Enhanced Chromium Recovery from Tannery Waste by Acid-Alkali Reaction in China

2014 ◽  
Vol 878 ◽  
pp. 185-193 ◽  
Author(s):  
Huai Li ◽  
Jian Zheng Li ◽  
Zi Fang Chi
Keyword(s):  
Sodium Hydroxide ◽  
Magnesium Oxide ◽  
High Efficiency ◽  
Trivalent Chromium ◽  
Cost Performance ◽  
Tannery Waste ◽  
Mixed Alkali ◽  
Mineral Acids ◽  
The Cost ◽  
Chromium Recovery

Leather processing is an important industry in China, and the discharge of chromium waste has been severely circumscribed. Though traditional processes for treating chromium waste have been widely used in tannery plants, technology adopting high efficiency and economic simultaneously is deficient. In order to develop an economic treatment for tannery waste, a mixed alkali of sodium hydroxide and magnesium oxide and diluted mineral acids were tested to improve the sedimentation effect of trivalent chromium from tannery wastewater. The results showed that the most feasible alkali was a mixture of sodium hydroxide and magnesium oxide with a mass ratio of 5:1 to balance the cost performance. The high chromium removal as 99.1% was obtained with a mixed alkali dosage only 0.2 g/L at pH 9.5, with a very low Cr-sludge yield. The effects of various factors on the extraction of trivalent chromium from Cr-sludge using mineral acids were investigated further more, and the results indicated that the feasible condition for chromium recovery from wet chromium sludge was as follows: 4% sulfuric acid as the leaching acid, chromium sludge (dry weight) load 23.55 g/L, extraction time 60 min, and reaction temperature 30°C. A chromium recovery of 20.86 mg/g was obtained under the feasible condition with a recovery rate of 91.8%. The method developed in the present study provided an effective solution to balance the cost performance for tannery waste treatment.

scholarly journals Chromium recovery from tannery sludge and its ash, based on hydrometallurgical methods

2019 ◽  
Vol 38 (1) ◽  
pp. 19-26 ◽  
Author(s):  
Erasmia Pantazopoulou ◽  
Anastasios Zouboulis
Keyword(s):  
Sodium Hydroxide ◽  
Chromium Content ◽  
Ph Value ◽  
Trivalent Chromium ◽  
Tannery Sludge ◽  
Sludge Treatment ◽  
Solid Ratio ◽  
Temperature Liquid ◽  
Dried Sludge ◽  
Chromium Recovery

The recovery of chromium from tannery sludge and from its respective ash constitutes an alternative process of tannery sludge treatment in order to ensure safe disposal. Chromium recovery was investigated based on simple hydrometallurgical processes, that is, leaching using aqueous solutions of acids. Leaching was applied either directly to air-dried sludge or to its respective ash, which results from thermal treatment of the air-dried sludge under anoxic conditions. The major parameters that influence the effectiveness of the leaching process were investigated to optimize chromium leaching. Specifically, contact time, pH value, temperature, liquid per solid ratio, and leaching agent (H2SO4 or HCl) were tested. Leached chromium, obtained directly from the initial tannery waste after 100 min leaching with H2SO4 at pH 1 and at 60°C, was used for the trivalent chromium precipitation by adding magnesia, calcium hydroxide, and sodium hydroxide as precipitation agents. The results revealed satisfactory leaching of trivalent chromium directly from the air-dried sludge. The chromium content in the solid precipitated using sodium hydroxide was about 59 wt %. In contrast, chromium was difficult to leach from the respective ash.

scholarly journals Optical spin-symmetry breaking for high-efficiency directional helicity-multiplexed metaholograms

2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Muhammad Ashar Naveed ◽  
Muhammad Afnan Ansari ◽  
Inki Kim ◽  
Trevon Badloe ◽  
Joohoon Kim ◽  
...  
Keyword(s):  
High Efficiency ◽  
Spin Symmetry ◽  
Cost Effective ◽  
Dielectric Materials ◽  
Additional Degree ◽  
Cost Effective Alternative ◽  
Spin Orbit Interactions ◽  
Smart Mobile ◽  
The Cost ◽  
Hydrogenated Amorphous

AbstractHelicity-multiplexed metasurfaces based on symmetric spin–orbit interactions (SOIs) have practical limits because they cannot provide central-symmetric holographic imaging. Asymmetric SOIs can effectively address such limitations, with several exciting applications in various fields ranging from asymmetric data inscription in communications to dual side displays in smart mobile devices. Low-loss dielectric materials provide an excellent platform for realizing such exotic phenomena efficiently. In this paper, we demonstrate an asymmetric SOI-dependent transmission-type metasurface in the visible domain using hydrogenated amorphous silicon (a-Si:H) nanoresonators. The proposed design approach is equipped with an additional degree of freedom in designing bi-directional helicity-multiplexed metasurfaces by breaking the conventional limit imposed by the symmetric SOI in half employment of metasurfaces for one circular handedness. Two on-axis, distinct wavefronts are produced with high transmission efficiencies, demonstrating the concept of asymmetric wavefront generation in two antiparallel directions. Additionally, the CMOS compatibility of a-Si:H makes it a cost-effective alternative to gallium nitride (GaN) and titanium dioxide (TiO2) for visible light. The cost-effective fabrication and simplicity of the proposed design technique provide an excellent candidate for high-efficiency, multifunctional, and chip-integrated demonstration of various phenomena.

scholarly journals Roughing Milling with Ceramic Tools in Comparison with Sintered Carbide on Nickel-Based Alloys

Coatings ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 734
Author(s):  
Pablo Fernández-Lucio ◽  
Octavio Pereira Neto ◽  
Gaizka Gómez-Escudero ◽  
Francisco Javier Amigo Fuertes ◽  
Asier Fernández Valdivielso ◽  
...  
Keyword(s):  
Cutting Speed ◽  
High Volume ◽  
Cemented Carbide ◽  
Performance Ratio ◽  
Cost Performance ◽  
Ceramic Tools ◽  
The Cost ◽  
Engine Components ◽  
Coated Carbide ◽  
Milling Tools

Productivity in the manufacture of aircrafts components, especially engine components, must increase along with more sustainable conditions. Regarding machining, a solution is proposed to increase the cutting speed, but engines are made with very difficult-to-cut alloys. In this work, a comparison between two cutting tool materials, namely (a) cemented carbide and (b) SiAlON ceramics, for milling rough operations in Inconel® 718 in aged condition was carried out. Furthermore, both the influence of coatings in cemented carbide milling tools and the cutting speed in the ceramic tools were analysed. All tools were tested until the end of their useful life. The cost performance ratio was used to compare the productivity of the tested tools. Despite the results showing higher durability of the coated carbide tool, the ceramic tools presented a better behavior in terms of productivity at higher speed. Therefore, ceramic tools should be used for higher productivity demands, while coated carbide tools for low speed-high volume material removal.

A Determinant Elimination Method for Bottleneck Assignment and Generalized Assignment Problems

2012 ◽  
Vol 239-240 ◽  
pp. 1522-1527
Author(s):  
Wen Bo Wu ◽  
Yu Fu Jia ◽  
Hong Xing Sun
Keyword(s):  
Computational Complexity ◽  
Optimization Algorithm ◽  
Assignment Problem ◽  
Numerical Experiments ◽  
High Efficiency ◽  
Synthesis Method ◽  
Assignment Problems ◽  
Generalized Assignment ◽  
The Cost ◽  
Time And Space Complexity

The bottleneck assignment (BA) and the generalized assignment (GA) problems and their exact solutions are explored in this paper. Firstly, a determinant elimination (DE) method is proposed based on the discussion of the time and space complexity of the enumeration method for both BA and GA problems. The optimization algorithm to the pre-assignment problem is then discussed and the adjusting and transformation to the cost matrix is adopted to reduce the computational complexity of the DE method. Finally, a synthesis method for both BA and GA problems is presented. The numerical experiments are carried out and the results indicate that the proposed method is feasible and of high efficiency.

Contour Extraction of Cerebrovascular Based on Maximum Optimization Cost

2011 ◽  
Vol 204-210 ◽  
pp. 1415-1418
Author(s):  
De Jiang Zhang ◽  
Na Na Dong ◽  
Xiao Mei Lin
Keyword(s):  
Dynamic Programming ◽  
Blood Vessel ◽  
High Efficiency ◽  
High Accuracy ◽  
Differential Method ◽  
Cost Curve ◽  
Contour Extraction ◽  
Target Image ◽  
The Cost ◽  
Conventional Algorithm

By studying the conventional algorithm of contour extraction, a new method of contour extraction in blood vessel of brain is proposed based on the MOC maximum optimization cost. First of all, the theory computes the gray differential of the image by conventional differential method to build the cost space. Then, by using dynamic programming theory, the maximum optimization cost curve in the space is extracted to serve as the specific cerebrovascular profile. The experiments show that this method ensures high efficiency in extracting cerebrovascular contour and a high accuracy in positioning cerebrovascular contour, and it diminishes the target image ambiguity caused by noise to improve the anti-interference ability of Contour extraction.

High-Efficiency Cut Blasting with Shell Radial Shaped Charge in Laboratory-Scale Blasting

2015 ◽  
Vol 1094 ◽  
pp. 445-450 ◽  
Author(s):  
Wei Chen ◽  
Hong Hao Ma ◽  
Zhao Wu Shen ◽  
De Bao Wang
Keyword(s):  
High Efficiency ◽  
Circular Tube ◽  
Rock Breaking ◽  
Shaped Charge ◽  
Axial Line ◽  
Rock Excavation ◽  
Crack Network ◽  
Utilization Ratio ◽  
The Cost ◽  
The Ideal

Due to the inefficiency problem of the cut blasting in rock excavation and rock breaking, a shell radial shaped charge device was proposed based of the ideal of ‘cutting to slotting’ and it was validated through experiments. For this device, the shell materials are used to be shaped materials and multiple shaped ring is designed on the circular tube. It can not only reduce charge quantity but also raise the utilization ratio of explosive energy. After explosion, multiple radial shaped charge jets can be formed along the axial line in sequence and then the surrounding rock mass would be cracked. The crack network will be formed along with the further extension of the fraction under the action of quasi static loading of detonation gas. The shell radial shaped charge device was tested through the cut blasting model experiment. Experimental results show that the utilization ratio of blasting hole nearly approaches 98% with this device. The blasting efficiency and cyclical footage can be improved effectively and the cost of drifting can also be reduced.

A weak derivative approach to optimization of threshold parameters in a multicomponent maintenance system

2001 ◽  
Vol 38 (02) ◽  
pp. 386-406 ◽  
Author(s):  
Bernd Heidergott
Keyword(s):  
Optimization Problems ◽  
Estimation Algorithm ◽  
Replacement Policy ◽  
Cost Performance ◽  
Weak Derivative ◽  
Preventive Replacement ◽  
Maintenance System ◽  
Threshold Optimization ◽  
Age Replacement ◽  
The Cost

We consider a multicomponent maintenance system controlled by an age replacement policy: when one of the components fails, it is immediately replaced; all components older than a threshold age θ are preventively replaced. Costs are associated with each maintenance action, such as replacement after failure or preventive replacement. We derive a weak derivative estimator for the derivative of the cost performance with respect to θ. The technique is quite general and can be applied to many other threshold optimization problems in maintenance. The estimator is easy to implement and considerably increases the efficiency of a Robbins-Monro type of stochastic approximation algorithm. The paper is self-contained in the sense that it includes a proof of the correctness of the weak derivative estimation algorithm.

scholarly journals The increased use value of bamboo leaves as silica source for t-type zeolite synthesis

2018 ◽  
Vol 197 ◽  
pp. 05003 ◽  
Author(s):  
Soni Setiadji ◽  
Citra Deliana Dewi Sundari ◽  
Endang Lala ◽  
Denia Febby Nurbaeti ◽  
Ira Novianti ◽  
...  
Keyword(s):  
Sem Analysis ◽  
High Price ◽  
Heating Process ◽  
Zeolite Synthesis ◽  
X Ray Diffraction ◽  
Cost Performance ◽  
Silica Source ◽  
Bamboo Leaves ◽  
Type Zeolite ◽  
The Cost

T-type zeolite can be used as catalyst, adsorbent, and membranes for gas separation. The synthesis of T-type zeolite needs to be optimized in both of the method and source of precursor, because of its relatively high price. In this research, the synthesis is done using silica extracted from bamboo leaves instead of commercial silica. This increases the value of the bamboo leaves and the cost-performance of zeolite synthesis. The silica was extracted from bamboo leaves ash using alkaline solvent. The extracted silica has 81.76% of purity and an amorphous phase. The T-type zeolite was synthesized using the molar composition of 0.15 Na2O : 0.025 Al : 0.15 K2O : 1 SiO2 : 15 H2O : 0.06 TMAOH, under hydrothermal method and heating process for 4 days, 60°C for 2 days and 120°C for the next 2 days. The characterization method using X-Ray Diffraction and Infra-Red Spectroscopy were performed to confirm the formation of T-type zeolite. The results of Scanning Electron Microscope (SEM) analysis show that the formed T-type zeolite has erionite cylindrical crystal shape.

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