An Approach to Improving the Morphology and Reliability of n-SiC Ohmic Contacts to SiC Using Second-Metal Contacts

Author(s):  
Matthew H. Ervin ◽  
Kenneth A. Jones ◽  
Un Chul Lee ◽  
Taniya Das ◽  
M.C. Wood
1998 ◽  
Vol 514 ◽  
Author(s):  
S. S. Lau

ABSTRACTIn this talk, we summarize the experimental results obtained on metal-GaN interactions in our laboratory. These interactions include the epitaxial growth of metal thin films on chemically cleaned GaN surfaces, metal silicides for Schottky contacts and metallization schemes for ohmic contacts. We found that many fcc and hcp metals can grow epitaxially on (0001) GaN surfaces at room temperature without in-situ surface cleaning. Metal silicide contacts (such as PtSi) may be more suitable for high temperature applications than elemental contacts, due to the thermal stability of silicides. The intrinsic mechanisms for ohmic behavior for various metal contacts are not well understood at present. More consistent barrier height values measured experimentally can shed light on this issue. Due to the defective nature of the GaN layers, carrier transport across the metal/GaN interface can be due to a number of transport mechanisms, thus making accurate determination of the barrier height difficult. In spite of these difficulties, it seems possible to draw certain general conclusions on the electrical behavior of metal contacts on n-GaN.


2006 ◽  
Vol 527-529 ◽  
pp. 859-862 ◽  
Author(s):  
Matthew H. Ervin ◽  
Kenneth A. Jones ◽  
Un Chul Lee ◽  
Taniya Das ◽  
M.C. Wood

While nickel ohmic contacts to n-type silicon carbide have good electrical properties, the physical contact, and therefore the reliability, can be poor. An approach is described for using the good electrical properties of Ni ohmic contacts while using another metal for its desired mechanical, thermal and/or chemical properties. In the present work, once the Ni contacts have been annealed forming nickel silicides and achieving low contact resistance, they are etched off. Removing the primary Ni contacts also eliminates the poor morphology, voids, and at least some of the excess carbon produced by the Ni/SiC reaction. The Ni contacts are then replaced by a second contact metal. This second metal displays low contact resistance as-deposited, indicating that the critical feature responsible for the ohmic contact has not been removed by the primary contact etch. Not only does this approach provide more flexibility for optimizing the contact for a given application, it also provides some insight into the ohmic contact formation mechanism.


2000 ◽  
Vol 640 ◽  
Author(s):  
Xaiobin Wang ◽  
Stanislav Soloviev ◽  
Ying Gao ◽  
G. Straty ◽  
Tangali Sudarshan ◽  
...  

ABSTRACTOhmic contacts to p-type SiC were fabricated by depositing Al/Ni and Al/Ti followed by high temperature annealing. A p-type layer was fabricated by Al or B diffusion from vapor phase into both p-type and n-type substrates. The thickness of the diffused layer was about 0.1–0.2 μm with surface carrier concentration of about 1.0×1019cm−3. Metal contacts to a p-type substrate with a background doping concentration of 1.2×1018cm−3, without a diffusion layer, were also formed. The values of specific contact resistance obtained by Circular Transmission Line Method (CTLM) and Transfer Length Method (TLM) for the n-type substrate, and by Cox & Strack method for p-type substrate, respectively, varied from 1.3×10−4Ωcm2 to 8.8×10−3 Ωcm2. The results indicate that the specific contact resistance could be significantly reduced by creating a highly doped diffused surface layer.


2009 ◽  
Vol 615-617 ◽  
pp. 581-584 ◽  
Author(s):  
Bharat Krishnan ◽  
Siva Prasad Kotamraju ◽  
Galyna Melnychuk ◽  
Neil Merrett ◽  
Yaroslav Koshka

Low-temperature halo-carbon homoepitaxial growth is suitable for selective epitaxial growth of 4H-SiC using SiO2 mask. A possibility of achieving high values of doping in combination with the selective growth makes it an alternative to ion implantation for selective doping in SiC. In this work, TMA doping in situ during a blanket low-temperature epitaxial growth was utilized to produce heavily Al doped SiC layers for Ohmic contact formation to p-type SiC. Nearly featureless epilayer morphology with Al atomic concentration exceeding 3x1020 cm-3 was obtained after growth at 13000C with the growth rate of 1.5 µm/hr. Ni TLM contacts with a thin adhesion layer of Ti were formed. The as-deposited metal contacts were almost completely Ohmic even before annealing. The specific contact resistance of 2x10-2 Ohm-cm2 and 6x10-5 Ohms-cm2 was achieved without and with contact annealing respectively. The resistivity of the epitaxial layers better than 0.01 Ohm cm was measured for Al atomic concentration of 2.7x1020 cm-3.


2021 ◽  
Vol 5 (1) ◽  
Author(s):  
Qianqian Wang ◽  
Liemao Cao ◽  
Shi-Jun Liang ◽  
Weikang Wu ◽  
Guangzhao Wang ◽  
...  

AbstractMetal contacts to two-dimensional (2D) semiconductors are often plagued by the strong Fermi level pinning (FLP) effect which reduces the tunability of the Schottky barrier height (SBH) and degrades the performance of 2D semiconductor devices. Here, we show that MoSi2N4 and WSi2N4 monolayers—an emerging 2D semiconductor family with exceptional physical properties—exhibit strongly suppressed FLP and wide-range tunable SBH. An exceptionally large SBH slope parameter of S ≈ 0.7 is obtained which outperforms the vast majority of other 2D semiconductors. Such intriguing behavior arises from the septuple-layered morphology of MoSi2N4 and WSi2N4 monolayers in which the semiconducting electronic states are protected by the outlying Si–N sublayer. We identify Ti, Sc, and Ni as highly efficient Ohmic contacts to MoSi2N4 and WSi2N4 with zero interface tunneling barrier. Our findings reveal the potential of MoSi2N4 and WSi2N4 as a practical platform for designing high-performance and energy-efficient 2D semiconductor electronic devices.


1984 ◽  
Vol 37 ◽  
Author(s):  
Pong-Fei Lu ◽  
D. C. Tsui ◽  
H. M. Cox

AbstractWe report two phenomena observed in the electrical transport through metal contacts to In0.53Ga0.47 As thin films. First, a surface accumulation layer of electrons is found at the oxide-In0.53Ga0.47 As interface of Pb-oxide-In0.53Ga0.47 As tunnel junctions, suggesting that the surface Fermi level is not pinned in In0.53Ga0.47 As, and ideal ohmic contacts to n- In0 53Ga0.47 As can be made by using low work function metals. Second, we observed a strong oscillatory conductance on the I-V characteristic of electrical transport through In- In0.53 Ga0.47As contacts, with a period approximating the LO-phonon energy of In0.53Ga0.47As. We explain the data by successive phonon emission in the high field transport of ballistic electrons and point out that the experiment is a solid state analogue of the Franck-Hertz experiment.


1997 ◽  
Vol 482 ◽  
Author(s):  
A. Sampath ◽  
H. M. Ng ◽  
D. Korakakis ◽  
T. D. Moustakas

AbstractIn this paper we report on the formation of ohmic contacts to n- AlxGa1-xN alloys. The films were produced by plasma-assisted MBE and doped n- type with silicon at doping levels between 1018 to 1019 cm-3. Contacts were formed by sequential deposition of 200 Å of Ti and 2000 Å of Al and the contact resistivities were determined from TLM measurements. For low Al- content (x<. 10) the I-V characteristics are linear with contact resistivities of between 10-4 to 10-5 cm2. The contacts become progressively non-ohmic at Al concentrations greater than 10%. There results are consistent with the Schottky limit being applicable to these alloys and thus the Ti/Al contact forms Schottky barriers with higher barrier height as the conduction band of the alloy moves towards the vacuum level.


1995 ◽  
Vol 405 ◽  
Author(s):  
M. A. George ◽  
D. J. Larkin ◽  
J. Petit ◽  
A. Burger ◽  
S. H. Morgan ◽  
...  

AbstractAluminum contacts on chemical vapor deposited (CVD) SiC films were studied to examine variations in the chemical, morphological and electrical properties of the samples. Nitrogen and aluminum doped substrates were prepared to give n-type and p-type SiC epilayers respectively. These preparations were examined by surface sensitive spectroscopies and by atomic force microscopy (AFM). Samples were studied both before and after the deposition of aluminum films to compare differences between SiC(p++)/metal and SiC(n++)/metal contact interfacial properties. Aluminum has generally been found to have good adherence to the n+ epilayer but do not form good ohmic contacts, while metal films deposited on p+ epilayers have had poor adherence but have been found to provide better ohmic character. AFM images revealed nanometer sized clusters, attributed to excess Si on the n+ epilayers, while no clusters were observed on the p+ epilayers. XPS studies of the as-prepared samples indicated that the n+ epilayers had higher concentrations of oxides which may enhance adhesion. The chemical composition and morphology is discussed and correlated to the electrical properties obtained for the various samples.


2013 ◽  
Vol 1553 ◽  
Author(s):  
Y. Pan ◽  
G. K. Reeves ◽  
P. W. Leech ◽  
P. Tanner ◽  
A. S. Holland

ABSTRACTAs ohmic contacts decrease in size and approach nanoscale dimensions, accurate electrical characterization is essential, requiring the development of suitable test structures for this task. We present here a new test structure derived from the standard three-contact circular transmission line model (CTLM) [1], for determining the specific contact resistivity of ohmic contacts. This test structure minimizes sources of error which arise from the CTLM by – (i) reducing the number of contacts within one test pattern from three to two, (ii) ensuring the assumption of equipotential metal contacts used in modelling is more easily attained experimentally, and (iii) allowing the fabrication of reduced geometrical dimensions essential for determining low specific contact resistivity values. The analytical expressions are presented and experiment results are undertaken to demonstrate the accuracy of the technique. There are no error corrections required for determining contact parameters using the presented test structure.


1989 ◽  
Vol 162 ◽  
Author(s):  
Dario Narducci ◽  
Jerome J. Cuomo ◽  
C. Richard Guarnieri ◽  
Stanley J. Whitehair

ABSTRACTPolycrystalline boron-doped diamond thin films were prepared by microwave-enhanced plasma-assisted chemical vapor deposition. Ti, V, Ta, Nb, Al, Mo and W contacts were prepared by physical vapor deposition and their behavior was studied as a function of the annealing temperature, atmosphere and duration. For Ti contacts, short heat treatments (less than 60 minutes) at 500 °C under argon atmosphere were found to make ohmic contacts for applied voltages up to 50 V. Longer annealing times, more reactive atmospheres, and higher temperatures degraded the contact characteristics. In order to obtain a more complete picture of the interface structure, the capacitance-voltage characteristics and the impedance spectra of the systems were measured between 10 K and 1000 K. The interface contribution to the overall dielectric behavior of the system shows much shallower depletion widths in Ti-diamond (ohmic) contacts than with the non-linear Nb and Ta contacts. The higher values of the contact resistance and the shallower depletion width with Ti can be explained in terms of formation of a thin carbide-like region at the metalsemiconductor interface. The space-charge region width as well as the distribution of localized states in the band gap were also determined. The effect of the microstructure on the electrical properties of the systems is discussed in comparison with the behavior of metal-contacts on single-crystal diamonds.


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