Effect of Variety and Morphology of Substrate on the Crystal Form of Calcium Carbonate Crystal

2011 ◽  
Vol 127 ◽  
pp. 168-171
Author(s):  
Wen Jie Ma ◽  
Xue Wu Wang
Keyword(s):  
Calcium Carbonate ◽  
Three Dimensional ◽  
Great Influence ◽  
Gold Surface ◽  
Crystal Form ◽  
Inorganic Materials ◽  
Biomimetic Synthesis ◽  
Polystyrene Spheres ◽  
Self Assembled ◽  
Different Diameters

Based on the basic principles of biomineralization, calcium carbonate (CaCO3) which has specific shapes can be synthesized by the biomimetic synthesis, using three-dimensional (3D) photonic crystals self-assembled by polystyrene spheres as the matrix (Ps film).The effects of variety and morphology of substrate on the crystal form and morphologies of CaCO3 were investigated. It was found that variety of substrates has great influence on the phase of calcium carbonate. On the Ps film, large amount of calcite and aragonite can be observed. SEM of the gold surface shows aragonite needles and vaterite. On the glass surface, large amount of vaterite can be observed. Ps films self-assembled by different diameters of polystyrene spheres have different morphologies and surface roughness, which have deep effects on the crystal form of calcium carbonate.This simple route might open opportunity to synthesis and the study of other novel inorganic materials.

Self-Assembly of Proteins into Three-Dimensional Structures Using Bio-Conjugation

2014 ◽  
Vol 1663 ◽  
Author(s):  
Garima Thakur ◽  
Kovur Prashanthi ◽  
Thomas Thundat
Keyword(s):  
Self Assembly ◽  
Three Dimensional ◽  
Gold Surface ◽  
Building Blocks ◽  
Growth Conditions ◽  
Base Layer ◽  
Chemical Structures ◽  
Molecular Building Blocks ◽  
Ring Structures ◽  
Self Assembled

ABSTRACTSelf–assembly of molecular building blocks provides an interesting route to produce well-defined chemical structures. Tailoring the functionalities on the building blocks and controlling the time of self-assembly could control the properties as well as the structure of the resultant patterns. Spontaneous self-assembly of biomolecules can generate bio-interfaces for myriad of potential applications. Here we report self-assembled patterning of human serum albumin (HSA) protein in to ring structures on a polyethylene glycol (PEG) modified gold surface. The structure of the self-assembled protein molecules and kinetics of structure formation entirely revolved around controlling the nucleation of the base layer. The formation of different sizes of ring patterns is attributed to growth conditions of the PEG islands for bio-conjugation. These assemblies might be beneficial in forming structurally ordered architectures of active proteins such as HSA or other globular proteins.

Biomimetic synthesis of novel calcium carbonate heterogeneous dendrites

2015 ◽  
Vol 39 (7) ◽  
pp. 5309-5315 ◽  
Author(s):  
Li Ma ◽  
Jianhua Zhu ◽  
Mingfang Cui ◽  
Lei Huang ◽  
Yiping Su
Keyword(s):  
Calcium Carbonate ◽  
Three Dimensional ◽  
Biomimetic Synthesis ◽  
Amorphous Coating ◽  
Functional Additives

Three-dimensional dendrites of calcium carbonate were successfully synthesized via a nonclassical crystallization pathway by combining two different functional additives. They showed fascinating heterogeneous superstructures made up of calcite scaffolding, aragonite shells, and an external amorphous coating.

Nanoscale Self-Assembly Using Ion and Electron Beam Techniques: A Rapid Review

MRS Advances ◽  
2020 ◽  
Vol 5 (64) ◽  
pp. 3507-3520
Author(s):  
Chunhui Dai ◽  
Kriti Agarwal ◽  
Jeong-Hyun Cho
Keyword(s):  
Electron Beam ◽  
Self Assembly ◽  
Ion Beam ◽  
Three Dimensional ◽  
The Self ◽  
Stress Generation ◽  
Rapid Review ◽  
High Yield ◽  
3D Nanostructures ◽  
Self Assembled

AbstractNanoscale self-assembly, as a technique to transform two-dimensional (2D) planar patterns into three-dimensional (3D) nanoscale architectures, has achieved tremendous success in the past decade. However, an assembly process at nanoscale is easily affected by small unavoidable variations in sample conditions and reaction environment, resulting in a low yield. Recently, in-situ monitored self-assembly based on ion and electron irradiation has stood out as a promising candidate to overcome this limitation. The usage of ion and electron beam allows stress generation and real-time observation simultaneously, which significantly enhances the controllability of self-assembly. This enables the realization of various complex 3D nanostructures with a high yield. The additional dimension of the self-assembled 3D nanostructures opens the possibility to explore novel properties that cannot be demonstrated in 2D planar patterns. Here, we present a rapid review on the recent achievements and challenges in nanoscale self-assembly using electron and ion beam techniques, followed by a discussion of the novel optical properties achieved in the self-assembled 3D nanostructures.

Advances in coupled axial turbine and nonaxisymmetric exhaust volute aerodynamics for turbomachinery

2020 ◽  
pp. 095441002096645
Author(s):  
Jie Gao ◽  
Chunde Tao ◽  
Dongchen Huo ◽  
Guojie Wang
Keyword(s):  
Performance Improvement ◽  
High Efficiency ◽  
Three Dimensional ◽  
Great Influence ◽  
Aerodynamic Characteristics ◽  
Turbine Engines ◽  
Gas Turbine Engines ◽  
Axial Turbine ◽  
Flow Interactions ◽  
And Performance

Marine, industrial, turboprop and turboshaft gas turbine engines use nonaxisymmetric exhaust volutes for flow diffusion and pressure recovery. These processes result in a three-dimensional complex turbulent flow in the exhaust volute. The flows in the axial turbine and nonaxisymmetric exhaust volute are closely coupled and inherently unsteady, and they have a great influence on the turbine and exhaust aerodynamic characteristics. Therefore, it is very necessary to carry out research on coupled axial turbine and nonaxisymmetric exhaust volute aerodynamics, so as to provide reference for the high-efficiency turbine-volute designs. This paper summarizes and analyzes the recent advances in the field of coupled axial turbine and nonaxisymmetric exhaust volute aerodynamics for turbomachinery. This review covers the following topics that are important for turbine and volute coupled designs: (1) flow and loss characteristics of nonaxisymmetric exhaust volutes, (2) flow interactions between axial turbine and nonaxisymmetric exhaust volute, (3) improvement of turbine and volute performance within spatial limitations and (4) research methods of coupled turbine and exhaust volute aerodynamics. The emphasis is placed on the turbine-volute interactions and performance improvement. We also present our own insights regarding the current research trends and the prospects for future developments.

Experimental investigation on the three-dimensional flow field from a meltblowing slot die

e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 724-732
Author(s):  
Changchun Ji ◽  
Yudong Wang
Keyword(s):  
Flow Field ◽  
Three Dimensional ◽  
Great Influence ◽  
Distribution Characteristics ◽  
Air Velocity ◽  
Three Dimensional Flow ◽  
Dimensional Flow ◽  
Airflow Distribution ◽  
Slot Die ◽  
Center Area

AbstractTo investigate the distribution characteristics of the three-dimensional flow field under the slot die, an online measurement of the airflow velocity was performed using a hot wire anemometer. The experimental results show that the air-slot end faces have a great influence on the airflow distribution in its vicinity. Compared with the air velocity in the center area, the velocity below the slot end face is much lower. The distribution characteristics of the three-dimensional flow field under the slot die would cause the fibers at different positions to bear inconsistent air force. The air velocity of the spinning centerline is higher than that around it, which is more conducive to fiber diameter attenuation. The violent fluctuation of the instantaneous velocity of the airflow could easily cause the meltblowing fiber to whip in the area close to the die.

scholarly journals Superhydrophilic Coating of Pine Wood by Plasma Functionalization of Self-Assembled Polystyrene Spheres

Coatings ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 114
Author(s):  
Sebastian Dahle ◽  
John Meuthen ◽  
René Gustus ◽  
Alexandra Prowald ◽  
Wolfgang Viöl ◽  
...  
Keyword(s):  
Dip Coating ◽  
Face Centered Cubic ◽  
Wood Substrate ◽  
Polystyrene Spheres ◽  
Pine Wood ◽  
Self Assembling ◽  
Monodisperse Polystyrene ◽  
Self Assembled ◽  
Face Centered ◽  
Plasma Functionalization

Self-assembling films typically used for colloidal lithography have been applied to pine wood substrates to change the surface wettability. Therefore, monodisperse polystyrene (PS) spheres have been deposited onto a rough pine wood substrate via dip coating. The resulting PS sphere film resembled a polycrystalline face centered cubic (FCC)-like structure with typical domain sizes of 5–15 single spheres. This self-assembled coating was further functionalized via an O2 plasma. This plasma treatment strongly influenced the particle sizes in the outermost layer, and hydroxyl as well as carbonyl groups were introduced to the PS spheres’ surfaces, thus generating a superhydrophilic behavior.

scholarly journals Engineering Comprehensive Model of Complex Wind Fields for Flight Simulation

Aerospace ◽  
2021 ◽  
Vol 8 (6) ◽  
pp. 145
Author(s):  
Jianwei Chen ◽  
Liangming Wang ◽  
Jian Fu ◽  
Zhiwei Yang
Keyword(s):  
Wind Field ◽  
Three Dimensional ◽  
Great Influence ◽  
Spatial Location ◽  
Flight Simulation ◽  
Comprehensive Model ◽  
Flight Trajectory ◽  
Wind Fields ◽  
Wind Field Simulation ◽  
Low Level Jet

A complex wind field refers to the typical atmospheric disturbance phenomena existing in nature that have a great influence on the flight of aircrafts. Aimed at the issues involving large volume of data, complex computations and a single model in the current wind field simulation approaches for flight environments, based on the essential principles of fluid mechanics, in this paper, wind field models for two kinds of wind shear such as micro-downburst and low-level jet plus three-dimensional atmospheric turbulence are established. The validity of the models is verified by comparing the simulation results from existing wind field models and the measured data. Based on the principle of vector superposition, three wind field models are combined in the ground coordinate system, and a comprehensive model of complex wind fields is established with spatial location as the input and wind velocity as the output. The model is applied to the simulated flight of a rocket projectile, and the change in the rocket projectile’s flight attitude and flight trajectory under different wind fields is analyzed. The results indicate that the comprehensive model established herein can reasonably and efficiently reflect the influence of various complex wind field environments on the flight process of aircrafts, and that the model is simple, extensible, and convenient to use.

scholarly journals Analysis of Turn-to-Turn Fault on Split-Winding Transformer Using Coupled Field-Circuit Approach

Processes ◽  
2021 ◽  
Vol 9 (8) ◽  
pp. 1314
Author(s):  
Cunxiang Yang ◽  
Yiwei Ding ◽  
Hongbo Qiu ◽  
Bin Xiong
Keyword(s):  
Low Voltage ◽  
Short Circuit ◽  
Three Dimensional ◽  
Great Influence ◽  
Normal Operation ◽  
Transient Field ◽  
Axial Forces ◽  
Leakage Field ◽  
Characteristics Analysis ◽  
Split Winding

The turn-to-turn faults (TTF) are also inevitable in split-winding transformers. The distorted leakage field generated by the TTF current results in large axial forces and end thrusts in the fault windings as well as affecting other branch windings normal operation, so it is of significance to study TTF of split-winding transformers. In this paper, the characteristics analysis of the split-winding transformer under the TTFs of the low voltage winding at different positions are presented. A 3600 KVA four split-windings transformer is taken as an example. Then, a simplified three-dimensional simplified model is established, taking into account the forces of the per-turn coil. The nonlinear-transient field-circuit coupled finite element method is used for the model. The leakage field distribution under the TTFs of the low voltage winding at different positions is studied. The resultant force of the short-circuit winding and the force of the per-turn coil are obtained. Subsequently, the force and current relationship between the branch windings are analyzed. The results show that the TTF at the specific location has a great influence on the axial windings on the same core, and the distorted leakage magnetic field will cause excessive axial force and end thrust of the normal and short-circuit windings. These results can provide a basis for the short-circuit design of split-winding transformer.

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