scholarly journals Chemistry, Processing, Properties, and Applications of Rubber Foams

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1565
Author(s):  
Ehsan Rostami-Tapeh-Esmaeil ◽  
Ali Vahidifar ◽  
Elnaz Esmizadeh ◽  
Denis Rodrigue

With the ever-increasing development in science and technology, as well as social awareness, more requirements are imposed on the production and property of all materials, especially polymeric foams. In particular, rubber foams, compared to thermoplastic foams in general, have higher flexibility, resistance to abrasion, energy absorption capabilities, strength-to-weight ratio and tensile strength leading to their widespread use in several applications such as thermal insulation, energy absorption, pressure sensors, absorbents, etc. To control the rubber foams microstructure leading to excellent physical and mechanical properties, two types of parameters play important roles. The first category is related to formulation including the rubber (type and grade), as well as the type and content of accelerators, fillers, and foaming agents. The second category is associated to processing parameters such as the processing method (injection, extrusion, compression, etc.), as well as different conditions related to foaming (temperature, pressure and number of stage) and curing (temperature, time and precuring time). This review presents the different parameters involved and discusses their effect on the morphological, physical, and mechanical properties of rubber foams. Although several studies have been published on rubber foams, very few papers reviewed the subject and compared the results available. In this review, the most recent works on rubber foams have been collected to provide a general overview on different types of rubber foams from their preparation to their final application. Detailed information on formulation, curing and foaming chemistry, production methods, morphology, properties, and applications is presented and discussed.

Author(s):  
Atoyebi Olumoyewa Dotun ◽  
Adeolu Adesoji Adediran ◽  
Adisa Cephas Oluwatimilehin

The current work reports on the fabrication of composite matrix from saw dust (SD) and recycled polyethylene terephthalate (PET) at different weight ratio by flat-pressed method. Wood plastic composites (WPCs) were made with a thickness of 15 mm after mixing the saw dust and PET followed by a three phase press cycle. Physical properties (Density, Water Absorption (WA) and Thickness Swelling (TS)) and Mechanical properties (Modulus of Elasticity (MOE) and Modulus of Rupture (MOR)) were determined base on the mixing ratios according to the standard. WA and TS were measured after 2 h and 24 h of immersion in water. The results showed that as the density increased, the SD content decreased from 90 % to 50 % into the matrix. However, WA and TS decreases when the PET content increased in the matrix. Remarkably, the MOE and MOR attained a maximum point at 964.199 N/mm2and 9.03 N/mm2respectively in 50 % SD content. In comparism with standard, boards D and E can be classified as medium density boards while A, B and C are low density boards. The results indicated that the fabrication of WPCs from sawdust and PET would technically be feasible for indoor uses in building due to favorable physical properties exhibited. The mechanical properties response showed that it cannot be used for structural or load bearing application.


Polymers ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1091 ◽  
Author(s):  
Eftihia Barnes ◽  
Jennifer A. Jefcoat ◽  
Erik M. Alberts ◽  
Mason A. McKechnie ◽  
Hannah R. Peel ◽  
...  

Cellulose nanofibrils (CNFs) are high aspect ratio, natural nanomaterials with high mechanical strength-to-weight ratio and promising reinforcing dopants in polymer nanocomposites. In this study, we used CNFs and oxidized CNFs (TOCNFs), prepared by a 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated oxidation process, as reinforcing agents in poly(vinylidene fluoride) (PVDF). Using high-shear mixing and doctor blade casting, we prepared free-standing composite films loaded with up to 5 wt % cellulose nanofibrils. For our processing conditions, all CNF/PVDF and TOCNF/PVDF films remain in the same crystalline phase as neat PVDF. In the as-prepared composites, the addition of CNFs on average increases crystallinity, whereas TOCNFs reduces it. Further, addition of CNFs and TOCNFs influences properties such as surface wettability, as well as thermal and mechanical behaviors of the composites. When compared to neat PVDF, the thermal stability of the composites is reduced. With regards to bulk mechanical properties, addition of CNFs or TOCNFs, generally reduces the tensile properties of the composites. However, a small increase (~18%) in the tensile modulus was observed for the 1 wt % TOCNF/PVDF composite. Surface mechanical properties, obtained from nanoindentation, show that the composites have enhanced performance. For the 5 wt % CNF/PVDF composite, the reduced modulus and hardness increased by ~52% and ~22%, whereas for the 3 wt % TOCNF/PVDF sample, the increase was ~23% and ~25% respectively.


2011 ◽  
Vol 399-401 ◽  
pp. 864-868
Author(s):  
Han Qiao Liu ◽  
Guo Xia Wei ◽  
Yin Liang ◽  
Jun Lan Yang

The glass-ceramics were made of arc-melting slag from incinerator fly ash mixed with glass cullet additive by sintering method. The effects of ball milling time and powder compaction pressure on the microstructure, physical and mechanical properties of the glass–ceramics were respectively investigated. Results showed that with milling time delaying, granularity of the parent glass evidently reduces, the major phases of glass–ceramics have no change but the diffraction peaks present intensive trend, the crystal sizes of glass–ceramics decrease, the properties such as volumetric densities, compressive strength, bending strength and toughness are improved, the appropriate milling time is 6h with fifty percent of the volume (d50 value) of 10.62μm. The physical and mechanical properties first increase and then decrease with compaction pressure increasing, and the optimal compaction pressure is 60MPa.


e-Polymers ◽  
2009 ◽  
Vol 9 (1) ◽  
Author(s):  
Morteza Ehsani ◽  
Ali Akbar Yousefi ◽  
Saeed Samiei Yeganeh

AbstractThe use of dynamic viscosity/time (temperature) cure curves is seen as a powerful technique to quantify formulation and resin design parameters. The behaviour of different thermoset powder coating systems, epoxy/polyester (50/50, 40/60 and 30/70) as well as the impact of the filler, the curing temperature and the frequency upon gel-time have been examined based upon the rheological measurements and compared with PE/TGIC systems. Two disparate methodologies have been utilized to determine gel-time. The behaviour of dissimilar systems bearing different formulations has been compared by means of the non-isothermal DSC test. The effects of resin percentage and the formulation on physical and mechanical properties of coating have been studied.


Holzforschung ◽  
2016 ◽  
Vol 70 (6) ◽  
pp. 557-565 ◽  
Author(s):  
Marjan Sedighi Gilani ◽  
Jürg Neuenschwander ◽  
Markus Heeb ◽  
Roman Furrer ◽  
Sergio J. Sanabria ◽  
...  

Abstract The goal of the current study was to investigate the physical and mechanical properties of mycowood as a high quality tone-wood, obtained from Norway spruce by treatment of the white rot fungus Physisporinus vitreus as a function of the treatment time. In focus was the stiffness to weight ratio, which is often considered a main criterion for tone-wood selection. The vibro-mechanical properties were tested by non-destructive methods. The change of color and density were also measured after 4–12 months of fungal incubation. Density decreased up to 5% after 12 months of fungal treatment. Sound velocity was measured in small size specimens by means of the free-free vibration approach, while in large specimens the air-coupled ultrasound method was applied. The two techniques gave similar results and indicated that the sound velocity decreased in mycowood. Internal damping was increased in mycowood to a higher extent than the reduction in the specific modulus of elasticity (E/ρ) and thus the sound velocity in the material. The sound velocity was decreasing with increasing incubation times and scattering of data with this regard was larger in the transversal than in the longitudinal direction. The sound radiation coefficient and the characteristic impedance were enhanced in mycowood and its color was more brownish and richer in tone.


2020 ◽  
Vol 70 (2) ◽  
pp. 167-180
Author(s):  
Vennapusa Vijaya Bhaskar ◽  
Kolla Srinivas ◽  
Devireddy Siva Bhaskara Rao

AbstractThe present work addresses the physical and mechanical properties of banana and palmyra fiber reinforced epoxy composites with the aim of study on the effect of weight ratio and fiber percentage. The banana and palmyra fibers were arranged with different weight ratios (1:1, 1:3, and 3:1) and then mixed with the epoxy matrix by hand lay-up technique to prepare the hybrid composites with various fiber percentages (10%, 20%, 30% and 40%). The properties are measured by testing its density, water absorption, tensile strength, impact strength, hardness and flexural strength and compared. From the results, it was indicated that addition of banana and palmyra fiber in to the matrix material up to 30% by fiber percentage results in increasing the mechanical properties and slightly variation with weight ratios. Interfacial analysis of the hybrid composites were also observed by using scanning electron microscope (SEM) to study the internal failures and micro structure of the tested specimen.


2020 ◽  
Vol 2020 ◽  
pp. 1-11
Author(s):  
Yvonne Konku-Asase ◽  
Abu Yaya ◽  
Kwabena Kan-Dapaah

The mechanical properties of plain polydimethylsiloxane (PDMS) and its nanocomposites have been exploited for various theranostic biomedical applications. Although several research groups have investigated the effects of preparation conditions—especially curing temperature and time—on bulk mechanical properties of plain PDMS, there are no reported similar studies for its nanocomposites. In this study, mechanical properties of PDMS reinforced by different volume fractions (ϕmnp=0–2 vol. %) of γ-Fe2O3 nanoparticles (NPs) were investigated and quantitative data presented for different curing temperatures (25, 100, and 150°C). To a large extent, γ-Fe2O3 NPs were uniformly dispersed in the PDMS matrix with no primary chemical bonds formed. For the temperatures tested, the data showed an increase for Young’s modulus (E) of about 170% (1.36–3.71 MPa) and a decrease of the ultimate tensile strength (UTS) of about 65% (6.48–2.93 MPa) with increasing concentration of the NPs. Furthermore, hardness (Shore A) (H) increased with curing temperature but decreased with concentration. Based on the findings, we conclude that the linear relationship between the calculated mechanical properties (E, UTS, H) and small ϕmnp is independent of the curing temperature. The experimental data provide useful background information for the selection of processing parameters for PDMS nanocomposite fabrication.


2019 ◽  
Vol 37 (5A) ◽  
pp. 181-187
Author(s):  
Jenan S. Kashan

This work take in consideration the application of Taguchi optimization methodology in optimizing the parameters for processing (composition, compounding pressure) and their effects on the output physical (Density and true porosity) properties and mechanical(fracture strength and microhardness) properties for the Nano HA,Al2O3 fillers reinforced HDPE hybrid composite material for orthodontic application. An orthogonal array of the Taguchi approach was used to analyses the effect of the processing parameters on the physical and mechanical properties. On the other hand, the surface roughness and particle size distribution were also calculated to study their effect on the output properties. The result shows that the Taguchi approach can determine the best combination of processing parameters that can provide the optimal physical and mechanical conditions, which are the optimum values (the optimum composition was15HA/ 5Al2O3/80HDPE, and optimum compounding pressure was102 MPa.


Author(s):  
Kamardeen Olajide Abdulrahman ◽  
Esther T. Akinlabi ◽  
Rasheedat M. Mahamood

Three-dimensional printing has evolved into an advanced laser additive manufacturing (AM) process with capacity of directly producing parts through CAD model. AM technology parts are fabricated through layer by layer build-up additive process. AM technology cuts down material wastage, reduces buy-to-fly ratio, fabricates complex parts, and repairs damaged old functional components. Titanium aluminide alloys fall under the group of intermetallic compounds known for high temperature applications and display of superior physical and mechanical properties, which made them most sort after in the aeronautic, energy, and automobile industries. Laser metal deposition is an AM process used in the repair and fabrication of solid components but sometimes associated with thermal induced stresses which sometimes led to cracks in deposited parts. This chapter looks at some AM processes with more emphasis on laser metal deposition technique, effect of LMD processing parameters, and preheating of substrate on the physical, microstructural, and mechanical properties of components produced through AM process.


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