scholarly journals Fabrication of Size- and Shape-Controlled Platinum Cones by Ion-Track Etching and Electrodeposition Techniques for Electrocatalytic Applications

2021 ◽  
Vol 5 (3) ◽  
pp. 21
Author(s):  
Yuma Sato ◽  
Hiroshi Koshikawa ◽  
Shunya Yamamoto ◽  
Masaki Sugimoto ◽  
Shin-ichi Sawada ◽  
...  

The micro/nanocone structures of noble metals play a critical role as heterogeneous electrocatalysts that provide excellent activity. We successfully fabricated platinum cones by electrodeposition using non-penetrated porous membranes as templates. This method involved the preparation of template membranes by the swift-heavy-ion irradiation of commercially available polycarbonate films and subsequent chemical etching in an aqueous NaOH solution. The surface diameter, depth, aspect ratio and cone angle of the resulting conical pores were controlled in the ranges of approximately 70–1500 nm, 0.7–11 μm, 4–12 and 5–13°, respectively, by varying the etching conditions, which finally produced size- and shape-controlled platinum cones with nanotips. In order to demonstrate the electrocatalytic activity, electrochemical measurements were performed for the ethanol oxidation reaction. The oxidation activity was found to be up to 3.2 times higher for the platinum cone arrays than for the platinum plate. Ion-track etching combined with electrodeposition has the potential to be an effective method for the fabrication of micro/nanocones with high electrocatalytic performance.

2012 ◽  
Vol 3 ◽  
pp. 860-883 ◽  
Author(s):  
Maria Eugenia Toimil-Molares

The combination of electrodeposition and polymeric templates created by heavy-ion irradiation followed by chemical track etching provides a large variety of poly- and single-crystalline nanowires of controlled size, geometry, composition, and surface morphology. Recent results obtained by our group on the fabrication, characterization and size-dependent properties of nanowires synthesized by this technique are reviewed, including investigations on electrical resistivity, surface plasmon resonances, and thermal instability.


2011 ◽  
Vol 104 (4) ◽  
pp. 1223-1227 ◽  
Author(s):  
R. S. Thomaz ◽  
C. T. Souza ◽  
R. M. Papaléo

Author(s):  
Charles W. Allen ◽  
Robert C. Birtcher

The uranium silicides, including U3Si, are under study as candidate low enrichment nuclear fuels. Ion beam simulations of the in-reactor behavior of such materials are performed because a similar damage structure can be produced in hours by energetic heavy ions which requires years in actual reactor tests. This contribution treats one aspect of the microstructural behavior of U3Si under high energy electron irradiation and low dose energetic heavy ion irradiation and is based on in situ experiments, performed at the HVEM-Tandem User Facility at Argonne National Laboratory. This Facility interfaces a 2 MV Tandem ion accelerator and a 0.6 MV ion implanter to a 1.2 MeV AEI high voltage electron microscope, which allows a wide variety of in situ ion beam experiments to be performed with simultaneous irradiation and electron microscopy or diffraction.At elevated temperatures, U3Si exhibits the ordered AuCu3 structure. On cooling below 1058 K, the intermetallic transforms, evidently martensitically, to a body-centered tetragonal structure (alternatively, the structure may be described as face-centered tetragonal, which would be fcc except for a 1 pet tetragonal distortion). Mechanical twinning accompanies the transformation; however, diferences between electron diffraction patterns from twinned and non-twinned martensite plates could not be distinguished.


2002 ◽  
Vol 82 (11) ◽  
pp. 2333-2339
Author(s):  
G. Schumacher ◽  
R. C. Birtcher ◽  
D. P. Renusch ◽  
M. Grimsditch ◽  
L. E. Rehn

1995 ◽  
Vol 35 (3) ◽  
pp. 603-608 ◽  
Author(s):  
S.R. Anderson ◽  
R.D. Schrimpf ◽  
K.F. Galloway ◽  
J.L. Titus

RSC Advances ◽  
2021 ◽  
Vol 11 (42) ◽  
pp. 26218-26227
Author(s):  
R. Panda ◽  
S. A. Khan ◽  
U. P. Singh ◽  
R. Naik ◽  
N. C. Mishra

Swift heavy ion (SHI) irradiation in thin films significantly modifies the structure and related properties in a controlled manner.


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