EFFECT OF LOW TEMPERATURE CO2 INJECTION IN HIGH TEMPERATURE OIL RESERVOIRS USING SLIMTUBE EXPERIMENT

2016 ◽  
Vol 78 (6-6) ◽  
Author(s):  
Zakaria Hamdi ◽  
Mariyamni Awang

A set of slimtube experiments is designed and presented to study the effect of cold temperature CO2 on recovery factor in reservoirs with high temperature. The comparison of the results indicates the positive effect of temperature on recovery trend in early stage as well as ultimate recovery in different injection pressures. The approach is based on a long slimtube to show the effect of temperature on the recovery. The study considers different temperatures and pressures of injection and reservoir allowing both miscible and immiscible flooding of CO2. Using non-isothermal conditions, the results show that, lowering temperature of injection can yield in higher recovery in early stage significantly. Also, considering ultimate recovery, it is observed that low temperature CO2 injection into high temperature reservoir can result in slightly higher recovery factor than isothermal injection. The reason for recovery increase is mainly due to elimination of the interfacial tension between CO2 and reservoir fluids especially near the injection point. Another finding is that the minimum miscibility pressures is lowered by means of lowering the temperature of injection which is again caused by elimination of interfacial tension between CO2 and oil. This is important because forming a single phase can increase the ability of CO2 to extract different components of the crude oil as well as lowering viscosity of the mixture, resulting in a better sweep efficiency. It appears that using liquid CO2 in high temperature reservoirs can be a promising method for better oil recovery in high temperature reservoirs. 

Energies ◽  
2019 ◽  
Vol 12 (12) ◽  
pp. 2319 ◽  
Author(s):  
Ahmed Fatih Belhaj ◽  
Khaled Abdalla Elraies ◽  
Mohamad Sahban Alnarabiji ◽  
Juhairi Aris B M Shuhli ◽  
Syed Mohammad Mahmood ◽  
...  

The applications of surfactants in Enhanced Oil Recovery (EOR) have received more attention in the past decade due to their ability to enhance microscopic sweep efficiency by reducing oil-water interfacial tension in order to mobilize trapped oil. Surfactants can partition in both water and oil systems depending on their solubility in both phases. The partitioning coefficient (Kp) is a key parameter when it comes to describing the ratio between the concentration of the surfactant in the oil phase and the water phase at equilibrium. In this paper, surfactant partitioning of the nonionic surfactant Alkylpolyglucoside (APG) was investigated in pre-critical micelle concentration (CMC) and post-cmc regimes at 80 °C to 106 °C. The Kp was then obtained by measuring the surfactant concentration after equilibration with oil in pre-cmc and post-cmc regimes, which was done using surface tension measurements and high-performance liquid chromatography (HPLC), respectively. Surface tension (ST) and interfacial tension (IFT) behaviors were investigated by performing pendant and spinning drop tests, respectively—both tests were conducted at high temperatures. From this study, it was found that APG was able to lower IFT as well as ST between water/oil and air/oil, and its effect was found to be more profound at high temperature. The partitioning test results for APG in pre-cmc and post-cmc regimes were found to be dependent on the surfactant concentration and temperature. The partitioning coefficient is directly proportional to IFT, where at high partitioning intensity, IFT was found to be very low and vice versa at low partitioning intensity. The effect of temperature on the partitioning in pre-cmc and post-cmc regimes had the same impact, where at a high temperature, additional partitioned surfactant molecules arise at the water-oil interface as the association of molecules becomes easier.


Energies ◽  
2020 ◽  
Vol 13 (12) ◽  
pp. 3135
Author(s):  
Fabiola D. S. Curbelo ◽  
Alfredo Ismael C. Garnica ◽  
Danilo F. Q. Leite ◽  
Amanda B. Carvalho ◽  
Raphael R. Silva ◽  
...  

Over time, oil production in a reservoir tends to decrease, which makes it difficult to flow through the reservoir to the well, making its production increasingly difficult and costly. Due to their physical properties, such as reducing the water/oil interfacial tension, surfactants have been used in enhanced oil recovery (EOR) processes, however, their adsorption presents as an undesirable and inevitable factor and can decrease the efficiency of the method. This work’s main objective is to evaluate the effect of glycerol in the adsorption of surfactants in sandstones, as well as in the recovery factor during EOR. Brine solutions containing the nonionic surfactant saponified coconut oil (SCO), with and without glycerol, were used in the adsorption and oil recovery tests in sandstone. Adsorption, recovery, rheological, and thermogravimetric analysis were carried out. Regarding the surfactant/glycerol/brine solution, there was an improvement in the oil mobility, as the glycerol contributed to an increase in the viscosity of the solution, thereby increasing the sweep efficiency. The recovery factor obtained for the surfactant solution with glycerol was satisfactory, being 53% higher than without glycerol, because it simultaneously provided an increase in viscosity and a decrease in interfacial tension, both of which are beneficial for the efficiency of the process.


Processes ◽  
2021 ◽  
Vol 9 (1) ◽  
pp. 94
Author(s):  
Asep Kurnia Permadi ◽  
Egi Adrian Pratama ◽  
Andri Luthfi Lukman Hakim ◽  
Doddy Abdassah

A factor influencing the effectiveness of CO2 injection is miscibility. Besides the miscible injection, CO2 may also contribute to oil recovery improvement by immiscible injection through modifying several properties such as oil swelling, viscosity reduction, and the lowering of interfacial tension (IFT). Moreover, CO2 immiscible injection performance is also expected to be improved by adding some solvent. However, there are a lack of studies identifying the roles of solvent in assisting CO2 injection through observing those properties simultaneously. This paper explains the effects of CO2–carbonyl and CO2–hydroxyl compounds mixture injection on those properties, and also the minimum miscibility pressure (MMP) experimentally by using VIPS (refers to viscosity, interfacial tension, pressure–volume, and swelling) apparatus, which has a capability of measuring those properties simultaneously within a closed system. Higher swelling factor, lower viscosity, IFT and MMP are observed from a CO2–propanone/acetone mixture injection. The role of propanone and ethanol is more significant in Sample A1, which has higher molecular weight (MW) of C7+ and lower composition of C1–C4, than that in the other Sample A9. The solvents accelerate the ways in which CO2 dissolves and extracts oil, especially the extraction of the heavier component left in the swelling cell.


Author(s):  
Ahmed Ragab ◽  
Eman M. Mansour

The enhanced oil recovery phase of oil reservoirs production usually comes after the water/gas injection (secondary recovery) phase. The main objective of EOR application is to mobilize the remaining oil through enhancing the oil displacement and volumetric sweep efficiency. The oil displacement efficiency enhances by reducing the oil viscosity and/or by reducing the interfacial tension, while the volumetric sweep efficiency improves by developing a favorable mobility ratio between the displacing fluid and the remaining oil. It is important to identify remaining oil and the production mechanisms that are necessary to improve oil recovery prior to implementing an EOR phase. Chemical enhanced oil recovery is one of the major EOR methods that reduces the residual oil saturation by lowering water-oil interfacial tension (surfactant/alkaline) and increases the volumetric sweep efficiency by reducing the water-oil mobility ratio (polymer). In this chapter, the basic mechanisms of different chemical methods have been discussed including the interactions of different chemicals with the reservoir rocks and fluids. In addition, an up-to-date status of chemical flooding at the laboratory scale, pilot projects and field applications have been reported.


2020 ◽  
Vol 60 (2) ◽  
pp. 662
Author(s):  
Saira ◽  
Furqan Le-Hussain

Oil recovery and CO2 storage related to CO2 enhance oil recovery are dependent on CO2 miscibility. In case of a depleted oil reservoir, reservoir pressure is not sufficient to achieve miscible or near-miscible condition. This extended abstract presents numerical studies to delineate the effect of alcohol-treated CO2 injection on enhancing miscibility, CO2 storage and oil recovery at immiscible and near-miscible conditions. A compositional reservoir simulator from Computer Modelling Group Ltd. was used to examine the effect of alcohol-treated CO2 on the recovery mechanism. A SPE-5 3D model was used to simulate oil recovery and CO2 storage at field scale for two sets of fluid pairs: (1) pure CO2 and decane and (2) alcohol-treated CO2 and decane. Alcohol-treated CO2 consisted of a mixture of 4 wt% of ethanol and 96 wt% of CO2. All simulations were run at constant temperature (70°C), whereas pressures were determined using a pressure-volume-temperature simulator for immiscible (1400 psi) and near-miscible (1780 psi) conditions. Simulation results reveal that alcohol-treated CO2 injection is found superior to pure CO2 injection in oil recovery (5–9%) and CO2 storage efficiency (4–6%). It shows that alcohol-treated CO2 improves CO2 sweep efficiency. However, improvement in sweep efficiency with alcohol-treated CO2 is more pronounced at higher pressures, whereas improvement in displacement efficiency is more pronounced at lower pressures. The proposed methodology has potential to enhance the feasibility of CO2 sequestration in depleted oil reservoirs and improve both displacement and sweep efficiency of CO2.


1969 ◽  
Vol 72 (3) ◽  
pp. 423-435 ◽  
Author(s):  
R. Q. Cannell

SUMMARYControlled-environment experiments showed that development of the coleoptile node tiller (T1) was suppressed much more than that of the tiller appearing in the axil of the first true leaf (T2) by high temperature (24/15 °C; 19/10 °C; 10/6 °C), by reduced photoperiod (16 h; 12·5 h) or by low light intensity (1100 ft-c; 1000 ft-c), but minimally in the newest variety, Deba Abed. Unlike previous field experiments, the T1 tiller appeared on more Spratt Archer than Maris Badger plants. Maris Badger plants produced more T1 tillers in a high-low temperature regime (19/10 °C; 10/6 °C) than in continuous low temperature (10/6 °C). In a field experiment T1 tiller number (and yield), but not the number of other major shoots, were severely reduced by late sowing of Spratt Archer, progressively reduced in Maris Badger, but minimally in Deba Abed. This seemed to be associated with higher temperatures at later sowings.


1943 ◽  
Vol 21c (8) ◽  
pp. 235-248 ◽  
Author(s):  
A. A. Hildebrand ◽  
L. W. Koch

During the summer of 1942 sugar beets growing in an experimental plot at the Harrow laboratory were destroyed by a root rot of a type that apparently has been reported only once previously on this host in North America. Wilting of the foliage first attracts attention to affected plants, the roots of which show, externally, grayish-brown discoloured areas and, internally, fairly sharply-delimited, grayish to coffee-coloured lesions, affected tissues being more or less spongy in consistency. The causal organism, found to be a wound parasite, has been identified as Rhizopus arrhizus Fischer. The effect of temperature on the growth in culture and on the pathogenicity of this fungus and of representatives of the species, R. oryzae and R. nigricans, has been studied. It has been found that R. arrhizus and R. oryzae are relatively high temperature organisms, showing optimum growth at about 34° to 36 °C., and each capable of infecting and destroying artificially injured sugar beets most rapidly between 30° and 40 °C. R. nigricans, also a wound parasite is, on the other hand, a relatively low temperature organism showing optimum growth in culture at about 24° and displaying highest infection capability at about 14° to 16 °C.


2012 ◽  
Vol 706-709 ◽  
pp. 768-773
Author(s):  
Masahiro Nishida ◽  
Koichi Hayashi ◽  
Junichi Nakagawa ◽  
Yoshitaka Ito

The influence of temperature on crater formation and ejecta composition in thick aluminum alloy targets were investigated for impact velocities ranging from approximately 1.5 to 3.5 km/s using a two-stage light-gas gun. The diameter and depth of the crater increased with increasing temperature. The ejecta size at low temperature was slightly smaller than that at high temperature and room temperature. Temperature did not affect the size ratio of ejecta. The scatter diameter of the ejecta at high temperature was slightly smaller than those at low and room temperatures.


1993 ◽  
Vol 310 ◽  
Author(s):  
Barbara Charlet ◽  
Kerrie E. Davies

AbstractPZT films were etched in an ECR microwave reactor with RF polarization.The etch rate was evaluated using various gas mixtures including combinations of two of the following: C12, NF3, SF6 and HBr. The etch rate was measured as a function of the percentage of one gas in the mixture. Other parameters investigated included gas pressure, bias voltage on the electrode and substrate temperature.Results of the effect of temperature show that etch rates are higher on high temperature substrates than on low temperature substrates. A mixture of C12 and SF2 provided a PZT etch rate of 750 Å / min on a substrate, at approximately 100 °C. We evaluated the resultant etch profile and surface roughness


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