Optical Diagnosis of Atmospheric Pressure Gas-Liquid Diffuse Discharge Excited by Nanosecond Pulse Voltage

2014 ◽  
Vol 1058 ◽  
pp. 158-161
Author(s):  
Ya Bo Wei ◽  
Li Zhang ◽  
Peng Chao Jiang ◽  
Shuai Zhang ◽  
De Zheng Yang

In this paper, A bipolar high voltage pulse with 20 ns rising time was employed to generate diffuse gas-liquid diffuse discharge in helium, and dielectric-free electrode configuration is used to generate room temperature plasma in small gas flow rate, which can be considered as a effective method to reduce the production cost. Discharge images, waveforms of pulse voltage and discharge current, and emission spectra of active species are measured.

Catalysts ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 508 ◽  
Author(s):  
Jie Zhang ◽  
Jiarui Chang ◽  
Ting Liu ◽  
Bula Cao ◽  
Yazhou Ding ◽  
...  

The reduction of CO2 is of great importance. In this paper, different types of bis(phosphinite) (POCOP) pincer nickel complexes, [2,6-(R2PO)2C6H3]NiX (R = tBu, iPr, Ph; X = SH, N3, NCS), were applied to the catalytic hydroboration of CO2 with catecholborane (HBcat). It was found that pincer complexes with tBu2P or iPr2P phosphine arms are active catalysts for this reaction in which CO2 was successfully reduced to a methanol derivative (CH3OBcat) with a maximum turnover frequency of 1908 h−1 at room temperature under an atmospheric pressure of CO2. However, complexes with phenyl-substituted phosphine arms failed to catalyze this reaction—the catalysts decomposed under the catalytic conditions. Complexes with iPr2P phosphine arms are more active catalysts compared with the corresponding complexes with tBu2P phosphine arms. For complexes with the same phosphine arms, the catalytic activity follows the series of mercapto complex (X = SH) ≈ azido complex (X = N3) >> isothiocyanato complex (X = NCS). It is believed that all of these catalytic active complexes are catalyst precursors which generate the nickel hydride complex [2,6-(R2PO)2C6H3]NiH in situ, and the nickel hydride complex is the active species to catalyze this reaction.


2016 ◽  
Vol 24 (3S2) ◽  
pp. 103-108
Author(s):  
Do Hoang Tung ◽  
Bach Sy Minh ◽  
Vu Thi Thom ◽  
Lam Thi Huyen Trang ◽  
Cao Thi Huong ◽  
...  

A cold atmospheric pressure gliding arc plasma jet hasbeen developed and applied to disinfection. The size of the plasma output is about 6 mm in diameter and 10 mm in length. Ar gas at a flow rate of 10 slm and 25 W plasma power are used. Plasma discharge is produced between the divergent electrodes and the jet appears as an effluence of the gas flow. When a \textnormal{pseudomonas} culture is placed at 8 mm below the torch for 1minute, where the gas is at room temperature, the bacteria within a 16 mm diameter circle are almost completely killed. As the UV radiation is well below the safety regulation, the bacteria are inactivated by the total effect of UV radiation and others like the reactive species and the charged particles.


2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Tiejian Liu ◽  
Yuxuan Zeng ◽  
Xin Xue ◽  
Yinyi Sui ◽  
Yingying Liang ◽  
...  

Atmospheric pressure plasma jet (APPJ) is a promising technique for the sterilization of pathogenic microorganisms in an ambient environment. In this work, a helium-APPJ was generated by double dielectric barrier discharge and applied to the sterilization of model microorganism in air and water. Discharge characteristics (including waveform and frequency of applied voltage), jet properties (such as feed gas flow rate, jet length, thermal effect, and optic emission spectra), and sterilization performance (in terms of clear/sterilized area, size of plaques, and sterilization efficiency) were investigated. Homogeneous helium plasma jet was generated in an energy-efficient way (18 kHz, 6 kV, 0.08 W) with a 19 mm jet and limited heating. The He-APPJ achieved good sterilization performances within very short treatment time (as short as 30 s). For surface sterilization, the area of clear zone and size of the plaque were 1809 mm2 and 48 mm, respectively, within 5 min treatment. For water sterilization, 99.8% sterilization efficiency was achieved within 5 min treatment. The optic emission spectra suggest that active species such as excited molecules, ions, and radicals were produced in the He-APPJ. The as-produced active species played important roles in the sterilization process.


2020 ◽  
Vol 75 (1) ◽  
pp. 15-21
Author(s):  
Yungang Zhang ◽  
Yongda Wang ◽  
Yunjie Liu ◽  
Xinyu Ai ◽  
Zhiguo Zhang ◽  
...  

Carbon disulfide, an important sulfur-containing species, has strong absorption lines in the wavelength range of 188 nm to 215 nm. It is difficult to accurately measure the absorption cross sections of carbon disulfide because carbon disulfide will be easily converted into carbon sulfide when it is exposed to ultraviolet light. In this study, the absorption cross sections of carbon disulfide were measured by reducing carbon disulfide conversion. The factors affecting carbon disulfide conversion, including gas flow rate, ultraviolet light intensity, and duration of illumination, were studied to reduce the conversion of carbon disulfide by controlling experimental conditions in the experiment. Finally, the absorption cross sections of carbon disulfide at room temperature and atmospheric pressure were calculated using the absorption spectrum and the carbon disulfide concentration in the absence of carbon disulfide conversion. The wavelengths of 16 absorption peaks on the carbon disulfide absorption cross sections of the vibration change were marked. Carbon disulfide has the maximum absorption cross section of 4.5 × 10–16 cm2/molecule at a wavelength of 198.10 nm.


2013 ◽  
Vol 178 (9) ◽  
pp. 651-655 ◽  
Author(s):  
Dana Skácelová ◽  
Vladimir Danilov ◽  
Jan Schäfer ◽  
Antje Quade ◽  
Pavel Sťahel ◽  
...  

2010 ◽  
Vol 107 (6) ◽  
pp. 063308 ◽  
Author(s):  
Y. Xian ◽  
X. Lu ◽  
Z. Tang ◽  
Q. Xiong ◽  
W. Gong ◽  
...  

2017 ◽  
Vol 19 (6) ◽  
pp. 064015 ◽  
Author(s):  
Muyang QIAN ◽  
Gui LI ◽  
Sanqiu LIU ◽  
Yu ZHANG ◽  
Shan LI ◽  
...  

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