scholarly journals Electromagnetic analysis of the lasing thresholds of hybrid plasmon modes of a silver tube nanolaser with active core and active shell

2019 ◽  
Vol 10 ◽  
pp. 294-304 ◽  
Author(s):  
Denys M Natarov ◽  
Trevor M Benson ◽  
Alexander I Nosich
Keyword(s):  
Active Region ◽  
Localized Surface Plasmon ◽  
Visible Range ◽  
Natural Mode ◽  
Geometrical Parameters ◽  
Electromagnetic Modeling ◽  
The Core ◽  
Active Core ◽  
Plasmon Modes ◽  
Threshold Gain

Results from the electromagnetic modeling of the threshold conditions of hybrid plasmon modes of a laser based on a silver nanotube with an active core and covered with an active shell are presented. We study the modes of such a nanolaser that have their emission wavelengths in the visible-light range. Our analysis uses the mathematically grounded approach called the lasing eigenvalue problem (LEP) for the set of the Maxwell equations and the boundary and radiation conditions. As we study the modes exactly at the threshold, there is no need to invoke nonlinear and quantum models of lasing. Instead, we consider a laser as an open plasmonic resonator equipped with an active region. This allows us to assume that at threshold the natural-mode frequency is real-valued, according to the situation where the losses, in the metal and for the radiation, are exactly balanced with the gain in the active region. Then the emission wavelength and the associated threshold gain can be viewed as parts of two-component eigenvalues, each corresponding to a certain mode. In the configuration considered, potentially there are three types of modes that can lase: the hybrid localized surface plasmon (HLSP) modes of the metal tube, the core modes, and the shell modes. The latter two types can be kept off the visible range in thin enough configurations. Keeping this in mind, we focus on the HLSP modes and study how their threshold gain values change with variations in the geometrical parameters of the nanotube, the core, and the shell. It is found that essentially a single-mode laser can be designed on the difference-type HLSP mode of the azimuth order m = 1, shining in the orange or red spectral region. Furthermore, the threshold values of gain for similar HLSP modes of order m = 2 and 3 can be several times lower, with emission in the violet or blue parts of the spectrum.

Cambiarenes: Single-Step Synthesis and Anion Binding of a Clip- Shaped Macrocycle with a Redox-Active Core

2019 ◽  
Author(s):  
Riley J. Petersen ◽  
Brett J. Rozeboom ◽  
Shalisa Oburn ◽  
Nolan Blythe ◽  
Tanner Rathje ◽  
...  
Keyword(s):  
Electron Density ◽  
Single Step ◽  
Anion Binding ◽  
Host Molecule ◽  
Selective Binding ◽  
The Core ◽  
Redox Active ◽  
Active Core ◽  
Guest Binding

<div>We report the synthesis of a novel macrocyclic host molecule that forms in a single step from commercially available starting materials. The core of the macrocycle backbone possesses two quinone rings and, thus, is redox-active. Host-guest binding involving the clip-shaped cavity indicates selective binding of pyridine <i>N</i>-oxides based of the electron density of and steric bulk of the anionic oxygen.</div>

scholarly journals Light-Scattering Simulations from Spherical Bimetallic Core–Shell Nanoparticles

Micromachines ◽  
2021 ◽  
Vol 12 (4) ◽  
pp. 359
Author(s):  
Francesco Ruffino
Keyword(s):  
Optical Properties ◽  
Light Scattering ◽  
Bimetallic Nanoparticles ◽  
Dominant Role ◽  
Scattered Light ◽  
Specific Interaction ◽  
Surface Enhanced Raman Spectroscopy ◽  
Localized Surface Plasmon ◽  
Core Shell ◽  
The Core

Bimetallic nanoparticles show novel electronic, optical, catalytic or photocatalytic properties different from those of monometallic nanoparticles and arising from the combination of the properties related to the presence of two individual metals but also from the synergy between the two metals. In this regard, bimetallic nanoparticles find applications in several technological areas ranging from energy production and storage to sensing. Often, these applications are based on optical properties of the bimetallic nanoparticles, for example, in plasmonic solar cells or in surface-enhanced Raman spectroscopy-based sensors. Hence, in these applications, the specific interaction between the bimetallic nanoparticles and the electromagnetic radiation plays the dominant role: properties as localized surface plasmon resonances and light-scattering efficiency are determined by the structure and shape of the bimetallic nanoparticles. In particular, for example, concerning core-shell bimetallic nanoparticles, the optical properties are strongly affected by the core/shell sizes ratio. On the basis of these considerations, in the present work, the Mie theory is used to analyze the light-scattering properties of bimetallic core–shell spherical nanoparticles (Au/Ag, AuPd, AuPt, CuAg, PdPt). By changing the core and shell sizes, calculations of the intensity of scattered light from these nanoparticles are reported in polar diagrams, and a comparison between the resulting scattering efficiencies is carried out so as to set a general framework useful to design light-scattering-based devices for desired applications.

scholarly journals Pixeled metasurface for multiwavelength detection of vitamin D

Nanophotonics ◽  
2020 ◽  
Vol 9 (12) ◽  
pp. 3921-3930
Author(s):  
Valentina Di Meo ◽  
Alessio Crescitelli ◽  
Massimo Moccia ◽  
Annamaria Sandomenico ◽  
Angela M. Cusano ◽  
...  
Keyword(s):  
Vitamin D ◽  
Small Molecules ◽  
Vibrational Excitation ◽  
Localized Surface Plasmon ◽  
Large Field ◽  
Geometrical Parameters ◽  
Single Chip ◽  
Large Area ◽  
Accurate Analysis ◽  
Hydroxyvitamin D

AbstractThe steadily increasing demand for accurate analysis of vitamin D level, via measurement of its best general marker, 25-hydroxyvitamin D (25(OH)D), pushes for the development of novel automated assays capable of working at very low concentrations. Here, we propose a plasmonic biosensor of 25(OH)D3 (calcifediol) based on surface-enhanced infrared absorption spectroscopy, which exploits the resonant coupling between plasmonic nanoantennas and vibrational excitation of small molecules. Specifically, our proposed platform features a large-area (several mm2) metasurface made of gold nanoantennas fabricated on a silicon substrate, comprising different macroregions (“pixels”) of area 500 × 500 µm2. In each pixel, the nanoantenna geometrical parameters are tuned so as to support localized surface plasmon resonances (and hence large field enhancements at the nanoscale) within different regions of the infrared spectrum. As a result, a single chip is capable of performing analysis from the region of functional groups to that of fingerprint. Two different designs are fabricated via electron beam lithography, functionalized with a correlated antibody for the detection of 25(OH)D3, and characterized via Fourier-transform infrared spectroscopy. Our experiments demonstrate the capability to detect a concentration as low as 86 pmol/L, and an amount of immobilized small molecules of 25(OH)D3 monohydrate (molecular weight: 418.65 g/mol) as low as 4.31 amol over an area of 100 × 100 µm2.

Free Vibration Analysis of Symmetric Sandwich Beams

2017 ◽  
Vol 872 ◽  
pp. 399-404
Author(s):  
Zakaria Ibnorachid ◽  
Khalid El Bikri ◽  
Lhoucine Boutahar
Keyword(s):  
Sandwich Beam ◽  
Free Vibration Analysis ◽  
Core Layer ◽  
Equation Of Motion ◽  
Geometrical Parameters ◽  
Symmetric Vibration ◽  
Materials Properties ◽  
The Core ◽  
Validation Of Results ◽  
Good Agreement

The aim of the present work is to study the linear free symmetric vibration of three-layer sandwich beam using the energy method. The zigzag model is used to describe the displacement field. The theoretical model is based on the top and bottom layers behave as Euler-Bernoulli beams while the core layer as a Timoshenko beam. Based on Hamilton’s principle, the governing equation of motion sandwich beam is obtained in order to calculate the linear frequency parameters. Two types of boundary conditions simple supported-simple-supported (SS-SS) and clamped-clamped (C-C) under the influence of materials properties and geometrical parameters are studied. The validation of results is done by comparing with another studies, which available in the literature and found good agreement between the studies.

Vibro-Acoustic Analysis and Topology Optimization of Anti-Tetra Chiral Auxetic Lattices Driven by Different Colored Noises

2020 ◽  
Vol 20 (11) ◽  
pp. 2050113
Author(s):  
A. Hosseinkhani ◽  
D. Younesian ◽  
M. Ranjbar
Keyword(s):  
Boundary Conditions ◽  
Natural Frequencies ◽  
Acoustic Analysis ◽  
Honeycomb Structure ◽  
Geometrical Parameters ◽  
Acoustic Behavior ◽  
The Finite Element Method ◽  
Load Spectrum ◽  
The Core ◽  
Radiated Sound

In this paper, we study vibro-acoustic behavior of auxetic sandwich panels subjected to different excitations and boundary conditions. The core of this panel has the auxetic feature (with negative Poisson’s ratio or NPR) with anti-tetrachiral honeycomb structure. Mechanical behavior of the core is formulated using theoretical relations presented for this kind of auxetic. Using the Finite Element Method, the modal analysis and spectral analysis of the structure are accomplished. Different random colored noises are applied as the system excitation. First, a parametric study is performed; and some interesting results are observed from investigating the effects of geometric parameters, boundary conditions, and noise color on the vibro-acoustic behavior of the structure. These parameters affect the natural frequencies, level of radiated sound, and mass of the structure. An optimization algorithm is applied to the geometrical parameters in order to simultaneously reduce the level of radiated sound and preserve the amount of total mass. By the use of the Genetic Algorithm (GA), we could achieve a remarkable noise attenuation gain. It is shown that the GA choses different optimized parameters for the structure according to the location of the load and frequency content of the load spectrum.

scholarly journals Clinical Applications of Visual Plasmonic Colorimetric Sensing

Sensors ◽  
2020 ◽  
Vol 20 (21) ◽  
pp. 6214
Author(s):  
Elba Mauriz
Keyword(s):  
Point Of Care ◽  
Clinical Diagnostics ◽  
Localized Surface Plasmon ◽  
Visible Range ◽  
Future Perspectives ◽  
Colorimetric Analysis ◽  
Colorimetric Sensing ◽  
Size Dependent ◽  
Clinical Biomarkers ◽  
Naked Eye Detection

Colorimetric analysis has become of great importance in recent years to improve the operationalization of plasmonic-based biosensors. The unique properties of nanomaterials have enabled the development of a variety of plasmonics applications on the basis of the colorimetric sensing provided by metal nanoparticles. In particular, the extinction of localized surface plasmon resonance (LSPR) in the visible range has permitted the exploitation of LSPR colorimetric-based biosensors as powerful tools for clinical diagnostics and drug monitoring. This review summarizes recent progress in the biochemical monitoring of clinical biomarkers by ultrasensitive plasmonic colorimetric strategies according to the distance- or the morphology/size-dependent sensing modes. The potential of colorimetric nanosensors as point of care devices from the perspective of naked-eye detection is comprehensively discussed for a broad range of analytes including pharmaceuticals, proteins, carbohydrates, nucleic acids, bacteria, and viruses such as Severe Acute Respiratory Syndrome Coronavirus 2 (SARS-CoV-2). The practical suitability of plasmonic-based colorimetric assays for the rapid visual readout in biological samples, considering current challenges and future perspectives, is also reviewed.

Temperature-Dependent Vibration of Various Types of Sandwich Beams with Porous FGM Layers

2020 ◽  
pp. 2150016
Author(s):  
Mohsen Rahmani ◽  
Sajjad Dehghanpour
Keyword(s):  
Thermal Stresses ◽  
Equations Of Motion ◽  
Functionally Graded ◽  
Geometrical Parameters ◽  
Type I ◽  
Sandwich Beams ◽  
Temperature Dependent ◽  
The Core ◽  
Graded Layers ◽  
Lagrange Strain

By using a high order sandwich beams theory which is modified by considering the transverse flexibility of the core, free vibration characteristics of two models of sandwich beams are studied in this paper. In type-I, functionally graded layers coat a homogeneous core, and in type-II, an FG core is covered by homogeneous face sheets. To increase the accuracy of the model of the FGM properties, even and uneven porosity distributions are applied, and all materials are considered temperature-dependent. Nonlinear Lagrange strain and thermal stresses of the face sheets and in-plane strain of the core are considered. To obtain the governing equations of motion, Hamilton’s principle is used and a Galerkin method is used to solve them for simply supported and clamped boundary conditions. To verify the results of this study, they are compared with the results of literatures. Also, the effect of variation of temperature, some geometrical parameters and porosities on the frequency are studied.

scholarly journals Ultrabroadband Absorption Enhancement via Hybridization of Localized and Propagating Surface Plasmons

Nanomaterials ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1625
Author(s):  
Tian Sang ◽  
Honglong Qi ◽  
Xun Wang ◽  
Xin Yin ◽  
Guoqing Li ◽  
...  
Keyword(s):  
Surface Plasmon ◽  
Near Infrared ◽  
Low Cost ◽  
Polarized Light ◽  
Wavelength Region ◽  
Transverse Magnetic ◽  
Localized Surface Plasmon ◽  
Absorption Enhancement ◽  
Geometrical Parameters ◽  
Light Illumination

Broadband metamaterial absorbers (MAs) are critical for applications of photonic and optoelectronic devices. Despite long-standing efforts on broadband MAs, it has been challenging to achieve ultrabroadband absorption with high absorptivity and omnidirectional characteristics within a comparatively simple and low-cost architecture. Here we design, fabricate, and characterize a novel compact Cr-based MA to achieve ultrabroadband absorption in the visible to near-infrared wavelength region. The Cr-based MA consists of Cr nanorods and Cr substrate sandwiched by three pairs of SiO2/Cr stacks. Both simulated and experimental results show that an average absorption over 93.7% can be achieved in the range of 400–1000 nm. Specifically, the ultrabroadband features result from the co-excitations of localized surface plasmon (LSP) and propagating surface plasmon (PSP) and their synergistic absorption effects, where absorption in the shorter and longer wavelengths are mainly contributed bythe LSP and PSP modes, respectively. The Cr-based MA is very robust to variations of the geometrical parameters, and angle-and polarization-insensitive absorption can be operated well over a large range of anglesunder both transverse magnetic(TM)- and transverse electric (TE)-polarized light illumination.

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