Study on Carbon Fiber Reinforced Chloroprene Rubber Composites

2014 ◽  
Vol 1052 ◽  
pp. 254-257 ◽  
Author(s):  
Wei Li Wu ◽  
Jiang Kun Li

Due to the low strength of ordinary rubber, poor high temperature resistance and abrasion resistance, limit their service life. In this paper, the high-performance carbon fiber (CF) was used as a reinforcement, the chloroprene rubber (CR) as the matrix, and coupling agent as a compatilizer, prepared carbon fiber/rubber composite materials. The content of carbon fiber was determined by testing the mechanical and thermal properties. The effect of coupling agent on the compatibility between rubber and carbon fiber was studied by using as a bonding agent. The compatibility of the carbon fiber and rubber were analyzed by scanning electron microscope (SEM). The results show that the formula obtained best mechanical properties is 100 phr chloroprene rubber, 12 phr carbon fiber, and 2.5 phr KH-550. And further demonstrate that compatibility of carbon fiber / chloroprene rubber with adding 12phr CF by SEM analysis.

Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 988
Author(s):  
Xiaolong Tian ◽  
Shuang Han ◽  
Qianxiao Zhuang ◽  
Huiguang Bian ◽  
Shaoming Li ◽  
...  

Carbon fiber significantly enhances the mechanical, thermal and electrical properties of rubber composites, which are widely used in aerospace, military, national defense and other cutting-edge fields. The preparation of a high-performance carbon fiber rubber composite has been a research hotspot, because the surface of carbon fiber is smooth, reactive inert and has a poor adhesion with rubber. In this paper, a high-performance rubber composite is prepared by mixing dopamine-modified staple carbon fiber with natural latex, and the mechanisms of modified carbon fiber-reinforced natural latex composite are explored. The experimental results show that the surface-modified staple carbon fiber forms uniform and widely covered polydopamine coatings, which significantly improve the interface adhesion between the carbon fiber and the rubber matrix. Meanwhile, when the concentration of dopamine is 1.5 g/L and the staple carbon fiber is modified for 6h, the carbon fiber rubber composite shows excellent conductivity, thermal conductivity, and dynamic mechanical properties, and its tensile strength is 10.6% higher than that of the unmodified sample.


2019 ◽  
Vol 26 (2) ◽  
pp. 205-209 ◽  
Author(s):  
Jingkai NIE ◽  
Guangke WANG ◽  
Dong HOU ◽  
Fu GUO ◽  
Yu HAN

This study first conducted surface modification of Ag-plated Tetrapod-like zinc oxide (T-ZnO) whiskers with the use of dopamine and prepared Ag-plated T-ZnO whiskers (T-ZnO@Ag) by means of chemical plating, in which AgNO3 solutions with different concentrations were used during the preparation. Micro-structures of the prepared T-ZnO@Ag powders were examined to evaluate the effect of AgNO3 concentration on Ag plating performance. Subsequently, conductive Si rubber samples were prepared, the T-ZnO@Ag powders were used as fillers, and the effectiveness of the related electromagnetic shielding was investigated in detail. The results showed that using AgNO3 solution with a concentration of 20 g/L, a continuous Ag coating-layer was observed on the surface of T-ZnO whiskers. It was evident that, when used as fillers, T-ZnO@Ag has a conductive threshold and when the mass fraction of the fillers exceeded 50 %, the T-ZnO@Ag whiskers that were uniformly dispersed in the matrix formed interconnected conductive paths. In this condition, the electromagnetic shielding effectiveness of the prepared T-ZnO@Ag/Si rubber composite reached up 90 dB.


2020 ◽  
Vol 846 ◽  
pp. 37-41
Author(s):  
Pattarabordee Khaigunha ◽  
Tanakorn Wongwuttanasatian ◽  
Amnart Suksri

This study investigates the effects of micron-sized eggshells filler on resistance to tracking and erosion of silicone rubber composite. Eggshells with particle size from 44 to 53 microns were filled into liquid room temperature vulcanizing (RTV) silicone rubber with 0, 5, 15, 25, and 30 part per hundred of rubber (phr). IEC-60587 inclined plane test (IPT) was employed to appraise the surface tracking resistance. Thermogravimetric analysis was conducted to evaluate its thermal stability. Experimental results revealed an improvement of tracking and erosion resistance due to an addition of eggshells particles. Furthermore, the thermal stability of the composites showed variation in the increasing amount of the filler. The filler indicated that higher thermal stability of eggshells influences the heat resistance of the matrix. An increase of the heat resistance resulted in the ability to slow down tracking growth and erosion in the discharge region.


1998 ◽  
Vol 71 (5) ◽  
pp. 866-888 ◽  
Author(s):  
B. L. Lee ◽  
B. H. Ku ◽  
D. S. Liu ◽  
P. K. Hippo

Abstract Fatigue failure mechanisms under low-frequency loading and their dependence on the strain properties were assessed for the rubber matrix composite of bias aircraft tire carcass reinforced by nylon cords as well as two model rubber composites reinforced by steel wire cables. Under cyclic tension at constant stress amplitude, these angle-plied, cord—rubber composite laminates exhibited localized damage in the form of cord—matrix debonding, matrix cracking, and delamination. The process of fatigue damage accumulation in the cord—rubber composite laminate was accompanied by a steady increase of cyclic strain (dynamic creep) and moderate temperature changes. The fatigue life was found to be linearly proportional to the inverse of the dynamic creep rate, i.e., the time required to increase cyclic strain by a unit amount. Regardless of the associated level of stress amplitude or fatigue life, the gross failure under low-frequency loading occurred when the total strain accumulation, i.e., cumulative creep strain, reached the static failure strain. The use of higher stress amplitude resulted in a decrease of fatigue life by simply shortening the time to reach the critical level of strain for gross failure. This observation indicates that the damage initiation and eventual structural failure of angle-plied, cord—rubber composite laminates are “ strain-controlled” processes. These critical strain properties appear to be controlled by the process of interfacial failure between the cord and matrix. Under static tension, the strain levels for cord—matrix debonding and gross failure of composite laminates showed no significant dependence on the level of carbon black loading of the matrix compound, despite the fact that carbon black loading strongly affected the modulus, strength and strain properties of the matrix. Also the number of debonding sites around the cut ends of cords increased at almost the same rate as the static strain increased regardless of the variation of matrix properties.


Author(s):  
Kumarjyoti Roy ◽  
Subhas Chandra Debnath ◽  
Debdipta Basu ◽  
Aphiwat Pongwisuthiruchte ◽  
Pranut Potiyaraj

ABSTRACT In recent years, the application of sol-gel science to industrial polymer research has offered advancements in rubber technology. The use of sol-gel–synthesized materials for the development of highly reinforced rubber composites is the most commonly adopted and popular method exercised by rubber scientists. This article comprehensively reviews the recent progress regarding preparation and properties of sol-gel–synthesized nanoparticles-based rubber composites. The pragmatic consequences of sol-gel–synthesized nanoparticles in rubber compounds are systematically described through rheological, mechanical, and thermal properties. Emphatic focus is given to understanding the reinforcement mechanism of rubber composites by the use of sol-gel–derived alkoxide silica as filler. The properties of rubber nanocomposites are usually dependent on the dispersion of sol-gel–synthesized nanoparticles into the rubber matrix. The results reviewed from prolific studies suggested that sol-gel science has tremendous potential to develop high performance rubber nanocomposites for future industrial application.


NANO ◽  
2020 ◽  
Vol 15 (06) ◽  
pp. 2050078
Author(s):  
Bo Yang ◽  
Dong An ◽  
Yaqing Liu ◽  
Shuaishuai Cheng ◽  
Zhiyi Zhang

Friction between filler/filler and filler/matrix in rubber composites is the main factor affecting the heat build-up. In this study, we used dodecanol and silane coupling agent KH-592 to co-modify silica to prepare silica/natural rubber (NR) composites. When dodecanol and KH-592 are grafted onto the surface of silica at the same time, dodecanol can also shield part of the hydroxyl groups by its molecular chain length, which further improves the dispersibility of silica particles. The silane coupling agent KH-592 can form a bridge structure between the silica and the NR matrix under the action of a mercapto group, and improve the interaction between the filler and the matrix. By controlling the use ratio of dodecanol and KH-592, the dispersion of the filler and the interaction between the filler and the matrix can be adjusted. Thereby, the friction between the filler/filler and the filler/matrix is reduced, and a low heat build-up rubber composite material is prepared. Through co-modification, we prepared a series of low-heat build-up silica/NR composites, where the minimum heat generation reached 13∘C. The co-modified silica/NR composite material not only meets the requirements of green tires, but also has low heat build-up characteristics, providing a new strategy for preparing green and energy-saving tires.


2020 ◽  
Vol 29 ◽  
pp. 2633366X2092255
Author(s):  
Yi-Fan Chen ◽  
Ying-Guo Zhou ◽  
Ming Huang

Poly(ethylene-2,6-naphthalene) (PEN) is one of the most important engineering polymers with high performance. However, the effects and foaming behavior of carbon fiber (CF)-reinforced PEN (CFRPEN) remain to be explored. In this study, PEN was used as the matrix for CF-reinforced composites, and its foaming behavior and mechanical properties were investigated. High mechanical properties can be evaluated through comparison with other similar CF-reinforced thermoplastic composites. A fabrication method to generate lightweight and high-strength CFRPEN composites is hence proposed.


Sign in / Sign up

Export Citation Format

Share Document