scholarly journals A Flexible Platform of Electrochemically Functionalized Carbon Nanotubes for NADH Sensors

Sensors ◽  
2019 ◽  
Vol 19 (3) ◽  
pp. 518 ◽  
Author(s):  
Aranzazu Heras ◽  
Fabio Vulcano ◽  
Jesus Garoz-Ruiz ◽  
Nicola Porcelli ◽  
Fabio Terzi ◽  
...  

A flexible electrode system entirely constituted by single-walled carbon nanotubes (SWCNTs) has been proposed as the sensor platform for β-nicotinamide adenine dinucleotide (NADH) detection. The performance of the device, in terms of potential at which the electrochemical process takes place, significantly improves by electrochemical functionalization of the carbon-based material with a molecule possessing an o-hydroquinone residue, namely caffeic acid. Both the processes of SWCNT functionalization and NADH detection have been studied by combining electrochemical and spectroelectrochemical experiments, in order to achieve direct evidence of the electrode modification by the organic residues and to study the electrocatalytic activity of the resulting material in respect to functional groups present at the electrode/solution interface. Electrochemical measurements performed at the fixed potential of +0.30 V let us envision the possible use of the device as an amperometric sensor for NADH detection. Spectroelectrochemistry also demonstrates the effectiveness of the device in acting as a voltabsorptometric sensor for the detection of this same analyte by exploiting this different transduction mechanism, potentially less prone to the possible presence of interfering species.

2018 ◽  
Vol 6 (5) ◽  
pp. 972-979 ◽  
Author(s):  
Tae-Yeon Hwang ◽  
Yomin Choi ◽  
YoSeb Song ◽  
Nu Si A. Eom ◽  
Seil Kim ◽  
...  

Monodispersed nano Pt catalyzed linear dense assembly of SWCNTs bundles on a noble multi-layered electrode system for cost-effective hydrogen sensor.


2016 ◽  
Vol 6 (24) ◽  
pp. 8418-8427 ◽  
Author(s):  
M. Buaki-Sogó ◽  
A. Vivian ◽  
L. A. Bivona ◽  
H. García ◽  
M. Gruttadauria ◽  
...  

Single walled carbon nanotubes were functionalized with imidazolium based salts and successfully used as catalysts for the conversion of CO2. The novel materials displayed excellent catalytic activity.


2016 ◽  
Vol 4 (7) ◽  
pp. 2473-2483 ◽  
Author(s):  
Yi Cheng ◽  
Amir Memar ◽  
Martin Saunders ◽  
Jian Pan ◽  
Chang Liu ◽  
...  

Dye functionalized double- and triple-walled carbon nanotubes are effective photoanodes for water splitting without the attachment of semiconductor and water oxidation catalysts.


Carbon ◽  
2012 ◽  
Vol 50 (7) ◽  
pp. 2524-2529 ◽  
Author(s):  
Zhanbing He ◽  
Xiaoxing Ke ◽  
Sara Bals ◽  
Gustaaf Van Tendeloo

2007 ◽  
Vol 334-335 ◽  
pp. 705-708 ◽  
Author(s):  
Ka Keung Wong ◽  
San Qiang Shi ◽  
Alan Kin Tak Lau

Although many studies have been conducted in the past few years on the possibility of using carbon nanotube (CNT) to improve the performance of polymer-based materials, some of the results were contradictory and lack of coherence. Thus, the in-depth understanding of CNT composites is required. In this paper, single-walled carbon nanotubes (SWNTs), which were functionalized by sonicating with nitric and sulfuric acids, will be used to fabricate a SWNT/epoxy composite. There are two reasons for functionalizing the SWNTs, they are (i) to improve the dispersion of the SWNTs in polymer, and (ii) to improve the interfacial bonding properties between the SWNTs and polymer matrix. Tensile property test and micro-hardness test will be carried out to examine the mechanical properties of the composites with different SWNT contents. Thermogravimetry Analysis (TGA) will be used to evaluate the thermal properties of the composites. Scanning Electron Microscope (SEM) will also be used to investigate the failure mechanism of the composites after tensile test. A comparison of the composites with functionalized and non-functionalized SWNTs will be given to elaborate the effect of nanotube functionalization.


This work is devoted to the study of the effect of carbon nanotubes functionalization on the electrical conductivity of composite materials based on them. Carbon nanotubes were functionalized by treatment in nitric acid and isopropyl alcohol. Changes in the morphology of multi-walled carbon nanotubes during liquid-phase functionalization were investigated using Auger-electron microscopy. Samples of composite material on the basis of initial and functionalized carbon nanotubes and epoxy resin were prepared and the concentration dependence of electrical conductivity using the four-probe method was studied. The study reveals the effect of functionalization in various solutions on the electrophysical properties of the obtained carbon nanotubes/epoxy composites.


RSC Advances ◽  
2016 ◽  
Vol 6 (82) ◽  
pp. 78692-78701 ◽  
Author(s):  
Nishesh Kumar Gupta ◽  
Arijit Sengupta ◽  
Anil Boda ◽  
V. C. Adya ◽  
Sk. Musharaf Ali

Selective phase separation of Pu4+ and PuO22+ was performed using N,N-dialkylamide functionalized multi-walled carbon nanotubes (AFMWCNTs).


2019 ◽  
Vol 39 (6) ◽  
Author(s):  
Syeda Ammara Shabbir ◽  
Sana Tariq ◽  
M. Gul Bahar Ashiq ◽  
Waqar A. Khan

Abstract Diabetes mellitus is a debilitating disease that affects each and every organ of human body. Hence it is important to continuously monitor the glucose level throughout the day and night. Glucose sensors are in great demand due to a rapid increase in diabetic community. A strategy has been implemented here to fabricate silver nanoparticles (AgNPs) with the support of functionalized carbon nanotubes (f-CNTs). Silver/carbon nanotubes (Ag/CNTs) nanocomposite electrode have been prepared by electrochemical process on Fluorine doped tin oxide (FTO) glass, by varying silver (Ag) concentrations for non-enzymatic glucose sensor. The variable Ag concentration in the morphology of Ag/CNTs nanocomposite has influenced the electrical conductivity, oxidation and reduction potential and electrochemical activity of glucose. Highest current density and good electrocatalytic activity for electrodes are obtained at 70 mM concentration of silver in Ag/CNTs composite. The present study indicates that the Ag/CNTs electrode is a possible substitute of the expensive glassy carbon electrode for enzyme-free glucose sensors.


RSC Advances ◽  
2014 ◽  
Vol 4 (34) ◽  
pp. 17454-17460 ◽  
Author(s):  
Dongming Zhang ◽  
Ke Ye ◽  
Kui Cheng ◽  
Yang Xu ◽  
Jinling Yin ◽  
...  

A simple method involving dyeing and electrodeposition is introduced to fabricate a three-dimensional Ni@multi-walled carbon nanotubes flexible electrode on wearable fabric.


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