Structural Transparency: New Materials for New Applications

Author(s):  
Christian Eckhardt ◽  
Jochen Stahl
Materials ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4132 ◽  
Author(s):  
Patricia Ponce-Peña ◽  
Martha Poisot ◽  
Alicia Rodríguez-Pulido ◽  
María Azucena González-Lozano

Potassium hexatitanate (PHT) with chemical formula K2Ti6O13 has a tunnel structure formed by TiO2 octahedra sharing edges or corners and with the potassium atoms located in the tunnels. This material has attracted great interest in the areas of photocatalysis, reinforcement of materials, biomaterials, etc. This work summarizes a large number of studies about methods to prepare PHT since particle size can be modified from millimeter to nanometric scale according to the applied method. Likewise, the synthesis method has influenced the material properties as band-gap and the final mechanical performance of composites when the reinforcement is PHT. The knowing of synthesis, properties and applications of PHT is worthwhile for the design of new materials and for the development of new applications taking advantage of their inherent properties.


1969 ◽  
Vol 42 (1) ◽  
pp. 30-70 ◽  
Author(s):  
Guy J. Crocker

Abstract The last general review of elastomeric adhesion and adhesives appeared in this journal eight years ago. At that time an attempt was made, at least in a limited way, to develop the subject from its scientific beginnings and to present a fairly broad and connected picture. The objective of the present review will be more modest, an up-dating only. Much of what was said in the earlier review remains pertinent and relevant today, and no attempt will be made to restate such material in detail, although summarization of current status will be attempted. On the theoretical side, emphasis will be on those studies which have modified earlier views, disproved some theories or strongly confirmed others, or unified previously disconnected observations. On the technological side, emphasis will be on new applications for adhesives, new adhesive raw materials and techniques and the increased scope they offer, and new materials to be bonded with the problems and challenges they engender. For some time, growth in adhesives has consistently outstripped the general economy, and elastomeric adhesives have more than held their own as compared with other types. Adhesive production in 1965 was estimated at 3.2 billion solid pounds. Probably at least 10% of this could be considered elastomeric, and, if expressed in dollar value, would be a much greater proportion. A recent estimate of growth rate for adhesives and sealants was 10% per year, approximately twice that of the dry rubber industry. There is every reason to believe that this trend will continue in the foreseeable future as the former psychological resistance to “gluing” as opposed to rivets, bolts, nails, and welds fast disappears. Accelerating economic growth has stimulated technical advances, and the reverse, and this is reflected in a burgeoning literature.


2005 ◽  
Vol 895 ◽  
Author(s):  
Erik K Rushton ◽  
Günter Oberdörster ◽  
Jacob Finkelstein

AbstractWith the passage of the National Nanoscale Initiative in 2001 there has been increasing attention and funding given to nanomaterial research. This has led to a number of new materials developed at the nanoscale (< 100 nm) level, which often possess chemical and physical properties distinct from those of their bulk materials. These unique qualities are proving to be quite useful in a number of new applications. For example, biological applications in imaging, treatment, and drug delivery are particularly promising as well as the increasing engineering potential of nanocircuitry and materials science. As the number of applications increases however, so too does the potential for human exposure to nanomaterials through a number of routes: dermal, ingestion, inhalation, and even injection. Interestingly some of the properties of these nanomaterials that make them useful in these emerging technologies are the same properties that can increase their toxic potential. This is leading to an emerging discipline – nanotoxicology, which can be defined as safety evaluation of engineered nanostructures and nanodevices. Nanotoxicology research will not only provide information for risk assessment of nanomaterials based on data for hazard identification, dose response relationships and biokinetics, but will also help to further advance the field of nanoresearch by providing information to alter undesirable nanomaterials properties. Although nanotoxicology is in its infancy, there are some preliminary studies with newly developed materials that provide some insight into potential effects, which when coupled with older studies provides some insight on how these nanomaterials impact the biological system. This presentation summarizes results of studies with nanosized particles with a focus on the respiratory system and skin as portals of entry. The ability of particles to translocate from their site of entry, their ability to elicit biological responses, and their presumed mechanisms of action will be highlighted. This will be an attempt to illustrate how pervasive these materials can be, which may or may not be detrimental. With proper toxicological assessment this potential may be harnessed leading to breakthroughs at the nanotechnology – biology interface.


2017 ◽  
Vol 57 (4) ◽  
Author(s):  
Edgar Alonso Reynoso-Soto ◽  
Sergio Pérez-Sicairos ◽  
Ana Patricia Reyes-Cruzaley ◽  
Christian Leonardo Castro-Riquelme ◽  
Rosa María Félix-Navarro ◽  
...  

Photocatalysis is a method widely used in the degradation of organic pollutants of the environment. The development of new materials is very important to improve the photocatalytic properties and to find new applications for TiO<sub>2</sub> as a photocatalyst. In this article we reported the synthesis of a photocatalyst based on TiO<sub>2</sub> doped with Zn<sup>2+</sup> ions highly efficient in the degradation of nitrobenzene. The results of photocatalytic activity experiments showed that the Zn<sup>2+</sup> doped TiO<sub>2</sub> is more active than un-doped TiO<sub>2</sub> catalyst with an efficiency of 99% for the nitrobenzene degradation at 120 min with an apparent rate constant of 35 × 10<sup>-3</sup> min<sup>-1</sup>.


Author(s):  
Roshan Plamthottam ◽  
Ye Shi ◽  
Erin Askounis ◽  
Yu Qiu ◽  
Zihang Peng ◽  
...  

2009 ◽  
Vol 71-73 ◽  
pp. 519-526 ◽  
Author(s):  
Eric Guibal ◽  
Thierry Vincent ◽  
Jean Roussy

Chitosan is an emblematic example of biopolymer that can be obtained from renewable resources (fungal biomass, crustacean shells…) and that can be used for binding a number of metal ions through different mechanisms (complexation, electrostatic attraction, ion pair formation). Chitosan was used for the sorption of various transition metals, from toxic (Hg(II), Cd(II), U(VI), Mo(VI), V(IV) and V(V) …) to strategic and valuable metals (Pd(II), Pt(IV), Au(III) …). However, the interactions of chitosan with metal ions are not strictly limited to environmental applications. Hence, the binding of metal ions on the biopolymer can be used for designing new materials or new applications. Some examples are reported below.


2019 ◽  
Vol 6 (1) ◽  
pp. 10 ◽  
Author(s):  
Giuliana Vinci ◽  
Mattia Rapa

Scientific research in the nanomaterials field is constantly evolving, making it possible to develop new materials and above all to find new applications. Therefore, nanoparticles (NPs) are suitable for different applications: nanomedicine, drug delivery, sensors, optoelectronics and food control. This review explores the recent trend in food control of using noble metallic nanoparticles as determination tools. Two major uses of NPs in food control have been found: the determination of contaminants and bioactive compounds. Applications were found for the determination of mycotoxins, pesticides, drug residues, allergens, probable carcinogenic compounds, bacteria, amino acids, gluten and antioxidants. The new developed methods are competitive for their use in food control, demonstrated by their validation and application to real samples.


2009 ◽  
Vol 87 (1) ◽  
pp. 8-29 ◽  
Author(s):  
Michael J.D Bosdet ◽  
Warren E Piers

The substitution of isoelectronic B–N units for C–C units in aromatic hydrocarbons produces novel heterocycles with structural similarities to the all-carbon frameworks, but with fundamentally altered electronic properties and chemistry. Since the pioneering work of Dewar some 50 years ago, the relationship between B–N and C–C and the wealth of parent all-carbon aromatics has captured the imagination of organic, inorganic, materials, and computational chemists alike, particularly in recent years. New applications in biological chemistry, new materials, and novel ligands for transition-metal complexes have emerged from these studies. This review is aimed at surveying activity in the area in the past couple of decades. Its organization is based on ring size and type of the all-carbon or heterocyclic subunit that the B–N analog is derived from. Structural aspects pertaining to the retention of aromaticity are emphasized, along with delineation of significant differences in physical properties of the B–N compound as compared to the C–C parent.Key words: boron-nitrogen heterocycles, aromaticity, organic materials, main-group chemistry.


2014 ◽  
Vol 1079-1080 ◽  
pp. 1142-1148
Author(s):  
Tatjana Tambovceva ◽  
Andrejs Tambovcevs

Nano- and new materials technology are strong research and product development targets, and new applications and solutions arise all the time. Nanotechnology will profoundly influence the competitiveness of companies in every industry. Adoption of technology and it competitiveness is a research topic within the nano-technology area. When examining the adoption of technology, there are various stakeholders and contexts to consider. The competitiveness of nano-technology is very important. However, competitiveness is a complex and multidimensional concept, encompassing various aspects that are difficult to measure. The aim of the research is to discuss the competitiveness of nano technology.The main methods applied by the authors are analysis of the scientific and other literature and logical approach.Evaluating competitiveness in nanotechnology industry is a complex process. This paper provides findings about factors of competitiveness and a managerial framework of nano- technology.


2021 ◽  
Vol 18 ◽  
pp. 1149-1163
Author(s):  
Mark J. Schulz ◽  
Sung Yong Kim ◽  
Ashley Kubley ◽  
David Mast ◽  
Vesselin Shanov

Nanotube macroscale materials such as yarns, tapes, and sheets provide combinations of material properties that are unique relative to existing materials. Although nanotube sheet and yarn commercialization is still an emerging activity, these materials may become important in the future Business and Economics of societies. Therefore, this paper surveys current worldwide efforts toward manufacturing and commercialization of nanotube macroscale materials. The survey will help researchers, investors and economists consider how the new materials might be used in new applications and how the materials might spur economic development. Nanotube macroscale materials consist of yarn, tapes, and sheets, and exclude powdered forms of nanotubes used as filler materials. Both Carbon Nanotube (CNT) and Boron Nitride Nanotube (BNNT) materials are considered. It is anticipated that macroscale sheet and yarn with customizable properties will have broad applications. This paper is organized to provide ideas for possible areas of applications of nanotube yarn and sheet, followed by a survey of current commercialization efforts. Manufacturing barriers that must be overcome to push the development of nanotube macroscale materials toward large scale commercialization are also discussed. The paper also provides references for researchers and industry professionals who may want to further develop and put nanotube macroscale materials into their own applications.


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