scholarly journals Diamond-Coated Silicon ATR Elements for Process Analytics

Sensors ◽  
2021 ◽  
Vol 21 (19) ◽  
pp. 6442
Author(s):  
Nicolai Arndt ◽  
Carsten Bolwien ◽  
Gerd Sulz ◽  
Frank Kühnemann ◽  
Armin Lambrecht
Keyword(s):  
Incidence Angle ◽  
Attenuated Total Reflection ◽  
Experimental Investigations ◽  
Diamond Coatings ◽  
Infrared Transmission ◽  
Mir Spectroscopy ◽  
Increased Sensitivity ◽  
The Stability ◽  
Atr Spectroscopy ◽  
Inline Measurement

Infrared attenuated total reflection (ATR) spectroscopy is a common laboratory technique for the analysis of highly absorbing liquids or solid samples. However, ATR spectroscopy is rarely found in industrial processes, where inline measurement, continuous operation, and minimal maintenance are important issues. Most materials for mid-infrared (MIR) spectroscopy and specifically for ATR elements do not have either high enough infrared transmission or sufficient mechanical and chemical stability to be exposed to process fluids, abrasive components, and aggressive cleaning agents. Sapphire is the usual choice for infrared wavelengths below 5 µm, and beyond that, only diamond is an established material. The use of diamond coatings on other ATR materials such as silicon will increase the stability of the sensor and will enable the use of larger ATR elements with increased sensitivity at lower cost for wavelengths above 5 µm. Theoretical and experimental investigations of the dependence of ATR absorbances on the incidence angle and thickness of nanocrystalline diamond (NCD) coatings on silicon were performed. By optimizing the coating thickness, a substantial amplification of the ATR absorbance can be achieved compared to an uncoated silicon element. Using a compact FTIR instrument, ATR spectra of water, acetonitrile, and propylene carbonate were measured with planar ATR elements made of coated and uncoated silicon. Compared to sapphire, the long wavelength extreme of the spectral range is extended to approximately 8 μm. With effectively nine ATR reflections, the sensitivity is expected to exceed the performance of typical diamond tip probes.

scholarly journals Combination of Self-Healing Butyl Rubber and Natural Rubber Composites for Improving the Stability

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 443
Author(s):  
Kunakorn Chumnum ◽  
Ekwipoo Kalkornsurapranee ◽  
Jobish Johns ◽  
Karnda Sengloyluan ◽  
Yeampon Nakaramontri
Keyword(s):  
Natural Rubber ◽  
Dynamic Mechanical Properties ◽  
Attenuated Total Reflection ◽  
Rubber Matrix ◽  
Self Healing ◽  
Mechanical And Electrical Properties ◽  
Natural Rubber Composites ◽  
Tan Δ ◽  
The Stability ◽  
Physical And Chemical

The self-healing composites were prepared from the combination of bromobutyl rubber (BIIR) and natural rubber (NR) blends filled with carbon nanotubes (CNT) and carbon black (CB). To reach the optimized self-healing propagation, the BIIR was modified with ionic liquid (IL) and butylimidazole (IM), and blended with NR using the ratios of 70:30 and 80:20 BIIR:NR. Physical and chemical modifications were confirmed from the mixing torque and attenuated total reflection-fourier transform infrared spectroscopy (ATR-FTIR). It was found that the BIIR/NR-CNTCB with IL and IM effectively improved the cure properties with enhanced tensile properties relative to pure BIIR/NR blends. For the healed composites, BIIR/NR-CNTCB-IM exhibited superior mechanical and electrical properties due to the existing ionic linkages in rubber matrix. For the abrasion resistances, puncture stress and electrical recyclability were examined to know the possibility of inner liner applications and Taber abrasion with dynamic mechanical properties were elucidated for tire tread applications. Based on the obtained Tg and Tan δ values, the composites are proposed for tire applications in the future with a simplified preparation procedure.

Experimentally Determined Stability Parameters of a Subsonic Cascade Oscillating Near Stall

1978 ◽  
Vol 100 (1) ◽  
pp. 111-120 ◽  
Author(s):  
F. O. Carta ◽  
A. O. St. Hilaire
Keyword(s):  
Phase Angle ◽  
Incidence Angle ◽  
Minor Effect ◽  
Significant Finding ◽  
Force Coefficient ◽  
Stability Parameters ◽  
Free System ◽  
Pressure Transducers ◽  
Moment Coefficient ◽  
The Stability

Tests were performed on a linear cascade of airfoils oscillating in pitch about their midchords at frequencies up to 17 cps, at free-stream velocities up to 200 ft/s, and at interblade phase angles of 0 deg and 45 deg, under conditions of high aerodynamic loading. The measured data included unsteady time histories from chordwise pressure transducers and from chordwise hot films. Unsteady normal force coefficient, moment coefficient, and aerodynamic work per cycle of oscillation were obtained from integrals of the pressure data, and indications of the nature and extent of the separation phenomenon were obtained from an analysis of the hot-film response data. The most significant finding of this investigation is that a change in interblade phase angle from 0 deg to 45 deg radically alters the character of the unsteady blade loading (which governs its motion in a free system) from stable to unstable. Furthermore, the stability or instability is governed primarily by the phase angle of the pressure distribution (relative to the blade motion) over the forward 10–15 percent of the blade chord. Reduced frequency and mean incidence angle changes were found to have a relatively minor effect on stability for the range of parameters tested.

Diffusion Measurements Using FT-IR ATR Spectroscopy: Lubricant Diffusion in Polypropylene

2002 ◽  
Vol 56 (4) ◽  
pp. 509-514 ◽  
Author(s):  
Xiaohua Yi ◽  
Karen Nerbonne ◽  
John Pellegrino
Keyword(s):  
Current Model ◽  
Mineral Oil ◽  
Attenuated Total Reflection ◽  
Lubricant Layer ◽  
Polymer Interfaces ◽  
Time Resolved ◽  
Polymer Sample ◽  
Ft Ir ◽  
Atr Spectroscopy ◽  
Poly Propylene

We present an experimental method for measuring diffusion of lubricants (or any highly viscous fluid) in polymers using Fourier transform infrared (FT-IR) attenuated total reflection (ATR) spectroscopy. Unlike the conventional FT-IR ATR diffusion measurement, in which a polymer sample is sandwiched between the penetrant and an internal reflection element (IRE), in this method, a thin layer of penetrant (for example, a lubricant) is sandwiched between the IRE and the polymer sample. This allows accurate control and measurement of the thickness of the lubricant layer, which, in turn, facilitates subsequent data analysis. The diffusion is studied by monitoring the time-resolved change in absorbance of either a unique polymer or penetrant band. A feature of this new method is that it can provide an estimate of solubility, as well as an estimate of the diffusivity of the penetrant in the polymer. Using this method, we studied the diffusion of mineral oil and a commercial fluorocarbon ether lubricant (Krytox® 143AC‡) in poly(propylene) (PP) film at room temperature. The experimental data was modeled using a Fickian model with impermeable and saturated boundary conditions applied at the IRE/lubricant and lubricant/polymer interfaces, respectively. The diffusivity and solubility of mineral oil in PP were found to be 1.34 ± 0.35 (×10−10) cm2/s and 0.77 ± 0.13 (×10−2) g/g of PP, respectively. The current model was unable to quantitatively describe the diffusion of the Krytox® 143AC in the PP, possibly due to excessive swelling.

Model Optimization and Stability of Hemoglobin Analysis in Human Soluble Blood Samples by FTIR/ATR Spectroscopy

2011 ◽  
Vol 55-57 ◽  
pp. 1168-1171
Author(s):  
Tao Pan ◽  
Ai Hong Peng ◽  
Wen Jie Huang
Keyword(s):  
Signal To Noise Ratio ◽  
Attenuated Total Reflection ◽  
Partial Least Square ◽  
Least Square ◽  
Model Optimization ◽  
Optimal Model ◽  
Blood Samples ◽  
Quantification Method ◽  
Atr Spectroscopy ◽  
Pls Method

Using Fourier transform infrared spectroscopy (FTIR), attenuated total reflection (ATR) technology and partial least square (PLS) method, the rapid quantification method of hemoglobin (HGB) in human soluble blood samples was established. Based on the distribution of samples’ HGB chemical value and absorbance on 1543 cm-1 which had the highest signal to noise ratio for HGB, all samples were divided into calibration set and prediction set for 50 times. PLS models were established for all divisions, based on the average data RMSEPAve, the stable optimal model was selected, the corresponding PLS factor, RMSEPAve and RP,Ave were 2, 6.81 g/L and 0.943 respectively.

Application Of Systems With Total Internal Reflection At Novosibirsk Free Electron Laser For Spectroscopy In The Terahertz Range

2016 ◽  
Vol 11 (3) ◽  
pp. 72-82
Author(s):  
Vasily Gerasimov ◽  
Elvira Grigorieva ◽  
Boris Knyazev ◽  
Yuliya Choporova
Keyword(s):  
Free Electron ◽  
Free Electron Laser ◽  
Quantum Cascade Lasers ◽  
Attenuated Total Reflection ◽  
Terahertz Range ◽  
Optical Systems ◽  
Early Diagnosis Of Cancer ◽  
Infrared Spectral ◽  
Atr Spectroscopy ◽  
Spectral Ranges

Attenuated total reflection (ATR) spectroscopy is widely used in the visible and infrared spectral ranges. Progress in the development of laboratory scale monochromatic sources of terahertz radiation, such as quantum cascade lasers, suggests that in the near future this kind of spectrometers will be widely spread in the terahertz range. For this reason, the development of ATR based methods and devices is highly relevant. In this paper, we discuss the features of the use of ATR spectroscopy in the terahertz range, and describe some of the optical systems, designed for experiments at the Novosibirsk free electron laser (NovoFEL). We show that in the terahertz range the ATR spectroscopy has a number of significant advantages over the absorption spectroscopy. As an example, we are discussing the possibility of using terahertz polarimetry to develop a method for early diagnosis of cancer via the detection of left-handed to right-handed polysaccharide enantiomers ratio. Spectra of selected polysaccharides were recorded with a standard Fourier spectrometer using developed by us an ATR unit. The possibility of studying the polarization characteristics of polysaccharides in aqueous solutions using spectrally selective polarimeter with the NovoFEL as a tunable radiation source was demonstrated.

scholarly journals Simultaneous Infrared Spectroscopy, Raman Spectroscopy and Luminescence Sensing: A Multi-Spectroscopic Analyti-cal Platform

2021 ◽  
Author(s):  
Sarah Klingler ◽  
Julian Hniopek ◽  
Robert Stach ◽  
Michael Schmitt ◽  
Jürgen Popp ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Environmental Chemistry ◽  
Attenuated Total Reflection ◽  
Liquid Volume ◽  
On Line ◽  
Atr Spectroscopy ◽  
Gas Tight ◽  
Scientific Questions ◽  
Minute Sample

Scientific questions in fields such as catalysis, monitoring of biological processes or environmental chemistry demand for analytical technologies combining orthogonal spectroscopies. Combined spectroscopic concepts facilitate in-situ on-line monitoring of dynamic processes providing for a better understanding of the involved reaction pathways. In the present study, a low-liquid-volume multi-spectroscopic platform was developed based on infrared attenuated total reflection (IR-ATR) spectroscopy combined with Raman spectroscopy and lumines-cence sensing. For demonstrating the measurement capabilities, exemplary analyte systems including water / heavy water and aqueous solutions of ammonium sulfate were analyzed as proof-of-principle studies. It was successfully demonstrated that three optical techniques may be integrated into a single analytical platform with-out interference providing synchronized and complementary datasets by probing the same minute sample vol-ume. In addition, the developed assembly provides a gas-tight lid sealing the headspace above the probed liq-uid for monitoring the concentration of molecular oxygen also in the gas phase via luminescence quenching. Hence, the entire assembly may be operated at inert conditions, as required for example during the analysis of photocatalytic processes.

Innovative Substrate-Integrated Hollow Waveguide Coupled Attenuated Total Reflection Sensors for Quantum Cascade Laser Based Infrared Spectroscopy in Harsh Environments

2021 ◽  
pp. 000370282110643
Author(s):  
Andrea Teuber ◽  
Robert Stach ◽  
Julian Haas ◽  
Boris Mizaikoff
Keyword(s):  
Quantum Cascade Lasers ◽  
Evanescent Field ◽  
Total Reflection ◽  
Attenuated Total Reflection ◽  
Ir Radiation ◽  
Metal Structures ◽  
Quantum Cascade ◽  
Hollow Waveguides ◽  
Optical Alignment ◽  
Atr Spectroscopy

An innovative mid-infrared spectroscopic sensor system based on quantum cascade lasers has been developed. The system combines the versatility of substrate-integrated hollow waveguides (IHWGs) with the robustness of attenuated total reflection (ATR) crystals employed as internal reflection waveguides for evanescent field sensing. IHWGs are highly reflective metal structures that propagate infrared (IR) radiation and were used as light pipes for coupling radiation into the ATR waveguide. The combined IHWG-ATR device has been designed such that the utmost stability and robustness of the optical alignment were ensured. This novel assembly enables evanescent field absorption measurements at yet unprecedently harsh conditions, that is, high pressure and temperature. Combining these advantages, this innovative sensor assembly is perfectly suited for taking ATR spectroscopy into the field where the robustness of the assembly and optical alignment is essential.

Dynamics and Stability of Partial Immersion Milling Operations

1999 ◽  
Author(s):  
M. X. Zhao ◽  
B. Balachandran ◽  
M. A. Davies ◽  
J. R. Pratt
Keyword(s):  
Hopf Bifurcation ◽  
Time Variation ◽  
Periodic Motion ◽  
Contact Time ◽  
Period Doubling ◽  
Experimental Investigations ◽  
Partial Immersion ◽  
Milling Operations ◽  
Wide Range ◽  
The Stability

Abstract In this paper, numerical and experimental investigations conducted into the dynamics and stability of partial immersion milling operations are presented. A mechanics based model is used for simulations of a wide range of milling operations and instabilities that arise due to regeneration and/or impact effects are studied. Poincaré sections are used to assess the stability of motions. The studies reveal that apart from Hopf bifurcation of a periodic motion, a period-doubling bifurcation of a periodic motion may also lead to chatter in partial immersion milling operations. Issues such as tooth contact time variation and structure of stability charts are also discussed.

Experimental Investigations of Lean Stability Limits of a Prototype Syngas Burner for Low Calorific Value Gases

2011 ◽  
Author(s):  
Ivan R. Sigfrid ◽  
Ronald Whiddon ◽  
Marcus Alde´n ◽  
Jens Klingmann
Keyword(s):  
Equivalence Ratio ◽  
Coal Gasification ◽  
Stability Limit ◽  
Calorific Value ◽  
Kinetic Mechanism ◽  
Experimental Investigations ◽  
Stirred Reactor ◽  
Wobbe Index ◽  
The Stability ◽  
Experimental Values

The lean stability limit of a prototype syngas burner is investigated. The burner is a three sector system, consisting of a separate igniter, stabilizer and Main burner. The ignition sector, Rich-Pilot-Lean (RPL), can be operated with both rich or lean equivalence values, and serves to ignite the Pilot sector which stabilizes the Main combustion sector. The RPL and Main sectors are fully premixed, while the Pilot sector is partially premixed. The complexity of this burner design, especially the ability to vary equivalence ratios in all three sectors, allows for the burner to be adapted to various gases and achieve optimal combustion. The gases examined are methane and a high H2 model syngas (10% CH4, 22.5% CO, 67.5% H2). Both gases are combusted at their original compositions and the syngas was also diluted with N2 to a low calorific value fuel with a Wobbe index of 15 MJ/m3. The syngas is a typical product of gasification of biomass or coal. Gasification of biomass can be considered to be CO2 neutral. The lean stability limit is localized by lowering the equivalence ratio from stable combustion until the limit is reached. To get a comparable blowout definition the CO emissions is measured using a non-dispersive infrared sensor analyzer. The stability limit is defined when the measured CO emissions exceed 200 ppm. The stability limit is measured for the 3 gas mixtures at atmospheric pressure. The RPL equivalence ratio is varied to investigate how this affected the lean blowout limit. A small decrease in stability limit can be observed when increasing the RPL equivalence ratio. The experimental values are compared with values from a perfectly stirred reactor modeled (PSR), under burner conditions, using the GRI 3.0 kinetic mechanism for methane and the San Diego mechanism for the syngas fuels.

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