Study on In Situ Carbon Dioxide-Generation Flooding

2012 ◽  
Vol 502 ◽  
pp. 179-183
Author(s):  
Hong Jing Zhang ◽  
Shuang Bo Dong ◽  
Zhe Kui Zheng
Keyword(s):  
Carbon Dioxide ◽  
Oil Recovery ◽  
Flow Direction ◽  
Physical Models ◽  
Viscosity Reduction ◽  
Oil Viscosity ◽  
Foamy Oil ◽  
Oil Displacement ◽  
Generation Technology

Aiming at the source and corrosiveness of carbon dioxide, the in-situ carbon dioxide generation technology to enhance oil recovery was proposed。This paper presents the in-situ carbon dioxide generation technology mechanism, the expansion, viscosity reduction; oil-displacement efficiency and foamy oil of this technology were experimentally evaluated by using microscopic models and physical models. The experimental results indicated that the in-situ carbon dioxide generation technology could be used to produce enough carbon dioxide and get good efficiencies of oil expansion, reduction of viscosity and enhancement of oil displacement. Under the conditions of 2010mPa•s in oil viscosity, 60°C and 10MPa, the volume of oil could be expanded by25%, and the viscosity of oil can reduced to 52.7% , and the CO2 can displacement，restraining viscous fingering and changing liquid flow direction and carrying the residual oil.

scholarly journals In-Situ Heavy Oil Aquathermolysis in the Presence of Nanodispersed Catalysts Based on Transition Metals

Processes ◽  
2021 ◽  
Vol 9 (1) ◽  
pp. 127
Author(s):  
Firdavs A. Aliev ◽  
Irek I. Mukhamatdinov ◽  
Sergey A. Sitnov ◽  
Mayya R. Ziganshina ◽  
Yaroslav V. Onishchenko ◽  
...  
Keyword(s):  
Metal Ions ◽  
Oil Recovery ◽  
Heavy Oil ◽  
Synergetic Effect ◽  
Field Tests ◽  
Water Soluble ◽  
Viscosity Reduction ◽  
Oil Viscosity ◽  
Catalytic Aquathermolysis

The aquathermolysis process is widely considered to be one of the most promising approaches of in-situ upgrading of heavy oil. It is well known that introduction of metal ions speeds up the aquathermolysis reactions. There are several types of catalysts such as dispersed (heterogeneous), water-soluble and oil soluble catalysts, among which oil-soluble catalysts are attracting considerable interest in terms of efficiency and industrial scale implementation. However, the rock minerals of reservoir rocks behave like catalysts; their influence is small in contrast to the introduced metal ions. It is believed that catalytic the aquathermolysis process initiates with the destruction of C-S bonds, which are very heat-sensitive and behave like a trigger for the following reactions such as ring opening, hydrogenation, reforming, water–gas shift and desulfurization reactions. Hence, the asphaltenes are hydrocracked and the viscosity of heavy oil is reduced significantly. Application of different hydrogen donors in combination with catalysts (catalytic complexes) provides a synergetic effect on viscosity reduction. The use of catalytic complexes in pilot and field tests showed the heavy oil viscosity reduction, increase in the content of light hydrocarbons and decrease in heavy fractions, as well as sulfur content. Hence, the catalytic aquathermolysis process as a distinct process can be applied as a successful method to enhance oil recovery. The objective of this study is to review all previously published lab scale and pilot experimental data, various reaction schemes and field observations on the in-situ catalytic aquathermolysis process.

Experimental Analysis of the Effects of Varying Temperature and Viscosities on Foamy Oil Production

2021 ◽  
Author(s):  
Jasmine Shivani Medina ◽  
Iomi Dhanielle Medina ◽  
Gao Zhang
Keyword(s):  
Oil Recovery ◽  
Heavy Oil ◽  
Elevated Temperatures ◽  
Oil Production ◽  
Oil Reservoirs ◽  
Oil Viscosity ◽  
Gas Recovery ◽  
Foamy Oil ◽  
Heavy Oil Reservoirs ◽  
Pressure Depletion

Abstract The phenomenon of higher than expected production rates and recovery factors in heavy oil reservoirs captured the term "foamy oil," by researchers. This is mainly due to the bubble filled chocolate mousse appearance found at wellheads where this phenomenon occurs. Foamy oil flow is barely understood up to this day. Understanding why this unusual occurrence exists can aid in the transfer of principles to low recovery heavy oil reservoirs globally. This study focused mainly on how varying the viscosity and temperature via pressure depletion lab tests affected the performance of foamy oil production. Six different lab-scaled experiments were conducted, four with varying temperatures and two with varying viscosities. All experiments were conducted using lab-scaled sand pack pressure depletion tests with the same initial gas oil ratio (GOR). The first series of experiments with varying temperatures showed that the oil recovery was inversely proportional to elevated temperatures, however there was a directly proportional relationship between gas recovery and elevation in temperature. A unique observation was also made, during late-stage production, foamy oil recovery reappeared with temperatures in the 45-55°C range. With respect to the viscosities, a non-linear relationship existed, however there was an optimal region in which the live-oil viscosity and foamy oil production seem to be harmonious.

Self-gasified biosystems for enhanced oil recovery

2021 ◽  
pp. 2150274
Author(s):  
B. A. Suleimanov ◽  
S. J. Rzayeva ◽  
U. T. Akhmedova
Keyword(s):  
Carbon Dioxide ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Experimental Studies ◽  
Microbial Enhanced Oil Recovery ◽  
Heterogeneous Porous Medium ◽  
Oil Displacement ◽  
Subcritical Region ◽  
Reservoir Conditions

Microbial enhanced oil recovery is considered to be one of the most promising methods of stimulating formation, contributing to a higher level of oil production from long-term fields. The injection of bioreagents into a reservoir results in the creation of oil-displacing agents along with a significant amount of gases, mainly carbon dioxide. Earlier, the authors failed to study the preparation of self-gasified biosystems and the implementation of the subcritical region (SR) under reservoir conditions. Gasified systems in the subcritical phase have better oil-displacing properties than nongasified systems. In a heterogeneous porous medium, the filtration profile of gasified liquids in the SR should be more uniform than for a degassed liquid. Based on experimental studies, the superior efficiency of oil displacement by gasified biosystems compared with degassed ones has been demonstrated. The possibility of efficient use of gasified hybrid biopolymer systems has been shown.

New In-situ Carbon Dioxide Generating Enhance Oil Recovery Technology

1999 ◽  
Author(s):  
I. S. Dzhafarov ◽  
S. V. Brezitsky ◽  
A. K. Shakhverdiev ◽  
G. M. Panakhov ◽  
B. A. Suleimanov
Keyword(s):  
Carbon Dioxide ◽  
Oil Recovery ◽  
Enhance Oil Recovery

scholarly journals Low-Abundance Dietzia Inhabiting a Water-Flooding Oil Reservoir and the Application Potential for Oil Recovery

2019 ◽  
Vol 2019 ◽  
pp. 1-11
Author(s):  
Peike Gao ◽  
Hongbo Wang ◽  
Guanxi Li ◽  
Ting Ma
Keyword(s):  
Oil Recovery ◽  
Water Flooding ◽  
Oil Reservoir ◽  
Displacement Efficiency ◽  
Oil Displacement ◽  
Recovery Potential ◽  
Oil Displacement Efficiency ◽  
Application Potential ◽  
Nutrient Injection

With the development of molecular ecology, increasing low-abundance microbial populations were detected in oil reservoirs. However, our knowledge about the oil recovery potential of these populations is lacking. In this study, the oil recovery potential of low-abundance Dietzia that accounts for less than 0.5% in microbial communities of a water-flooding oil reservoir was investigated. On the one hand, Dietzia sp. strain ZQ-4 was isolated from the water-flooding reservoir, and the oil recovery potential was evaluated from the perspective of metabolisms and oil-displacing test. On the other hand, the strain has alkane hydroxylase genes alkB and P450 CYP153 and can degrade hydrocarbons and produce surfactants. The core-flooding test indicated that displacing fluid with 2% ZQ-4 fermentation broth increased 18.82% oil displacement efficiency, and in situ fermentation of ZQ-4 increased 1.97% oil displacement efficiency. Furthermore, the responses of Dietzia in the reservoir accompanied by the nutrient stimulation process was investigated and showed that Dietzia in some oil production wells significantly increased in the initial phase of nutrient injection and sharply decreased along with the continuous nutrient injection. Overall, this study indicates that Dietzia sp. strain has application potential for enhancing oil recovery through an ex situ way, yet the ability of oil recovery in situ based on nutrient injection is limited.

Asphaltene Deposition Induced by Carbon Oxide and its Influence on Displacement Efficiency

2012 ◽  
Vol 594-597 ◽  
pp. 2451-2454
Author(s):  
Feng Lan Zhao ◽  
Ji Rui Hou ◽  
Shi Jun Huang
Keyword(s):  
Crude Oil ◽  
Oil Recovery ◽  
Carbon Oxide ◽  
Viscosity Reduction ◽  
Core Flooding ◽  
Displacement Efficiency ◽  
Oil Composition ◽  
Oil Viscosity ◽  
Asphaltene Deposition ◽  
Total Oil

CO2is inclined to dissolve in crude oil in the reservoir condition and accordingly bring the changes in the crude oil composition, which will induce asphaltene deposition and following formation damage. In this paper, core flooding device is applied to study the effect of asphaltene deposition on flooding efficiency. From the flooding results, dissolution of CO2into oil leads to recovery increase because of crude oil viscosity reduction. But precipitated asphaltene particles may plug the pores and throats, which will make the flooding effects worse. Under the same experimental condition and with equivalent crude oil viscosity, the recovery of oil with higher proportion of precipitated asphaltene was relatively lower during the CO2flooding, so the asphltene precipitation would affect CO2displacement efficiSubscript textency and total oil recovery to some extent. Combination of static diffusion and dynamic oil flooding would provide basic parameters for further study of the CO2flooding mechanism and theoretical evidence for design of CO2flooding programs and forecasting of asphaltene deposition.

Indoor Study of Viscosity Reducer for Thickened Oil of Huancai

2012 ◽  
Vol 268-270 ◽  
pp. 547-550
Author(s):  
Qing Wang Liu ◽  
Xin Wang ◽  
Zhen Zhong Fan ◽  
Jiao Wang ◽  
Rui Gao ◽  
...  
Keyword(s):  
Interfacial Tension ◽  
Oil Recovery ◽  
Heavy Oil ◽  
High Viscosity ◽  
Oil Field ◽  
Viscosity Reduction ◽  
Oil Viscosity ◽  
Low Viscosity ◽  
Viscosity Reducer ◽  
Oil Water

Liaohe oil field block 58 for Huancai, the efficiency of production of thickened oil is low, and the efficiency of displacement is worse, likely to cause other issues. Researching and developing an type of Heavy Oil Viscosity Reducer for exploiting. The high viscosity of W/O emulsion changed into low viscosity O/W emulsion to facilitate recovery, enhanced oil recovery. Through the experiment determine the viscosity properties of Heavy Oil Viscosity Reducer. The oil/water interfacial tension is lower than 0.0031mN•m-1, salt-resisting is good. The efficiency of viscosity reduction is higher than 90%, and also good at 180°C.

High-Pressure Data and Modeling Results for Phase Behavior and Asphaltene Onsets of Gulf of Mexico Oil Mixed With Nitrogen

2014 ◽  
Vol 17 (03) ◽  
pp. 384-395 ◽  
Author(s):  
Odd Steve Hustad ◽  
Na Jia ◽  
Karen Schou Pedersen ◽  
Afzal Memon ◽  
Sukit Leekumjorn
Keyword(s):  
High Pressure ◽  
Gulf Of Mexico ◽  
Phase Behavior ◽  
Oil Recovery ◽  
Positive Impact ◽  
Viscosity Reduction ◽  
Fluid Composition ◽  
Viscosity Data ◽  
Oil Viscosity ◽  
Reservoir Fluid

Summary This paper presents fluid composition, high-pressure pressure/volume/temperature (PVT) measurements, and equation-of-state (EoS) modeling results for a recombined Tahiti oil, Gulf of Mexico (GoM), and for the oil mixed with nitrogen in various concentrations. The data include: Upper and lower asphaltene onset pressures and bubblepoint pressures for the reservoir fluid swelled with nitrogen. At the reservoir conditions of 94 MPa (13,634 psia) and 94°C (201.2°F), asphaltene precipitation is seen after the addition of 27 mol% of nitrogen. Viscosity data for the swelled fluids showing that the addition of nitrogen significantly reduces the oil viscosity. Slimtube runs indicating that the minimum miscibility pressure (MMP) of the oil with nitrogen is significantly higher than estimated from published correlations. The data were modeled with the volume-corrected Soave-Redlich-Kwong (SRK) EoS and the perturbed-chain statistical association fluid theory (PC-SAFT) EoS. Although both equations provide a good match of the PVT properties of the reservoir fluid, PC-SAFT is superior to the SRK EoS for simulating the upper asphaltene onset pressures and the liquid-phase compressibility of the reservoir fluid swelled with nitrogen. Nitrogen-gas flooding is expected to have a positive impact on oil recovery because of its favorable oil-viscosity-reduction and phase behavior effects.

scholarly journals An experimental investigation of asphaltene stability in heavy crude oil during carbon dioxide injection

2019 ◽  
Vol 10 (3) ◽  
pp. 919-931 ◽  
Author(s):  
Sherif Fakher ◽  
Mohamed Ahdaya ◽  
Mukhtar Elturki ◽  
Abdulmohsin Imqam
Keyword(s):  
Carbon Dioxide ◽  
Crude Oil ◽  
Pore Size ◽  
Oil Recovery ◽  
Asphaltene Precipitation ◽  
Carbon Dioxide Injection ◽  
Oil Viscosity ◽  
Membrane Pore ◽  
Pore Sizes ◽  
Filter Membrane

Abstract Carbon dioxide (CO2) injection is one of the most applied enhanced oil recovery methods in the hydrocarbon industry, since it has the potential to increase oil recovery significantly and can help reduce greenhouse gases through carbon storage in hydrocarbon reservoirs. Carbon dioxide injection has a severe drawback, however, since it induces asphaltene precipitation by disrupting the asphaltene stability in crude oil that bears even the slightest asphaltene concentration. This can result in severe operational problems, such as reservoir pore plugging and wellbore plugging. This research investigates some of the main factors that impact asphaltene stability in crude oil during CO2 injection. Initially, asphaltene precipitation, flocculation, and deposition were tested using visual tests without CO2 in order to evaluate the effect of oil viscosity and temperature on asphaltene stability and content in the crude oil. The results obtained from the visualization experiments were correlated to the Yen–Mullins asphaltene model and were used to select the proper chemical to alter the oil’s viscosity without strongly affecting asphaltene stability. After performing the visual asphaltene tests, a specially designed filtration vessel was used to perform the oil filtration experiments using filter membranes with a micron and nanometer pore size. The effect of varying CO2 injection pressure, oil viscosity, filter membrane pore size, and filter membrane thickness on asphaltene stability in crude oil was investigated. The results were then correlated with the Yen–Mullins asphaltene model to characterize the asphaltene size within the oil as well. Results showed that as the oil viscosity increased, the asphaltene concentration in the oil also increased. Also, the asphaltene concentration and filter cake thickness increased with the decrease in filter membrane pore size, since the asphaltene particles either plugged up the smaller pores, or the asphaltene nanoaggregates were larger than the pore sizes, and thus the majority of them could not pass. This research studies asphaltene instability in crude oil during CO2 injection in different pore sizes, and correlates the results to the principle of the Yen–Mullins model for asphaltenes. The results from this research can help emphasize the factors that will impact asphaltene stability during CO2 injection in different pore sizes in order to help reduce asphaltene-related problems that arise during CO2 injection in hydrocarbon reservoirs.

The Effect of Phase Equilibria on the CO2 Displacement Mechanism

1979 ◽  
Vol 19 (04) ◽  
pp. 242-252 ◽  
Author(s):  
R.S. Metcalfe ◽  
Lyman Yarborough
Keyword(s):  
Carbon Dioxide ◽  
Phase Equilibria ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Miscible Displacement ◽  
Co2 Flooding ◽  
Recovery Method ◽  
Two Fluids ◽  
Reservoir Conditions

Abstract Carbon dioxide flooding under miscible conditions is being developed as a major process for enhanced oil recovery. This paper presents results of research studies to increase our understanding of the multiple-contact miscible displacement mechanism for CO2 flooding. Carbon dioxide displacements of three synthetic oils of increasing complexity (increasing number of hydrocarbon components) are described. The paper concentrates on results of laboratory flow studies, but uses results of phase-equilibria and numerical studies to support the conclusions.Results from studies with synthetic oils show that at least two multiple-contact miscible mechanisms, vaporization and condensation, can be identified and that the phase-equilibria data can be used as a basis for describing the mechanism. The phase-equilibria change with varying reservoir conditions, and the flow studies show that the miscible mechanism depends on the phase-equilibria behavior. Qualitative predictions with mathematical models support our conclusions.Phase-equilibria data with naturally occurring oils suggest the two mechanisms (vaporization and condensation) are relevant to CO2 displacements at reservoir conditions and are a basis for specifying the controlling mechanisms. Introduction Miscible-displacement processes, which rely on multiple contacts of injected gas and reservoir oil to develop an in-situ solvent, generally have been recognized by the petroleum industry as an important enhanced oil-recovery method. More recently, CO2 flooding has advanced to the position (in the U.S.) of being the most economically attractive of the multiple-contact miscibility (MCM) processes. Several projects have been or are currently being conducted either to study or use CO2 as an enhanced oil-recovery method. It has been demonstrated convincingly by Holm and others that CO2 can recover oil from laboratory systems and therefore from the swept zone of petroleum reservoirs using miscible displacement. However, several contradictions seem to exist in published results.. These authors attempt to establish the mechanism(s) through which CO2 and oil form a miscible solvent in situ. (The solvent thus produced is capable of performing as though the two fluids were miscible when performing as though the two fluids were miscible when injected.) In addition, little experimental work has been published to provide support for the mechanisms of multiple-contact miscibility, as originally discussed by Hutchinson and Braun.One can reasonably assume that the miscible CO2 process will be related directly to phase equilibria process will be related directly to phase equilibria because it involves intimate contact of gases and liquids. However, no data have been published to indicate that the mechanism for miscibility development may differ for varying phase-equilibria conditions.This paper presents the results of both flow and phase-equilibria studies performed to determine the phase-equilibria studies performed to determine the mechanism(s) of CO2 multiple-contact miscibility. These flow studies used CO2 to displace three multicomponent hydrocarbon mixtures under first-contact miscible, multiple-contact miscible, and immiscible conditions. Results are presented to support the vaporization mechanism as described by Hutchinson and Braun, and also to show that more than one mechanism is possible with CO2 displacements. The reason for the latter is found in the results of phase-equilibria studies. SPEJ P. 242

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