Effect of Cross-Linking Degree on Hydrogels using Surfactant Detergent as Template

2011 ◽  
Vol 284-286 ◽  
pp. 1827-1830 ◽  
Author(s):  
Kun Chen ◽  
Qing Song Zhang ◽  
Li Chen

To avoid the formation of layer-pore structure and flocculation caused by the excessive introduction of nonionic surfactant detergent polyoxyethylene 20 cetyl ether (Brij58) into polyN-isopropylacrylamide/inorganic nanoclay hectorite hydrogels network (PLH hydrogels), inorganic nanoclay hectorite content, severed as physical cross-linker, was increased from 1wt% to 3wt%. The morphology, temperature- responsibility, capacity of water absorption and swelling kinetics of resulting PHL hydrogels were investigated by SEM, DSC and Gravimetric method, respectively. It was found that PLH hydrogels would keep well honeycomb-like pore with increasing hectorite content. Furthermore, PLH hydrogels exhibited good temperature sensitivity regardless of physical cross-linker content.

2009 ◽  
Vol 23 (06n07) ◽  
pp. 1365-1370 ◽  
Author(s):  
QINGSONG ZHANG ◽  
YIPING ZHAO ◽  
LI CHEN

As a kind of novel biopolymer material with good biodegradability and biocompatibility, poly(β-hydroxybutyrate-co-valerate)(PHBV) was introduced into organic/inorganic network structure of nanocomposite hydrogels prepared by in-situ free-radical polymerization based on monomer N-isopropylacrylamide(NIPAM) and physical cross-linker hectorite. As viewed from appearance of the hydrogels, obvious change occurred from transparent to white with the increase of PHBV content, which reflects the structural shift from homogeneity to inhomogeneity. The swelling ratio and swelling kinetics of thermo-sensitive poly( NIPAM / PHBV /Hectorite) hydrogels with different PHBV content was investigated by gravimetric method. It was found that the incorporation of PHBV decreases the swelling ratio of pure poly( NIPAM /Hectorite) hydrogels on account of hydrophobicity of PHBV . Furthermore, in the case of swelling kinetics, the result of linear regression shows that relaxation of polymer chains of the hydrogels controls the swelling process.


2020 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Tantan Shao ◽  
Xiaolong Chen ◽  
Lijun Chen

Purpose Silane cross-linkers have been used to strengthen the mechanical stabilities and friction resistance of plastic products. Therefore, the effect of silane cross-linkers on latex has been studied through preparing modified self-cross-linking long fluorocarbon polyacrylate latex. In this paper, nonionic surfactant alcohol ether glycoside (AEG1000) and anionic polymerizable surfactant 1-allyloxy-3-(4-nonylphenol)-2-propanol polyoxyethylene (10) ether ammonium sulfate (DNS-86) acted as mixed emulsifier and 3-(methacryloyloxy) propyltrimethoxysilane (KH-570) and bis (2-ethylhexyl) maleate (DOM) were used as functional monomers. Design/methodology/approach The modified acrylate polymer latex was synthesized through the semi-continuous seeded emulsion polymerization with methyl methacrylate (MMA), butyl acrylate (BA), dodecafluoroheptyl methacrylate (DFMA) and hydroxypropyl methacrylate (HPMA) as main monomers. Potassium persulfate (KPS) was applied to initiate polymerization reaction, nonionic surfactant AEG1000 and DNS-86 acted as emulsifier, KH-570 and DOM were used as functional monomers, respectively. Findings The optimum conditions of synthesizing the modified latex were the following. The mass ratio of monomers containing MMA, BA, DFMA, HPMA, KH-570 and DOM was 13.58:13.58:0.90:1.20:0.15:0.60, the usage of initiator KPS was 0.5% of the total weight of monomers and the amount of emulsifier was 7% of all monomers with AEG1000:DNS-86 = 1:1. The results indicated that the conversion of monomer was 99% and the coagulation was about 2.0%. Originality/value The resultant latex was modified silane cross-linker KH-570 and DOM, which positively affected the comprehensive properties of latex and its film. Apart from this, the novel mixed emulsifier was used to improve the size and distribution of latex particles and reduce environmental problems caused by the use of emulsifiers.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Joan Carlos Alves Pereira ◽  
Wilton Pereira da Silva ◽  
Renato Costa da Silva ◽  
Cleide Maria Diniz P.S. e Silva ◽  
Josivanda Palmeira Gomes

PurposeTo describe water absorption by the rice grains over time, diffusion and empirical models were used. Also, an optimization software was developed in this study to determine parameters and their uncertainties for the diffusion models (LS Optimizer, for partial differential equations). Parameters (and their uncertainties) for empirical models were determined by LAB Fit Curve Fitting Software.Design/methodology/approachHeat and mass diffusion phenomena are found in various processes of technological interest, including pasteurization, drying and water immersion of agricultural products, among others. The objective of this work was to study the process of water absorption by rice grains with and without husk, using diffusion and empirical models to describe the absorption kinetics. Rice grains were immersed (approximately 10 g for each experiment) in drinking water maintained at constant temperatures of 28, 40 and 50 C. In the experiments, the water contents absorbed by rice grains over time were obtained by the gravimetric method.FindingsAmong empirical models, Peleg was the most satisfactory to describe the kinetics of water absorption by rice without husk, while the Silva et alii model had the best statistical indicators for rice with husk. It was also verified that a diffusion model with boundary condition of the first kind showed the best (or equivalent) results in the description of all processes of kinetics of water absorption by rice grains, with and without husk. For grains without husk, the effective mass diffusivities were (1.186 ± 0.045) × 10−9, (1.312 ± 0.024) × 10−9 and (2.133 ± 0.028) × 10−9 m2 min−1, for the immersion temperatures of 28, 40 and 50C, respectively. For grains with husk, diffusivities were (0.675 ± 0.011) × 10−9 and (1.269 ± 0.017) × 10−9 m2 min−1, for temperatures of 28 and 50 C, respectively.Originality/valueThis work developed a solver for the diffusion equation in cylindrical geometry and presented the LS Optimizer software developed to determine differential equation parameters through experimental data sets.


1974 ◽  
Vol 249 (8) ◽  
pp. 2478-2482
Author(s):  
William D. Fordham ◽  
Charles Gilvarg

Gels ◽  
2021 ◽  
Vol 7 (3) ◽  
pp. 102
Author(s):  
Ferenc Horkay

The objective of this article is to introduce the readers to the field of polyelectrolyte gels. These materials are common in living systems and have great importance in many biomedical and industrial applications. In the first part of this paper, we briefly review some characteristic properties of polymer gels with an emphasis on the unique features of this type of soft material. Unsolved problems and possible future research directions are highlighted. In the second part, we focus on the typical behavior of polyelectrolyte gels. Many biological materials (e.g., tissues) are charged (mainly anionic) polyelectrolyte gels. Examples are shown to illustrate the effect of counter-ions on the osmotic swelling behavior and the kinetics of the swelling of model polyelectrolyte gels. These systems exhibit a volume transition as the concentration of higher valence counter-ions is gradually increased in the equilibrium bath. A hierarchy is established in the interaction strength between the cations and charged polymer molecules according to the chemical group to which the ions belong. The swelling kinetics of sodium polyacrylate hydrogels is investigated in NaCl solutions and in solutions containing both NaCl and CaCl2. In the presence of higher valence counter-ions, the swelling/shrinking behavior of these gels is governed by the diffusion of free ions in the swollen network, the ion exchange process and the coexistence of swollen and collapsed states.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ajibola B. Oyedeji ◽  
Olajide P. Sobukola ◽  
Ezekiel Green ◽  
Oluwafemi A. Adebo

AbstractThe physical properties and water absorption kinetics of three varieties of Mucuna beans (Mucuna pruriens, Mucuna rajada and Mucuna veracruz) were determined in this study. Physical properties including length, width, thickness, geometric mean diameter, sphericity, porosity, bulk density, area, volume and one thousand seed mass were calculated while hydration kinetics was studied by soaking Mucuna beans in water at 30 °C, 40 °C and 50 °C and measuring water uptake at 9 h interval. Peleg’s equation was used to model the hydration characteristics and Arrhenius equation was used to describe the effect of temperature on Peleg’s rate constant k1 and to obtain the activation energies for soaking. Significant variations were observed in almost all the physical properties of the different varieties, however, there were no significant differences (p < 0.05) in their thicknesses and bulk densities. The effectiveness of fit of Peleg’s model (R2) increased with increase in soaking temperature. Peleg’s rate constant k1 decreased with increase in soaking temperature while k2 increased with temperature increase. Activation energies of Mucuna pruriens, Mucuna rajada and Mucuna veracruz were 1613.24 kJ/mol, 747.95 kJ/mol and 2743.64 kJ/mol, respectively. This study provides useful information about the properties of three varieties of Mucuna beans that could be of importance to processors and engineers for process design and optimization.


Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1204
Author(s):  
Mengna Chen ◽  
Xuelong Chen ◽  
Caiyan Zhang ◽  
Baozheng Cui ◽  
Zewen Li ◽  
...  

One type of low-cost and eco-friendly organic‒inorganic superabsorbent composite (SAPC) was synthesized by free radical polymerization of acrylic acid (AA), starch (ST), sodium alginate (SA) and kaolin (KL) in aqueous solution. The structure and morphology of the SAPC were characterized by Fourier transform infrared spectrometer (FT-IR), scanning electron microscope (SEM), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). The influence of different reaction conditions on water absorption of SAPC, i.e., SA and KL contents, AA neutralization degree (ND), potassium persulfate (KPS) and N, N′-methylenebisacrylamide (MBA) loading were systematically studied. Under the optimal synthesis conditions, very high water absorption of 1200 g/g was achieved. The swelling kinetic mechanism of SAPC was studied by pseudo-second order swelling kinetics model and Ritger‒Peppas model. The performances of SAPC under different environments were tested and results revealed that this new SAPC had excellent swelling capacity, high water retention, good salt tolerance in monovalent salt solution (NaCl solution) and good pH tolerance between 4 and 10.


Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 478
Author(s):  
Gjylije Hoti ◽  
Fabrizio Caldera ◽  
Claudio Cecone ◽  
Alberto Rubin Pedrazzo ◽  
Anastasia Anceschi ◽  
...  

The cross-linking density influences the physicochemical properties of cyclodextrin-based nanosponges (CD-NSs). Although the effect of the cross-linker type and content on the NSs performance has been investigated, a detailed study of the cross-linking density has never been performed. In this contribution, nine ester-bridged NSs based on β-cyclodextrin (β-CD) and different quantities of pyromellitic dianhydride (PMDA), used as a cross-linking agent in stoichiometric proportions of 2, 3, 4, 5, 6, 7, 8, 9, and 10 moles of PMDA for each mole of CD, were synthesized and characterized in terms of swelling and rheological properties. The results, from the swelling experiments, exploiting Flory–Rehner theory, and rheology, strongly showed a cross-linker content-dependent behavior. The study of cross-linking density allowed to shed light on the efficiency of the synthesis reaction methods. Overall, our study demonstrates that by varying the amount of cross-linking agent, the cross-linked structure of the NSs matrix can be controlled effectively. As PMDA βCD-NSs have emerged over the years as a highly versatile class of materials with potential applications in various fields, this study represents the first step towards a full understanding of the correlation between their structure and properties, which is a key requirement to effectively tune their synthesis reaction in view of any specific future application or industrial scale-up.


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