scholarly journals Structural Adhesives Tapes Based on a Solid Epoxy Resin and Multifunctional Acrylic Telomers

Polymers ◽  
2021 ◽  
Vol 13 (20) ◽  
pp. 3561
Author(s):  
Mateusz Weisbrodt ◽  
Agnieszka Kowalczyk ◽  
Krzysztof Kowalczyk

Thermally curable pressure-sensitive structural adhesives tapes (SATs) were compounded using a solid epoxy resin and multifunctional acrylic telomer solutions (MATs) prepared by a thermally initiated telomerization process in an epoxy diluent containing two kinds of telogens (CBr4 or CBrCl3). Dynamic viscosity, K-value, and volatile mater content in MATs (i.e., MAT-T with CBr4, MAT-B with CBrCl3) were investigated in relation to telogen type and content. The influence of MATs on the self-adhesive features and curing behavior of UV-crosslinked tapes as well as on the shear strength of thermally cured aluminum–SAT–aluminum joints was investigated as well. Increasing the telogen dose (from 5 to 15 wt. parts) caused significant improvement in the adhesion (+315% and +184%), tack (+147% and +298%), and cohesion (+414% and +1716%) of SATs based on MAT-T and MAT-B, respectively. Additionally, MATs with high telogen content (especially the MAT-T-type) improved the resistance of cured joints to aviation fuel, humidity, and elevated temperature. The highest overlap shear strength values were registered for SATs based on MATs containing 7.5 wt. parts of CBr4 (16.7 MPa) or 10 wt. parts of CBrCl3 (15.3 MPa).

2021 ◽  
pp. 096739112098651
Author(s):  
Saeedeh Saadatyar ◽  
Mohammad Hosain Beheshty ◽  
Razi Sahraeian

Unidirectional carbon fiber-reinforced epoxy (UCFRE) is suffering from weak transverse mechanical properties and through-thickness properties. The effect of different amount (0.1, 0.3 and 0.5 phr which is proportional to 0.09, 0.27 and 0.46 wt%, respectively) of multiwall carbon nanotube (MWCNT), on transverse tensile properties, flexural strength, fracture toughness in transverse and longitudinal fiber directions, interlaminar shear strength and lap shear strength of UCFRE has been investigated. Dicyandiamide was used as a thermal curing agent of epoxy resin. MWCNT was dispersed in the epoxy resin by ultrasonic instrument and their dispersion state was investigated by scanning electron microscopy (SEM). The curing behavior of epoxy resin and its nanocomposites was assessed by differential scanning calorimetry. Results show that transverse tensile strength, modulus and strain-at-break were increased by 28.5%, 25% and 14%, respectively by adding 0.1 phr of MWCNT. Longitudinal flexural properties of UCFRE was not changed by adding different amount of MWCNT. Although longitudinal flexural strength was increased by 5% by adding 0.1 phr of MWCNT. Fracture toughness in transverse and longitudinal fiber directions was increased by 39% and 9%, respectively at 0.3 phr of MWCNT. Results also show that interlaminar shear strength and lap shear strength were increased at 0.3 phr of MWCNT by 8% and 5%, respectively. These increases in mechanical properties were due to the good adhesion of fibers to the matrix, interlocking and toughening action of MWCNT as revealed by SEM.


2020 ◽  
Vol 40 (4) ◽  
pp. 314-320 ◽  
Author(s):  
Tariq Aziz ◽  
Hong Fan ◽  
Xiangwei Zhang ◽  
Farman Ullah Khan ◽  
Shah Fahad ◽  
...  

AbstractThe adhesive properties of a self-prepared bio-based epoxy resin with native cellulose nanocrystals (CNCs) are evaluated in this article. The porosity of actual CNCs is high. The most promising finding is the acquisition of high tensile modulus. The addition of CNC composites significantly increased the tensile modulus at lower wt.%, and the maximum crystallinity of CNCs was obtained. Bearing in mind the advantages of CNCs, scanning electron microscopy (SEM) showed a uniform distribution of concentrated CNCs. Clusters were formed at higher CNCs ratios, and the composite matrix content with high CNCs produced good expansion, low crystallinity, and increased elongation. Our analysis showed that the original CNCs were more evenly distributed in the self-prepared bio-based epoxy resin, which enhanced transformation, supported by improved dispersion of native CNCs. The presence of native CNCs greatly improved and enhanced the bonding performance of the bio-based epoxy resin in the interface area. Enhancing the mechanical properties of native CNCs has broad application prospects in environmental areas. This suggests that the widespread use of native CNCs in environmental engineering applications is feasible, especially in terms of adhesives properties.


SINERGI ◽  
2021 ◽  
Vol 25 (3) ◽  
pp. 361
Author(s):  
Muhamad Fitri ◽  
Shahruddin Mahzan ◽  
Imam Hidayat ◽  
Nurato Nurato

The development of composite materials is increasingly widespread, which require superior mechanical properties. From many studies, it is found that the mechanical properties of composite materials are influenced by various factors, including the reinforcement content, both in the form of fibers and particle powder. However, those studies have not investigated the effect of the hardener weight fraction on the mechanical properties of resin composite materials. Even though its function as a hardener is likely to affect its mechanical properties, it might obtain the optimum composition of the reinforcing content and hardener fraction to get the specific mechanical properties. This study examines the effect of hardener weight fraction combined with fiber powder content on mechanical properties of EPR-174 epoxy resin matrix composite and determines the optimum of Them. The research was conducted by testing a sample of composite matrix resin material reinforced with coconut fiber powder. The Powder content was made in 3 levels, i.e.: 6%, 8%, and 10%. While the hardener fraction of resin was made in 3 levels, i.e.: 0.4, 0.5, and 0.6. The test results showed that pure resin had the lowest impact strength of 1.37 kJ/m2. The specimen with a fiber powder content of 6% has the highest impact strength i.e.: 4.92 kJ/m2. The hardener fraction of 0.5 has the highest impact strength i.e.: 4.55 kJ/m2. The fiber powder content of 8% produced the highest shear strength i.e.: 1.00 MPa. Meanwhile, the hardener fraction of 0.6 has the highest shear strength i.e.: 2.03 MPa.


2021 ◽  
Vol 2021 ◽  
pp. 1-14
Author(s):  
Xiaoguang Zheng ◽  
Qi Ren ◽  
Huan Xiong ◽  
Xiaoming Song

As one of the major contributors to the early failures of steel bridge deck pavements, the bonding between steel and asphalt overlay has long been a troublesome issue. In this paper, a novel composite bonding structure was introduced consisting of epoxy resin micaceous iron oxide (EMIO) primer, solvent-free epoxy resin waterproof layer, and ethylene-vinyl acetate (EVA) hot melt pellets. A series of strength tests were performed to study its mechanical properties, including pull-off strength tests, dumbbell tensile tests, lap shear tests, direct tension tests, and 45°-inclined shear tests. The results suggested that the bonding structure exhibited fair bonding strength, tensile strength, and shear strength. Anisotropic behaviour was also observed at high temperatures. For epoxy resin waterproof layer, the loss of bonding strength, tensile strength, and shear strength at 60°C was 70%, 35%, and 39%, respectively. Subsequent pavement performance-oriented tests included five-point bending tests and accelerated wheel tracking tests. The impacts of bonding on fatigue resistance and rutting propagation were studied. It was found that the proposed bonding structure could provide a durable and well-bonded interface and was thus beneficial to prolong the fatigue lives of asphalt overlay. The choice of bonding materials was found irrelevant to the ultimate rutting depth of pavements. But the bonding combination of epoxy resin waterproof and EVA pellets could delay the early-stage rutting propagation.


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