigments, which were characterized in terms of their physicochemical properties. The new hybrid pigments were applied in acrylonitrile-butadiene (NBR) and ethylene-propylene (EPM) rubber composites and cured with sulfur and peroxide curing systems, respectively. The mechanical properties, dispersion quality, and flame-retardant properties of the NBR/hybrid and EPM/hybrid pigment composites were determined by dynamic mechanical analysis (DMA), SEM, and microscale combustion calorimetry (MCC). Complex experimental investigations revealed that the layered nature of hybrid pigments could improve the barrier ability and flame retardancy of elastomer composites. In comparison to unmodified aluminum-magnesium hydroxycarbonate, the modified LH dye structures contributed to significantly decrease the heat release rate and the total heat release of the NBR and EPM composites, offering a new approach to imparting low flammability to elastomer materials.

Light-cured dental composites characterization by Electron Microscopy

1990 ◽  
Vol 48 (4) ◽  
pp. 428-429
Author(s):  
B. M. Culbertson ◽  
M. L. Devinev ◽  
E. C. Kao
Keyword(s):  
Electron Microscopy ◽  
Mechanical Analysis ◽  
Service Performance ◽  
Dental Composite ◽  
Dental Composites ◽  
Neat Resin ◽  
Scanning Calorimetry ◽  
Research Meeting ◽  
Formulation Variables

The service performance of current dental composite materials, such as anterior and posterior restoratives and/or veneer cements, needs to be improved. As part of a comprehensive effort to find ways to improve such materials, we have launched a broad spectrum study of the physicochemical and mechanical properties of photopolymerizable or visible light cured (VLC) dental composites. The commercially available VLC materials being studied are shown in Table 1. A generic or neat resin VLC system is also being characterized by SEM and TEM, to more fully understand formulation variables and their effects on properties.At a recent dental research meeting, we reported on the differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) characterization of the materials in Table 1. It was shown by DSC and DMA that the materials are substantially undercured by commonly used VLC techniques. Post curing in an oral cavity or a dry environment at 37 to 50°C for 7 or more hours substantially enhances the cure of the materials.

Experimental Characterization of Mechanical Behavior of Cord-Rubber Composites

1982 ◽  
Vol 10 (1) ◽  
pp. 37-54 ◽  
Author(s):  
M. Kumar ◽  
C. W. Bert
Keyword(s):  
Response Characteristic ◽  
Cord Compression ◽  
Complete Characterization ◽  
Strain Response ◽  
Strain Gages ◽  
Experimental Characterization ◽  
Rubber Composites ◽  
Stress Strain ◽  
Strain Data

Abstract Unidirectional cord-rubber specimens in the form of tensile coupons and sandwich beams were used. Using specimens with the cords oriented at 0°, 45°, and 90° to the loading direction and appropriate data reduction, we were able to obtain complete characterization for the in-plane stress-strain response of single-ply, unidirectional cord-rubber composites. All strains were measured by means of liquid mercury strain gages, for which the nonlinear strain response characteristic was obtained by calibration. Stress-strain data were obtained for the cases of both cord tension and cord compression. Materials investigated were aramid-rubber, polyester-rubber, and steel-rubber.

Synthesis and characterization of flame-retardant-wrapped carbon nanotubes and its flame retardancy in epoxy nanocomposites

2021 ◽  
pp. 096739112110245
Author(s):  
Jiangbo Wang
Keyword(s):  
Carbon Nanotubes ◽  
Heat Release ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Total Heat Release ◽  
Pristine Cnts ◽  
Peak Heat Release Rate ◽  
Ep Matrix ◽  
Better Than

A novel phosphorus-silicon containing flame-retardant DOPO-V-PA was used to wrap carbon nanotubes (CNTs). The results of FTIR, XPS, TEM and TGA measurements exhibited that DOPO-V-PA has been successfully grafted onto the surfaces of CNTs, and the CNTs-DOPO-V-PA was obtained. The CNTs-DOPO-V-PA was subsequently incorporated into epoxy resin (EP) for improving the flame retardancy and dispersion. Compared with pure EP, the addition of 2 wt% CNTs-DOPO-V-PA into the EP matrix could achieve better flame retardancy of EP nanocomposites, such as a 30.5% reduction in peak heat release rate (PHRR) and 8.1% reduction in total heat release (THR). Furthermore, DMTA results clearly indicated that the dispersion for CNTs-DOPO-V-PA in EP matrix was better than pristine CNTs.

scholarly journals Sustainability Investigation of Vehicles’ CO2 Emission in Hungary

2021 ◽  
Vol 13 (15) ◽  
pp. 8237
Author(s):  
István Árpád ◽  
Judit T. Kiss ◽  
Gábor Bellér ◽  
Dénes Kocsis
Keyword(s):  
Energy Efficiency ◽  
Co2 Emissions ◽  
Energy Supply ◽  
Internal Combustion Engines ◽  
Combustion Engines ◽  
The European Union ◽  
New Approach ◽  
Technology System ◽  
Low Co2

The regulation of vehicular CO2 emissions determines the permissible emissions of vehicles in units of g CO2/km. However, these values only partially provide adequate information because they characterize only the vehicle but not the emission of the associated energy supply technology system. The energy needed for the motion of vehicles is generated in several ways by the energy industry, depending on how the vehicles are driven. These methods of energy generation consist of different series of energy source conversions, where the last technological step is the vehicle itself, and the result is the motion. In addition, sustainability characterization of vehicles cannot be determined by the vehicle’s CO2 emissions alone because it is a more complex notion. The new approach investigates the entire energy technology system associated with the generation of motion, which of course includes the vehicle. The total CO2 emissions and the resulting energy efficiency have been determined. For this, it was necessary to systematize (collect) the energy supply technology lines of the vehicles. The emission results are not given in g CO2/km but in g CO2/J, which is defined in the paper. This new method is complementary to the European Union regulative one, but it allows more complex evaluations of sustainability. The calculations were performed based on Hungarian data. Finally, using the resulting energy efficiency values, the emission results were evaluated by constructing a sustainability matrix similar to the risk matrix. If only the vehicle is investigated, low CO2 emissions can be achieved with vehicles using internal combustion engines. However, taking into consideration present technologies, in terms of sustainability, the spread of electric-only vehicles using renewable energies can result in improvement in the future. This proposal was supported by the combined analysis of the energy-specific CO2 emissions and the energy efficiency of vehicles with different power-driven systems.

scholarly journals An Intrinsic Characterization of Five Points in a CAT(0) Space

2020 ◽  
Vol 8 (1) ◽  
pp. 114-165
Author(s):  
Tetsu Toyoda
Keyword(s):  
Metric Space ◽  
Isometric Embedding ◽  
Metric Spaces ◽  
Necessary Conditions ◽  
New Approach ◽  
Intrinsic Characterization ◽  
New Family

AbstractGromov (2001) and Sturm (2003) proved that any four points in a CAT(0) space satisfy a certain family of inequalities. We call those inequalities the ⊠-inequalities, following the notation used by Gromov. In this paper, we prove that a metric space X containing at most five points admits an isometric embedding into a CAT(0) space if and only if any four points in X satisfy the ⊠-inequalities. To prove this, we introduce a new family of necessary conditions for a metric space to admit an isometric embedding into a CAT(0) space by modifying and generalizing Gromov’s cycle conditions. Furthermore, we prove that if a metric space satisfies all those necessary conditions, then it admits an isometric embedding into a CAT(0) space. This work presents a new approach to characterizing those metric spaces that admit an isometric embedding into a CAT(0) space.

scholarly journals Avoided motifs: short amino acid strings missing from protein datasets

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Pablo Mier ◽  
Miguel A. Andrade-Navarro
Keyword(s):  
Amino Acids ◽  
Amino Acid ◽  
Protein Function ◽  
Large Protein ◽  
New Approach ◽  
Cellular Context ◽  
Human Proteins ◽  
Context Specific ◽  
Protein Datasets

Abstract According to the amino acid composition of natural proteins, it could be expected that all possible sequences of three or four amino acids will occur at least once in large protein datasets purely by chance. However, in some species or cellular context, specific short amino acid motifs are missing due to unknown reasons. We describe these as Avoided Motifs, short amino acid combinations missing from biological sequences. Here we identify 209 human and 154 bacterial Avoided Motifs of length four amino acids, and discuss their possible functionality according to their presence in other species. Furthermore, we determine two Avoided Motifs of length three amino acids in human proteins specifically located in the cytoplasm, and two more in secreted proteins. Our results support the hypothesis that the characterization of Avoided Motifs in particular contexts can provide us with information about functional motifs, pointing to a new approach in the use of molecular sequences for the discovery of protein function.

A new approach to the bienergy and biangle of a moving particle lying in a surface of lorentzian space

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Talat Körpınar ◽  
Yasin Ünlütürk
Keyword(s):  
Vector Fields ◽  
Elastic Surface ◽  
Geometrical Characterization ◽  
Lorentzian Space ◽  
New Approach ◽  
Darboux Vector ◽  
Moving Particle ◽  
The Relationship ◽  
Surface Curve

AbstractIn this research, we study bienergy and biangles of moving particles lying on the surface of Lorentzian 3-space by using their energy and angle values. We present the geometrical characterization of bienergy of the particle in Darboux vector fields depending on surface. We also give the relationship between bienergy of the surface curve and bienergy of the elastic surface curve. We conclude the paper by providing bienergy-curve graphics for different cases.

scholarly journals Introducing the HD+B model for pulsar wind nebulae: a hybrid hydrodynamics/radiative approach

2020 ◽  
Vol 494 (3) ◽  
pp. 4357-4370
Author(s):  
B Olmi ◽  
D F Torres
Keyword(s):  
Gamma Ray ◽  
High Energy ◽  
Theoretical Modelling ◽  
X Rays ◽  
Pulsar Wind Nebulae ◽  
New Approach ◽  
Energy Gamma ◽  
Radiative Model ◽  
Pulsar Wind

ABSTRACT Identification and characterization of a rapidly increasing number of pulsar wind nebulae is, and will continue to be, a challenge of high-energy gamma-ray astrophysics. Given that such systems constitute -by far- the most numerous expected population in the TeV regime, such characterization is important not only to learn about the sources per se from an individual and population perspective, but also to be able to connect them with observations at other frequencies, especially in radio and X-rays. Also, we need to remove the emission from nebulae in highly confused regions of the sky for revealing other underlying emitters. In this paper, we present a new approach for theoretical modelling of pulsar wind nebulae: a hybrid hydrodynamic-radiative model able to reproduce morphological features and spectra of the sources, with relatively limited numerical cost.

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