Preparation and Performance Research of Polyimide Modified Nylon Resin

2011 ◽  
Vol 236-238 ◽  
pp. 548-551
Author(s):  
Hong Kai Zhao ◽  
Li Guang Xiao ◽  
Xiao Jing Zhang

High performance trend of plastics has become a hot spot of current research. Select bisphenol A dianhydride and bisphenol A diamine with excellent water resistance as the reactant monomers to obtain anhydride-terminated polyimide with very high molecular weight by two-step polymerization, graft the active radicals of acyl caprolactam using the activity of anhydride and obtain PI modified nylon resin by polymerization. It is proved that the reaction in each above step is successful through infrared analysis. Through microscopic analysis, the molecules of polyimide does not enter crystallization phase of nylon resin, but forms compact lamellar crystals existing in nylon matrix.

2011 ◽  
Vol 295-297 ◽  
pp. 21-25
Author(s):  
Hong Kai Zhao ◽  
Li Guang Xiao ◽  
Hong Jie Wang

High performance trend of plastics has become a hot spot of current research. Select bisphenol A dianhydride and bisphenol A diamine with excellent water resistance as the reactant monomers to obtain anhydride-terminated polyimide with very high molecular weight by two-step polymerization, graft the active radicals of acyl caprolactam using the activity of anhydride and obtain PI modified nylon resin by polymerization.When the system temperature is above 160 °C and the added modifiers are greater than 10%, the system viscosity increases very fast; when the system temperature reaches 140 °C and the added modifiers are at 5%, the system viscosity increases very slowly. It is proved that the reaction in each above step is successful through infrared analysis. The mechanical properties of modified PI nylon increases with the increase of consumption and molecular weight of polyimide, when the molecular weight is selected to be about 8000~10000 and the adding amount is 10wt%~15 wt%, the tensile strength reaches over 85MPa, the notch impact strength is increased to 19.6kJ.m-2 and the elongation at break reaches 18%, which are remarkably better than general engineering plastics.Through microscopic analysis, the molecules of polyimide does not enter crystallization phase of nylon resin, but forms compact lamellar crystals existing in nylon matrix.


2014 ◽  
Vol 1052 ◽  
pp. 242-248
Author(s):  
Hong Kai Zhao ◽  
Hong Li Wang

Through the polymerization and grafting reaction of bisphenol A dianhydride and bisphenol A diamine, the polyimide activator (PI activator) of acyl caprolactam end capping is obtained and then the anionic in-situ polymerization modified nylon 6 resin is obtained. Viscosity analysis shows that PI consumption is higher than 0.1 (of monomer mass), the reaction temperature is higher than 160°C, the viscosity rises rapidly in a short time and the rapid polymerization molding can be realized; when PI consumption is higher than 0.15 (of monomer mass), the water absorption of matrix resin will be lower than 1.4%; compared with the nylon resin, its water absorption is significantly lowered and its mechanical property is improved greatly; microscopic analysis shows that PI molecules fail to enter the crystalline phase of the nylon 6 and form lamellar crystals in the nylon matrix, which plays a role of enhancement and obstruction; differential thermal analysis shows that PI reduces the melting enthalpy and melting point temperature of nylon 6 resin, which indicates that PI reduces the crystallization capacity of nylon 6.


1987 ◽  
Vol 107 ◽  
Author(s):  
P.K. Vasudev ◽  
K.W. Terrill ◽  
S. Seymour

AbstractThe use of ultrathin SIMOX wafers for fabricating submicrometer CMOS integrated circuits is described. It is demonstrated from ring oscillator speeds that properly designed devices can exhibit very high transconductance and performance superior to circuits using bulk Si.


2011 ◽  
Vol 2011 ◽  
pp. 1-6 ◽  
Author(s):  
M. H. Ghadiry ◽  
Asrulnizam Abd Manaf ◽  
M. T. Ahmadi ◽  
Hatef Sadeghi ◽  
M. Nadi Senejani

A novel full adder circuit is presented. The main aim is to reduce power delay product (PDP) in the presented full adder cell. A new method is used in order to design a full-swing full adder cell with low number of transistors. The proposed full adder is implemented in MOSFET-like carbon nanotube technology and the layout is provided based on standard 32 nm technology from MOSIS. The simulation results using HSPICE show that there are substantial improvements in both power and performance of the proposed circuit compared to the latest designs. In addition, the proposed circuit has been implemented in conventional 32 nm process to compare the benefits of using MOSFET-like carbon nanotubes in arithmetic circuits over conventional CMOS technology. The proposed circuit can be applied in very high performance and ultra-low-power applications.


Author(s):  
D. E. Newbury ◽  
R. D. Leapman

Trace constituents, which can be very loosely defined as those present at concentration levels below 1 percent, often exert influence on structure, properties, and performance far greater than what might be estimated from their proportion alone. Defining the role of trace constituents in the microstructure, or indeed even determining their location, makes great demands on the available array of microanalytical tools. These demands become increasingly more challenging as the dimensions of the volume element to be probed become smaller. For example, a cubic volume element of silicon with an edge dimension of 1 micrometer contains approximately 5×1010 atoms. High performance secondary ion mass spectrometry (SIMS) can be used to measure trace constituents to levels of hundreds of parts per billion from such a volume element (e. g., detection of at least 100 atoms to give 10% reproducibility with an overall detection efficiency of 1%, considering ionization, transmission, and counting).


Alloy Digest ◽  
2017 ◽  
Vol 66 (12) ◽  

Abstract Alloy C688 is a high-performance copper alloy with very high conductivity. This datasheet provides information on composition, physical properties, hardness, elasticity, tensile properties, and bend strength. It also includes information on corrosion resistance as well as forming and joining. Filing Code: Cu-867. Producer or source: Gebr. Kemper GmbH + Company KG Metallwerke.


Alloy Digest ◽  
2017 ◽  
Vol 66 (10) ◽  

Abstract Alloy KHP 7025 (UNS C70250) is a high-performance copper alloy with very high conductivity. Uses include connector springs, tabs, contact springs, switches, relays, and leadframes. This datasheet provides information on composition, physical properties, hardness, elasticity, tensile properties, and bend strength. It also includes information on corrosion resistance as well as forming, machining, and joining. Filing Code: Cu-865. Producer or source: Gebr. Kemper GmbH + Company KG Metallwerke.


2017 ◽  
pp. 96-103 ◽  
Author(s):  
Gillian Eggleston ◽  
Isabel Lima ◽  
Emmanuel Sarir ◽  
Jack Thompson ◽  
John Zatlokovicz ◽  
...  

In recent years, there has been increased world-wide concern over residual (carry-over) activity of mostly high temperature (HT) and very high temperature (VHT) stable amylases in white, refined sugars from refineries to various food and end-user industries. HT and VHT stable amylases were developed for much larger markets than the sugar industry with harsher processing conditions. There is an urgent need in the sugar industry to be able to remove or inactivate residual, active amylases either in factory or refinery streams or both. A survey of refineries that used amylase and had activated carbon systems for decolorizing, revealed they did not have any customer complaints for residual amylase. The use of high performance activated carbons to remove residual amylase activity was investigated using a Phadebas® method created for the sugar industry to measure residual amylase in syrups. Ability to remove residual amylase protein was dependent on the surface area of the powdered activated carbons as well as mixing (retention) time. The activated carbon also had the additional benefit of removing color and insoluble starch.


1994 ◽  
Author(s):  
Bruce Bradtmiller ◽  
Sherri Upchurch-Blackwell ◽  
Henry W. Case ◽  
Thomas D. Churchhill ◽  
Daniel N. Mountjoy

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