Carbon Dioxide (CO2) Foam Stability Dependence on Nanoparticle Concentration for Enhanced Oil Recovery (EOR)

2014 ◽  
Vol 548-549 ◽  
pp. 1876-1880 ◽  
Author(s):  
T.A.T. Mohd ◽  
A. H. M. Muhayyidin ◽  
Nurul Aimi Ghazali ◽  
M.Z. Shahruddin ◽  
N. Alias ◽  
...  
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Foam Stability ◽  
Foam Height ◽  
Sweep Efficiency ◽  
Low Viscosity ◽  
Reservoir Conditions ◽  
Foam Properties ◽  
Foam Generator ◽  
Foam Flooding

Foam flooding is an established approach in Enhanced Oil Recovery (EOR) to recover a significant quantity of the residual oil left in the reservoir after primary and secondary recovery. However, foam flooding faces various problems due to low viscosity effect, which reduces its efficiency in recovering oil. Using surfactant to stabilize CO2foam may reduce mobility and improve areal and vertical sweep efficiency, but the potential weaknesses are such that high surfactant retention in porous media and unstable foam properties under high temperature reservoir conditions. Nanoparticles have higher adhesion energy to the fluid interface, which potentially stabilize longer lasting foams. Thus, this paper is aimed to investigate the CO2foam stability and mobility characteristics at different concentration of nanosilica, brine and surfactant. Foam generator has been used to generate CO2foam and analyze its stability under varying nanosilica concentration from 100 - 5000 ppm, while brine salinity and surfactant concentration ranging from 0 to 2.0 wt% NaCl and 0 – 10000 ppm, respectively. Foam stability was investigated through observation of the foam bubble size and the reduction of foam height inside the observation tube. The mobility was reduced as the concentration of nanosilica increased with the presence of surfactant. After 150 minutes of observation, the generated foam height reduced by 10%. Liquid with the presence of both silica nanoparticles and surfactant generated more stable foam with lower mobility. It can be concluded that the increase in concentration of nanosilica and addition of surfactant provided significant effects on the foam stability and mobility, which could enhance oil recovery.

Advances in Evaluation of Surfactant Performances at High Temperature by Static Foam Tests

2016 ◽  
Vol 1133 ◽  
pp. 634-638 ◽  
Author(s):  
Mudassar Mumtaz ◽  
Isa Mohd Tan ◽  
Muhammad Mushtaq ◽  
Muhammad Sagir
Keyword(s):  
High Temperature ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Foam Stability ◽  
Foam Height ◽  
Surfactant Molecule ◽  
Sweep Efficiency ◽  
Endurance Time ◽  
Alpha Olefin ◽  
Designed Experiment

—Foam stability and mobility reduction are the key parameters for foam assisted enhanced oil recovery. The harsh conditions such as high temperature, pressure and salinity present in an oil reservoir tend to destabilise the foam leading to poor sweep efficiency. Screening for the best performing foaming recipes has been performed to ascertain foam stability in the presence and absence of oil. Static foam test has been performed in order to study the foam stability and foam oil interactions at 90°C. Two anionic surfactants, alpha olefin sulphonate (AOS14-16) and methyl ester sulphonate (MES16-18) were mixed with betaine (foam booster) in different proportions to design the formulations. In addition to the ternary formulations, binary formulation involving surfactant and betaine were also evaluated for foam stability. For the study of oil effects on foaming performance of surfactant formulation, n-decane, diesel and Dulang crude oil are used. The recipes were evaluated by static foam tests to note the foam height and endurance time. It was found that the anionic surfactant played a major role in foam stability and the betaine was found less significant. However, the betaine alone was found effective for foaming and was poor for endurance time. While in mixture, the surfactant and betaine were found to interact strongly and a profound synergistic effect was noted. During oil interaction studies, the alkane type oils of low molecular weight become solubilised with surfactant molecule forming an emulsion and hence decimate the foam stability. However, higher alkanes with molecular chain more than ten carbon atoms (decane) stabilised the foam because of low solubilisation efficiency between surfactant and oil to form emulsions. The obtained results of the designed experiment have been analysed and discussed in detail to understand the contribution of individual component as well as their interactions with each other in order to stabilize foams.Keywords—Static Foam, Foam-Oil interactions, AOS, MES, Enhanced Oil Recovery

Laboratory Evaluation on Foaming Agent for High-Temperature and High-Salinity Reservoir

2014 ◽  
Vol 884-885 ◽  
pp. 82-86
Author(s):  
Ji Chao Fang ◽  
Cai Li Dai ◽  
Kai Wang ◽  
Qin Fang Ding ◽  
Si Yu Wang
Keyword(s):  
High Temperature ◽  
Oil Recovery ◽  
Foam Stability ◽  
Pressure Rise ◽  
Laboratory Evaluation ◽  
Total Recovery ◽  
Foaming Agent ◽  
Reservoir Conditions ◽  
Foam Flooding ◽  
Enhance Oil Recovery

In order to further enhance oil recovery (EOR) of the high temperature and high salt oil fields by foam flooding, one foaming agent was screened by airflow method. The influence of oil-water and pressure on foamability and stability were evaluated,and oil displacement experiment was also conducted. The results show that CS-1 foaming agent has better foamability and stability than the others under the reservoir conditions (Temperature 110 °C, Salinity 11.52×104 mg/L, Ca2+&Mg2+ 7654 mg/L). The foam stability will be better as the pressure rise or be worse when it met the crude oil. Oil recovery was improved by 4.13% after waterflood and the total recovery is 60.75%.

scholarly journals Nuclear Magnetic Resonance Evaluation Study for Effect of Foam flooding in Heterogeneous Cores

2020 ◽  
Vol 213 ◽  
pp. 01025
Author(s):  
Shuai Hua ◽  
Yuan Li ◽  
Qinfeng Di
Keyword(s):  
Oil Recovery ◽  
Foam Stability ◽  
Dynamic Change ◽  
Water Flooding ◽  
Sweep Efficiency ◽  
Displacement Effect ◽  
Oil Displacement ◽  
Profile Control ◽  
Foam Flooding ◽  
Heterogeneous Cores

Foam flooding demonstrated the ability to solve the viscous fingering problem of gas flooding and increase the sweep efficiency in enhancing oil recovery. It is commonly used in development of heterogeneous reservoirs. While the characteristics of fluid migration in pores and between layers were still unclear. In this paper, Dynamic change of oil and water with different foam quality was tested during foam flooding by NMR method. Oil displacement effect of water flooding and foam flooding was compared. The results showed the foam quality affected the foam stability and profile control effect. Compared with water flooding, the foam could increase the recovery rate of the low-permeability layer, and the foam system with high stability had a high sweep efficiency and a high oil displacement efficiency in the heterogeneous cores.

scholarly journals Properties of Biodegradable Polymer from Terrestrial Mushroom for Potential Enhanced Oil Recovery

2020 ◽  
Vol 20 (6) ◽  
pp. 1382
Author(s):  
Tengku Amran Tengku Mohd ◽  
Shareena Fairuz Abdul Manaf ◽  
Munawirah Abd Naim ◽  
Muhammad Shafiq Mat Shayuti ◽  
Mohd Zaidi Jaafar
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Biodegradable Polymer ◽  
Polymer Concentration ◽  
Polymer Flooding ◽  
Mobility Control ◽  
Sweep Efficiency ◽  
Reservoir Conditions ◽  
Infrared Spectrometer ◽  
Original Oil In Place

Polymer flooding could enhance the oil recovery by increasing the viscosity of water, thus, improving the mobility control and sweep efficiency. It is essential to explore natural sources of polymer, which is biologically degradable and negligible to environmental risks. This research aims to produce a biodegradable polymer from terrestrial mushroom, analyze the properties of the polymer and investigate the oil recovery from polymer flooding. Polysaccharide biopolymer was extracted from mushroom and characterized using Fourier Transform Infrared Spectrometer (FTIR), while the polymer viscosity was investigated using an automated microviscometer. The oil recovery tests were conducted at room temperature using a sand pack model. It was found that polymer viscosity increases with increasing polymer concentration and decreases when increase in temperature, salinity, and concentration of divalent ions. The oil recovery tests showed that a higher polymer concentration of 3000 ppm had recovered more oil with an incremental recovery of 25.8% after waterflooding, while a polymer concentration of 1500 pm obtained incremental 22.2% recovery of original oil in place (OOIP). The oil recovery from waterflooding was approximately 25.4 and 24.2% of the OOIP, respectively. Therefore, an environmentally friendly biopolymer was successfully extracted, which is potential for enhanced oil recovery (EOR) application, but it will lose its viscosity performance at certain reservoir conditions.

scholarly journals Biopolymer Solution Evaluation Methodology: Thermal and Mechanical Assessment for Enhanced Oil Recovery with High Salinity Brines

Processes ◽  
2019 ◽  
Vol 7 (6) ◽  
pp. 339 ◽  
Author(s):  
Mohammad Al-Saleh ◽  
Abdirahman Yussuf ◽  
Mohammad Jumaa ◽  
Abbas Hammoud ◽  
Tahani Al-Shammari
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
High Salinity ◽  
Evaluation Process ◽  
Polymer Flooding ◽  
Evaluation Methodology ◽  
Sweep Efficiency ◽  
Essential Properties ◽  
Reservoir Conditions ◽  
Strong Candidate

The methodology to study an eco-friendly and non-toxic, Schizophyllan, biopolymer for enhanced oil recovery (EOR) polymer flooding is described. The methodology is divided into two parts; the first part estimates the molar concentration of the biopolymer, which is needed to prepare the biopolymer solution with optimal viscosity. This is required to improve the sweep efficiency for the selected reservoir in Kuwait. The second part of this generalized methodology evaluates the biopolymer solution capability to resist degradation and maintain its essential properties with the selected reservoir conditions. The evaluation process includes thermal and mechanical assessment. Furthermore, to study the biopolymer solution behavior in both selected reservoir and extreme conditions, the biopolymer solution samples were prepared using 180 g/L and 309 g/L brine. It was found that the prepared biopolymer solution demonstrated great capability in maintaining its properties; and therefore, can be introduced as a strong candidate for EOR polymer flooding with high salinity brines.

scholarly journals Polymer viscosifier systems with potential application for enhanced oil recovery: a review

2021 ◽  
Vol 76 ◽  
pp. 65
Author(s):  
Kelly Lúcia Nazareth Pinho de Aguiar ◽  
Luiz Carlos Magalhães Palermo ◽  
Claudia Regina Elias Mansur
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Polymer Concentration ◽  
High Viscosity ◽  
Water Soluble ◽  
Recovery Factor ◽  
Sweep Efficiency ◽  
Polymeric Fluids ◽  
Excellent Thermal Stability ◽  
Reservoir Conditions

Due to the growing demand for oil and the large number of mature oil fields, Enhanced Oil Recovery (EOR) techniques are increasingly used to increase the oil recovery factor. Among the chemical methods, the use of polymers stands out to increase the viscosity of the injection fluid and harmonize the advance of this fluid in the reservoir to provide greater sweep efficiency. Synthetic polymers based on acrylamide are widely used for EOR, with Partially Hydrolyzed Polyacrylamide (PHPA) being used the most. However, this polymer has low stability under harsh reservoir conditions (High Temperature and Salinity – HTHS). In order to improve the sweep efficiency of polymeric fluids under these conditions, Hydrophobically Modified Associative Polymers (HMAPs) and Thermo-Viscosifying Polymers (TVPs) are being developed. HMAPs contain small amounts of hydrophobic groups in their water-soluble polymeric chains, and above the Critical Association Concentration (CAC), form hydrophobic microdomains that increase the viscosity of the polymer solution. TVPs contain blocks or thermosensitive grafts that self-assemble and form microdomains, substantially increasing the solution’s viscosity. The performance of these systems is strongly influenced by the chemical group inserted in their structures, polymer concentration, salinity and temperature, among other factors. Furthermore, the application of nanoparticles is being investigated to improve the performance of injection polymers applied in EOR. In general, these systems have excellent thermal stability and salinity tolerance along with high viscosity, and therefore increase the oil recovery factor. Thus, these systems can be considered promising agents for enhanced oil recovery applications under harsh conditions, such as high salinity and temperature. Moreover, stands out the use of genetic programming and artificial intelligence to estimate important parameters for reservoir engineering, process improvement, and optimize polymer flooding in enhanced oil recovery.

scholarly journals Research progress of viscoelastic surfactants for enhanced oil recovery

2021 ◽  
pp. 014459872098020
Author(s):  
Ruizhi Hu ◽  
Shanfa Tang ◽  
Musa Mpelwa ◽  
Zhaowen Jiang ◽  
Shuyun Feng
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
High Efficiency ◽  
Research Progress ◽  
Surfactant Flooding ◽  
Sweep Efficiency ◽  
The World ◽  
Washing Efficiency ◽  
Viscoelastic Surfactants ◽  
Viscoelastic Surfactant

Although new energy has been widely used in our lives, oil is still one of the main energy sources in the world. After the application of traditional oil recovery methods, there are still a large number of oil layers that have not been exploited, and there is still a need to further increase oil recovery to meet the urgent need for oil in the world economic development. Chemically enhanced oil recovery (CEOR) is considered to be a kind of effective enhanced oil recovery technology, which has achieved good results in the field, but these technologies cannot simultaneously effectively improve oil sweep efficiency, oil washing efficiency, good injectability, and reservoir environment adaptability. Viscoelastic surfactants (VES) have unique micelle structure and aggregation behavior, high efficiency in reducing the interfacial tension of oil and water, and the most important and unique viscoelasticity, etc., which has attracted the attention of academics and field experts and introduced into the technical research of enhanced oil recovery. In this paper, the mechanism and research status of viscoelastic surfactant flooding are discussed in detail and focused, and the results of viscoelastic surfactant flooding experiments under different conditions are summarized. Finally, the problems to be solved by viscoelastic surfactant flooding are introduced, and the countermeasures to solve the problems are put forward. This overview presents extensive information about viscoelastic surfactant flooding used for EOR, and is intended to help researchers and professionals in this field understand the current situation.

scholarly journals Enhanced Oil Recovery: Chemical Flooding

2021 ◽  
Author(s):  
Ahmed Ragab ◽  
Eman M. Mansour
Keyword(s):  
Interfacial Tension ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Recovery Phase ◽  
Mobility Ratio ◽  
Chemical Flooding ◽  
Sweep Efficiency ◽  
Oil Displacement ◽  
Remaining Oil ◽  
Oil Displacement Efficiency

The enhanced oil recovery phase of oil reservoirs production usually comes after the water/gas injection (secondary recovery) phase. The main objective of EOR application is to mobilize the remaining oil through enhancing the oil displacement and volumetric sweep efficiency. The oil displacement efficiency enhances by reducing the oil viscosity and/or by reducing the interfacial tension, while the volumetric sweep efficiency improves by developing a favorable mobility ratio between the displacing fluid and the remaining oil. It is important to identify remaining oil and the production mechanisms that are necessary to improve oil recovery prior to implementing an EOR phase. Chemical enhanced oil recovery is one of the major EOR methods that reduces the residual oil saturation by lowering water-oil interfacial tension (surfactant/alkaline) and increases the volumetric sweep efficiency by reducing the water-oil mobility ratio (polymer). In this chapter, the basic mechanisms of different chemical methods have been discussed including the interactions of different chemicals with the reservoir rocks and fluids. In addition, an up-to-date status of chemical flooding at the laboratory scale, pilot projects and field applications have been reported.

Low Tension Foam Flooding for Chemical Enhanced Oil Recovery in Heterogeneous Systems

2018 ◽  
Author(s):  
Ruth Hahn ◽  
Kerry Spilker ◽  
Dennis Alexis ◽  
Harry Linnemeyer ◽  
Taimur Malik ◽  
...  
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Heterogeneous Systems ◽  
Foam Flooding ◽  
Low Tension
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