Low-Temperature Synthesis and Characterization of Single-Phase BiFeO3 Nano-Crystallites
2012 ◽
Vol 164
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pp. 115-119
Keyword(s):
X Ray
◽
Single-phase BiFeO3 (BFO) nano-crystallites were successfully synthesized in the temperature range of 500 750 oC by a simple diluted HNO3 sol method. During the crystallization process no intermediate phases were observed. As an example, we studied the electronic structure and thermodynamic stability of the BFO nano-crystallites calcined at 750 oC by X-ray photoelectron spectroscopy (XPS) and differential scanning calorimetry (DSC). The XPS showed that the oxidation state of Fe is Fe3+. The DSC indicated a novel exothermic peak at about 769 oC during cooling, which might be due to Bi2Fe4O9 or some other phases produced in the decomposition of BFO at high temperature.
2003 ◽
Vol 18
(7)
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pp. 1535-1542
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2005 ◽
Vol 23
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pp. 231-234
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1999 ◽
Vol 14
(5)
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pp. 1805-1813
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2008 ◽
Vol 368-372
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pp. 1215-1217