Preparation of Polyaniline/Cotton Composite for Cr (VI) Removal in Solution

2017 ◽  
Vol 1142 ◽  
pp. 285-290 ◽  
Author(s):  
Tian Qi Hao ◽  
Yi Zhen Zhan ◽  
Bao Jiang Liu ◽  
Wei Wang ◽  
Dan Yu
Keyword(s):  
Adsorption Isotherm ◽  
Adsorption Kinetics ◽  
Rate Equation ◽  
Removal Rate ◽  
Oxidative Polymerization ◽  
Isothermal Model ◽  
Pseudo Second Order ◽  
Prepared Composite ◽  
Order Rate Equation

In this work, polyaniline (PANI)/cotton composite was prepared by in-situ oxidative polymerization and applied to remove Cr (VI) in solution. The as-prepared composite shows a high Cr (VI) removal rate (93.81%) at pH=2. Meanwhile, the adsorption kinetics follows the pseudo-second-order rate equation and the adsorption isotherm data fits well to the Langmuir isothermal model.

Adsorption of Phosphorus by Lithium Silica Fume

2013 ◽  
Vol 368-370 ◽  
pp. 692-696
Author(s):  
Wei Lan Lin ◽  
Jin Chuan Gu ◽  
Yu Heng Wang ◽  
Wen Yuan Wang
Keyword(s):  
Silica Fume ◽  
Adsorption Kinetics ◽  
Removal Rate ◽  
Freundlich Isotherm ◽  
Good Method ◽  
Order Equation ◽  
Isotherm Equation ◽  
Dosage Effects ◽  
Adsorption Capacities ◽  
Pseudo Second Order

adsorption is a good method to remove phosphorus. In the experiment, lithium silica fume is used as the adsorption material, adsorption isotherms ,kinetics and dosage effects were examined. It shows that the adsorption kinetics data are consistent with the pseudo-second-order equation and the adsorption is easy to happen. Freundlich isotherm equation is fit for description of the adsorption. The maximum adsorption capacities on lithium silica fume is 1.166 mg/g. When dosage get to 12 g/l and the concentration of phosphorus solution is 2 mg/l, the removal rate reach to 95% at 308k.

Adsorption of Alizarin Red from Aqueous Solution Using Ultra-Fine Fly Ash

2012 ◽  
Vol 518-523 ◽  
pp. 2307-2314 ◽  
Author(s):  
Bei Gang Li ◽  
Li Yuan Zhao
Keyword(s):  
Aqueous Solution ◽  
Fly Ash ◽  
Rate Equation ◽  
Removal Rate ◽  
Physical Adsorption ◽  
Particle Diffusion ◽  
Alizarin Red ◽  
Order Rate ◽  
Intra Particle Diffusion ◽  
Order Rate Equation

Alizarin Red (AR) has been shown to be effectively removed from aqueous solution using the ultrafine fly ash (UFA) prepared by ball milling from raw fly ash (FA), a low-cost industrial solid waste. The maximum removal rate was 91.04% in a solution of initial AR concentration of 700 mg/L, adsorption time of 60 min at pH 5.0 and temperature of 25°C. Compared with FA, the adsorption capacity of UFA is higher for AR removal. Effects of important parameters, contact time, adsorbate concentration, pH and temperature, were investigated. The UFA and AR-loaded UFA were characterized by FT-IR. The equilibrium, kinetics and thermodynamics of AR adsorption onto UFA were evaluated. The AR uptake process followed the pseudo-second-order rate equation well, but the pseudo-first-order rate equation and intra-particle diffusion equation could only be applied to describe the initial stage of adsorption, furthermore, intra-particle diffusion might be the rate-controlling step of fast adsorption process. The sorption decreased with increasing temperature and the adsorption apparent activation energy was 8.28kJ/mol. Langmuir isotherm equation could better describe the adsorption equilibrium at different temperatures, compared with Freundlich model. Thermodynamic parameters, ΔG, ΔH and ΔS, were also calculated. The results inferred that the adsorption of AR/UFA system was feasible, spontaneous and exothermic nature of the process which was mainly controlled by physical adsorption.

scholarly journals Removal of triphenylmethane dye from aqueous solutions through an adsorption process over waste materials

2020 ◽  
Vol 10 (4) ◽  
pp. 5772-5779
Keyword(s):  
Adsorption Isotherm ◽  
Adsorption Capacity ◽  
Dye Removal ◽  
Functional Group ◽  
Adsorption Process ◽  
Removal Rate ◽  
Freundlich Isotherm ◽  
Second Order ◽  
Pseudo Second Order ◽  
Best Fit

Water pollution is the most significant issue due to rapid growing industrial development especially textile dye industry. Therefore, the adsorption process experiment was conducted to determine the removal ability of the adsorbent chosen. The removal rate and adsorption capacity of Phenol red and Cresol were analyzed by using eggshell adsorbent in the adsorption process. The experiment was conducted with parameters of initial concentration, dosage, pH and contact time. Results indicated that the removal rate achieved more than 90% and the adsorption capacity exceeded more than 5 mg/g. The functional group before adsorption process eggshell adsorbent and after adsorption process eggshell adsorbent was analyzed by using FTIR (Fourier Transform Infrared Spectroscopy). The study of adsorption isotherm and kinetics model was carried out to identify the efficiency of the eggshell adsorbent reacting with the dye solution. The adsorption isotherm that applied in this research was Langmuir isotherm, Jovanovic isotherm and Freundlich isotherm. Moreover, Pseudo-first-order and Pseudo-second-order chosen were conducted to determine the kinetic studies. In short, eggshell adsorbent is highly effective on dye removal through adsorption capacity. The functional group of the eggshell adsorbent was found such as alcohols, phenol, alkanes, carbonyls, ester, saturated aliphatic, aldehydes, aromatics, 2°amines and phosphorus. For kinetics study, Freundlich isotherm was analyzed as the best fit isotherm model as it achieved the highest R2 value which is closed to 1 and Pseudo-second-order was analyzed as the best fit kinetic model in this experiment. Therefore, eggshell adsorbent is highly effective in dye removal.

Biosorption of Lignin Compounds Using Biomass Derived from Eichhornia crassipes: Batch Studies

2008 ◽  
Vol 6 (1) ◽  
Author(s):  
Renganathan Sahadevan ◽  
Ajit Balaji Kannavadi Devaraj ◽  
Dharmendira Kumar Mahendradas ◽  
Baskar Gurunathan ◽  
Manickam Velan
Keyword(s):  
Rate Equation ◽  
Eichhornia Crassipes ◽  
Second Order ◽  
Isotherm Model ◽  
Batch Studies ◽  
First Order ◽  
Order Rate ◽  
Pseudo Second Order ◽  
Pseudo First Order ◽  
Order Rate Equation

Biosorption of lignin compounds by the Eichhornia crassipes was investigated in batch studies. Batch experiments were conducted to study the effect of initial sorbent dosage, solution pH and lignin compounds concentration. Langmuir and Freundlich adsorption isotherm models were used to represent the equilibrium data. The Freundlich isotherm model was found to be fitted very well with the experimental data when compared to Langmuir isotherm model. The results showed that the equilibrium uptake capacity was found to be increased with decrease in biomass dosage. The lignin compound removal was influenced by the initial lignin compounds concentration. The sorption results were analysed for pseudo first order and pseudo second order kinetic model. It was observed that the kinetic data fitted very well with the pseudo second order rate equation when compared to the pseudo first order rate equation. Sorption results were analyzed for the intra particle diffusion model.

The Bentonite Copolymer Composite for Removing Lead Ions

2013 ◽  
Vol 750-752 ◽  
pp. 47-50
Author(s):  
Wen Juan He ◽  
Yu Feng He ◽  
Zhen Hua Zhang ◽  
Ju Hua Guo ◽  
Rong Min Wang
Keyword(s):  
Kinetic Model ◽  
Maleic Anhydride ◽  
In Situ Polymerization ◽  
Removal Rate ◽  
Order Kinetic ◽  
Adsorption Dynamics ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Polymer Adsorbent

In this paper, a new kind of clay copolymer adsorbent, bentonite compositing with maleic anhydride (MAH)-acrylic acid (AA)-vinyl acetate (VAc) copolymer (NaB/PMAV) was prepared by in-situ polymerization. It was used as polymer adsorbent for removing Pb (II) ions in wastewater.. Under the optimal condition of adsorption, the removal rate reached to 94.4% and the adsorption capacity got to 235.9 mg/g. Adsorption dynamics were consistent with pseudo-second-order kinetic model and isotherm model can meet the Langmuir isotherm.

Adsorption-Desorption Characteristics of E.coli by Quartz Sands of Different Particle Size

2014 ◽  
Vol 955-959 ◽  
pp. 436-444
Author(s):  
Zhi Rong Wang ◽  
Wei Li Wang ◽  
Xiao Yan Zhu ◽  
Jing Lan Wang ◽  
Zhi Jie Han ◽  
...  
Keyword(s):  
Particle Size ◽  
Rate Equation ◽  
Second Order ◽  
E Coli ◽  
Order Rate ◽  
Quartz Sands ◽  
Pseudo Second Order ◽  
Adsorption Desorption ◽  
Adsorption Quantity ◽  
Order Rate Equation

Adsorption-desorption characteristics of E. coli by quartz sands of five different particle size (351、319、217、71、27μm) were studied using batch equilibrium method. The results showed that quartz sands had great adsorption quantity of E. coli. The adsorption ratio could reach above 95%,when the initial microbial concentration was 109 cfu/mL. With the decreased of the quartz sand particle size,the adsorption quantity increased,and adsorption reached balance faster. The Pseudo-second-order rate equation is optimal to describe adsorption kinetics of E. coli by quartz sands, and the isothermal adsorption process is suitable to describe using Henry equation. Quartz sands had small desorption ratio of E. coli,the desorption ratio increased as quartz sands particle size increased, the largest desorption ratio was only 3.6%.The desorption dynamic processes and desorption isothermal processes also can be decreased using Pseudo-second-order rate equation and Henry equation respectively. Desorption of E. coli on quartz sands existed obvious hysteresis. It indicated there existed irreversible adsorption between E. coli and quartz sands, which the E. coli adsorbed was hard to desorb. The average particle size of quartz sands have some relevance with the parameters of Henry equation and Pseudo-second-order rate equation. This shows that particle size is one of the important factors that affect the adsorption and desorption.

Adsorption Kinetics of Nickel Etioporphyrin on VTB-Asphaltene in N-Pentane Solution

2013 ◽  
Vol 781-784 ◽  
pp. 24-29
Author(s):  
Fei Fei Chen ◽  
Zhi Ming Xu ◽  
Xue Wen Sun ◽  
Suo Qi Zhao
Keyword(s):  
Adsorption Kinetics ◽  
Oil Sands ◽  
Removal Rate ◽  
Adsorption Rate ◽  
Low Molecular Weight ◽  
Pseudo Second Order ◽  
Alkane Solvents ◽  
Solvent Deasphalting ◽  
Oil Sands Bitumen ◽  
Kinetics Of

It is important to find out how to strengthen the interaction between nickel porphyrins and asphaltene in the alkane solvents of the low molecular weight for raising the removal rate of nickel in the solvent deasphalting process. Therefore, the adsorption kinetics, which describes how the nickel etioporphyrins are adsorbed on asphaltene (the vacuum residue of Canadian oil sands bitumen (VTB)) in the n-pentane solvent, are investigated. The results show that a certain amount of nickel porphyrins is absorbed on the asphaltene of VTB, which means there is a certain adsorption between asphaltene and nickel porphyrins. The adsorption rate is affected by the dosage of asphaltene, the concentration of the n-pentane solution containing nickel porphyrins and the temperature. A comparison in the four kinds of kinetic models on the overall adsorption rate shows that adsorption process can be perfectly described by the pseudo second-order equation.

scholarly journals Kinetika Adsorpsi Gas Benzena Pada Karbon Aktif Tempurung Kelapa

Jurnal MIPA ◽  
2013 ◽  
Vol 2 (2) ◽  
pp. 100
Author(s):  
Rizky B. Holle ◽  
Audy D. Wuntu ◽  
Meiske S. Sangi
Keyword(s):  
Activated Carbon ◽  
Rate Equation ◽  
Order Rate Constant ◽  
Second Order ◽  
Coconut Shell ◽  
Benzene Adsorption ◽  
Order Rate ◽  
Pseudo Second Order ◽  
Order Rate Equation ◽  
Gaseous Benzene

Telah diteliti kinetika adsorpsi gas benzena pada karbon aktif tempurung kelapa yang diaktivasi dengan NaCl dengan tujuan menentukan model kinetika yang dapat diaplikasikan untuk adsorpsi gas benzena pada karbon aktif tempurung kelapa. Data adsorpsi dianalisis dengan menggunakan empat model persamaan laju adsorpsi yaitu (1) persamaan laju order pertama pseudo Lagergren, (2) persamaan laju order kedua pseudo Ho, (3) persamaan Elovich, dan (4) persamaan Ritchie. Hasil kajian menunjukkan bahwa model kinetika dengan persamaan laju order ke-2 pseudo Ho adalah yang paling sesuai diaplikasikan untuk adsorpsi gas benzena pada karbon aktif tempurung kelapa. Dari model kinetika order ke-2 pseudo Ho diperoleh konstanta adsorpsi benzena sebesar 1,63x10-4 g mg-1 min-1. Nilai energi adsorpsi menunjukkan bahwa benzena teradsorpsi secara fisik pada adsorben.Kinetics of gaseous benzene adsorption on coconut shell NaCl-activated carbon had been studied. The research was aimed to determine the appropriate kinetic model applied to gaseous benzene adsorption on the adsorbent. Adsorption data was analyzed using four kinetic models of adsorption rate equation, which were (1) Lagergren’s pseudo first order rate equation, (2) Ho’s pseudo second order rate equation, (3) Elovich‘s equation, and (4) Ritchie’s equation. The results showed that the Ho’s pseudo second order rate equation was best applied to gaseous benzene adsorption on coconut shell activated carbon. The second order rate constant for benzene adsorption was 1.63x10-4 g mg-1 min-1. The value of adsorption energy showed that benzene was physically adsorbed on the adsorbent.

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