scholarly journals Physical and Mechanical Properties of Ammonia-Treated Black Locust Wood

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 377 ◽  
Author(s):  
Mariana Domnica Stanciu ◽  
Daniela Sova ◽  
Adriana Savin ◽  
Nicolae Ilias ◽  
Galina A. Gorbacheva

Because of the uneven colour of black locust wood, different technologies are used to change the colour, the bestknown being chemical and thermal treatments. Some of them affect the mechanical properties of wood, such as elasticity modulus, strength, durability. This study aims to compare the physical and mechanical properties of black locust wood control samples and treated wood samples with ammonia hydroxide, in terms of density profile, colour values (CIE L*, a*, b*), mechanical properties of samples subjected to static bending, viscous-elastic properties (storage modulus (E’), loss modulus (E”) and damping (tanδ)). Two types of ammonia-fuming treatment were applied on samples: first treatment T1-5% concentration of ammonia hydroxide for 30 days; second treatment T2-10% concentration for 60 days. The results highlighted the following aspects: the overall colour change in the case of the second treatment is 27% in comparison with 7% recorded for the control samples; the lightness and yellowness values are the most affected by the second ammonia treatment of black locust wood. The density increased with almost 20% due to ammonium fuming (10% concentration/60 days); in case of static bending, the elastic modulus (MOE) tends to decrease with increasing the exposure time to ammonium, but the modulus of rupture (MOR) increases with almost 17% and the breaking force increases too, with almost 41%. In the case of dynamic mechanical analysis, the temperature leads to different viscous-elastic behaviour of each type of samples.

2012 ◽  
Vol 576 ◽  
pp. 314-317
Author(s):  
Sinin Hamdan ◽  
M. Saiful Islam

Five types of selected tropical light hardwoods were chemically modified with benzene diazonium salt to improve their physical and mechanical properties. Benzene diazonium salt underwent a coupling reaction with wood which was confirmed through FT-IR analysis. The compressive modulus of the treated wood increased, whereas modulus of rupture was shown to decrease on treatment. The modified wood samples had higher hardness (Shore D) values compared to that of the control ones.


2015 ◽  
Vol 50 (3) ◽  
pp. 189-192 ◽  
Author(s):  
SA Shanu ◽  
AK Das ◽  
MM Rahman ◽  
M Ashaduzzaman

This experiment was carried out to analyze the effects of CCB (chromate-copper-boron) preservative treatment on physical and mechanical properties of Albizia richardiana wood using dipping method. Retention of preservative was maximum at 8% concentration of the preservatives. Based on the retention at this concentration, the physical and mechanical properties of the treated wood were examined. The density of untreated A. richardiana wood was 521 kg/m3. It changed to 542 kg/m3 on treatment. This increase in density by 2.30% for treated wood was significant. On the other hand, modulus of rupture (MOR) increased significantly from 93 to 107 N/mm2 on treatment of the wood. The modulus of elasticity (MOE) increased from 3205 to 4861 N/mm2. Physical and mechanical properties of the wood improved by treating with CCB preservative.Bangladesh J. Sci. Ind. Res. 50(3), 189-192, 2015


Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2359
Author(s):  
Harmaen Ahmad Saffian ◽  
Masayuki Yamaguchi ◽  
Hidayah Ariffin ◽  
Khalina Abdan ◽  
Nur Kartinee Kassim ◽  
...  

In this study, Kraft lignin was esterified with phthalic anhydride and was served as reinforcing filler for poly(butylene succinate) (PBS). Composites with different ratios of PBS, lignin (L), modified lignin (ML) and kenaf core fibers (KCF) were fabricated using a compounding method. The fabricated PBS composites and its counterparts were tested for thermal, physical and mechanical properties. Weight percent gain of 4.5% after lignin modification and the FTIR spectra has confirmed the occurrence of an esterification reaction. Better thermo-mechanical properties were observed in the PBS composites reinforced with modified lignin and KCF, as higher storage modulus and loss modulus were recorded using dynamic mechanical analysis. The density of the composites fabricated ranged from 1.26 to 1.43 g/cm3. Water absorption of the composites with the addition of modified lignin is higher than that of composites with unmodified lignin. Pure PBS exhibited the highest tensile strength of 18.62 MPa. Incorporation of lignin and KCF into PBS resulted in different extents of reduction in tensile strength (15.78 to 18.60 MPa). However, PBS composite reinforced with modified lignin exhibited better tensile and flexural strength compared to its unmodified lignin counterpart. PBS composite reinforced with 30 wt% ML and 20 wt% KCF had the highest Izod impact, as fibers could diverge the cracking propagation of the matrix. The thermal conductivity value of the composites ranged from 0.0903 to 0.0983 W/mK, showing great potential as a heat insulator.


2018 ◽  
Vol 2018 ◽  
pp. 1-11 ◽  
Author(s):  
Chatree Homkhiew ◽  
Surasit Rawangwong ◽  
Worapong Boonchouytan ◽  
Wiriya Thongruang ◽  
Thanate Ratanawilai

The aim of this work is to investigate the effects of rubberwood sawdust (RWS) size and content as well as the ratio of natural rubber (NR)/high-density polyethylene (HDPE) blend on properties of RWS reinforced thermoplastic natural rubber (TPNR) composites. The addition of RWS about 30–50 wt% improved the modulus of the rupture and tensile strength of TPNR composites blending with NR/HDPE ratios of 60/40 and 50/50. TPNR composites reinforced with RWS 80 mesh yielded better tensile strength and modulus of rupture than the composites with RWS 40 mesh. The TPNR/RWS composites with larger HDPE content gave higher tensile, flexural, and Shore hardness properties and thermal stability as well as lower water absorption. The TPNR/RWS composites with larger plastic content were therefore suggested for applications requiring high performance of thermal, physical, and mechanical properties.


2020 ◽  
Vol 01 (01) ◽  
Author(s):  
M A Zulhakimie ◽  
◽  
Anika Zafiah M. Rus ◽  
N S S Sulong ◽  
A Syah Z A ◽  
...  

Wood powder filler applied to the bio-based and epoxy polymer foams has the potential to reinforce the polymer foam structure. The 'Meranti' wood filler type was used as the filler in this analysis. In order to observe the pore size of each sample when exposed to different hours of UV exposure using optical microscopy (OM), this study was made.This analysis was conducted to compare the mechanical properties of each sample with different filler ratios of 0 wt%, 5 wt%, 10 wt%, 15wt% and 20 wt% at different UV exposure hours, which is 0 hour to 6000 hours with a 2000 hour rapid increase. Using the DMA Q800 TA unit, the mechanical properties were studied. In order to obtain the product of their mechanical properties, samples having a scale of 40 x 10 x 5 mm were clamped into the machine. The results will show the value of tan δ, loss modulus and storage modulus from the DMA test.The tan δ value shows that the high tanδvalue will be produced by the higher ratio filler. In contrast to bio-based polymer foams, epoxy polymer foams with powder fillers have the highest tan δ value. It shows that the higher filler ratio can be reported with the lower tan δ value. As the filler ratio filler in the polymer foams increased, the consequence of storage and loss modulus was found to increase. The greater the modulus of loss and the modulus of storage, the lower the temperature. As energy is lost as heat during UV irradiation exposure, bio-based polymer foams with a high powder filler ratio can dissipate more energy.


2017 ◽  
Vol 41 (1) ◽  
Author(s):  
Mírian de Almeida Costa ◽  
Cláudio Henrique Soares Del Menezzi

ABSTRACT Thermo-mechanical treatment is a technique for wood modification in which samples are densified by means of heat and mechanical compression, applied perpendicularly to fibers, which under different combinations of time, temperature, and pressure increases wood density and thus improve some of its properties. This study aimed to treat thermo-mechanically parica plywood and observe the effects on its physical and mechanical properties. Specimens were submitted to two treatments, 120 and 150 ºC, remaining under pressure for seven minutes and, subsequently, under zero pressure for 15 minutes. Results showed a significant increase in specific mass from 0.48 g cm-3 to an average of 0.56 g cm-3, and a compression ratio of about 31.7% on average. Physical properties also varied significantly and results showed that treated samples swelled and absorbed more water than those untreated, leading to a greater thickness non-return rate. This indicates the proposed thermal treatments did not release the internal compressive stress generated during panel pressing, not improving its dimensional stability as a result. On the other hand, mechanical properties were positively affected, leading to an increase of 27.5% and 51.8% in modulus of rupture after treatments at 120 and 150 ºC, respectively. Modulus of elasticity and glue-line shear strength did not vary statistically and Janka hardness was 29.7% higher after treatment at 150 ºC.


2017 ◽  
Vol 54 (3) ◽  
pp. 543-545 ◽  
Author(s):  
Yusrina Mat Daud ◽  
Kamarudin Hussin ◽  
Azlin Fazlina Osman ◽  
Che Mohd Ruzaidi Ghazali ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
...  

Preparation epoxy based hybrid composites were involved kaolin geopolymer filler, organo-montmorillonite at 3phr by using high speed mechanical stirrer. A mechanical behaviour of neat epoxy, epoxy/organo-montmorillonite and its hybrid composites containing 1-8phr kaolin geopolymer filler was studied upon cyclic deformation (three-point flexion mode) as the temperature is varies. The analysis was determined by dynamic mechanical analysis (DMA) at frequency of 1.0Hz. The results then expressed in storage modulus (E�), loss modulus (E�) and damping factor (tan d) as function of temperature from 40 oC to 130oC. Overall results indicated that E�, E�� and Tg increased considerably by incorporating optimum 1phr kaolin geopolymer in epoxy organo-montmorillonite hybrid composites.


2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Lijuan Ping ◽  
Yubo Chai ◽  
Fangwen Zhang ◽  
Bailing Sun ◽  
Junliang Liu

In the study, we report that a safe and simple way for upgrading inferior rubber wood through the combined modification of environment-friendly MUG resin was synthesized from glyoxal, melamine, urea, and other additives. MUG-treated wood samples were prepared with six different MUG resin concentrations (5, 15, 25, 35, 45, and 55 wt %) into the wood matrix and then heated and polymerized to form a solid and hydrophobic MUG resin in the wood scaffold, and the physico-mechanical properties were evaluated. As the MUG resin concentration increased, the weight percent gain and density increased, water uptake and leachability decreased, and the antiswelling efficiency increased at first and then decreased. MUG-treated wood sample can be prepared when the MUG resin concentration was set as 25%, and the physical properties of treated wood was optimum. Scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy analysis showed that the MUG resin is widely distributed in the cell lumens and cell walls. With enhanced physico-mechanical properties, MUG-treated wood sample can be well used as a promising alternative to existing engineered wood products for structural applications.


2019 ◽  
Vol 7 (1) ◽  
Author(s):  
. Erma ◽  
Fadiilah H Usman ◽  
. Muflihati

Physical and mechanical properties of wood is one of the basic properties that need to be known in the selection of wood, because the physical and mechanical properties of wood are not the same height on the stem. Increased wood demand gives the opportunity to use wood that is not yet known for its marketing, one of which is Salam wood (Syzygium polianthum (Wight) Walp). The purpose of this research was to determine the physical and mechanical properties of Salam wood based on the height of the stem so that Salam wood can be optimally utilized by testing based on Classification SNI – 5 PKKI 1961. Methods of making test and test examples based on British Standard Methods No. 373-1957. The results showed that Salam wood has physical properties with an average  brown colour, the moisture content 3,13 % , density  0,58 kg/cm2 , Depreciation 2,59 %. Salam has mechanical properties with an average height position stem from base to tip with Modulus of Elastiscity (MOE)  97.701,54 , Modulus of Rupture (MOR) 659,18  and  Modulus Crushing  Streang 342,86 . Salam can be classified into strong class III and based on its properties and mechanics, it is suitable for use as a lightweight construction and furniture.Keywords: Density, depreciation, MCS, MOE, moisture content, MOR


2018 ◽  
Vol 7 (1) ◽  
Author(s):  
Mayang Archila ◽  
Farah Diba ◽  
Dina Setyawati ◽  
. Nurhaida

The objective of this research is to evaluate the effect of the number of composite layers on the quality of the composite board from sago bark waste and plastic waste, and the number of composite layers that produce the best quality on composite board. The composite board is made with size 30 cm x 30 cm x 1 cm. The composition and division of the material was carried out manually with the polypropylene distribution divided into three parts: the front and rear respectively of 15%, and the center 70% of the plastic weight. Target density of composite boards was 0.7 g / cm3. The treatment used is based on the number of layers composing, which is 5 layers, 7 layers, 9 layers, 11 layers and 13 layers. After mixed the sago bark particle and waste of polypropylene, the materials then compressed with hot press at 180oC with pressure about ± 25 kg / cm2 for 10 minutes. The composite boards then tested the quality included physical and mechanical properties. Testing of physical and mechanical properties refers to JIS A 5908-2003 standard. Physical properties consist of density, moisture content, thickness swelling, and water absorption. Mechanical properties consist of modulus of rupture, modulus of elasticity, internal bonding, and modulus of screw holding strength. The study used a completely randomized design experiment consisting of 5 treatments and 3 replications. The results showed the average value of composite density was range between 0.6962 – 0.7896 g/cm3, the moisture content was range between 4.3388 % - 6.8066%, the thickness swelling was range between 8.2605% - 11.9615%, and water absorption was range between 17.2380% - 22.3867%. The average value of modulus of rupture was range between 60,0632 kg/cm2 – 64,4068 kg/cm2, the modulus of elasticity was range between 17935,1813g/cm2 – 32841,8278 kg/cm2, the internal bonding was range between 1,9268 kg/cm2  - 5,4119 kg/cm2, and the modulus of screw holding strength was range between 78,2530 kg/cm2 – 92,9677 kg/cm2. The composite board made from sago stem bark waste and polypropylene waste plastic with 13 layers treatment is the best composite board and fulfilled the JIS A 5908-2003 standard. Keywords: bark of sago, composite boards, layer of composite, polypropylenes plastic, waste


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