scholarly journals Glucose Addition Enhanced the Advanced Treatment of Coking Wastewater

Water ◽  
2021 ◽  
Vol 13 (23) ◽  
pp. 3365
Author(s):  
Na Li ◽  
Yu Xia ◽  
Xuwen He ◽  
Weijia Li ◽  
Lianhua Yuan ◽  
...  
Keyword(s):  
High Throughput Sequencing ◽  
Oxygen Demand ◽  
Advanced Treatment ◽  
Secondary Effluent ◽  
Coking Wastewater ◽  
Glucose Addition ◽  
Refractory Organic Matter ◽  
Recalcitrant Compounds ◽  
Polycyclic Aromatic ◽  
Removal Efficiencies

Biological processes have high removal efficiencies and low operational costs, but the secondary effluent of coking wastewater (CWW), even at a low concentration, is difficult for microorganisms to degrade directly. In this study, glucose was used as a carbon source and co-metabolic substrate for microbial acclimation in order to enhance the advanced treatment of coking wastewater (CWW). The removal performance of the pollutants, especially recalcitrant compounds, was studied and the changes in the microbial community structure after activated sludge acclimation were analyzed. The effect of glucose addition on the secondary biochemical effluent of coking wastewater (SBECW) treatment by the acclimated sludge was further studied by a comparison between the performance of two parallel reactors seeded with the acclimated sludge. Our results showed that the concentrations of chemical oxygen demand (COD), total organic carbon (TOC), and UV absorption at 254 nm (UV254) of the wastewater decreased in the acclimation process. Refractory organic matter, such as polycyclic aromatic hydrocarbons and nitrogen-containing heterocyclics, in the SBECW was effectively degraded by the acclimated sludge. High-throughput sequencing revealed that microbes with a strong ability to degrade recalcitrant compounds were enriched after acclimation, such as Thauera (8.91%), Pseudomonas (3.35%), and Blastocatella (10.76%). Seeded with the acclimated sludge, the reactor with the glucose addition showed higher COD removal efficiencies than the control system without glucose addition (p < 0.05). Collectively, glucose addition enhanced the advanced treatment of coking wastewater (CWW).

Advanced Treatment of Coking Wastewater by Oxidation Process Using Pyrite and Hydrogen Peroxide

2013 ◽  
Vol 726-731 ◽  
pp. 2521-2525
Author(s):  
Zhi Yong Zhang ◽  
De Li Wu
Keyword(s):  
Hydrogen Peroxide ◽  
Oxidation Process ◽  
Low Cost ◽  
Oxygen Demand ◽  
Utilization Efficiency ◽  
Advanced Treatment ◽  
Coking Wastewater ◽  
Second Stage ◽  
Potential Alternative ◽  
High Utilization

Coking wastewater is a kind of recalcitrant wastewater including complicate compositions. Advanced treatment of coking wastewater by Fenton-Like reaction using pyrite as catalyst was investigated in this paper. The results show that the chemical oxygen demand (COD) of coking wastewater decreased significantly by method of coagulation combined with two-stage oxidation reaction. COD of wastewater can decrease from 250mg/l to 45mg/l after treatment, when 2g/L pyrite was used in each stage oxidation and the dosage of hydrogen peroxide (H2O2) is 0.2ml/l for first stage treatment, 0.1ml/l for second stage treatment respectively. The pyrite is effective to promote Fenton-Like reaction with low cost due to high utilization efficiency of H2O2, moreover, catalyst could be easily recovered and reused. The Fenton-Like reaction might be used as a potential alternative to advanced treatment of recalcitrant wastewater.

Advanced Treatment of Coking Wastewater by Sequencing Batch MBR-RO

2013 ◽  
Vol 838-841 ◽  
pp. 2791-2796
Author(s):  
Jiao Wang
Keyword(s):  
Advanced Treatment ◽  
Coking Wastewater ◽  
Removal Efficiencies

A sequencing batch MBR-RO system has been developed to treat coking wastewater, focusing attention on the COD and TN removal efficiencies. Operational results over 60 days showed that the sequencing batch MBR-RO system had a great impact on removals of COD and TN. the removal efficiencies of COD and TN were 93% and 96% respectively. Final concentrations in the effluent of 0.24 mg phenols/L, 0.02 mg cyanides /L, 28.7 mg COD/L and 4.53 mg TN/L were obtained. In addition, the flux of MBR and RO lost 65.3% and 73.2% respectively.

scholarly journals Advanced nitrogen removal from municipal wastewater treatment plant secondary effluent using a deep bed denitrification filter

2018 ◽  
Vol 77 (11) ◽  
pp. 2723-2732 ◽  
Author(s):  
Xiaowei Zheng ◽  
Shenyao Zhang ◽  
Jibiao Zhang ◽  
Deying Huang ◽  
Zheng Zheng
Keyword(s):  
Wastewater Treatment ◽  
Quartz Sand ◽  
High Throughput Sequencing ◽  
Municipal Wastewater ◽  
Nitrate Nitrogen ◽  
Treatment Plant ◽  
Oxygen Demand ◽  
Secondary Effluent ◽  
Municipal Wastewater Treatment ◽  
Microbial Distribution

Abstract With the improvement of wastewater discharge standards, wastewater treatment plants (WWTPs) are continually undergoing technological improvements to meet the evolving standards. In this study, a quartz sand deep bed denitrification filter (DBDF) was used to purify WWTP secondary effluent, utilizing high nitrate nitrogen concentrations and a low C/N ratio. Results show that more than 90% of nitrate nitrogen (NO3-N) and 75% of chemical oxygen demand (COD) could be removed by the 20th day of filtration. When the filter layer depth was set to 1,600 mm and the additional carbon source CH3OH was maintained at 30 mg L−1 COD (20 mg L−1 methanol), the total nitrogen (TN) and COD concentrations of DBDF effluent were stabilized below 5 and 30 mg L−1, respectively. Analysis of fluorescence revealed that DBDF had a stronger effect on the removal of dissolved organic matter (DOM), especially of aromatic protein-like substances. High throughput sequencing and qPCR results indicate a distinctly stratified microbial distribution for the main functional species in DBDF, with quartz sand providing a good environment for microbes. The phyla Proteobacteria, Bacteroidetes, and Chloroflexi were found to be the dominant species in DBDF.

scholarly journals Removal of PAHs from leachate using a combination of chemical precipitation and Fenton and ozone oxidation

2018 ◽  
Vol 78 (5) ◽  
pp. 1064-1070 ◽  
Author(s):  
H. Ates ◽  
M. E. Argun
Keyword(s):  
Statistical Significance ◽  
Oxygen Demand ◽  
Chemical Precipitation ◽  
Operating Conditions ◽  
Program Optimization ◽  
Ozone Oxidation ◽  
Treatment Processes ◽  
Micropollutant Removal ◽  
Polycyclic Aromatic ◽  
Removal Efficiencies

Abstract In this study, six emerging pollutants, belonging to the polycyclic aromatic hydrocarbons (PAHs) group, found in landfill leachate were investigated for their removal by sequential treatment processes including chemical precipitation (CP), Fenton oxidation (FO) and ozone oxidation (OO). Each treatment process was run under different conditions using an experimental design program. Optimization of both CP and FO processes was designed based on the measured values of the residual chemical oxygen demand (COD) of the samples analyzed. The analysis of variance test was applied to the obtained results for determination of statistical significance of the model. Removal efficiencies of micropollutants were determined in the optimal conditions both for CP and FO processes. Samples obtained after these processes were treated with different pH and ozonation times for observing the performances of ozonation on micropollutant removal under different operating conditions. In this study, the removal of acenaphthylene, acenaphthene, fluorene, phenanthrene, fluoranthene and pyrene micropollutants was investigated. The values obtained for PAHs in leachate were determined to be above 10 ppb. In the CP process, the removal efficiencies for PAHs were ranged between 6% and 40% except for pyrene. Removal efficiencies of all micropollutants with FO were over 70% except for fluorene (55%). The removal efficiencies of the investigated micropollutants were 80–100% as a result of consecutive treatment processes including CP, FO and OO respectively.

Advanced electro-Fenton degradation of biologically-treated coking wastewater using anthraquinone cathode and Fe-Y catalyst

2011 ◽  
Vol 64 (1) ◽  
pp. 63-69 ◽  
Author(s):  
Haitao Li ◽  
Yuping Li ◽  
Hongbin Cao ◽  
Xingang Li ◽  
Yi Zhang
Keyword(s):  
Biological Process ◽  
Zeolite Y ◽  
Engineering Application ◽  
Oxygen Demand ◽  
Advanced Treatment ◽  
Coking Wastewater ◽  
Neutral Solution ◽  
Great Role ◽  
Cathodic Potential ◽  
H2o2 Decomposition

The electrocatalytic activity of bare and 2-ethyl anthraquinone-modified graphite felt (2-EAQ/GF) toward oxygen reduction was investigated using a cyclic voltammetry technique in a neutral solution. The prepared cathodes were tested for electrogeneration of H2O2 and electro-Fenton oxidation (EFO) treatment of neutral coking wastewater (CW) after biological process, using a graphite anode and Fe-zeolite Y catalyst. The results showed that (i) H2O2 yield and current efficiency greatly depended on cathodic potential and materials; (ii) hydroxyl radicals, generated from Fe-zeolite Y-catalyzed H2O2 decomposition, played a great role in EFO treatment, while anodic direct and indirect oxidation was insignificant; (iii) chemical oxygen demand, total organic carbon (TOC) and acute toxicity of wastewater decreased by 40–50, 30–40 and 50–60%, respectively, and biodegradability increased after 1 h of EFO treatment. Due to the free-pH adjustment, EFO presents a potential engineering application for advanced treatment of CW.

scholarly journals Advanced treatment of petrochemical secondary effluent by Fenton: performance and organics removal characteristics

2017 ◽  
Vol 75 (6) ◽  
pp. 1431-1439 ◽  
Author(s):  
Min Xu ◽  
Changyong Wu ◽  
Yuexi Zhou
Keyword(s):  
Oxygen Demand ◽  
Cod Removal ◽  
Advanced Treatment ◽  
Secondary Effluent ◽  
Fenton Process ◽  
Direct Oxidation ◽  
Initial Ph ◽  
And Migration ◽  
Chemical Sludge

The Fenton process was used to treat petrochemical secondary effluent. The effects of initial pH, H2O2, and FeSO4·7H2O dosages on chemical oxygen demand (COD) removal, the dissolved organic matter (DOM) removal and the transformation and migration of typical organic matters during the treatment process were investigated. The results showed that the optimum conditions were initial pH of 3.0, H2O2 (30%) dosage of 0.4 mL/L, and FeSO4·7H2O dosage of 1.0 g/L. The highest COD removal efficiency of 61.9% could be achieved for this condition when the average influent COD was 78.5 mg/L. Most of the DOM in the petrochemical wastewater could be removed effectively by Fenton through direct oxidation and coagulation. For example, for trans-1,2-dichlorocyclopentane, results showed that 56.3% of it could be removed by Fenton oxidation, while 13.3% of it could be absorbed by the in situ generated Fenton chemical sludge. The Fenton process is simple and it is suitable for the advanced treatment of petrochemical secondary effluent.

scholarly journals The Use of Sodium Carbonate—Hydrogen Peroxide (2/3) in the Modified Fenton Reaction to Degradation PAHs in Coke Wastewater

Proceedings ◽  
2019 ◽  
Vol 16 (1) ◽  
pp. 44
Author(s):  
Kozak ◽  
Włodarczyk-Makuła
Keyword(s):  
Hydrogen Peroxide ◽  
Organic Pollutants ◽  
Sodium Carbonate ◽  
Uv Light ◽  
Oxygen Demand ◽  
Organic Matrix ◽  
Coke Wastewater ◽  
Polycyclic Aromatic ◽  
Pahs Concentration ◽  
Modified Fenton

The aim of the research was to determine the effectiveness of removing micro-organic pollutants, including PAHs, using the modified Fenton method. The tested material was pretreated coke wastewater, in which the initial chemical oxygen demand (COD) value and initial polycyclic aromatic hydrocarbons (PAHs) concentration were determined. The samples were then subjected to an oxidation procedure. Before the process, the pH was adjusted to 3.5–3.8. Next, the following doses of sodium carbonate—hydrogen peroxide (2/3): 1.2 g/L, 1.5 g/L and 2 g/L, and a constant dose of iron sulphate were added. The next step was exposing the samples to UV light for 6 min and separating the organic matrix from the samples of wastewater. After the tests, the final value of the COD and the final PAHs concentration were determined. The average content of organic pollutants in pretreated coke wastewater determined by the COD index was 538 mg/L, and after the oxidation process, the COD index decreased in the range from 9 to 29%. The efficiency of the degradation of the sum of 16 PAHs was varied and was in the range of 94–97.6%. The research results show that sodium carbonate—hydrogen peroxide (2/3) can be used for the degradation of organic pollutants, such as PAHs, in the modified Fenton process.

Treatment of Palm Oil Mill Effluent (POME) Supernatants Using Aerobic Attached–Growth System: Trickling Filter as a Case Study

2012 ◽  
Author(s):  
Ahmad Zuhairi Abdullah ◽  
Mohamad Hakimi Ibrahim ◽  
Mohd. Omar Ab. Kadir
Keyword(s):  
Palm Oil ◽  
Colloidal Particles ◽  
Oxygen Demand ◽  
Cod Removal ◽  
Palm Oil Mill Effluent ◽  
Trickling Filter ◽  
Biomass Hydrolysis ◽  
Removal Efficiencies ◽  
Palm Oil Mill ◽  
Hydrolysis Of

Kertas kerja ini membincangkan tentang kecekapan penuras cucur dalam merawat supernatan kumbahan kilang kelapa sawit (POME). Supernatan POME diperoleh menerusi dua jenis perawatan. Dalam perawatan 1, pengendapan graviti digunakan untuk menyingkir pepejal boleh mendak. Perawatan 2 digunakan untuk menyingkir pepejal boleh mendak dan gumpalan partikal dengan menggunakan 350 ppm alum. Influen dialurkan secara titisan pada biojisim yang terlekat pada penyokong pepejal rawak PVC setinggi 1 m. Penuras cucur berupaya menyingkir lebih daripada 90.0% dari keperluan oksigen biologi (BOD) dan keperluan oksigen kimia (COD) di bawah 1 m3/m2–hari. Pada 2.53 m3/m2–hari, influen dengan Perawatan 1 menghasilkan kecekapan penyingkiran COD sebanyak 40.3%, berbanding 83.1% bila Perawatan 2 digunakan. Perkara ini berlaku berikutan penyingkiran bahan organik tak boleh resap semasa Perawatan 2. Kecekapan penyingkiran menurun dengan meningkatnya bebanan hidraulik kerana wujudnya kelemahan dalam hidrolisis bahan tak boleh resap kepada substratum larut. Dengan edaran semula (α=1), penyingkiran BOD dan COD yang lebih tinggi dicapai di bawah 7 m3/m2–hari. Pencapaian ini disebabkan oleh bebanan organik yang lebih rendah serta pergedaran semula enzim dan biojisim yang aktif kepada sistem. Perawatan 2 menghasilkan enap cemar yang lebih tinggi kerana penukaran substratum boleh larut kepada biojisim tak boleh larut. Hidrolisis bahan organik tak boleh resap didapati berlaku secara aktif pada bahagian atas penuras cucur sementara bahagian bawahnya cenderung mengoksidakan substratum organik. Kata kunci: POME, turas cucur, bahan organik bolehresap, penggumpalan, alir semula This paper discusses the efficiency of a trickling filter to treat Palm Oil Mill Effluent (POME) supernatants. POME supernatants were obtained via two treatments. In Treatment 1, gravity sedimentation was used to remove settleable solids. In Treatment 2, both settleable solids and colloidal particles were removed using 350 ppm of alum. The influents were allowed to trickle over biomass attached to 1 m high random PVC solid support. Below 1 m3/m2–day, the filter demonstrated Biological Oxygen Demand (BOD) and Chemical Oxygen Demand (COD) removal efficiencies of more than 90.0%. At 2.53 m3/m2–day, the influent with Treatment 1 gave a COD removal efficiency of 40.3%, but increased to 83.1% when the influent with Treatment 2 was used. This was ascribed to the removal of non–diffusible organics during Treatment 2. The removal efficiencies decreased with an increase in hydraulic loading due to limitations in the hydrolysis of non–diffusibles into soluble substrates. With recirculation (α=1), higher BOD and COD removals were achieved below 7.0 m3/m2–day, attributed to lower organic loading and the recycling of active enzyme and biomass to the system. The influent with Treatment 2 demonstrated higher sludge production due to higher conversion of soluble substrates into insoluble biomass. Hydrolysis of non–diffusible organics mainly took place at upper reaches of the filter column while lower reaches were involved in oxidizing the organic subtrates. Key words: POME, trickling filter, diffusible organic, coagulation, recirculation

Sign in / Sign up

Export Citation Format

Share Document