scholarly journals The Effect of Carbonyl and Hydroxyl Compounds on Swelling Factor, Interfacial Tension, and Viscosity in CO2 Injection: A Case Study on Aromatic Oils

Processes ◽  
2021 ◽  
Vol 9 (1) ◽  
pp. 94
Author(s):  
Asep Kurnia Permadi ◽  
Egi Adrian Pratama ◽  
Andri Luthfi Lukman Hakim ◽  
Doddy Abdassah
Keyword(s):  
Interfacial Tension ◽  
Oil Recovery ◽  
Viscosity Reduction ◽  
Co2 Injection ◽  
Minimum Miscibility Pressure ◽  
Lower Viscosity ◽  
Hydroxyl Compounds ◽  
Swelling Factor

A factor influencing the effectiveness of CO2 injection is miscibility. Besides the miscible injection, CO2 may also contribute to oil recovery improvement by immiscible injection through modifying several properties such as oil swelling, viscosity reduction, and the lowering of interfacial tension (IFT). Moreover, CO2 immiscible injection performance is also expected to be improved by adding some solvent. However, there are a lack of studies identifying the roles of solvent in assisting CO2 injection through observing those properties simultaneously. This paper explains the effects of CO2–carbonyl and CO2–hydroxyl compounds mixture injection on those properties, and also the minimum miscibility pressure (MMP) experimentally by using VIPS (refers to viscosity, interfacial tension, pressure–volume, and swelling) apparatus, which has a capability of measuring those properties simultaneously within a closed system. Higher swelling factor, lower viscosity, IFT and MMP are observed from a CO2–propanone/acetone mixture injection. The role of propanone and ethanol is more significant in Sample A1, which has higher molecular weight (MW) of C7+ and lower composition of C1–C4, than that in the other Sample A9. The solvents accelerate the ways in which CO2 dissolves and extracts oil, especially the extraction of the heavier component left in the swelling cell.

scholarly journals Molecular Modeling of CO2 and n-Octane in Solubility Process and α-Quartz Nanoslit

Energies ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 3045 ◽  
Author(s):  
Jun Pu ◽  
Xuejie Qin ◽  
Feifei Gou ◽  
Wenchao Fang ◽  
Fengjie Peng ◽  
...  
Keyword(s):  
Interfacial Tension ◽  
Oil Recovery ◽  
Interfacial Properties ◽  
Co2 Injection ◽  
Displacement Efficiency ◽  
Co2 Solubility ◽  
Minimum Miscibility Pressure ◽  
Tertiary Oil Recovery ◽  
Secondary Oil Recovery ◽  
Dynamics Simulations

After primary and secondary oil recovery, CO2-enhanced oil recovery (EOR) has become one of the most mentioned technologies in tertiary oil recovery. Since the oil is confined in an unconventional reservoir, the interfacial properties of CO2 and oil are different from in conventional reservoirs, and play a key role in CO2 EOR. In this study, molecular dynamics simulations are performed to investigate the interfacial properties, such as interfacial tension, minimum miscibility pressure (MMP), and CO2 solubility. The vanishing interfacial tension method is used to get the MMP (~10.8 MPa at 343.15 K) which is in agreement with the reported experimental data, quantitatively. Meanwhile, the diffusion coefficients of CO2 and n-octane under different pressures are calculated to show that the diffusion is mainly improved at the interface. Furthermore, the displacement efficiency and molecular orientation in α-quartz nanoslit under different CO2 injection ratios have been evaluated. After CO2 injection, the adsorbed n-octane molecules are found to be displaced from surface by the injected CO2 and, then, the orientation of n-octane becomes more random, which indicates that and CO2 can enhance the oil recovery and weaken the interaction between n-octane and α-quartz surface. The injection ratio of CO2 to n-octane is around 3:1, which could achieve the optimal displacement efficiency.

scholarly journals A new slick water system for hydraulic fracturing in tight reservoir to enhance imbibition oil recovery

2021 ◽  
Vol 303 ◽  
pp. 01001
Author(s):  
Yu Haiyang ◽  
Ji Wenjuan ◽  
Luo Cheng ◽  
Lu Junkai ◽  
Yan Fei ◽  
...  
Keyword(s):  
Contact Angle ◽  
Interfacial Tension ◽  
Hydraulic Fracturing ◽  
Oil Recovery ◽  
Water System ◽  
Natural Fracture ◽  
Fracturing Fluid ◽  
The Core ◽  
Ultralow Permeability

In order to give full play to the role of imbibition of capillary force and enhance oil recovery of ultralow permeability sandstone reservoir after hydraulic fracturing, the mixed water fracture technology based on functional slick water is described and successfully applied to several wells in oilfield. The core of the technology is determination of influence factors of imbibition oil recovery, the development of new functional slick water system and optimization of volume fracturing parameters. The imbibition results show that it is significant effect of interfacial tension, wetting on imbibition oil recovery. The interfacial tension decreases by an order of magnitude, the imbibition oil recovery reduces by more than 10%. The imbibition oil recovery increases with the contact angle decreasing. The emulsifying ability has no obvious effect on imbibition oil recovery. The functional slick water system considering imbibition is developed based on the solution rheology and polymer chemistry. The system has introduced the active group and temperature resistant group into the polymer molecules. The molecular weight is controlled in 1.5 million. The viscosity is greater than 2mPa·s after shearing 2h under 170s-1 and 100℃. The interfacial tension could decrease to 10-2mN/m. The contact angle decreased from 58° to 22° and the core damage rate is less than 12%. The imbibition oil recovery could reach to 43%. The fracturing process includes slick water stage and linear gel stage. 10% 100 mesh ceramists and 8% temporary plugging agents are carried into the formation by functional slick water. 40-70 mesh ceramists are carried by linear gel. The liquid volume ratio is about 4:1 and the displacement is controlled at 10-12m3/min. The sand content and fracturing fluid volumes of single stage are 80m3 and 2500 m3 respectively. Compared with conventional fracturing, due to imbibition oil recovery, there is only 25% of the fracturing fluid flowback rate when the crude oil flew out. When the oil well is in normal production, about 50% of the fracturing fluid is not returned. It is useful to maintain the formation energy and slow down the production decline. The average cumulative production of vertical wells is greater than 2800t, and the effective period is more than 2 years. This technology overcoming the problem of high horizontal stress difference and lack of natural fracture has been successfully applied in Jidong Oilfield ultralow permeability reservoir. The successful application of this technology not only helps to promote the effective use of ultralow permeability reservoirs, but also helps to further clarify the role of imbibition recovery, energy storage and oil-water replacement mechanism.

scholarly journals The Role of Salinity and Brine Ions in Interfacial Tension Reduction While Using Surfactant for Enhanced Oil Recovery

2015 ◽  
Vol 9 (9) ◽  
pp. 722-726 ◽  
Author(s):  
S.N. Hosseini ◽  
M.T. Shuker ◽  
Z. Hosseini ◽  
T. Joao Tomocene ◽  
A. Shabib-asl ◽  
...  
Keyword(s):  
Interfacial Tension ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Tension Reduction

Indoor Study of Viscosity Reducer for Thickened Oil of Huancai

2012 ◽  
Vol 268-270 ◽  
pp. 547-550
Author(s):  
Qing Wang Liu ◽  
Xin Wang ◽  
Zhen Zhong Fan ◽  
Jiao Wang ◽  
Rui Gao ◽  
...  
Keyword(s):  
Interfacial Tension ◽  
Oil Recovery ◽  
Heavy Oil ◽  
High Viscosity ◽  
Oil Field ◽  
Viscosity Reduction ◽  
Oil Viscosity ◽  
Low Viscosity ◽  
Viscosity Reducer ◽  
Oil Water

Liaohe oil field block 58 for Huancai, the efficiency of production of thickened oil is low, and the efficiency of displacement is worse, likely to cause other issues. Researching and developing an type of Heavy Oil Viscosity Reducer for exploiting. The high viscosity of W/O emulsion changed into low viscosity O/W emulsion to facilitate recovery, enhanced oil recovery. Through the experiment determine the viscosity properties of Heavy Oil Viscosity Reducer. The oil/water interfacial tension is lower than 0.0031mN•m-1, salt-resisting is good. The efficiency of viscosity reduction is higher than 90%, and also good at 180°C.

scholarly journals Minimum miscibility pressure computation in eor by flare gas flooding

2018 ◽  
Vol 10 (2) ◽  
pp. 61
Author(s):  
Tjokorde Walmiki Samadhi ◽  
Utjok W.R. Siagian ◽  
Angga P Budiono
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Gas Injection ◽  
Molar Ratio ◽  
Co2 Injection ◽  
Co2 Flooding ◽  
Minimum Miscibility Pressure ◽  
Gas Flooding ◽  
Model Oil ◽  
Gas Drive

The technical feasibility of using flare gas in the miscible gas flooding enhanced oil recovery (MGF-EOR) is evaluated by comparing the minimum miscibility pressure (MMP) obtained using flare gas to the MMP obtained in the conventional CO2 flooding. The MMP is estimated by the multiple mixing cell calculation method with the Peng-Robinson equation of state using a binary nC5H12-nC16H34 mixture at a 43%:57% molar ratio as a model oil. At a temperature of 323.15 K, the MMP in CO2 injection is estimated at 9.78 MPa. The MMP obtained when a flare gas consisting of CH4 and C2H6 at a molar ratio of 91%:9% is used as the injection gas is predicted to be 3.66 times higher than the CO2 injection case. The complete gas-oil miscibility in CO2 injection occurs via the vaporizing gas drive mechanism, while flare gas injection shifts the miscibility development mechanism to the combined vaporizing / condensing gas drive. Impact of variations in the composition of the flare gas on MMP needs to be further explored to confirm the feasibility of flare gas injection in MGF-EOR processes. Keywords: flare gas, MMP, miscible gas flooding, EORAbstrakKonsep penggunaan flare gas untuk proses enhanced oil recovery dengan injeksi gas terlarut (miscible gas flooding enhanced oil recovery atau MGF-EOR) digagaskan untuk mengurangi emisi gas rumah kaca dari fasilitas produksi migas, dengan sekaligus meningkatkan produksi minyak. Kelayakan teknis injeksi flare gas dievaluasi dengan memperbandingkan tekanan pelarutan minimum (minimum miscibility pressure atau MMP) untuk injeksi flare gas dengan MMP pada proses MGF-EOR konvensional menggunakan injeksi CO2. MMP diperkirakan melalui komputasi dengan metode sel pencampur majemuk dengan persamaan keadaan Peng-Robinson, pada campuran biner nC5H12-nC16H34 dengan nisbah molar 43%:57% sebagai model minyak. Pada temperatur 323.15 K, estimasi MMP yang diperoleh dengan injeksi CO2 adalah 9.78 MPa. Nilai MMP yang diperkirakan pada injeksi flare gas yang berupa campuran CH4-C2H6 pada nisbah molar 91%:9% sangat tinggi, yakni sebesar 3.66 kali nilai yang diperoleh pada kasus injeksi CO2. Pelarutan sempurna gas-minyak dalam injeksi CO2 terbentuk melalui mekanisme dorongan gas menguap (vaporizing gas drive), sementara pelarutan pada injeksi flare gas terbentuk melaui mekanisme kombinasi dorongan gas menguap dan mengembun (vaporizing/condensing gas drive). Pengaruh variasi komposisi flare gas terhadap MMP perlu dikaji lebih lanjut untuk menjajaki kelayakan injeksi flare gas dalam proses MGF-EOR.Kata kunci: flare gas, MMP, miscible gas flooding, EOR

scholarly journals NANO-SURFACTANT HUFF AND PUFF OPTIMATIZATION IN MARGINAL X FIELD USING COMMERCIAL SIMULATOR

2019 ◽  
Vol 42 (2) ◽  
pp. 51-57
Author(s):  
Ariel Paramastya ◽  
Steven Chandra ◽  
Wijoyo Niti Daton ◽  
Sudjati Rachmat
Keyword(s):  
Interfacial Tension ◽  
Production Rate ◽  
Oil Recovery ◽  
Oil And Gas ◽  
Oil Production ◽  
Full Scale ◽  
Economic Aspect ◽  
Economic Optimization ◽  
Single Well

Economic optimization of an oil and gas project is an obligation that has to be done to increase overall profi t, whether the fi eld is still economically feas ible or the fi eld has surpassed its economic limit. In this case, a marginal fi eld waschosen for the study. In this marginal fi eld EOR methods have been used to boost the production rate. However, a full scale EOR method might not be profi table due to the amount of resources that is required to do it. Alternatively, Huff and Puff method is an EOR technique that is reasonable in the scope of single well. The Huff and Puff method is an EOR method where a single well serves as both a producer and an injector. The technique of Huff and Puff: (1) The well isinjected with designed injection fl uid, (2) the well is shut to let the fl uid to soak in the reservoir for some time, and (3) the well is opened and reservoir fl uids are allowed to be produced. The injection fl uid (in this case, nano surfactant) is hypothesized to reduce interfacial tension between the oil and rock, thus improving the oil recovery. In this study, the application of Huff and Puff method using Nanoparticles (NPs) as the injected fl uid, as a method of improving oil recovery is presented in a case study of a fi eld in South Sumatra. The study resulted that said method yields an optimum Incremental Oil Production (IOP) in which the economic aspect gain more profi t, and therefore it is considered feasible to be applied in the fi eld.

Applied Research of Heat Self-Generated CO2 Technology in Steam Huff and Puff

2014 ◽  
Vol 1010-1012 ◽  
pp. 1693-1698
Author(s):  
Yi Ding ◽  
Guo Wei Qin ◽  
Peng Liu ◽  
Zi Li Fan ◽  
Hong Wei Xiao ◽  
...  
Keyword(s):  
Interfacial Tension ◽  
Oil Recovery ◽  
Heavy Oil ◽  
Field Experiments ◽  
Reduction Rate ◽  
Viscosity Reduction ◽  
Oil Viscosity ◽  
Blowing Agent ◽  
Steam Flooding ◽  
Gas Flooding

Heat self-generated CO2 technique is proposed, which is focused on the problems of recovery difficulty, poor effect steam soaking and so on for heavy oil reservoirs. This technology is combining of steam flooding and gas flooding and so on. Its main mechanism is the application of steam heating blowing agent to generate a large volume of gases (including CO2, NH3, etc) in the formation. While some of these gases acting with the oil to reduce the oil viscosity, some form miscible flooding to reduce water interfacial tension, so as to achieve the purpose of enhancing oil recovery. An optimized selection of the heat blowing agents was performed. By comparison the difference before and after the reaction of blowing agent solution, the increase of alkaline is occurred after the reaction, and is helpful to reduce oil viscosity and lower interfacial tension, etc. Studies indicate that heat-generating CO2 flooding technology can get a maximum viscosity reduction rate of 76.7%, oil-water interfacial tension decreased by 54.77%, further improve oil recovery by 4.17% based on the steam drive, which shows a technical advantage toward conventional EOR method. The field experiments indicate that the technique can greatly improve the oil production, which will provide a powerful technical supporting for the efficient development of heavy oil.

EFFECT OF LOW TEMPERATURE CO2 INJECTION IN HIGH TEMPERATURE OIL RESERVOIRS USING SLIMTUBE EXPERIMENT

2016 ◽  
Vol 78 (6-6) ◽  
Author(s):  
Zakaria Hamdi ◽  
Mariyamni Awang
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Interfacial Tension ◽  
Oil Recovery ◽  
Early Stage ◽  
Recovery Factor ◽  
Effect Of Temperature ◽  
Co2 Injection ◽  
Sweep Efficiency ◽  
Injection Point

A set of slimtube experiments is designed and presented to study the effect of cold temperature CO2 on recovery factor in reservoirs with high temperature. The comparison of the results indicates the positive effect of temperature on recovery trend in early stage as well as ultimate recovery in different injection pressures. The approach is based on a long slimtube to show the effect of temperature on the recovery. The study considers different temperatures and pressures of injection and reservoir allowing both miscible and immiscible flooding of CO2. Using non-isothermal conditions, the results show that, lowering temperature of injection can yield in higher recovery in early stage significantly. Also, considering ultimate recovery, it is observed that low temperature CO2 injection into high temperature reservoir can result in slightly higher recovery factor than isothermal injection. The reason for recovery increase is mainly due to elimination of the interfacial tension between CO2 and reservoir fluids especially near the injection point. Another finding is that the minimum miscibility pressures is lowered by means of lowering the temperature of injection which is again caused by elimination of interfacial tension between CO2 and oil. This is important because forming a single phase can increase the ability of CO2 to extract different components of the crude oil as well as lowering viscosity of the mixture, resulting in a better sweep efficiency. It appears that using liquid CO2 in high temperature reservoirs can be a promising method for better oil recovery in high temperature reservoirs. 

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