scholarly journals Non-Chloride in Situ Preparation of Nano-Cuprous Oxide and Its Effect on Heat Resistance and Combustion Properties of Calcium Alginate

Polymers ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 1760 ◽  
Author(s):  
Peiyuan Shao ◽  
Peng Xu ◽  
Lei Zhang ◽  
Yun Xue ◽  
Xihui Zhao ◽  
...  
Keyword(s):  
Thermal Degradation ◽  
Heat Release ◽  
Hybrid Materials ◽  
Heat Release Rate ◽  
Release Rate ◽  
Cuprous Oxide ◽  
Calcium Alginate ◽  
Combustion Process ◽  
Protective Layer ◽  
Combustion Properties

With Cu2+ complexes as precursors, nano-cuprous oxide was prepared on a sodium alginate template excluded of Cl− and based on which the calcium alginate/nano-cuprous oxide hybrid materials were prepared by a Ca2+ crosslinking and freeze-drying process. The thermal degradation and combustion behavior of the materials were studied by related characterization techniques using pure calcium alginate as a comparison. The results show that the weight loss rate, heat release rate, peak heat release rate, total heat release rate and specific extinction area of the hybrid materials were remarkably lower than pure calcium alginate, and the flame-retardant performance was significantly improved. The experimental data indicates that nano-cuprous oxide formed a dense protective layer of copper oxide, calcium carbonate and carbon by lowering the initial degradation temperature of the polysaccharide chain during thermal degradation and catalytically dehydrating to char in the combustion process, and thereby can isolate combustible gases, increase carbon residual rates, and notably reduce heat release and smoke evacuation.

scholarly journals Investigating Combustion Process of N-Butanol-Diesel Blends in a Diesel Engine with Variable Compression Ratio

2021 ◽  
Vol 3 (3) ◽  
pp. 618-628
Author(s):  
György Szabados ◽  
Kristóf Lukács ◽  
Ákos Bereczky
Keyword(s):  
Heat Release ◽  
Heat Release Rate ◽  
Compression Ratio ◽  
Release Rate ◽  
Ignition Delay ◽  
Alternative Fuels ◽  
Internal Combustion Engines ◽  
Combustion Process ◽  
Injection Angle ◽  
Combustion Properties

The search for alternative fuels for internal combustion engines is ongoing. Among the alternatives, plant-based fuels can also be mentioned. Alcohol is not a common fuel for diesel engines because the physical and chemical properties of the alcohols are closer to those of gasoline. In our research, the combustion properties of diesel-n-butanol mixtures have been investigated to obtain results on the effect of butanol blending on combustion. Among the combustion properties, ignition delay, in-cylinder pressure, and heat release rate can be mentioned. They have been observed under different compression conditions on an engine on which the compression ratio can be adjusted. The method used was a quite simple one, so the speed of the engine was set to a constant 900 rpm without load, while three compression ratios (19.92, 15.27, and 12.53) were adjusted with a fuel flow rate of 13 mL/min and the pre-injection angle of 18° BTDC. Blending butanol into the investigated fuel does not significantly affect maximal values of indicated pressure, while much more effect on the pressure rising rate can be detected. Furthermore, heat release rate and ignition delay increased at every compression ratio investigated. Despite the low blending rates of butanol in the mixtures, butanol significantly affects the combustion parameters, especially at high compression ratios.

Simultaneous Imaging of OH* Chemiluminescence and Flame Luminosity of Diesel and Biodiesel Spray Combustion

2011 ◽  
Author(s):  
Ji Zhang ◽  
Tiegang Fang
Keyword(s):  
Ambient Temperature ◽  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Soot Formation ◽  
Combustion Process ◽  
Spray Combustion ◽  
Chemiluminescence Intensity ◽  
High Temperature Reaction ◽  
The Impact

The research on the spray combustion of diesel and biodiesel is vital to the understanding of emission formation and optimal utilization of fuel. This paper studies the biodiesel and diesel spray combustion in a constant volume chamber under different simulated diesel engine conditions. The ambient temperature at fuel injection varied from 800K to 1200K, while the ambient oxygen concentration was maintained at 21%. Simultaneous high speed imaging of OH* chemiluminescence and flame luminosity was employed to visualize the whole combustion process. Heat release rate was analyzed based on the measured combustion pressure. The apparent heat release rate analysis shows that biodiesel has a shorter ignition delay time than diesel, and biodiesel has a smaller cumulative heat release value due to its lower heating value. The overlaying image of OH* chemiluminescence and flame luminosity clearly identifies the high temperature reaction regions and soot formation regions. The line-of-sight images agree with the published observation that the hydroxyl radical is formed on the lean side of the flame edge. Decreasing ambient temperature greatly reduces the OH* chemiluminescence intensity of the diesel combustion, while the impact is smoother and milder for biodiesel combustion. Biodiesel shows a significantly lower level of flame luminosity than diesel under all conditions. These combined observations lead to a speculation that the soot oxidation process may serve as an important contributor to OH* chemiluminescence intensity for late stage combustion, and biodiesel shows a tendency to produce less soot than diesel under the investigated conditions.

Influence of the Spatial and Temporal Interaction Between Diesel Pilot and Directly Injected Natural Gas Jet on Ignition and Combustion Characteristics

2017 ◽  
Author(s):  
Georg Fink ◽  
Michael Jud ◽  
Thomas Sattelmayer
Keyword(s):  
Natural Gas ◽  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Combustion Process ◽  
Gas Jet ◽  
Injection Timing ◽  
Release Rates ◽  
Temporal Interaction ◽  
The Impact

In this paper, pilot-ignited high pressure dual-fuel (HPDF) combustion of a natural gas jet is investigated on a fundamental basis by applying two separate single-hole injectors to a rapid compression expansion machine (RCEM). A Shadowgraphy system is used for optical observations, and the combustion progress is assessed in terms of heat release rates. The experiments focus on the combined influence of injection timing and geometrical jet arrangement on the jet interaction and the impact on the combustion process. In a first step, the operational range for successful pilot self-ignition and transition to natural gas jet combustion is determined, and the restricting phenomena are identified by analyzing the shadowgraph images. Within this range, the combustion process is assessed by evaluation of ignition delays and heat release rates. Strong interaction is found to delay or even prohibit pilot ignition, while it facilitates a fast and stable onset of the gas jet combustion. Furthermore, it is shown that the heat release rate is governed by the time of ignition with respect to the start of natural gas injection — as this parameter defines the level of premixing. Evaluation of the time of gas jet ignition within the operability map can therefore directly link a certain spatial and temporal interaction to the resulting heat release characteristics. It is finally shown that controlling the heat release rate through injection timing variation is limited for a certain angle between the two jets.

scholarly journals Flame-Retardant and Thermal Degradation Mechanism of Caged Phosphate Charring Agent with Melamine Pyrophosphate for Polypropylene

2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Xuejun Lai ◽  
Jiedong Qiu ◽  
Hongqiang Li ◽  
Xingrong Zeng ◽  
Shuang Tang ◽  
...  
Keyword(s):  
Thermal Degradation ◽  
Heat Release ◽  
Flame Retardant ◽  
Heat Release Rate ◽  
Release Rate ◽  
Degradation Mechanism ◽  
Limiting Oxygen Index ◽  
Thermal Degradation Mechanism ◽  
Charring Agent ◽  
Ul 94

An efficient caged phosphate charring agent named PEPA was synthesized and combined with melamine pyrophosphate (MPP) to flame-retard polypropylene (PP). The effects of MPP/PEPA on the flame retardancy and thermal degradation of PP were investigated by limiting oxygen index (LOI), vertical burning test (UL-94), cone calorimetric test (CCT), and thermogravimetric analysis (TGA). It was found that PEPA showed an outstanding synergistic effect with MPP in flame retardant PP. When the content of PEPA was 13.3 wt% and MPP was 6.7 wt%, the LOI value of the flame retardant PP was 33.0% and the UL-94 test was classed as a V-0 rating. Meanwhile, the peak heat release rate (PHRR), average heat release rate (AV-HRR), and average mass loss rate (AV-MLR) of the mixture were significantly reduced. The flame-retardant and thermal degradation mechanism of MPP/PEPA was investigated by TGA, Fourier transform infrared spectroscopy (FTIR), TG-FTIR, and scanning electron microscopy-energy dispersive X-ray spectrometry (SEM-EDXS). It revealed that MPP/PEPA could generate the triazine oligomer and phosphorus-containing compound radicals which changed the thermal degradation behavior of PP. Meanwhile, a compact and thermostable intumescent char was formed and covered on the matrix surface to prevent PP from degrading and burning.

scholarly journals Analysis on Pattern of Heat Release Rate in Two-Stroke Slow Speed Diesel Engine (2nd Report: Prediction of the Combustion Process)

2003 ◽  
Vol 38 (5) ◽  
pp. 303-308
Author(s):  
Takeshi Imahashi ◽  
Eiji Tomita ◽  
Sadami Yoshiyama ◽  
Kouji Moriyama
Keyword(s):  
Diesel Engine ◽  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Combustion Process ◽  
Slow Speed

Experimental and Theoretical Optimization of Combustion Chamber and Fuel Distribution for the Low Emission DI Diesel Engine

2001 ◽  
Author(s):  
Yoshiyuki Kidoguchi ◽  
Michiko Sanda ◽  
Kei Miwa
Keyword(s):  
Diesel Engine ◽  
Heat Release ◽  
Combustion Chamber ◽  
Heat Release Rate ◽  
Release Rate ◽  
Combustion Process ◽  
Mixture Distribution ◽  
Initial Mixture ◽  
Injection Timing ◽  
Initial Heat

Abstract This study investigated the effect of combustion chamber geometry and initial mixture distribution on combustion process in a direct-injection diesel engine by means of experiment and CFD calculation. The high squish combustion chamber with squish lip could produce simultaneous reduction of NOx and particulate emissions with retarded injection timing in the real engine experiment. According to the CFD computation, the high squish combustion chamber with central pip is effective to continue combustion under the squish lip until the end of combustion and the combustion region forms rich and high turbulence atmosphere, which reduces NOx emissions. This chamber can also reduce initial burning because combustion continues under the squish lip. The CFD computation is also carried out in order to investigate the effect of initial mixture distribution on combustion process. The results suggest that mixture distribution affects the history of heat release rate. When fuel is distributed in the bottom or wide region in the combustion chamber, burned gas tends to spread to the cavity center and initial heat release rate becomes high. On the contrary, the high squish combustion chamber with central pip produces lower initial heat release rate because combustion with local rich condition continues long under the squish lip. Diffusion burning is promoted by high swirl motion in this chamber with keeping lower initial heat release rate.

scholarly journals A Study of the Thermal Degradation and Combustion Characteristics of Some Materials Commonly Used in the Construction Sector

Polymers ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 1833 ◽  
Author(s):  
Javier Arturo Piedrahita Solorzano ◽  
Khalid Abu Mohammad Moinuddin ◽  
Svetlana Tretsiakova-McNally ◽  
Paul Joseph
Keyword(s):  
Thermal Degradation ◽  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Inner Core ◽  
Thermo Gravimetric Analysis ◽  
Gravimetric Analysis ◽  
Combustion Heat ◽  
Internal Core ◽  
Combustion Flow

In the present work, some materials that are commonly used in the construction industry were studied with regard to their thermal degradation characteristics and combustion attributes. These included façade materials for pre-fabricated houses, such as the layers of cross-laminated timber (CLT) and the inner core of aluminium composite panels (ACPs). The relevant investigations were carried out by employing thermo-gravimetric analysis (TGA) and pyrolysis combustion flow calorimetry (PCFC). The Arrhenius parameters and the associated calorimetric quantities, i.e., heat release rates, temperature to the peak heat release rate, heats of combustion, heat release capacities, and char yields, were also evaluated. These parameters showed that CLT is more fire retarded than the polymeric internal core of ACP façade materials. Furthermore, some valuable correlations among the various test quantities were found. For instance, a good correlation exists between the general profiles of the thermograms obtained through TGA runs and the heat release rate (HRR) traces from PCFC measurements. Depending on the nature of the materials, the char yields measured by PCFC can be 4–20 times higher than the ones obtained through TGA.

Numerical Simulation on the Combustion Characteristics of Armored Vehicle Diesel in Plateau Area

2012 ◽  
Vol 457-458 ◽  
pp. 607-610
Author(s):  
Feng Lu ◽  
Meng Chao Guo ◽  
Guang Jun Guo
Keyword(s):  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Combustion Process ◽  
Combustion Characteristics ◽  
Maximum Increase ◽  
Injection Angle ◽  
Maximum Value ◽  
Plateau Area ◽  
Armored Vehicle

A simulation model on working process of certain armored vehicle turbocharged diesel engine is proposed with Hiroyasu combustion model.Then the combustion characteristics of the diesel in 4km altitude is calculated. The combustion process is improved via adjusting optimum advanced injection angle(θi) which performed in plateau area.The results show: when the altitude is from 0m to 4000m, the center of gravity for heat release rate is delayed 7°CA,HRRmax (maximum value of Heat Release Rate) reduces 0.009KJ/°CA, pmax (maximum value of cylinder Pressure ) reduces1.6MPa,Tmax(maximum value of combus -tion temperature ) increases 220°C above. When θi is advanced during possible scope, HRRmax increases 0.008KJ/°CA,pmax increases 1.0MPa,Tmax increase 150°C. In view of the restriction of the pmax and the maximum increase rate of p, the optimum θi is fixed on to advanced 4°CA. The simulation results supply a research foundation for the improvement of diesel performance in Plateau.

scholarly journals Internal combustion engine diagnostics using statistically processed Wiebe function

2021 ◽  
Vol 23 (3) ◽  
pp. 505-511
Author(s):  
Jan Famfulik ◽  
Michal Richtar ◽  
Jakub Smiraus ◽  
Petra Muckova ◽  
Branislav Sarkan ◽  
...  
Keyword(s):  
Internal Combustion Engine ◽  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Combustion Engine ◽  
Combustion Process ◽  
Internal Combustion ◽  
Accurate Estimation ◽  
Release Process ◽  
Wiebe Function

The aim of the article is to present the concept of an indirect diagnostic method using the assessment of the variability of the amount of released heat (mass fraction burn) and the heat release rate. The Wiebe function for the assessment of variability has been used. The Wiebe function parameters from the course of the high-pressure indication in the cylinder of internal combustion engine using linear regression have been calculated. From a sufficiently large number of measured samples, the upper and lower limits of the Wiebe function parameters have been statistically determined. Lower and upper limits characterize variability of the heat release process not only in terms of quantity but also in terms of heat release rate. The assessment of variability is thus more complicated than using one integral indicator, typically the mean value of amount of the released heat. The procedure enabling a more accurate estimation of heat generation beginning has been shown. For the combustion process variability assessment of the engine, statistical test of relative frequencies has been used.

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