Integrated technology for conditioning low-mineralized cold ground water

Author(s):  
А.В. Селюков

Сообщается о новой комплексной технологии кондиционирования холодных маломинерализованных подземных вод. Технология разрабатывалась для целей хозяйственно-питьевого водоснабжения нефтегазоносных районов Тюменского Севера. При благополучном соотношении ресурсов пресной воды и фактического объема водопотребления в этом регионе России вопрос питьевого водоснабжения из подземных горизонтов остается острым из-за проблемного качества воды и низкой эффективности очистных сооружений. Технология предназначена для очистки от железа, марганца, сероводорода и обеспечивает стабилизационную обработку воды. Основные работы, включавшие лабораторные исследования и пилотные испытания, выполнены в период 2001–2020 годов. На основе разработанных технологических решений построены и успешно эксплуатируются водопроводные очистные сооружения в городах Ноябрьске (75 тыс. м3/сут, 2006 г.) и Новом Уренгое (65 тыс. м3/сут, 2007 г.). Дополнительные испытания технологии, проведенные в Ханты-Мансийске и Комсомольске-на-Амуре, подтвердили ее эффективность. Технология предусматривает применение в качестве основных реагентов пероксида водорода и перманганата калия для окисления примесей воды, а также щелочного реагента для корректировки рН и стабилизационной обработки. Для обеспечения требований стандарта ВОЗ по содержанию железа и марганца дополнительно может использоваться флокулянт. Обобщены данные по составу подземных вод, использованных для испытаний, и на их основе определена рекомендуемая область применения разработанной технологии. Приведена принципиальная технологическая схема кондиционирования холодных маломинерализованных подземных вод, учитывающая 15-летний опыт эксплуатации построенных станций, а также современные решения по дозированию и смешению реагентов. Указано, что данная технология обеспечивает также частичное снижение содержания кремния в очищенной воде (до 30%). Разработанная технология позволяет получать стабильную питьевую воду при нормативном остаточном содержании железа, марганца и сероводорода. An advanced integrated technology for conditioning low-mineralized cold groundwater is presented. The technology was developed for the purpose of supplying drinking water to the oil and gas-bearing regions of the Tyumen North. With a favorable ratio of fresh water resources and the actual volume of water consumption in this region of Russia, the issue of drinking water supply from underground aquifers remains acute due to the problematic water quality and low efficiency of the treatment facilities. The technology is intended for removing iron, manganese, hydrogen sulfide and providing for the stabilization treatment of water. The main work including laboratory studies and pilot tests was carried out in the period 2001–2020. On the basis of the developed process solutions, water treatment facilities have been built and successfully operated in the cities of Noyabrsk (75 thousand m3/day, 2006) and Novy Urengoy (65 thousand m3/day, 2007). Additional tests of the technology carried out in Khanty-Mansiisk and Komsomolsk-on-Amur confirmed its effectiveness. The technology involves using hydrogen peroxide and potassium permanganate as the basic chemicals for the oxidation of water pollutants, as well as using an alkaline chemical for pH adjustment and stabilization treatment. To meet the requirements of the WHO standard for the concentrations of iron and manganese, an additional flocculant can be used. The data on the composition of groundwater used for testing are summarized, and on their basis the recommended area of ​​application of the developed technology is determined. The basic process flow scheme of conditioning low-mineralized cold groundwater in view of 15 years of experience in operating the existing facilities, and of advanced solutions for dosing and mixing of chemicals, is presented. It is indicated that the technology also provides for a partial reduction in the silicon concentration in purified water (up to 30%). The developed technology ensures stable drinking water with a standard residual concentration of iron, manganese and hydrogen sulfide.

Author(s):  
R.F. Mambetov ◽  
◽  
V.M. Kushnarenko ◽  
E.V. Ganin ◽  
◽  
...  
Keyword(s):  

2015 ◽  
Author(s):  
P.E.. E. Dan Mueller

Abstract The recycling and reuse of produced water (defined as hydraulic fracturing flowback water and formation water) is an increasing practice driven by competing demands for water sources and limited options for produced water disposal. The final disposition of reused/recycled produced water dictates the level of treatment with typically minimal treatment required when produce water is reused for fracturing subsequent wells and higher levels of treatment required when produced water is recycled for other purposes or potentially discharged to surface water bodies. The latter scenario, discharge of treated produced water is specifically addressed. Clean Water Act National Pollutant Discharge Elimination System (NPDES) permits for direct discharge of oil and gas generated discharge are currently prohibited east of the 98th meridian. West of the 98th meridian, direct discharge of treated oil and gas wastewater is allowed under specific conditions. Regardless of location (east or west of the 98th meridian), centralized wastewater treatment facilities (CWTs) can be permitted to treat and discharge oil and gas wastewater or CWT discharge may be accepted for further treatment and ultimate discharge at publically owned wastewater treatment facilities (POTWs). The EPA is currently developing effluent limitation guidelines (ELGs) for pretreatment of oil and gas wastewater sent to POTWs for treatment and discharge and recently submitted for comment Final 2012 and Preliminary 2014 Effluent Guidelines Program Plans; both addressed in this paper. Discussed are the various treatment technologies currently deployed and permitting issues associated with the treatment facilities. When treating produced water for discharge, constituent levels in the effluent stream and the waste side streams (consisting of a concentration of constituents removed as part of the water treatment processes) must be monitored to ensure proper management.


2018 ◽  
Vol 167 ◽  
pp. 550-557 ◽  
Author(s):  
Elise G. Elliott ◽  
Xiaomei Ma ◽  
Brian P. Leaderer ◽  
Lisa A. McKay ◽  
Courtney J. Pedersen ◽  
...  

2020 ◽  
Vol 2 (1) ◽  
pp. 27
Author(s):  
Amvrosios G. Georgiadis ◽  
Nikolaos D. Charisiou ◽  
Ioannis V. Yentekakis ◽  
Maria A. Goula

The removal of hydrogen sulfide (H2S) from gas streams with varying overall pressure and H2S concentrations is a long-standing challenge faced by the oil and gas industries. The present work focuses on H2S capture using metal–organic frameworks (MOFs), in an effort to shed light on their potential as adsorbents in the field of gas storage and separation. MOFs hold great promise as they make possible the design of structures from organic and inorganic units, but also, they have provided an answer to a long-time challenging issue, i.e., how to design extended structures of materials. Moreover, the functionalization of the MOF’s surface can result in increased H2S uptake. For example, the insertion of 1% of a fluorinated linker in MIL-101(Cr)-4F(1%) allows for enhanced H2S capture. Although noticeable efforts have been made in studying the adsorption capacity of H2S using MOFs, there is a clear need for gaining a deeper understanding in terms of their thermal conductivities and specific heats in order to design more stable adsorption beds, experiencing high exothermicity. Simply put, the exothermic nature of adsorption means that sharp rises in temperature can negatively affect the bed stability in the absence of sufficient heat transfer. The work presented herein provides a detailed discussion by thoroughly combining the existing literature on new developments in MOFs for H2S removal, and tries to provide insight into new areas for further research.


Author(s):  
Н.Д. Айсунгуров ◽  
П.С. Цамаева ◽  
А.А. Эльмурзаев ◽  
С.С. Юсупов

Экономической составляющей нашей страны была и остается топливно-энергетическая промышленность, в частности нефтегазовая отрасль промышленности. Снижение объемов добычи жидких углеводородов из-за истощения огромного количества эксплуатируемых скважин заставляет искать пути решения возникающих проблем. Одним из решений такого рода проблем видится увеличение числа эксплуатации нефтегазовых скважин, которые сталкиваются с проблемами из-за высокого содержания в составе вредных компонентов, в частности сероводорода. Ведущие нефтяные компании имеют свое видение решения этих проблем. Исследования ученых в этой области предлагают свои решения подобного рода вопросов. Одним из таких предложений является разработка технологии утилизации сероводорода путем окисления газов кислородом воздуха на твердых катализаторах. В статье предлагается метод выделения серы из высококонцентрированного сероводородсодержащего газа в кипящем слое катализатора. Авторами проведены испытания предлагаемого метода на опытной установке и даны рекомендации по проведению такого рода исследований. The economic component of our country has been and remains the fuel and energy industry, in particular the oil and gas industry. The decline in liquid hydrocarbon production, due to the depletion of a huge number of exploited wells, makes us look for ways to solve the problems that arise. One of the solutions to this kind of problems seems to be an increase in the number of oil and gas wells that encounter problems due to the high content of harmful components, in particular hydrogen sulfide. Leading oil campaigns have their own vision for solving these problems. Researches of scientists in this area offer their solutions to this kind of issues. One of such proposals is the development of technology for the utilization of hydrogen sulfide by oxidizing gases with atmospheric oxygen on solid catalysts. The article proposes a method for the separation of sulfur from highly concentrated hydrogen sulfide-containing gas in a fluidized bed of catalyst. The authors tested the proposed method in a pilot plant and made recommendations for conducting this kind of research.


Author(s):  
V.N. Melikhov ◽  
N.A. Krylov ◽  
I.V. Shevchenko ◽  
V.L. Shuster

Regarding the South Caspian oil and gas province, it is concluded that the Pliocene productivity prevails in the western part of the province, and that the gas and oil prospects of the eastern land side in the Mesozoic are prioritized. A retrospective analytical review of geological and geophysical data and publications on the Mesozoic of Southwestern Turkmenistan was carried out, which showed the low efficiency of the performed seismic and drilling operations in the exploration and evaluation of very complex Mesozoic objects. A massive resumption of state-of-the-art seismic exploration and appraisal drilling in priority areas and facilities performed by leading Russian companies is proposed. For some areas, a new, increased estimate of the projected gas resources is given. An example of modern high-efficiency additional exploration of the East Cheleken, a small Pliocene gas and oil field, which turned this field into a large one in terms of reserves, is given.


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