Judd-Ofelt Analysis of a Dendrtic Type Europium Complex/Silicone Rubber

2011 ◽  
Vol 233-235 ◽  
pp. 1227-1230 ◽  
Author(s):  
Hao Liang ◽  
Fang Xie
Keyword(s):  
Cross Sections ◽  
Silicone Rubber ◽  
Radiative Lifetime ◽  
Radiative Transition ◽  
Optical Devices ◽  
Europium Complex ◽  
Stimulated Emission ◽  
Ofelt Theory ◽  
Intensity Parameters ◽  
Radiative Transition Rate

A dendritic type europium complex/silicone rubber has been prepared. According to the luminescence spectrum, the Judd-Ofelt theory was adopted to calculate the intensity parameters Ω2and Ω4. The total radiative transition rate (640.1 s-1), radiative lifetime (1.562 ms) and the stimulated emission cross-sections (46.19×10-22cm2) of the5D0exciting state have been evaluated. Analysis reveals that the europium (III) chelating polymer is promising for use in optical devices.

Fluorescence and Judd-Ofelt Analysis of Er3+ Doped CaF2 Transparent Ceramic

2014 ◽  
Vol 875-877 ◽  
pp. 23-27
Author(s):  
Ru Zhen Xing ◽  
Bing Chu Mei ◽  
Jing Hong Song ◽  
Xiao Nv Li
Keyword(s):  
Excited States ◽  
Cross Sections ◽  
Fluorescence Spectra ◽  
Room Temperature ◽  
Transition Probabilities ◽  
Radiative Transition ◽  
Transparent Ceramic ◽  
Ofelt Theory ◽  
Radiation Trapping ◽  
Intensity Parameters

In this paper, we evaluated the spectra parameters of Er3+.The absorption spectra of Er3+:CaF2transparent ceramic was measured at room temperature (RT). Based on the Judd–Ofelt theory, the intensity parameters were Ω2= 5.02×10−20cm2, Ω4= 3.40×10−20cm2and Ω6= 0.38×10−20cm2, and then the values of the radiative transition probabilities, radiative lifetimes and integrated emission cross-sections of excited states were calculated. Full width at half maximum (FWHM) of the fluorescence spectra for4I13/2→4I15/2transition was investigated, being 17nm. The decay time was found to be 24.3ms, which is longer than the theoretically calculated value indicating a radiation trapping effect in this work.

PHYSICAL, ABSORPTION AND FLUORESCENCE SPECTRAL STUDIES OF Pr3+ IONS DOPED LITHIUM BISMUTH BORATE GLASSES

2013 ◽  
Vol 22 ◽  
pp. 298-304
Author(s):  
BEENA BHATIA ◽  
VISHAL PARIHAR
Keyword(s):  
Transition Probability ◽  
Emission Cross Section ◽  
Radiative Lifetime ◽  
Branching Ratio ◽  
Emission Spectra ◽  
Radiative Transition ◽  
Stimulated Emission ◽  
Radiative Properties ◽  
Spectral Studies ◽  
Intensity Parameters

Glasses of the system: xB2O3-10Bi2O3-30Li2O-xPr6O11 where x =1, 1.5 and 2 were prepared by melt quenching technique. Optical absorption and emission spectra have been recorded. The intensities of f-f transition are calculated in term of Judd-Ofelt (JO) intensity parameters Ωλ (λ = 2, 4 and 6). Using the fluorescence data and these Ωλ parameters, various radiative properties like transition probability (Arad), branching ratio (βR), radiative lifetime (τR), and stimulated emission cross section (σp), of various emission lines have been evaluated. The branching ratio for 3P0→3H4 transition is 56% and the predicted spontaneous radiative transition probability rates are fairly high 16411 s−1. This is beneficial for lasing emission.

scholarly journals Radiative and non-radiative transitions of excited Ti3+ cations in sapphire

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Avry Shirakov ◽  
Zeev Burshtein ◽  
Yehoshua Shimony ◽  
Eugene Frumker ◽  
Amiel A. Ishaaya
Keyword(s):  
Temperature Dependence ◽  
Electronic State ◽  
Fluorescence Lifetime ◽  
Radiative Lifetime ◽  
Radiative Transition ◽  
Zero Temperature ◽  
Thermal Phonon ◽  
Radiative Transitions ◽  
Thermal Enhancement ◽  
Radiative Transition Rate

AbstractWe have measured the fluorescence quantum efficiency in Ti3+:sapphire single crystals between 150 K and 550 K. Using literature-given effective fluorescence lifetime temperature dependence, we show that the zero temperature radiative lifetime is (4.44 ± 0.04) μs, compared to the 3.85 μs of the fluorescence lifetime. Fluorescence lifetime thermal shortening resolves into two parallel effects: radiative lifetime shortening, and non-radiative transition rate enhancement. The first is due to thermally enhanced occupation of a ΔE = 1,700 cm−1 higher (top) electronic state of the upper multiplet, exhibiting a transition oscillator strength of f = 0.62, compared to only 0.013 of the bottom electronic state of the same multiplet. The non-radiative rate relates to multi-phonon decay transitions stimulated by the thermal phonon occupation. Thermal enhancement of the configuration potential anharmonicity is also observed. An empiric expression for the figure-of-anharmonicity temperature dependence is given as $$\hat{{\bf{H}}}$$Hˆ (T) = $$\hat{{\bf{H}}}$$Hˆ (0)(1 + β exp(−ℏωco /kBT )), where $$\hat{{\bf{H}}}$$Hˆ (0) = 0.276, β = 5.2, ℏωco = 908 cm−1, and kB is the Boltzmann constant.

Quenching of CO(B1Σ+,υ=0)by He,Ne,Ar,H2and D2

1973 ◽  
Vol 28 (5) ◽  
pp. 717-724 ◽  
Author(s):  
F. J. Comes ◽  
E. H. Fink
Keyword(s):  
Cross Sections ◽  
Transition Probabilities ◽  
Radiative Lifetime ◽  
Radiative Transition ◽  
Experimental Conditions ◽  
Steady State Fluorescence ◽  
Resonance Band ◽  
Straight Lines ◽  
Effective Collision ◽  
Sample Pressure

Excitation of CO molecules into the lowest vibrational level of the B1Σ+ electronic state by absorption of the (B 1Σ+υ′=0 →X 1Σ+ ,υ′′=0) resonance band at 1150 Å has been studied under various experimental conditions by observing the steady state fluorescence of the (B 1Σ+→A1Π) Angstrom bands. Stern-Volmer plots of the fluorescence intensities at the addition of various foreign gases yielded straight lines whose slopes k̃qм = kqм · τeff were strongly dependent on the CO sample pressure. This effect was found to be due to changes of the effective radiative lifetime of the B 1Σ+υ′=0 because of resonance trapping of the (0,0) band of the (B → X) fluorescence. The CO(B 1Σ+υ′=0) molecules are found to be quenched by He, Ne, Ar, H2 and D2 with effective collision cross sections of 0.23, 0.48, 22.4, 10.7, and 11.4 Å2, respectively, at 298 °K. In addition, an approximate value for the ratio ABA/ (ABA+ABX)of the radiative transition probabilities of the (B → A) and (B → X) transitions could be derived from the measurements.

scholarly journals Optical Transition Probabilities of Er3+Ions in ErBa3B9O18Crystal

2015 ◽  
Vol 2015 ◽  
pp. 1-4
Author(s):  
Ming He ◽  
Tiezheng Liu ◽  
Junling Xiu ◽  
Yuanguang Tang ◽  
Zhihua Zhang
Keyword(s):  
Optical Absorption ◽  
Cross Sections ◽  
Transition Probabilities ◽  
Optical Transition ◽  
Radiative Lifetime ◽  
Absorption Data ◽  
Birefringent Crystal ◽  
Intensity Parameters ◽  
Thin Disk Laser ◽  
Er Doped

The optical absorption and emission intensity of luminescent and birefringent crystal ErBa3B9O18were examined from optical absorption data based on Judd-Ofelt theory. The three intensity parametersΩt(t=2,4,6) are 3.10 × 10−20, 0.87 × 10−20, and 1.80 × 10−20 cm2, respectively. From the obtained intensity parameters, the radiative probabilitiesAr, radiative lifetimeτf, fluorescence branching ratiosβc, and integrated emission cross sections∑have been calculated. In comparison with other Er-doped luminescent crystals, ErBa3B9O18may find application in thin disk laser.

scholarly journals Luminescence Properties and Judd–Ofelt Analysis of Various ErF3 Concentration-Doped BaF2 Crystals

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4221
Author(s):  
Andrei Racu ◽  
Marius Stef ◽  
Gabriel Buse ◽  
Irina Nicoara ◽  
Daniel Vizman
Keyword(s):  
Transition Probability ◽  
Radiative Lifetime ◽  
Branching Ratio ◽  
Radiative Transition ◽  
Ion Concentration ◽  
Uv Emission ◽  
Intensity Parameters ◽  
Decay Times ◽  
Emission Behavior ◽  
Millisecond Range

The influence of erbium ion concentration on the optical properties of BaF2:ErF3 crystals was investigated. Four ErF3 concentration (0.05, 0.08, 0.15 and 0.5 mol% ErF3)-doped BaF2 crystals were obtained using the Bridgman technique. Room temperature optical absorption in the 250–850 nm spectral range was measured, and the photoluminescence (PL) and decay times were also investigated. The Judd–Ofelt (JO) approximation was used, taking into account four absorption peaks (at 377, 519, 653 and 802 nm). The JO intensity parameters, Ωt (t = 2, 4, 6), were calculated. The influence of the ErF3 concentration on the JO parameters, branching ratio, radiative transition probability and radiative lifetime were studied. The obtained results were compared with measured values and with those reported in the literature. Under excitation at 380 nm, the well-known green (539 nm) and red (668 nm) emissions were obtained. The calculated and experimental radiative lifetimes were in millisecond range for green and red emissions. The intensity of the PL spectra varied with the Er3+ ion concentration. The emission intensity increased linearly or exponentially, depending on the ErF3 concentration. Under excitation at 290 nm, separate to the green and red emissions, a new UV emission band (at 321 nm) was obtained. Other research has not reported the UV emission or the influence of ErF3 concentration on emission behavior.

scholarly journals Synthesis, Structural and Luminescence Studies of Europium Doped Borate Glasses

2020 ◽  
Vol 9 (1) ◽  
pp. 9-16
Author(s):  
V L Usharani ◽  
B Eraiah
Keyword(s):  
Cross Sections ◽  
Transition Probabilities ◽  
Emission Cross Section ◽  
Radiative Lifetime ◽  
Emission Spectra ◽  
Optical Gain ◽  
Stimulated Emission ◽  
Melt Quenching ◽  
Fibre Amplifiers ◽  
Quenching Method

Different concentration of (0.1, 0.2, 0.3, 0.4, 0.5, 1.0 & 1.5) mol% of europium doped lead borate lithium glasses were prepared by melt quenching method. The properties of thermal, photoluminescence & structural were analyzed using DTA, FTIR and emission spectra. Emission spectra was used to evaluate the Judd-Ofelt (JO) parameters. Radiative parameters like stimulated emission cross-sections (σe), effective band width (∆λeff), transition probabilities (A), optical gain bandwidths (σe x ∆λeff), radiative lifetime (τrad) and optical gain (σe x τrad) values were evaluated for the transition 5D0→7Fj (j=1, 2, 3 and 4) of Eu3+ ions. The outcome of transition 5D0→7F4 at its highest value of branching ratios and stimulated emission cross-section are evaluated with the literature. Hence we can could the prepared host glass doped with Eu3+ ions are good fibre amplifiers and it can be used as a red laser.

scholarly journals Optical properties of Eu3+ ions in boro-tellurite glass

2016 ◽  
Vol 26 (1) ◽  
pp. 25
Author(s):  
Ngo Van Tam ◽  
Vu Phi Tuyen ◽  
Phan Van Do
Keyword(s):  
Cross Sections ◽  
Tellurite Glass ◽  
Transition Probabilities ◽  
Emission Spectra ◽  
Branching Ratios ◽  
Stimulated Emission ◽  
Radiative Properties ◽  
Phonon Coupling ◽  
Intensity Parameters ◽  
Electron Phonon Coupling

The excitation, emission spectra and and lifetime of Eu-doped borotellurite glasses (BTe) have been investigated. The sideband phonon energy and electron-phonon coupling strength (g) have been found. The intensity parameters Ωλ were calculated from the emission spectrum. These parameters were used to predict radiative properties such as transition probabilities (AR), calculated branching ratios (βR) and stimulated emission cross-sections (σλp) for 5D0→7HJHFJ transitions.

Absorbance and Fluorescence Spectral Analysis of Sm3+ Ions Doped Bismuth Boro-Silicate Glasses

2012 ◽  
Vol 585 ◽  
pp. 279-283 ◽  
Author(s):  
Sunil Bhardwaj ◽  
Rajni Shukla ◽  
Sujata Sanghi ◽  
Ashish Agarwal ◽  
Inder Pal
Keyword(s):  
Transition Probabilities ◽  
Transition Probability ◽  
Branching Ratio ◽  
Life Time ◽  
Radiative Transition ◽  
Stimulated Emission ◽  
Radiative Properties ◽  
Potential Candidate ◽  
Borosilicate Glasses ◽  
Intensity Parameters

Glasses having compositions 20B2O3.(79.5-x)Bi2O3.xSiO2(10 ≤ x ≤ 40) doped with 0.5 mol% of Sm3+ions were prepared by melt quench technique. The amorphous nature of the glasses was confirmed by X-ray diffraction studies. The spectroscopic properties of Sm3+ions in bismuth borosilicate glasses as a function of bismuth oxide were investigated using optical absorption and fluorescence spectra. The Judd-Ofelt theory has been employed to calculate transitions probability from the data of absorption cross-section of several f-f transitions. The intensity parameters Ω2is related to the symmetry of glass hosts, where as the parameter Ω6is inversely proportional to the rare earth oxygen (RE-O) covalency. The variation of Ω4with Bi2O3content has been attributed to rigidity of the samples. Using the Judd Ofelt intensity parameters the other radiative properties like radiative transition probability, radiative life time, branching ratio and the stimulated emission cross-sections of prepared BBSS glasses have been calculated. A bright fluorescent orange emission at 600 nm (4G5/2→6H7/2) of Sm3+ion has been investigated as a function of Bi2O3in host glass. The radiative transition probabilities of Sm3+ions are large in bismuth borosilicate glasses, suggesting the suitability of these glasses as potential candidate for laser application.

scholarly journals Temperature-Dependent Stimulated Emission Cross-Section in Nd3+:YLF Crystal

Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 431
Author(s):  
Giorgio Turri ◽  
Scott Webster ◽  
Michael Bass ◽  
Alessandra Toncelli
Keyword(s):  
Cross Section ◽  
Cross Sections ◽  
Room Temperature ◽  
Radiative Decay ◽  
Emission Cross Section ◽  
Spectroscopic Properties ◽  
Stimulated Emission ◽  
Different Temperatures ◽  
Stimulated Emission Cross Section ◽  
Semi Empirical

Spectroscopic properties of neodymium-doped yttrium lithium fluoride were measured at different temperatures from 35 K to 350 K in specimens with 1 at% Nd3+ concentration. The absorption spectrum was measured at room temperature from 400 to 900 nm. The decay dynamics of the 4F3/2 multiplet was investigated by measuring the fluorescence lifetime as a function of the sample temperature, and the radiative decay time was derived by extrapolation to 0 K. The stimulated-emission cross-sections of the transitions from the 4F3/2 to the 4I9/2, 4I11/2, and 4I13/2 levels were obtained from the fluorescence spectrum measured at different temperatures, using the Aull–Jenssen technique. The results show consistency with most results previously published at room temperature, extending them over a broader range of temperatures. A semi-empirical formula for the magnitude of the stimulated-emission cross-section as a function of temperature in the 250 K to 350 K temperature range, is presented for the most intense transitions to the 4I11/2 and 4I13/2 levels.

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